What are dislocations? Recap of 3.14/3.40 Lecture on 9/27/2012 Sangtae Kim Oct/2/2012.
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Transcript of What are dislocations? Recap of 3.14/3.40 Lecture on 9/27/2012 Sangtae Kim Oct/2/2012.
What are dislocations? Recap of 3.14/3.40 Lecture on 9/27/2012
Sangtae KimOct/2/2012
• What are dislocations?• Why are they important?• How do they move in the crystal?• A research topic related to dislocations
Contents
What are dislocations?
• 1D Line defects, in which crystal registry is lost• A machine to cut bonds on one plane, and then re-
stitch them together, one by one– Dislocation Glide
• Carry local deformation and stress• Edge, screw, mixed dislocations
Edge dislocation
• Simple cubic illustration
• Illustration with bonds• Local environment is
different only at the core.• Localized shear
• b perpendicular to line direction
Edge dislocation
• Simple cubic illustration
• Illustration with bonds• Local environment is
different only at the core.• Localized shear
• b perpendicular to line direction
Screw dislocation
view from top
Screw dislocation
view from top
• b parallel to line direction
Screw dislocation
Screw dislocation
Fantastic!
In reality
• Mixed dislocations – b at some angle to the line direction.-- e.g. dislocation loops from the Frank Reed source
Why are they important?
• It controls the yield strength and subsequent plastic deformation at ordinary temperature.
• Electric defects in semiconductors and optical materials – they are undesirable there.
• We can understand 2D defects as a set of 1D defects
How do they move?
• Glide - slip plans• Climb - 1D defects: vacancy, interstitials• In reality, there are bits of both +
entanglement
Glide Motion
Glide Motion
Slip
Climb
• Collective vacancy motion/interstitials required.
• So to harden a material, we want more climb, instead of glide to harden a material.
Hardening Mechanism
A Research Question
• LiCoO2: typical battery cathode material• Li removal with no structural change
Transition Metal
Alkali Metal (Na or Li)
A Research Question
• Iso-structural NaCoO2 shows change.
O3 – P3 transformation
A ---------------- A
B ---------------- B
C ---------------- B
A ---------------- C
B ---------------- CC ---------------- A
A ---------------- A
B ---------------- B
O3 Layered P3 Layered
Na
TM
O3 – P3 transformation
A ---------------- A
B ---------------- B
C ---------------- B
A ---------------- C
B ---------------- CC ---------------- A
A ---------------- A
B ---------------- B
O3 Layered P3 Layered
Na
TM
Sangtae Kim, [email protected]
Edge dislocation
• Simple cubic illustration
Edge dislocation
• Simple cubic illustration