Vacu-Flo Degasser Manual t

VACU-FLO™ 500 & 1200

DEGASSERS Issued 15 Aug 09 Rev. 31 May 10

Maintenance & Operation Manual

Derrick Equipment Company 15630 Export Plaza Drive

Houston, Texas 77032 Phone: 281.590.3003

Toll Free: 1.866.DERRICK Fax: 281.442.6948

www.derrickequipment.com

UNIT NUMBER IS KEY TO DERRICK SERVICE

All inquiries to Derrick must include the equipment unit number. The stainless steel unit number tag attached to each piece of Derrick equipment is your key to efficient service and support.

Typical Derrick Unit Number

This unique number gives vital information to Service personnel who use it to identify the correct parts when filling orders, provide accurate responses to service questions, track documentation, and trace the equipment’s history or configuration. In short, the unit number provides the critical information needed to ensure that Derrick customers receive the best possible service.

The unit number consists of a two-character alphabetic prefix that identifies the equipment type and a series of numeric characters that signify the sequence of the machine’s manufacture. For example, unit number MA000001 would be the first screening machine manufactured by Derrick. Alphabetic prefixes currently in use are:

MA - Screening Machine AD - Desilter and Desander

DG - Degasser AG - Mud Agitator

CF - Centrifuge SF - Screen Frame

To ensure that it will remain intact over many years of rigorous service, the heavy-gage tag is riveted to a structural member such as the shaker support structure. It is not to be confused with any other identifier on the machine such as a vibrator motor serial number.

For convenient availability, the unit number is also recorded in the Operation and Maintenance manual shipped with the equipment. When contacting Derrick for any equipment question or need, always have the unit number in your possession. It’s the best way to get the most efficient service from our dedicated Service and Engineering personnel.

ABOUT THIS MANUAL This document is published in both printed and electronic form. In the electronic manual, all sections and paragraphs listed in the CONTENTS are linked to the corresponding text. Navigate the electronic manual as follows: 1. To view any desired information, display the CONTENTS page and move the

cursor to the desired paragraph or section title. 2. To display the desired information, click on the listing when the pointing

finger appears over the text. 3. When finished viewing the text, press Alt + left arrow key to return to the

CONTENTS page. 4. If desired to return to the same information, press Alt + right arrow. To locate

a different item, repeat steps 1 and 2.

The content of this document is subject to change at any time. Information provided does not cover all details or variations possible with DERRICK equipment, nor does it cover every contingency that may be met in conjunction with installation, operation, maintenance, or troubleshooting of the equipment. Should additional information be required, or should situations arise that are not covered by this manual, bring the matter to the attention of your local DERRICK representative or the Service Department at DERRICK Corporation in Buffalo, New York.

Copyright 2009 by DERRICK CORPORATION

CONTENTS

15 Oct 09 TOC-1 Degasser

Section Page

1 - Introduction................................................................................................................ 1-1

Overview .................................................................................................................... 1-1

Safety ......................................................................................................................... 1-2

Equipment Use........................................................................................................... 1-2

Description and Operation.......................................................................................... 1-2

Major Components ..................................................................................................... 1-3

Product Support ......................................................................................................... 1-7

2 - Safety .......................................................................................................................... 2-1

Introduction ................................................................................................................ 2-1

Warnings .................................................................................................................... 2-1

Material Safety Data Sheets (MSDSs) ....................................................................... 2-3

3 - Installation.................................................................................................................. 3-1

General ...................................................................................................................... 3-1

Safety ......................................................................................................................... 3-1

Installation Sequence................................................................................................. 3-1

Storage....................................................................................................................... 3-2

Site Preparation and Clearance Requirements.......................................................... 3-3

Moving/Positioning the Equipment ............................................................................. 3-3

Inlet Connections ....................................................................................................... 3-5

Eductor Connections.................................................................................................. 3-5

Centrifugal Pump Installation Requirements .............................................................. 3-5

Electric Power Connections ....................................................................................... 3-7

Three-Way Control Valve Arm ................................................................................... 3-8

Machine Startup ......................................................................................................... 3-8

4 - Operating Instructions .............................................................................................. 4-1

General ...................................................................................................................... 4-1

Operating Safety ........................................................................................................ 4-1

Initial Startup .............................................................................................................. 4-1

Normal Startup and Operation ................................................................................... 4-3

Abnormal Operation ................................................................................................... 4-3

Normal Shutdown....................................................................................................... 4-3

Emergency Shutdown ................................................................................................ 4-3

CONTENTS

TOC-2 15 Oct 09

Section Page

5 - Maintenance............................................................................................................... 5-1

General ...................................................................................................................... 5-1

Routine Maintenance................................................................................................. 5-1

Vacuum Pump ........................................................................................................... 5-2

Vacuum Pump Motor ................................................................................................. 5-4

Eductor ...................................................................................................................... 5-4

Troubleshooting ......................................................................................................... 5-4

Parts Replacement .................................................................................................... 5-6

Recommended Spare Parts....................................................................................... 5-6

6-7 - Not Used

8 - Reference Drawings.................................................................................................. 8-1

9 - Installation and Maintenance Log............................................................................ 9-1

10 - Supplier Data ............................................................................................................ 10-1

SECTION 1 - INTRODUCTION

OVERVIEW

This manual provides installation, operation, and maintenance instructions for the Derrick Vacu-Flo™ 500 and 1200 Degassers (Figure 1-1). The manual is divided into several sections to assist the user in readily accessing the information.

Personnel responsible for transporting, installing, operating, adjusting, or maintaining this equipment should be required to read and understand the information and instructions in this manual. One copy of this manual should be available and accessible at the equipment location.

For maximum safety and performance, no additions and/or changes may be made to the equipment without the explicit written permission of Derrick Corporation. Genuine Derrick repair/replacement parts are required.

Figure 1-1 Derrick Vacu-Flo™ 1200 Degasser

SAFETY

Section 2 of this manual contains relevant safety information relating to both operation and maintenance of this equipment. Be sure this information is read and understood by all personnel.

DO NOT operate the equipment if defective or faulty mechanical or electrical components are detected.

31 May 10 1-1 Degasser

INTRODUCTION

1-2 31 May 10

EQUIPMENT USE

The degasser and associated components are designed exclusively for releasing gases from slurries. Derrick Corporation does not authorize any other use of this equipment. Intended usage of equipment includes compliance with the operating, maintenance, and safety procedures included in this manual.

