Viomax CAS51D Technical Information€¦ · 1 Measuring receiver with filter 2 Cuvette gap 3 Strobe...
Transcript of Viomax CAS51D Technical Information€¦ · 1 Measuring receiver with filter 2 Cuvette gap 3 Strobe...
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Application
SAC measurement• Organic load in WWTP inlet• Organic load WWTP outlet• Discharger monitoring• Organic load in drinking waterNitrate measurement• Nitrate measurement in natural bodies of water• Monitoring nitrate content in WWTP outlet• Monitoring nitrate content in aeration basins• Monitoring and optimizing denitrification phases
Your benefits
• Affordable, environmentally friendly product– No complicated sampling and treatment– Chemical-free measurement
– Low-maintenance• Data conditioning in the sensor
– Minimum sensitivity to interference during signaltransmission
– Short response time• Early, continuous detection of load peaks without delay• Ready for use thanks to factory calibration• Standardized communication (Memosens technology)
enables "plug and play"• Very long maintenance intervals thanks to compressed air
cleaning• Customer calibrations with 1 - 5 points (max.) - in the lab or
at place of installation
Products Solutions Services
Technical InformationViomax CAS51DPhotometric sensor for SAC or nitrate measurement
TI00459C/07/EN/14.1771368387
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Function and system design
Measuring principle The light from a pulsed, high-stability strobe lamp (item 3) passes through the measurementsection 1) (item 2). A beam splitter (item 6) directs the light beam to the two receivers (items 1 and5). A filter upstream from the receivers only lets through light in the measuring wavelength orreference wavelength.
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1 Measuring principle of nitrate sensor
1 Measuring receiver with filter2 Cuvette gap3 Strobe lamp4 Lens5 Reference receiver with filter6 Beam splitter
Within the measurement section, the medium in the cuvette (water, dissolved substances andparticles) absorbs light across the entire spectrum. In the measuring wavelength range, themeasured component 2) takes an additional part of its energy from the light.
The ratio of the light signal of the measuring wavelength to the light signal of the referencewavelength is used to calculate the measured value.• If only water and turbidity are present, both signals are attenuated to the same degree and the
ratio remains constant.• If the medium contains the measured component, the signal of the measuring wavelength is
attenuated more and the ratio changes.This change in the ratio can be converted to determine the nitrate concentration or the SAC value.This dependency is non-linear.
Conclusion:• Long measurement sections are required for low concentrations of the measured component.
For clear water measurements, this is achieved with the 8 mm cuvette for nitrate measurementand the 40 mm cuvette for SAC measurement.
• For high turbidity values, longer measurement sections result in the total absorption of light - themeasured values are no longer valid.For media with high turbidity values (activated sludge applications), the nitrate sensor with the 2mm cuvette returns good, reliable measured values.The SAC sensor with the 2 mm cuvette is ideal for measuring the organic load in the inlet ofmunicipal wastewater treatment plants.
Nitrate measurement The sensor is designed for measuring nitrate. As nitrite is also measured, it could also be regarded asan NOx sensor.
Nitrate ions absorb UV light in the range of approx. 190 to 230 nm. Nitrite ions have a similarabsorption rate in the same range.
1) Measurement section = open path through cuvette2) Nitrate or substances that contribute to the spectral absorption coefficient (SAC)
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The sensor measures the light intensity of the 214 nm wavelength (measuring channel). At thiswavelength, nitrate and nitrite ions absorb light in proportion to their concentration, while the lightintensity in the reference channel remains virtually unchanged at 254 nm.
Interference factors, such as turbidity, fouling or organic hydrocarbons, are factored outmathematically.
The signal ratio between the reference wavelength and measurement wavelength constitutes themeasurement result. This ratio is converted to the concentration of nitrate using the calibrationcurve programmed into the sensor.
Cross-interference whenmeasuring nitrate
The following have a direct impact on the measuring range:• Total solids (TS) and turbidity• Sludge properties• NitriteTrends:• A higher proportion of TS or greater turbidity reduces the upper end of the measuring range,
resulting in a smaller measuring range.• High COD 3) levels reduce the upper end of the measuring range, resulting in a smaller measuring
range.• Nitrite is measured as nitrate, thus resulting in a higher measured value.The following can be deduced from the interdependencies cited above:• Sludge floc causes scattering in the medium, resulting in the attenuation of both the measuring
and reference signal to varying degrees. This in turn can bring about a change in the nitrate valuedue to turbidity.
• High concentrations of oxidizable substances 4) in the medium may result in an increase in themeasured value.
