Trace elements in size-segregated urban aerosol in relation to the ...
Vertical Profiles of Trace Gas and Aerosol Properties over ... · Vertical Profiles of Trace Gas...
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Vertical Profiles of Trace Gas and Aerosol Properties over the Eastern North AtlanticYang Wang, Guangjie Zheng, Swarup China, Michel Jensen, Daniel Knopf, Alex Laskin, Alyssa A Matthews, David Mechem, Fan Mei, Ryan Moffet, Tamara Pinterich, Arthur J Sedlacek, John Shilling, Stephen Springston, Jason Tomlinson, Daniel Veghte, Robert Wood, Maria Zawadowicz, and Jian Wang*
Washington University in St. LouisBrookhaven National LaboratoryPacific Northwest National LaboratoryStony Brook UniversityPurdue UniversityUniversity of KansasArgonne National LaboratoryUniversity of Washington
*Contact information: [email protected]
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Processes governing the aerosol properties at ENA
• Long-term ground observation at ENA• Aerosols are governed by different
processes at ENA• Strong seasonal variabilities in aerosol
population and controlling processes• Lack of aircraft-based observations
Zheng, G., et al. (2018). Atmospheric Chemistry and Physics 18(23): 17615-17635.
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Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA)
• 2 intense operation periods (IOPs) • Early summer (June to July, IOP1) of 2017 • Winter (January to February, IOP2) of 2018
• “L-shaped” flight pattern• Vertical profiles of trace gas and aerosol properties 3
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Cluster analysis of back trajectories during flight days
• MBL heights: 1220±450 (IOP1) and 1640±480 m (IOP2)• 3 altitudes: 500 m, 1500 m, 3000 m
North AmericaArcticAzores high
Wintertime air mass originates from above 3000 m
4Stein, A. et al., Bulletin of the American Meteorological Society, 96, 2059-2077, 2015.
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Gas species
Difference in ambient temperature and saturation vapor pressure
Major sink of CO is OH radicalVertical trend: • Continental temperature• Vertical transport
• Water vapor (WV), carbon monoxide (CO), and ozone (O3)
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Gas species
• Major sink of O3 is the formation of OH during photolysis
• Water vapor (WV), carbon monoxide (CO), and ozone (O3)
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Aerosol number concentrations and sizes
Higher total concentration in the FT
Dominated by Aitken-mode aerosols
Lower Accumulation-mode aerosol concentration in the FT
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FT is unlikely the source of accumulation mode aerosols in the MBL
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Aerosol number concentrations and sizes
Smaller Aitken- and Accumulation-mode size in the FT (surface growth and in-cloud processing)
Higher volatile fraction in the FT (influence of new particle formation)
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Aerosol number concentrations and sizesSeasonal variation: higher summertime concentration in all size ranges at all altitudes• Influence of long-range transport and potentially stronger new particle formation
Summertime volatile fraction is lower than wintertime
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Average aerosol size distributions
• Total aerosol concentration: higher in summer
• Large difference in Aitken-mode size
• New particle formation during winter
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Aerosol chemical compositions
• Sulfate, organics, and ammonium constitute majority of non-refractory aerosol mass• Higher sulfate concentration in the MBL• BC concentration is higher in the FT (long-range transport)
• Anthropogenic pollution or biomass burning aerosols? 11
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Aerosol scattering properties• Scattering coefficients at wavelengths of 700, 550, and 450 nm
• Higher values in the MBL• Ångström exponent is lower at surface due to sea spray aerosols
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Conclusions
• Vertical profiles of trace gas and aerosol properties
• Higher CO and O3 concentrations during winter due to reduced sink
• Stronger influence of long-range transport during summer
• Higher aerosol concentration during summer at all altitudes
• Larger particle sizes due to stronger surface growth
Future plans:
• Identify the source of the long-range transport aerosols
• Aerosol composition and back trajectories
• Impact of synoptic conditions on aerosol and trace gas properties
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