DESCRIPTION AND OPERATION

A combination of atmospheric and vacuum degassing principles are used to remove entrapped gases from the drilling fluid. Drilling mud is delivered from the mud tank to the degasser’s mud inlet connection. The Vacu-Flo 500 degasser processes 500 gallons per minute (gpm), and the Model 1200 handles 950 gpm. The principal difference between the two models is the leaf area. For efficient gas removal at its higher flow rates, the leaf area of the Vacu-Flo 1200 is nearly triple that of the Model 500.

A vacuum pump produces a low-pressure condition inside the chamber that helps release the gas bubbles from the mud. The vacuum pump is driven by an explosion-proof motor having a variable-speed drive to provide adjustment for changing loads. The degasser’s interior vacuum (up to 29” mercury) draws the mud upward into the center standpipe. Mud sprays out the standpipe’s ejector ports onto the leaves, a stacked array of conical, corrugated baffles. As the mud spreads rapidly outward across the corrugated surfaces and onto the interior wall of the degasser, gas escapes into the reduced-pressure environment and is drawn off by the vacuum pump. The mud continually flows off the leaves and into the pool of de-gassed mud at the bottom of the vessel. A centrifugal pump supplied by the customer pumps mud from the tank through the eductor, which continually draws de-gassed mud out of the chamber.

Inlet flow rate and chamber vacuum level are automatically controlled by a mechanism that responds to the level of de-gassed mud in the bottom of the chamber. A jet pump (eductor) draws the de-gassed mud from the bottom of the degasser chamber and discharges into a receiving tank.

The degasser receives drilling fluid through the feed connection on the side of the vacuum chamber (Figure 1-2). After entrapped gas is released from the slurry, it falls to the bottom of the vacuum chamber and is then returned to the discharge connection. The degasser uses vacuum, impact/turbulence, and maximum surface area exposure to remove gas from the mud. These features are described in the following paragraphs.

Low Pressure - The degasser vacuum chamber’s low-pressure interior environment allows the entrapped gas bubbles in the mud to naturally expand. As the gas bubbles become larger, they float more easily, tending to move closer to the surface where they are more likely to be released from the mud.

Impact/Turbulence - Forcing the mud through small ports in the standpipe causes it to strike the leaves and sidewalls of the vacuum chamber with considerable force. The resultant turbulence further exposes the entrapped gas to the low-pressure environment. Any remaining gas bubbles are therefore permitted to break free.

Maximum Surface Exposure - As the mud is sprayed out the standpipe ports, it is distributed in thin sheets over a series of conical, corrugated leaves. The leaves disperse the mud, thereby increasing the surface area exposed to the vacuum so that more of the entrapped gas can be released.

INTRODUCTION


Figure 1-2 Degasser Functional Diagram

MAJOR COMPONENTS

The degasser (Figure 1-3) consists of a skid-mounted vacuum chamber, electric motor-driven vacuum pump, liquid trap, air filter, three-way valve, and separately installed eductor assembly. These components are described in the following paragraphs.

Figure 1-3 Degasser Side View

INTRODUCTION

1-4 31 May 10

Vacuum Chamber

The vacuum chamber has domed top and bottom heads with inlet and outlet connections to transport fluid in and out of the vessel. Two inlet connections permit either a left or right orientation to accommodate the customer’s existing piping arrangement. A cap is provided to close unused connection. An electrical junction box with integral start-stop contactor is mounted on the side of the vacuum chamber. An access panel is provided on the side of the chamber for inspection and maintenance of the interior components.

A fitting at the top of the vessel connects to the vacuum pump, which draws a vacuum of up to 29 inches of mercury (Hg) inside the chamber. The standpipe in the center of the chamber has a series of ports that disperse the drilling fluid outward at high velocity onto conical, corrugated leaves. A float assembly inside the chamber controls the fluid level by activating a three-way valve, which partially vents the chamber to the atmosphere as the fluid level rises.

Eductor Assembly

A venturi-type jet pump, the eductor assembly removes de-gassed mud from the bottom of the vacuum chamber and delivers it to the de-gassed mud tank. The eductor is operated by mud that is drawn from the same de-gassed mud tank and pumped through to the eductor nozzle. A customer-supplied centrifugal pump maintains a continuous flow of mud from the suction tank into the eductor nozzle. The restricted venturi accelerates the mud as it flows through eductor, creating a low-pressure condition that draws degassed mud from the bottom of the degasser and expels it into the de-gassed mud tank.

Vacuum Pump

The two-cylinder, single-stage vacuum pump is mounted on the skid adjacent to the vacuum chamber. A flexible hose connects the pump inlet to the fitting at the top of the vacuum chamber. By drawing a vacuum inside the chamber, the pump creates a siphon that causes fluid to be drawn from the tank and rise into the standpipe. The pump operates continuously, as chamber vacuum is controlled by the three-way valve installed on the vacuum chamber.

The pump is belt-driven by a 5 HP explosion-proof electric motor and is capable of drawing a vacuum of 29 inches Hg inside the chamber. For optimum versatility, the motor is available in a variety of three-phase power configurations, including 240/480 Vac 60 Hz, 190/380 Vac 50 Hz, 575 Vac 60Hz, and 415 Vac 50 Hz. Power is supplied to the drive motor from the degasser’s START switch on the electrical junction box. A customer-supplied motor starter applies power to the degasser’s junction box. For safety, an emergency shutoff switch is recommended.

The inlet side of each pump cylinder is connected to a common manifold, and the outlets also share a common outlet manifold. During the suction stroke, gas is drawn from the degasser chamber through the inlet manifold and cylinder inlet valves and into the cylinders. On the compression stroke, the inlet valve closes and the outlet valve opens, permitting gas to be exhausted through the outlet manifold.

INTRODUCTION


Liquid Trap and Gas Filter

To protect the pump inlet from liquid drawn out of the vacuum chamber a liquid trap (Figure 1-4) is installed in the suction line. Gas drawn out the top of the vacuum chamber flows downward and through the liquid trap before entering the air filter. In the liquid trap, any liquid in the gas stream falls to the bottom of the trap, while gas flows out the top fitting to the air filter. The trap contains a float valve that closes off the outlet port if liquid level rises excessively. A drain valve is provided on the side of the trap to facilitate periodic moisture removal.

The gas filter is installed in the line between the liquid trap and three-way valve. Moisture-free gas leaving the liquid trap is filtered before flowing into the pump inlet. The filter protects the pump inlet from particulates that could cause premature wear of the pump’s internal components. A condensate drain is installed on the bottom of the filter to remove any accumulated moisture.

