We use a two-color SANDVIK PRE-COATED STRIP FOR · PDF fileSANDVIKS PRE-COATED SOLUTION 3...
Transcript of We use a two-color SANDVIK PRE-COATED STRIP FOR · PDF fileSANDVIKS PRE-COATED SOLUTION 3...
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We use a two-color
headline system to
highlight our rational and
emotional side alike. The
first line appears in blue
(the rational side), the
second line in orange (the
emotional side) and the
duality principle is reflected
in the wording of the
headline.
This system refers to the
first page title only, all
other headlines are blue.
Learn more about our
verbal identity in the
Sandvik Brand Identity
Directives, which you can
download at the Intranet >
home.sandvik.com/brand
SANDVIK PRE-COATED STRIP FOR METALLIC
BPP IN PEMFC APPLICATIONS
ANNA JANSSON SENIOR RESEARCHER, COATED STRIP PRODUCTS
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AGENDA
• Sandvik pre-coated solution
• Sandvik Sanergy LT for PEM fuel cells
• Forming of plates
• Short stack test
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SANDVIKS PRE-COATED SOLUTION
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NANOTECHNOLOGY READY FOR MASSPRODUCTION
1. Cleaning/inspection
2. Coating
Coating of layers by Sandvik's continuous evaporation process.
3. Inspection
Automatic X-ray inspection devices measure the thickness and
quality of the coating.
4. Testing, slitting and packaging
Stainless Steel
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High capacity PVD coating line
Coil • Width: < 800 mm
• Thickness: 0,07-0,8 mm
Coating • Homogeneous or heterogeneous
• Multiple layers in one coating run
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COIL COATING CONCEPT
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SHORTENING THE VALUE CHAIN
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SANDVIK SANERGY LT
FOR PEMFC
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• Requirements of a BPP
− Good corrosion resistance
− Low contact resistance (ICR)
− Prevent formation of oxide scale on SS
− Good formability / coating adhesion
• Sandvik Sanergy LT
− Graphite-like carbon (GLC) coating
− Metallic interlayer
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MEASURING INTERFACIAL CONTACT RESISTANCE (ICR)
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Method according to D.P. Davies et al
and modified by H.Wang et al.
F(N)
U
Au-coated Cu cylinders
GDL
Sample I GDL
F(N)
I = 1 A/cm2
R= 20 mm
Sample size variable
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IN-HOUSE ICR MEASUREMENT
• Importance of ICR measurement
− Key parameter for coating development
− Process optimisation
− Product quality control
• Setup
− Dedicated for ICR
− Stable
− Method error ± 0,2 mΩ*cm2
− CE-certified
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FORMING OF COIL-COATED MATERIAL
• Forming operation produces cracks in the coating
• Impact on ICR?
1. Biaxial strain, 12%
2. ICR
3. Potentiostatic test
• 100h @ 0,7V (vs Ag/AgCl)
• pH3 , H2SO4
• 80ºC, N2
4. ICR
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FORMING OF COIL-COATED MATERIAL
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∆ICR = -1 ± 0,2 mΩ*cm2
Unstrained 12% biaxial strain
Sandvik C
As produced 3,1 3,5
Corr. test (100h) 4,9 3,9
0
1
2
3
4
5
6
ICR
(m
Ω*c
m2)
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FORMING OF COIL-COATED MATERIAL
• Coating adhesion is key
• No negative impact on ICR as
a result of forming operation
• Exposure of underlying
substrate
− Choice of substrate important
− Publishable data of Me ion
release not available
− Long-standing relationships
with OEMs indication of stable
performance
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∆ICR =
-1 ± 0,2 mΩ*cm2
Unstrained 12% biaxial strain
Sandvik C
As produced 3,1 3,5
Corr. test (100h) 4,9 3,9
0
1
2
3
4
5
6
ICR
(m
Ω*c
m2)
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DEGRADATION TESTING OF ELRING KLINGER - PEMFC
NM 5 STACK
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RESULTS LOAD CYCLE TESTING (NUMERICAL STATISTICAL ANALYSIS)
• 10 cell short stack
• Load cycle testing
• Low pressure operation
• Degradation rate : ~ 4-9
μV/h at different load
levels (220/120/40 A)
• Test ongoing
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ELRING KLINGER STACK TEST - COMMENTS
• A load-cycle for fork-lifts is employed
• Plates experience up to 40%
elongation during the forming
operation
• Polarization curve showed similar
behavior to Au-coated reference
plates – Good performance!
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THANK YOU!
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Anna Jansson
Coated Strip Products, R&D
Sandvik Materials Technology
Phone +4626269508