• Nitrite absorbs light in a similar wavelength range to nitrate and is measured along with nitrate.The dependency is constant: 1.0 mg/l nitrite is displayed as 0.8 mg/l nitrate.
• An adjustment to the customer process is always worthwhile.
SAC measurement Many organic substances absorb light in the range of 254 nm. In the SAC sensor, absorption on themeasuring wavelength (254 nm) is compared with the largely unaffected reference measurement at550 nm.
KHP (potassium hydrogen phthalate C8H5KO4) is the established organic reference in SACmeasurement operations. That is why the sensor is calibrated in the factory using KHP.
The SAC value can be regarded as a trend indicator of the organic load in a medium. For thispurpose, it is converted to COD, TOC, BOD and DOC 5) using predefined, adjustable factors:c (TOC) = 0.4705 * c (KHP)c (COD) = 1.176 * c (KHP)c (BOD) = 1.176 * c (KHP)c (DOC) = 0.4705 * c (KHP)The ratio to SAC (based on KHP) is calculated as follows:1/m = 1.487 mg/l COD = 1.487 mg/l BOD = 0.595 mg/l TOC = 0.595 mg/l DOCMany components that absorb light at 254 nm deviate significantly from KHP in terms of theirabsorption behavior. For this reason, an adjustment to the customer process is worthwhile.
Cross-interference whenmeasuring SAC
The following have a direct impact on the measuring range:• COD• ColorTrends:• Oxidizable substances, absorbing at 550 nm, distort the measurement result. In instances of this
nature, a comparison or calibration is necessary.• Coloration that absorbs in the green spectral range increases the measured value.• Oxidizable substances with different spectral properties to KHP (potassium hydrogen phthalate)
distort the measurement result. In instances of this nature, a comparison or adjustment isnecessary.
3) COD = Chemical Oxygen Demand4) Specified as COD. Corresponds to the quantity of oxygen that would be required to oxidize the substances if oxygen were the oxidizing agent.5) Chemical Oxygen Demand (COD), Total Organic Carbon (TOC), Biochemical Oxygen Demand (BOD), Dissolved Organic Carbon (DOC)
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Measuring system A complete measuring system comprises:• Viomax CAS51D• Liquiline CM44x multi-channel transmitter• Universal installation or flow assembly
– Flexdip CYA112 and Flexdip CYH112 holder or– Flowfit CYA251 or 71110000 (for clear water)
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2 Example of a measuring system with flow assembly for clear water
1 Transmitter CM44x2 Sensor Viomax CAS51D3 Flow assembly4 Holders (included in the flow assembly delivery)
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Input
Measured values NitrateNO3-N [mg/l], NO3 [mg/l]SACSAC [1/m], COD [mg/l], TOC [mg/l], BOD [mg/l], DOC [mg/l], transmission [%]
Measuring ranges CAS51D-**A2 (2 mm gap width) 0.1 to 50 mg/l NO3-N0.4 to 200 mg/l NO3Clear water and sludge activation
CAS51D-**A1 (8 mm gap width) 0.01 to 20 mg/l NO3-N0.04 to 80 mg/l NO3Clear water (for a COD (KHP) concentration of up to 125 mg/land up to 50 FNU turbidity based on the mineral component ofkaolin)
CAS51D-**C1 (40 mm gap width) SAC 0.1 to 50 1/mCOD/BOD 0.15 to 75 mg/l 1)
TOC/DOC 0.06 to 30 mg/l 1)
Clear water, small measuring range, drinking water
CAS51D-**C2 (8 mm gap width) SAC 0.5 to 250 1/mCOD/BOD 0.75 to 370 mg/l 1)
TOC/DOC 0.3 to 150 mg/l 1)
Clear water, average measuring range, drinking water, WWTPoutlet, monitoring of water bodies
CAS51D-**C3 (2 mm gap width) SAC 1.5 to 700 1/mCOD/BOD 2.5 to 1000 mg/l 1)
TOC/DOC 0.9 to 410 mg/l 1)
Organic load in inlet, discharger monitoring, industrial processes
1) equivalent KHP
The possible measuring range depends to a large extent on the medium characteristics.
Empirical values for typical COD measuring ranges
Inlet of municipal WWTP 0 to 4000 mg/l COD
Inlet from dairy-processing industry 0 to 10 000 mg/l COD
Inlet from chemical industry 0 to 10 000 mg/l COD
Power supplyYou have the following connection options:• via M12 connector (version: fixed cable, M12 connector)• via sensor cable to the plug-in terminals of a sensor input on the transmitter (version: fixed cable,
end sleeves)
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3 Sensor connection to sensor input (left) or via M12 connector (right)
The maximum cable length is 100 m (328 ft).