Figure 1-4 Degasser Top View

INTRODUCTION

1-6 31 May 10

Three-Way Valve

The three-way valve (Figure 1-5) is mounted on the vacuum chamber behind the vacuum pump. Its purpose is to control pressure inside the vacuum chamber and, coincidentally the fluid level, by dividing the gas drawn from the chamber between the vacuum pump and vent. A control arm connected to the float inside the chamber operates the valve. During degasser operation, the valve spool is moved up and down by the float linkage in response to varying fluid levels. A rise in fluid level positions the valve spool to vent more gas while reducing gas flow to the vacuum pump. This causes chamber pressure to rise, reducing the siphoning effect, and slowing the flow of fluid drawn into the chamber. As the level falls, the valve reduces venting while directing more gas to the vacuum pump, which then reduces chamber pressure, increasing the siphon, and allowing more fluid to be drawn into the chamber.

Figure 1-5 Three-Way Valve Connections

INTRODUCTION


PRODUCT SUPPORT Derrick offers 24-hour-per-day, 7-day-per-week product support. Product support includes screen replacement / ordering information and repair / replacement parts and service for the entire product line. Refer to the following table for the parts / service center nearest you.

PARTS SALES & SERVICE LOCATIONS

Colorado - 970.241.2417

Louisiana

Broussard - 877.635.3354

Mississippi

Laurie - 877.635.3354

New York - Corporate Headquarters

Buffalo - 716.683.9010

Oklahoma

Oklahoma City - 405.208.4070

Texas

Houston (Oilfield Headquarters) - 866.DERRICK (337.7425)

Bridgeport - 940.210.9975

Corpus Christi - 361.664.2410

Texas (Cont’d)

Longview - 337.298.9411

Midland - 432.230.3720

Wyoming - 307.265.0445

Germany - 011.49.5162.98580

CONTACT INFORMATION

Location Telephone Facsimile (FAX) E-Mail / Website

Derrick Corporation 590 Duke Road Buffalo, New York 14225 USA

716.683.9010 716.683.4991 General Service Manager [email protected]

Derrick Equipment Company 15630 Export Plaza Drive Houston, Texas 77032 USA

281.590.3003 281.442.6948 General Manager [email protected]

SECTION 2 - SAFETY

INTRODUCTION

This section contains a summary of WARNINGS used in this manual and a list of material safety data sheets (MSDSs) applicable to the equipment. The Vacu-Flo™ Degasser has been designed to perform the stated functions safely.

WARNINGS

All persons responsible for operation and maintenance of this equipment must read and understand all safety information in this manual prior to operating and/or maintaining the equipment. The safety warnings listed below are included in applicable procedures throughout this manual.

Sound

WARNING! TO PROTECT AGAINST HEARING LOSS, HEARING PROTECTION SHOULD BE WORN AT ALL TIMES WHEN WORKING ON OR NEAR DERRICK MACHINES.

Electrical Hazards

WARNING! TO AVOID SERIOUS PERSONAL INJURY BE SURE EQUIPMENT IS LOCKED OUT, TAGGED OUT, AND DE-ENERGIZED PRIOR TO PERFORMING MAINTENANCE AND/OR ADJUSTMENTS.

WARNING! MOTOR MUST BE OPERATED AT THE DESIGNATED SUPPLY VOLTAGE.

WARNING! HIGH VOLTAGE MAY BE PRESENT. BE SURE FUSED DISCONNECT SUPPLYING ELECTRICAL POWER TO THIS EQUIPMENT IS OPEN. LOCK-OUT AND TAG-OUT POWER SUPPLY TO PREVENT ACCIDENTAL APPLICATION OF POWER WHILE MAINTENANCE AND/OR ADJUSTMENTS ARE IN PROGRESS.

WARNING! ELECTRICAL CONNECTIONS MUST BE MADE IN ACCORDANCE WITH THE NATIONAL ELECTRICAL CODE (NEC) AND ALL APPLICABLE LOCAL CODES. FAILURE TO COMPLY MAY RESULT IN AN UNSAFE CONDITION THAT COULD INJURE PERSONNEL OR DAMAGE EQUIPMENT. ENSURE THAT ALL ELECTRICAL AND CONDUIT CONNECTIONS ARE SECURE.

15 Apr 11 2-1 Degasser

SAFETY

Equipment Handling

WARNING! USE SPREADER BARS TO PREVENT DAMAGE WHEN LIFTING THE EQUIPMENT.

WARNING! TO ENSURE PROPER BALANCE AND ORIENTATION WHEN UNIT IS RAISED AND PREVENT DAMAGE TO COMPONENTS, ATTACH LIFTING SLINGS ONLY TO LABELLED LIFTING POINTS. DO NOT ATTEMPT LIFTING BY ATTACHMENT TO ANY OTHER LOCATION.

WARNING! BE SURE THAT HANDLING DEVICES HAVE SUFFICIENT LIFTING CAPACITY TO SAFELY HANDLE THE WEIGHT OF THE EQUIPMENT.

WARNING! WHEN USING AN OVERHEAD LIFTING DEVICE, USE ALL FOUR LIFT POINTS PROVIDED. DO NOT ATTEMPT TO LIFT MACHINE USING ANY OTHER ATTACHMENT MEANS.

Operation

WARNING! ALL OPERATING AND MAINTENANCE PERSONNEL MUST READ AND UNDERSTAND ALL SAFETY INFORMATION IN THIS MANUAL BEFORE WORKING WITH THE EQUIPMENT.

Maintenance

WARNING! HIGH VOLTAGE MAY BE PRESENT. ALWAYS OPEN FUSED DISCONNECT SUPPLYING ELECTRIC POWER TO THE EQUIPMENT, AND LOCK OUT AND TAG OUT POWER SUPPLY BEFORE PERFORMING ANY MAINTENANCE AND/OR ADJUSTMENTS OF EQUIPMENT.

2-2 15 Apr 11

SAFETY

15 Apr 11 2-3 Degasser

MATERIAL SAFETY DATA SHEETS (MSDSs)

Material Safety Data Sheets (MSDSs) for exterior finish products are included on the following pages to advise personnel of the properties and any possible hazards associated with these materials. Emergency first-aid procedures, special precautions, emergency telephone number, and other relevant data are contained in the MSDSs. These documents were prepared by the product manufacturers, which have sole responsibility for accuracy of the information.

The MSDSs in this section are current as of the publication date of this manual and are supplied only for reference. Checking with the product manufacturer for updates is recommended and is the responsibility of the customer.

In addition to the MSDSs, manufacturer’s specifications are listed for the approved bearing greases and anti-seize lubricant for the Vacu-Flo Degasser. Gearbox oils are listed in the manufacturer’s manual included in Section 10.

