XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.
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Transcript of XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.
![Page 1: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/1.jpg)
XAFS Data Booklet Proposal
Raúl Barrea and Tsu-Chien Weng
BioCAT, IIT
03-22-2005
![Page 2: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/2.jpg)
![Page 3: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/3.jpg)
Why Another Booklet?
•Official guideline from IXS to standardize sample preparation, XAFS measurement, data analysis, and report format
•Educational purpose
•Advertisement for IXS and APS
![Page 4: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/4.jpg)
Things to Discuss
•Booklet contents
•Contributors
•Funding
•Distribution
•Publishing timeline
![Page 5: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/5.jpg)
Booklet Outline1. X-ray Properties of the Elements
2. XAFS Basics
3. Guideline for Sample Preparation
4. XAFS Experiments
5. Data Analysis
6. Report Format
7. XAFS Beamlines
![Page 6: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/6.jpg)
1. X-ray Properties of the Elements
•X-ray absorption edge and emission energies
•Mass absorption coefficients
![Page 7: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/7.jpg)
2. XAFS Basics
•History
•Theory
•EXAFS and XANES
•Capabilities and limitations
•Applications
![Page 8: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/8.jpg)
3. Guideline for Sample
Preparation•Solid sample
– thickness (self-absorption)
– packing (pin hole effect)
•Solution sample
– contamination from free metal ions
– background from buffers (Cl, P, etc.)
•Drawing of sample cells
![Page 9: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/9.jpg)
4. XAFS Experiments•X-ray optics
– high-order harmonics (detuned, rejection)
– energy calibration•Sample cell– cryostat, high-pressure, solution, etc.– radiation damage
•Detectors– absorption (ion-chamber, PSD)– fluorescence excitation (SSD, bent Laue,
MAAD, crystal mirror)– energy resolution, ICR
![Page 10: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/10.jpg)
5. Data Analysis
•Energy calibration
•Background subtraction and normalization
•EXAFS data interpretation
– choice of model
– degree of freedom
![Page 11: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/11.jpg)
6. Report Format•Experiment details– beamline(s), x-ray optics– means of energy calibration– sample preparation (thickness,
buffers)– fluorescence window size– scan time, count-rates
•Data analysis– threshold energy– degree of freedom vs. num of
variables– (reduced) goodness of fit
![Page 12: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/12.jpg)
7. XAFS Beamlines
•Characteristics of each XAFS beamline
– source (BM, ID)
– energy range
– spot size (unfocused, focused)
– sample cell (cryostat, high-pressure, etc.)
– detector(s)
– specialties (time-resolved, RIXS, etc.)
![Page 13: XAFS Data Booklet Proposal Raúl Barrea and Tsu-Chien Weng BioCAT, IIT 03-22-2005.](https://reader036.fdocuments.net/reader036/viewer/2022083009/56649f305503460f94c4bab0/html5/thumbnails/13.jpg)
Things to Discuss
•Booklet contents
•Contributors
•Funding (APS? DOE? Private companies?)
•Distribution (hardcopy, electronic)
•Publishing timeline (9-12 months?)