Performance characteristics
Reference operatingconditions
20°C (68 °F), 1013 hPa (15 psi)
Measured error 6) Nitrate For 0.1 to 50 mg/l NO3-N (2 mm cuvette gap):2 % of full-scale value above 10 mg/l±0.2 mg/l below 10 mg/l
For 0.01 to 20 mg/l NO3-N (8 mm cuvette gap):2 % of full-scale value above 2 mg/l±0.04 mg/l below 2 mg/l
SAC 2 % of full-scale value when measuring with potassiumhydrogen phthalate (KHP) as the standard
Repeatability 6) NitrateAt least ±0.2 mg/l NO3-NSAC0.5 % of end of measuring range (for homogeneous media)
Detection limits Nitrate• CAS51D-AAA1
0.003 mg/l NO3-N• CAS51D-AAA2
0.013 mg/l NO3-N
6) The measured error contains all the uncertainties of the sensor and transmitter (electrode system). It does not contain all the uncertaintiescaused by the reference material and adjustments that may have been performed.
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SACIn relation to the standard potassium hydrogen phthalate (KHP):• CAS51D-AAC1
0.045 mg/l COD• CAS51D-AAC2
0.3 mg/l COD• CAS51D-AAC3
1.5 mg/l COD
Limits of determination Nitrate• CAS51D-AAA1
0.01 mg/l NO3-N• CAS51D-AAA2
0.043 mg/l NO3-NSACIn relation to the standard potassium hydrogen phthalate (KHP):• CAS51D-AAC1
0.15 mg/l COD• CAS51D-AAC2
1.0 mg/l COD• CAS51D-AAC3
5.0 mg/l COD
Long-term drift NitrateBetter than 0.1 mg/l NO3-N over one weekSACBetter than 0.2 % of end of measuring range over one week
Installation
Installation conditions Mounting location
‣ Choose a mounting location that can be easily accessed at a later stage.‣ Ensure that upright posts and fittings are fully secured and vibration-free.‣ Select an installation location that produces a typical nitrate concentration / a typical SAC value
for the application in question.‣ Do not install the sensor above aeration discs. Oxygen bubbles may accumulate at the cuvette gap
and distort the measured value.
Installation position
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4 Sensor orientation, arrow =direction of flow
‣ Align the sensor so that the cuvette gap is rinsed by means ofthe flow.
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Flexdip CYA112 wastewater assembly and Flexdip CYH112 bracket
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5 Horizontal, fixed installation
The installation angle is 90°.‣ Align the sensor in such a way that the
cuvette gap is rinsed by means of the flow.
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6 Suspended vertically from a chain
The installation angle is 0°. Tried and testedarrangement when operating in ventilated zones.‣ Ensure that the sensor is adequately cleaned.
There must be no buildup on the opticalwindows.
Flow assembly CAS51D 2-40 mm for small sample volumes
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7 Horizontally, in flow assembly, arrow points in the direction of flow
1 Sensor2 Flow assembly3 Medium outlet4 Medium inflow5 Window, required for aligning the sensor
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Flowfit CYA251 flow assembly
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8 Horizontally, in flow assembly CYA251, arrow points in the direction of flow
1 Sensor2 Medium outlet3 Cap4 Flow assembly5 Medium inflow6 Rinse connection
Environment
Ambient temperature range -20 to +60 °C (-4 to 140 °F)
Storage temperature -20 to +70 °C (0 to 160 °F)
Degree of protection IP 68 (1 m (3.3 ft) water column over 60 days, 1 mol/l KCl)
Process
Process temperature 5 to 50 °C (41 to 122 °F)
Process pressure (absolute) 0.5 to 10 bar (7 to 145 psi) absolute
Minimum flow No minimum flow required.
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Mechanical construction
Dimensions Sensor
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NPT “¾
G1
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(1
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40 (1.57)
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(0
.55
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.79
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10 Sensor with 8 mm gap width, dimensions inmm (inch)
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(0
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.47
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.5 (
0.5
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40 (1.57)
NPT “¾
G1
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Flow assembly
Ø 6.5 (0.26)
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** 70 (2.76)6
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** Variable length
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Cleaning unit
20.5
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13 Dimensions in mm (inch)
1 Adapter 8 mm with 300 mm hose (only for 8 mm connection)2 Connection 6 mm or 6.35 mm (¼")A Sensor (2mm oder 8 mm gap)C SAC sensor (40 mm gap)
Weight Approx. 1.6 kg (3.53 lbs) (without cable)
Materials Sensor Stainless steel 1.4404 (AISI 316 L)Optical windows Quartz glassO-rings EPDM
Process connections G1 and NPT ¾''
Certificates and approvals
The product meets the requirements of the harmonized European standards. As such, it complieswith the legal specifications of the EU directives. The manufacturer confirms successful testing of theproduct by affixing to it the mark.