To ensure that current information is available, the MSDS for each product should be obtained at the time of purchase. Please note that all lubricants listed are equivalent and approved for bearing and other lubrication requirements.

MATERIAL DESCRIPTION – WHERE USED MSDS No. / Date

Paints

PPG Dimetcote 302H Green 302F0250 Resin – Top Coat 1302H-5A / 04-11-10

PPG Dimetcote 203H Clear 302G0910 Cure – Top Coat 1302H-B / 01-21-10

PPG PSX 700 Neutral Tint Resin – Undercoat PX700T3 / 02-28-08

PPG PSX 700FD Cure – Undercoat PX700FD-B / 01-11-07

Lubricants and Sealants*

(40°F (4.4° C) and below ISO 32 non-detergent lubricating oil - Vacuum Pump

40°F to 80°F (4.4°C to 26.7°C) ISO 100 non-detergent lubricating oil - Vacuum Pump

80°F to 125°F (26.7°C to 51.7°C) ISO 150 non-detergent lubricating oil - Vacuum Pump

Contact Manufacturer

Loctite 76764 Anti-Seize Lubricant - Fasteners 76764 / 09-27-04

* Equivalent product may be substituted for listed items.

DIMETCOTE 302H GREEN 302F0250 RESINProduct name

Product and company identification:

1 .

DI302H-5APPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

SupplierCode

Emergency telephonenumber

:

:

:

Technical Phone Number : (412) 492-5200 (ALLISON PARK, PA) 8:00 a.m. - 5:00 p.m. EST

Material Safety Data Sheet

Date of issue 7 July 2010Version 11

Emergency overview

Hazards identification

Potential acute health effects

May be harmful if swallowed.

EyesSkin

Inhalation

Ingestion

See toxicological information (section 11)

WARNING!:

::

:

:

Medical conditionsaggravated by over-exposure

Pre-existing skin disorders and disorders involving any other target organs mentioned inthis MSDS as being at risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptomsRepeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain andnervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causesheadaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeatedexposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expectedfrom exposure to noise alone.

Keep away from flames, such as a pilot light, and any object that sparks, such as anelectric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Donot swallow. Do not get on skin or clothing. Avoid contact with eyes. Use only withadequate ventilation. Keep container tightly closed and sealed until ready for use. Washthoroughly after handling.

FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSESRESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.MAY BE HARMFUL IF SWALLOWED. SANDING AND GRINDING DUSTS MAY BEHARMFUL IF INHALED. MAY CAUSE EYE IRRITATION. PROLONGED ORREPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINSMATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

Harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth andthroat.

Moderately irritating to eyes.May cause skin dryness and irritation. May cause an allergic skin reaction.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous MaterialsInformation System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8United States - Canada - Mexico

DIMETCOTE 302H GREEN 302F0250 RESINProduct name11Product code Date of issue VersionDI302H-5A 7 July 2010

Composition/information on ingredients3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.

Zinc powder - zinc dust (stabilized) 7440-66-6 30 - 60Cement, portland, chemicals 65997-15-1 10 - 30heptan-2-one 110-43-0 7 - 13Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]

25036-25-3 5 - 10

Phenol, 4-(1,1-dimethylethyl)-, polymer with 2-(chloromethyl)oxirane and 4,4'-(1-methylethylidene)bis[phenol] Average Molecular Weight <=700

67924-34-9 1 - 5

Barium sulfate 7727-43-7 1 - 5n-Butyl acetate 123-86-4 0.5 - 1.5

Name CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open.Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognized skin cleanser. Do NOT use solvents or thinners.Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.If swallowed, seek medical advice immediately and show this container or label.Keep person warm and at rest. Do not induce vomiting.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of thisproduct, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have MaterialSafety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool. Fire water contaminated with this materialmust be contained and prevented from being discharged to any waterway, sewer ordrain.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion. Runoff to sewer may create fire orexplosion hazard.

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :Do not use water jet.

Suitable :Not suitable :

Hazardous combustionproducts

: Decomposition products may include the following materials:carbon oxidessulfur oxideshalogenated compoundsmetal oxide/oxides

Flammability of the product :



No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8).

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air). Water polluting material. May be harmful to theenvironment if released in large quantities.

Personal precautions :

Large spill :

6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Persons with a history of skin sensitization problems should not be employedin any process in which this product is used. Do not breathe vapor or mist. Do notswallow. Do not get on skin or clothing. Avoid contact with eyes. Avoid release to theenvironment. Use only with adequate ventilation. Wear appropriate respirator whenventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. To avoid fire orexplosion, dissipate static electricity during transfer by grounding and bonding containersand equipment before transferring material. Empty containers retain product residue andcan be hazardous. Do not reuse container.

Handling and storageHandling

Storage

:

:

7 .

Exposure controls/personal protection8 .

Cement, portland, chemicals TWA 10 mg/m³ 5 mg/m³ R15 mg/m³ TD

10 mg/m³ TD 10 mg/m³ Notestablished

STEL Notestablished

Notestablished

Notestablished

20 mg/m³ Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Not

established

Name Result ACGIH OSHA Ontario Mexico PPG




Acceptable Maximum PeakA =ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.

Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Personal protectionEyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:butyl rubberGloves :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

= Threshold Limit ValueTLVTWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.

Fume=FIPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHAR = Respirable

OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

STEL Notestablished

Notestablished

Notestablished

100 ppm Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________Barium sulfate TWA 10 mg/m³ 5 mg/m³ R

15 mg/m³ TD10 mg/m³ TD 0.5 mg/m³

(as Ba)Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________n-Butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not

establishedSTEL 200 ppm Not

established200 ppm 200 ppm Not

established____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL =

=

Short term Exposure limit values



>37.78°C (>100°F)

Liquid.

39% (v/v), 12.88% (w/w)

Not available.

Not available.2.48

Not available.0.4 kPa (3 mm Hg)

Not available.

Not available.Not available.

Boiling/condensation pointMelting/freezing point

46 (butyl acetate = 1)

Physical and chemical propertiesPhysical state

pH

Specific gravity

Vapor pressureVapor densityVolatilityOdor thresholdEvaporation rate

OdorColor

:

::::::

:::::

Flash point : Closed cup: 37.22°C (99°F)Explosion limits : Lower: 1.2%

9 .

Octanol/water partitioncoefficient

: Not available.

% Solid. (w/w) : 87.12

Density ( lbs / gal ) : 20.7

The product may not be stable under certain conditions of storage or use.

