Valence shell electron pair repulsion (VSEPR) model:
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Transcript of Valence shell electron pair repulsion (VSEPR) model:
Valence shell electron pair repulsion (VSEPR) model:
Predict the geometry of the molecule from the electrostatic repulsions between the electron (bonding and nonbonding) pairs.
AB2 2 0
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
10.1
linear linear
B B
AB2 2 0 linear linear
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB3 3 0trigonal planar
trigonal planar
10.1
AB2 2 0 linear linear
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB3 3 0trigonal planar
trigonal planar
10.1
AB4 4 0 tetrahedral tetrahedral
AB2 2 0 linear linear
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB3 3 0trigonal planar
trigonal planar
10.1
AB4 4 0 tetrahedral tetrahedral
AB5 5 0trigonal
bipyramidaltrigonal
bipyramidal
AB2 2 0 linear linear
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB3 3 0trigonal planar
trigonal planar
10.1
AB4 4 0 tetrahedral tetrahedral
AB5 5 0trigonal
bipyramidaltrigonal
bipyramidal
AB6 6 0 octahedraloctahedral
bonding-pair vs. bondingpair repulsion
lone-pair vs. lone pairrepulsion
lone-pair vs. bondingpair repulsion> >
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB3 3 0trigonal planar
trigonal planar
AB2E 2 1trigonal planar
bent
10.1
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB3E 3 1
AB4 4 0 tetrahedral tetrahedral
tetrahedraltrigonal
pyramidal
10.1
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
AB4 4 0 tetrahedral tetrahedral
10.1
AB3E 3 1 tetrahedraltrigonal
pyramidal
AB2E2 2 2 tetrahedral bent
H
O
H
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
10.1
AB5 5 0trigonal
bipyramidaltrigonal
bipyramidal
AB4E 4 1trigonal
bipyramidaldistorted
tetrahedron
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
10.1
AB5 5 0trigonal
bipyramidaltrigonal
bipyramidal
AB4E 4 1trigonal
bipyramidaldistorted
tetrahedron
AB3E2 3 2trigonal
bipyramidalT-shaped
ClF
F
F
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
10.1
AB5 5 0trigonal
bipyramidaltrigonal
bipyramidal
AB4E 4 1trigonal
bipyramidaldistorted
tetrahedron
AB3E2 3 2trigonal
bipyramidalT-shaped
AB2E3 2 3trigonal
bipyramidallinear
I
I
I
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
10.1
AB6 6 0 octahedraloctahedral
AB5E 5 1 octahedral square pyramidal
Br
F F
FF
F
Class
# of atomsbonded to
central atom
# lonepairs on
central atomArrangement of electron pairs
MolecularGeometry
VSEPR
10.1
AB6 6 0 octahedraloctahedral
AB5E 5 1 octahedral square pyramidal
AB4E2 4 2 octahedral square planar
Xe
F F
FF