EAC version The product has been certified according to guidelines TP TC 004/2011 and TP TC 020/2011 whichapply in the European Economic Area (EEA). The EAC conformity mark is affixed to the product.
Ordering information
Product page www.endress.com/cas51d
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Product Configurator On the product page there is a "Configure" button to the right of the product image Configure.1. Click this button.
The Configurator opens in a separate window.2. Select all the options to configure the device in line with your requirements.
In this way, you receive a valid and complete order code for the device.3. Export the order code as a PDF or Excel file. To do so, click the appropriate button on the right
above the selection window.
For many products you also have the option of downloading CAD or 2D drawings of theselected product version. Click the tab for this CAD and select the desired file type usingpicklists.
Scope of delivery The delivery comprises:• Sensor in the version ordered• Operating Instructions
Accessories
Assemblies FlexdipCYA112• Immersion assembly for water and wastewater• Modular assembly system for sensors in open basins, channels and tanks• Material: PVC or stainless steel• Product Configurator on the product page: www.endress.com/cya112
Technical Information TI00432C
Flowfit CYA251• Connection: See product structure• Material: PVC-U• Product Configurator on the product page: www.endress.com/cya251
Technical Information TI00495C
Flow assembly for CAS51D• For small flow volumes• Connection: hose, OD 6 mm• Material: PVC-U• Two brackets for CAS51D• Order number: 71110000
Holder Flexdip CYH112• Modular holder system for sensors and assemblies in open basins, channels and tanks• For Flexdip CYA112 water and wastewater assemblies• Can be affixed anywhere: on the ground, on the capstone, on the wall or directly onto railings.• Stainless steel version• Product Configurator on the product page: www.endress.com/cyh112
Technical Information TI00430C
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Compressed air cleaning Compressed air cleaning for CAS51D• Connection: 6 or 8 mm (metric) or 6.35 mm (¼")• Order numbers for sensor with 2 mm gap or 8 mm gap:
– 6 mm (with 300 mm hose and 8 mm adapter)Order No.: 71110787
– 6.35 mm (¼")Order No.: 71110788
• Order numbers for sensor with 40 mm gap:– 6 mm (with 300 mm hose and 8 mm adapter)
Order No.: 71126757– 6.35 mm (¼")
Order No.: 71126758
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A Cleaning for sensors with 2 mm and 8 mm gapB Cleaning for sensors with 40 mm gap1 Adapter, 8 mm2 300 mm hose (Ø = 6 mm)3 Coupling, 6 mm or 6.35 mm (¼") for 2 mm and 8 mm gap4 Coupling, 6 mm or 6.35 mm (¼") for 40 mm gap
Compressor• For compressed air cleaning• 230 V AC order no. 71072583• 115 V AC order no. 71194623
Standard solutions Nitrate standard solutions, 1 liter• 5 mg/l NO3-N, order number: CAY342-V10C05AAE• 10 mg/l NO3-N, order number: CAY342-V10C10AAE• 15 mg/l NO3-N, order number: CAY342-V10C15AAE• 20 mg/l NO3-N, order number: CAY342-V20C10AAE• 30 mg/l NO3-N, order number: CAY342-V20C30AAE• 40 mg/l NO3-N, order number: CAY342-V20C40AAE• 50 mg/l NO3-N, order number: CAY342-V20C50AAEKHP standard solutionCAY451‐V10C01AAE, 1000 ml parent solution 5 000 mg/l TOC
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Function and system designMeasuring principleNitrate measurementCross-interference when measuring nitrateSAC measurementCross-interference when measuring SACMeasuring system
InputMeasured valuesMeasuring ranges
Power supplyPerformance characteristicsReference operating conditionsMeasured errorRepeatabilityDetection limitsLimits of determinationLong-term drift
InstallationInstallation conditions
EnvironmentAmbient temperature rangeStorage temperatureDegree of protection
ProcessProcess temperatureProcess pressure (absolute)Minimum flow
Mechanical constructionDimensionsWeightMaterialsProcess connections
Certificates and approvalsCEEAC version
Ordering informationProduct pageProduct ConfiguratorScope of delivery
AccessoriesAssembliesHolderCompressed air cleaningStandard solutions