Reactive or incompatible with the following materials:,water,acids,oxidizingmaterials,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoidincreased storage temperature. Pressure hazard

Stability and reactivityStabilityConditions to avoid

Materials to avoid

Hazardous decompositionproductsHazardous polymerization

::

:

:

:

10 .

Toxicological information11 .

Conclusion/Summary : Not available.Chronic toxicity

Conclusion/Summary : Not available.

Carcinogenicity

Defatting irritant? : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.

Target organs : Contains material which causes damage to the following organs: brain.Contains material which may cause damage to the following organs: peripheral nervoussystem, upper respiratory tract, skin, eyes, central nervous system (CNS), nose/sinuses,throat.

heptan-2-one LD50 Oral Rat 1.6 g/kg -LD50 Dermal Rabbit 10.206 g/kg -

n-Butyl acetate LD50 Oral Rat 10.768 g/kg -LD50 Dermal Rabbit >17600 mg/kg -LC50 InhalationVapor

Rat 390 ppm 4 hours

Product/ingredient name Result Species Dose ExposureAcute toxicity




Mutagenicity

Teratogenicity

Reproductive toxicity

Classification

Barium sulfate A4 - - - - -Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.Fertility effects : No known significant effects or critical hazards.

Teratogenicity : No known significant effects or critical hazards.

Ecological informationEnvironmental effects : Water polluting material. May be harmful to the environment if released in large

quantities.

12 .

Other adverse effects : No known significant effects or critical hazards.

Aquatic ecotoxicity

Zinc powder - zinc dust(stabilized)

Acute LC50 0.24 mg/L Fresh water Fish - Rainbow trout,donaldson trout -Oncorhynchus mykiss

96 hours

_________________________________ ________________________________ __________Acute LC50 68 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________heptan-2-one Acute LC50 131000 to 137000 ug/L

Fresh waterFish - Fathead minnow - Pimephalespromelas

96 hours

______________________ _________________________________ ________________________________ __________Barium sulfate Acute EC50 32000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours______________________ _________________________________ ________________________________ __________n-Butyl acetate Acute LC50 18000 to 19000 ug/L Fresh

waterFish - Fathead minnow - Pimephalespromelas

96 hours

______________________ _________________________________ ________________________________ __________

Product/ingredientname

SpeciesResult Exposure

The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products via alicensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees. Section 6. Accidental release measures

Transport information14 .Regulation UN number Proper shipping name Classes PG*UN 1263 Paint. 3 III

Additional information-

IMDG 1263 Paint.. Marine pollutant (Zinc powder- zinc dust (stabilized))

3 Marine pollutantIII

DOT -1263 3Paint. III



Transport information14 .

CERCLA: Hazardous substances.: Zinc powder - zinc dust (stabilized): 1000 lbs. (454 kg);butan-1-ol: 5000 lbs. (2270 kg); n-Butyl acetate: 5000 lbs. (2270 kg); polychloro copperphthalocyanine;

Reportable quantity RQ :PG* : Packing group

Regulatory information

U.S. Federal regulations

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B:Material causing immediate and serious toxic effects (Toxic). Class D-2B: Materialcausing other toxic effects (Toxic).

:

:

SARA 313

Canada

United States

Mexico

15 .

TSCA 12(b) annual export notification: No products were found.TSCA 12(b) one-time export: No products were found.

CERCLA: Hazardous substances.: Zinc powder - zinc dust (stabilized): 1000 lbs. (454kg); butan-1-ol: 5000 lbs. (2270 kg); n-Butyl acetate: 5000 lbs. (2270 kg); polychlorocopper phthalocyanine;

At least one component is not listed.At least one component is not listed in DSL but all such components are listed inNDSL.All components are listed or exempted.

Product as-supplied is Exempt .

Substance Use RestrictedNot determined.

All components are listed or exempted.


Japan inventory (ENCS) :

New Zealand ( NZIoC )

CAS number Concentration

United States inventory (TSCA 8b) :Australia inventory (AICS)Canada inventory ( DSL ) :

China inventory (IECSC) :

Korea inventory (KECI) :

Philippines inventory (PICCS) :

:

:

Additional environmental information is contained on the Environmental Data Sheet for this product, which canbe obtained from your PPG representative.

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Zinc powder - zinc dust (stabilized); n-Butyl acetate; Barium sulfate; Cement, portland, chemicals; heptan-2-one

Supplier notification : Zinc powder - zinc dust (stabilized) 7440-66-6 30 - 60

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

Zinc powder - zinc dust (stabilized) 7440-66-6 N N N Y NCement, portland, chemicals 65997-15-1 N N N N Nheptan-2-one 110-43-0 Y N Y N NPhenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]

25036-25-3 Y N N N N

Phenol, 4-(1,1-dimethylethyl)-,polymer with 2-(chloromethyl)oxirane and 4,4'-(1-methylethylidene)bis[phenol]Average Molecular Weight <=700

67924-34-9 Y N N N N

Barium sulfate 7727-43-7 N N N N Nn-Butyl acetate 123-86-4 Y N Y N N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y N Y Y N

Chemical name



Regulatory information15 .

3 3 1HealthFlammability ReactivityClassification

: : :

Other informationHazardous Material Information System (U.S.A.)

3

13National Fire Protection Association (U.S.A.)Health InstabilityFlammability

Health Flammability Physical hazards

DisclaimerThe information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.

Date of previous issue 8/22/2009.:

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that preparedthe MSDS

: EHS

:: :

: : :3

3

1( * ) - Chroniceffects


DIMETCOTE 302H CLEAR 302G0910 CUREProduct name


1 .

DI302H-BPPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

SupplierCode


:

:

:



Date of issue 6 July 2010Version 11

Emergency overview



May be harmful if swallowed. Corrosive to the digestive tract. Causes burns.

Eyes

Skin

Inhalation

Ingestion


DANGER!:

:

:

:

:


Pre-existing respiratory and skin disorders and disorders involving any other targetorgans mentioned in this MSDS as being at risk may be aggravated by over-exposure tothis product.

:

2 .

Over-exposure signs/symptomsRepeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain andnervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causesheadaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeatedexposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expectedfrom exposure to noise alone.

Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not swallow.Do not ingest. Do not get in eyes or on skin or clothing. Use only with adequateventilation. Keep container tightly closed and sealed until ready for use. Washthoroughly after handling.

COMBUSTIBLE LIQUID AND VAPOR. CAUSES DIGESTIVE TRACT, EYE AND SKINBURNS. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES RESPIRATORYTRACT IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY AND SKINREACTION. MAY BE HARMFUL IF INHALED OR SWALLOWED. PROLONGED ORREPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINSMATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouthand throat. May cause sensitization by inhalation. Exposure to decomposition productsmay cause a health hazard. Serious effects may be delayed following exposure.

Corrosive to eyes. Causes burns.

Corrosive to the skin. Causes burns. Toxic in contact with skin. May cause an allergicskin reaction.



DIMETCOTE 302H CLEAR 302G0910 CUREProduct name11Product code Date of issue VersionDI302H-B 6 July 2010



NJTS 80100337-5132 Proprietary 30 - 60heptan-2-one 110-43-0 10 - 30proprietary amine adduct Not available. 10 - 30butan-1-ol 71-36-3 7 - 13TRIETHYLENETETRAMINE 112-24-3 1 - 5

Name CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

In case of inhalation of decomposition products in a fire, symptoms may be delayed. Theexposed person may need to be kept under medical surveillance for 48 hours.

Notes to physician

:

:

:

:

:

4 .





Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.

Combustible liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion.



:

5 .




: Decomposition products may include the following materials:carbon oxidesnitrogen oxides


No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Do not breathe vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8).



: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air).


6 .



Accidental release measures6 .Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Persons with a history of skin sensitization problems or asthma, allergies orchronic or recurrent respiratory disease should not be employed in any process in whichthis product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyesor on skin or clothing. Use only with adequate ventilation. Wear appropriate respiratorwhen ventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. To avoid fire orexplosion, dissipate static electricity during transfer by grounding and bonding containersand equipment before transferring material. Empty containers retain product residue andcan be hazardous. Do not reuse container.


Storage

:

:

7 .



C = Ceiling Limit

Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSS


Fume=F

heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Notestablished

STEL Notestablished

Notestablished

Notestablished

100 ppm Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________butan-1-ol TWA 20 ppm 100 ppm 20 ppm Not

establishedNotestablished

STEL Notestablished

Notestablished

Notestablished

50 ppm C Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________TRIETHYLENETETRAMINE TWA Not

establishedNotestablished

0.5 ppm Notestablished

1 ppm

____________________________ ___________ ___________ ___________ ___________ ___________ ___________


STEL =

=

Short term Exposure limit values



Exposure controls/personal protection8 .TD = Total dust

By spraying: air-fed respirator. By other operations than spraying, in well ventilatedareas, air-fed respirators could be replaced by a combination charcoal filter andparticulate filter mask. Respirator selection must be based on known or anticipatedexposure levels, the hazards of the product and the safe working limits of the selectedrespirator.

Chemical splash goggles and face shield.



Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:

nitrile, neopreneGloves :









IPEL = Internal Permissible Exposure Limit= Occupational Safety and Health Administration.OSHA

R = RespirableOSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

>37.78°C (>100°F)

Liquid.

39% (v/v), 34.69% (w/w)

Not available.

Not available.0.9

Not available.

0.41 kPa (3.1 mm Hg)

Not available.




pH

Specific gravity

Vapor pressure

Vapor densityVolatilityOdor threshold

OdorColor

:

::::::

:

:::


9 .




Physical and chemical properties9 .42 (butyl acetate = 1)Evaporation rate :


: Not available.

% Solid. (w/w) : 65.31

Stable under recommended storage and handling conditions (see section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strongacids,strong alkalis



Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.


Materials to avoid


::

:

:

:

10 .




Carcinogenicity

Mutagenicity

Teratogenicity




Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.


Defatting irritant? : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.

Target organs : Contains material which causes damage to the following organs: brain, ears.Contains material which may cause damage to the following organs: blood, kidneys,lungs, liver, mucous membranes, peripheral nervous system, upper respiratory tract,skin, eyes, central nervous system (CNS), nose/sinuses, throat.

heptan-2-one LD50 Oral Rat 1.6 g/kg -LD50 Dermal Rabbit 10.206 g/kg -

butan-1-ol LD50 Oral Rat 0.79 g/kg -LD50 Dermal Rabbit 3400 mg/kg -LC50 InhalationVapor

Rat 8000 ppm 4 hours

TRIETHYLENETETRAMINE LD50 Oral Rat 2500 mg/kg -LD50 Dermal Rabbit 805 mg/kg -




Ecological informationEnvironmental effects : No known significant effects or critical hazards.

12 .

Other adverse effects : No known significant effects or critical hazards.

Aquatic ecotoxicity

heptan-2-one Acute LC50 131000 to 137000 ug/LFresh water

Fish - Fathead minnow - Pimephalespromelas

96 hours

______________________ _________________________________ ________________________________ __________butan-1-ol Acute LC50 100 to 500 mg/L Fresh

waterFish - Bluegill - Lepomis macrochirus 96 hours

_________________________________ ________________________________ __________Acute EC50 1983000 to 2072000 ug/LFresh water

Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________TRIETHYLENETETRAMINE Acute LC50 33900 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours______________________ _________________________________ ________________________________ __________

Product/ingredientname

SpeciesResult Exposure


Waste disposal



:

13 .


Transport information14 .Regulation UN number Proper shipping name Classes PG*UN 1263 Paint. 3 III


IMDG 1263 Paint. 3 -III

DOT RemarksUSA Only: Can be reclassifiedas Combustible Liquid. Non-Bulk highway shipments (Lessthan or Equal to 450Liters) canbe shipped as non-regulated.

1263 3Paint. III

CERCLA: Hazardous substances.: butan-1-ol: 5000 lbs. (2270 kg);Reportable quantity RQ :PG* : Packing group


At least one component is not listed.All components are listed or exempted.All components are listed or exempted.

Product as-supplied is Exempt .

Not determined.At least one component is not listed.


Japan inventory (ENCS) :

United States inventory (TSCA 8b) :Australia inventory (AICS)Canada inventory ( DSL ) :China inventory (IECSC) :

Korea inventory (KECI) :New Zealand ( NZIoC ) :

:






WHMIS (Canada) Class E: Corrosive liquid. Class B-3: Combustible liquid with a flash point between37.8°C (100°F) and 93.3°C (200°F). Class D-1B: Material causing immediate andserious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Verytoxic). Class D-2B: Material causing other toxic effects (Toxic).

:

:

SARA 313

Canada

United States

Mexico



CERCLA: Hazardous substances.: butan-1-ol: 5000 lbs. (2270 kg);

: : :


CAS number Concentration

Philippines inventory (PICCS) :


SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: TRIETHYLENETETRAMINE; butan-1-ol; heptan-2-one

Supplier notification : butan-1-ol 71-36-3 7 - 13

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

NJTS 80100337-5132 Proprietary Y N N N Nheptan-2-one 110-43-0 Y N Y N Nproprietary amine adduct Not available. Y N N N Nbutan-1-ol 71-36-3 Y N Y N NTRIETHYLENETETRAMINE 112-24-3 Y N N N N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y N Y N N

Chemical name


2



Disclaimer


16 .




: EHS

:: :

: : :3 *

3




Other information16 .The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.


PSX 700 NEUTRAL TINT RESINProduct name


1 .

PX700T3PPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

SupplierCode


:

:

:



Date of issue 25 March 2010Version 9.01

Emergency overview



May be harmful if swallowed.

EyesSkin

Inhalation

Ingestion


WARNING!:

::

:

:


Pre-existing skin disorders and disorders involving any other target organs mentioned inthis MSDS as being at risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptomsTrimethoxysilanes are capable of forming methanol if hydrolyzed or ingested. If swallowed, methanol may be harmful orfatal or cause blindness.

Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist.Use only with adequate ventilation. Keep container tightly closed and sealed until readyfor use. Wash thoroughly after handling.

CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSEALLERGIC SKIN REACTION. MAY BE HARMFUL IF INHALED OR SWALLOWED.CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouthand throat. Exposure to decomposition products may cause a health hazard. Seriouseffects may be delayed following exposure.

Severely irritating to eyes. Risk of serious damage to eyes.Severely irritating to the skin. May cause an allergic skin reaction.



Proprietary silicone Proprietary 15 - 40PROPRIETARY EPOXY Not available. 15 - 40Wollastonite (Ca(SiO3)) 13983-17-0 10 - 30Poly(oxy-1,2-ethanediyl), α-(nonylphenyl)-ω-hydroxy-, branched, phosphates 68412-53-3 1 - 5bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 41556-26-7 1 - 5

Name CAS number %


PSX 700 NEUTRAL TINT RESINProduct name9.01Product code Date of issue VersionPX700T3 25 March 2010

Composition/information on ingredients3 .There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion


Notes to physician

:

:

:

:

:

4 .



Use an extinguishing agent suitable for the surrounding fire.


Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.

In a fire or if heated, a pressure increase will occur and the container may burst. Vaporsmay accumulate in low or confined areas or travel a considerable distance to a source ofignition and flash back.



:

5 .

Special exposure hazards :None known.



: Decomposition products may include the following materials:carbon oxidesnitrogen oxideshalogenated compoundsmetal oxide/oxides


No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment (see section 8).





6 .



Accidental release measures6 .Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas. Washspillages into an effluent treatment plant or proceed as follows. Contain and collectspillage with non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13). Dispose of via a licensed waste disposal contractor. Contaminatedabsorbent material may pose the same hazard as the spilled product. Note: see section1 for emergency contact information and section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop upif water-soluble or absorb with an inert dry material and place in an appropriate wastedisposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination. Do not store above the following temperature:120F / 49C.

Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Persons with a history of skin sensitization problems should not be employedin any process in which this product is used. Do not swallow. Do not get in eyes or onskin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation.Wear appropriate respirator when ventilation is inadequate. Keep in the originalcontainer or an approved alternative made from a compatible material, kept tightly closedwhen not in use. Vapors are heavier than air and may spread along floors. Emptycontainers retain product residue and can be hazardous. Do not reuse container. If thismaterial is part of a multiple component system, read the Material Safety Data Sheet(s)for the other component or components before blending as the resulting mixture mayhave the hazards of all of its parts.


Storage

:

:

7 .


Chemical splash goggles.Personal protection

Eyes :

nitrile, neopreneGloves :

Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vaporor mist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits.







Exposure controls/personal protection8 .If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.


Skin

Respiratory

:

:



>37.78°C (>100°F)

Liquid.

1% (v/v), 0.540001% (w/w)

Not available.

Not available.1.29

Not available.0.64 kPa (4.8 mm Hg)

Not available.





pH

Specific gravity


OdorColor

:

::::::

:::::


9 .


: Not available.

% Solid. (w/w) : 99.46



Reactive or incompatible with the following materials:,acids



Avoid increased storage temperature. Pressure hazard

Stability and reactivityStabilityConditions to avoidMaterials to avoidHazardous decompositionproductsHazardous polymerization

::::

:

10 .






Carcinogenicity

Mutagenicity

Teratogenicity






Target organs : Contains material which causes damage to the following organs: upper respiratory tract,skin, eyes.

bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate

LD50 Oral Rat 3.125 g/kg -Product/ingredient name Result Species Dose ExposureAcute toxicity


12 .


Waste disposal



:

13 .


Transport information14 .Regulation UN number Proper shipping name Classes PG*UN None. Not regulated. None. -


IMDG None. Not regulated. None. --

DOT -None. None.Not regulated. -

CERCLA: Hazardous substances.: No products were found.Reportable quantity RQ :PG* : Packing group





WHMIS (Canada) Class D-2B: Material causing other toxic effects (Toxic).

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: No products were found.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Noproducts were found.

:

:

SARA 313

Canada

United States

Mexico

15 .



CERCLA: Hazardous substances.: No products were found.

: : :

At least one component is not listed.All components are listed or exempted.All components are listed or exempted.


Not determined.All components are listed or exempted.



Product name CAS number ConcentrationPoly(oxy-1,2-ethanediyl), α-(nonylphenyl)-ω-hydroxy-, branched, phosphates

68412-53-3 1 - 5Form R - Reportingrequirements

:

United States inventory (TSCA 8b) :Australia inventory (AICS)Canada inventory ( DSL ) :China inventory (IECSC) :

Japan inventory (ENCS) :Korea inventory (KECI) :New Zealand ( NZIoC ) :Philippines inventory (PICCS) :

:




1



Disclaimer


16 .




: EHS

:: :

: : :3

3




Other information16 .The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.


PSX 700FD CUREProduct name


1 .

PX700FD-BPPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

SupplierCode


:

:

:



Date of issue 14 November 2009Version 9.01

Emergency overview



May be harmful if swallowed. May cause burns to mouth, throat and stomach.

EyesSkin

Inhalation

Ingestion


DANGER!:

::

:

:


None known.:

2 .

Over-exposure signs/symptomsTrimethoxysilanes are capable of forming methanol if hydrolyzed or ingested. If swallowed, methanol may be harmful orfatal or cause blindness.

Keep away from heat, sparks and flame. Do not swallow. Do not get in eyes or on skinor clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Keepcontainer tightly closed and sealed until ready for use. Wash thoroughly after handling.

COMBUSTIBLE LIQUID AND VAPOR. CAUSES EYE BURNS. CAUSESRESPIRATORY TRACT AND SKIN IRRITATION. MAY BE HARMFUL IF INHALED,ABSORBED THROUGH SKIN OR SWALLOWED.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouthand throat. Exposure to decomposition products may cause a health hazard. Seriouseffects may be delayed following exposure.

Corrosive to eyes. Causes burns.Harmful in contact with skin. Severely irritating to the skin.




Proprietary silane Proprietary 40 - 70Proprietary silane Proprietary 10 - 30dibutylbis(pentane-2,4-dionato-O,O')tin 22673-19-4 3 - 7

Name CAS number %


PSX 700FD CUREProduct name9.01Product code Date of issue VersionPX700FD-B 14 November 2009

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion


Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open.Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognized skin cleanser. Do not use solvents or thinners.Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.If swallowed, seek medical advice immediately and show this container or label.Keep person warm and at rest. Do not induce vomiting.




Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.

Combustible liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion. Vapors may accumulate in low orconfined areas or travel a considerable distance to a source of ignition and flash back.



:

5 .




: Decomposition products may include the following materials:carbon oxidesnitrogen oxidesmetal oxide/oxides


No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Do not breathe vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8).

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.





Large spill :

6 .



Accidental release measures6 .Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination. Do not store above thefollowing temperature: 120F / 49C.

Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathingvapor or mist. Use only with adequate ventilation. Wear appropriate respirator whenventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. Vapors are heavier thanair and may spread along floors. To avoid fire or explosion, dissipate static electricityduring transfer by grounding and bonding containers and equipment before transferringmaterial. Empty containers retain product residue and can be hazardous. Do not reusecontainer. If this material is part of a multiple component system, read the MaterialSafety Data Sheet(s) for the other component or components before blending as theresulting mixture may have the hazards of all of its parts.


Storage

:

:

7 .



C = Ceiling Limit

= Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSSTD = Total dust


Consult local authorities for acceptable exposure limits.Recommended monitoringprocedures



Fume=FIPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHAR = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous

Substances=Z

dibutylbis(pentane-2,4-dionato-O,O')tin

TWA 0.1 mg/m³(as Sn)

0.1 mg/m3 (asSn) TD0.1 mg/m3 (asSn)

Notestablished

Notestablished

Notestablished

STEL 0.2 MG/M3 Notestablished

Notestablished

Notestablished

Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________





If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.

Chemical splash goggles and face shield.



Skin

Respiratory

:

:

:nitrile, neopreneGloves :






>37.78°C (>100°F)

Liquid.

0% (v/v), 0% (w/w)

Not available.

Not available.0.95

Not available.0 kPa (0 mm Hg)

Not available.





pH

Specific gravity


OdorColor

:

::::::

:::::

Flash point : Closed cup: 82.22°C (180°F)

9 .


: Not available.

% Solid. (w/w) : 100





Reactive or incompatible with the following materials:,acids,oxidizing materials,strongalkalis



Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoidincreased storage temperature. Pressure hazard


Materials to avoid


::

:

:

:

10 .



Conclusion/Summary : Not available.Carcinogenicity


MutagenicityConclusion/Summary : Not available.

TeratogenicityConclusion/Summary : Not available.

Reproductive toxicityConclusion/Summary : Not available.





Proprietary silane LD50 Oral Rat 1780 mg/kg -LD50 Dermal Rabbit 4 mL/kg -

dibutylbis(pentane-2,4-dionato-O,O')tin LD50 Oral Rat >2 g/kg -



12 .


Waste disposal



:

13 .




Transport information14 .Regulation UN number Proper shipping name Classes PG*UN 3066 Paint 8 II


IMDG 3066 Paint 8 -II

DOT -3066 8Paint II

CERCLA: Hazardous substances.: No products were found.Reportable quantity RQ :PG* : Packing group



WHMIS (Canada) Class E: Corrosive liquid. Class B-3: Combustible liquid with a flash point between37.8°C (100°F) and 93.3°C (200°F). Class D-2B: Material causing other toxic effects(Toxic).

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Proprietary silaneSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Proprietary silane: Immediate (acute) health hazard

:

:Canada

United States

Mexico

15 .

2 3 1HealthFlammability Reactivity

Classification


CERCLA: Hazardous substances.: No products were found.

: : :

All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.

All components are listed or exempted.All components are listed or exempted.


All components are listed or exempted.United States inventory (TSCA 8b) :Australia inventory (AICS)Canada inventory :China inventory (IECSC) :Europe inventory :Japan inventory (ENCS) :Korea inventory (KECI) :New Zealand :Philippines inventory (PICCS) :

:



2Health Flammability Physical hazards

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.

: : :3 * 1( * ) - Chroniceffects



Other information16 .


DisclaimerThe information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.


The customer is responsible for determining the PPE code for this material.



: EHS

:: :3


Item No. : 76764 / IDH No. 235005 Product name: Silver Grade Anti-Seize Lubricant 1 of 5


Revision Date: 06/05/2006 Issue date: 06/05/2006

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: Silver Grade Anti-Seize Lubricant Item No. : 76764 / IDH No. 235005 Product type: Lubricant Region: United States Company address: Henkel Corporation 1001 Trout Brook Crossing Rocky Hill, Connecticut 06067

Contact Information: Telephone: (860) 571-5100 Emergency telephone: (860) 571-5100 Internet: www.loctite.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components % ACGIH TLV OSHA PEL OTHER Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5

30-60 5 mg/m³ TWA (mist) 10mg/m³ STEL (mist)

5 mg/m³ TWA (mist) None

Graphite 7782-42-5

10-30 2 mg/m³ TWA respirable fraction, all forms except

graphite fibers

15 mg/m³ (total), 5 mg/m³ (respirable)

None

Calcium oxide 1305-78-8

10-30 2 mg/m³ TWA 5 mg/m³ (TWA) None

Distillates (petroleum), hydrotreated light naphthenic 64742-53-6


5 mg/m³TWA ( mist) None

Aluminum 7429-90-5

5-10 10 mg/m³ TWA metal dust 5 mg/m³ TWA as Al

15 mg/m³ TWA (total), 5 mg/m³( respirable)

None

Distillates (petroleum), straight-run middle 64741-44-2


5 mg/m³ mist None

Silica, quartz 14808-60-7

0.1-1 0.05 mg/m³ TWA respirable fraction

0.1mg/m³ TWA (respirable)

None

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

HMIS: Physical state: Paste HEALTH: 1 Color: Silver FLAMMABILITY: 1 Odor: Hydrocarbon-like PHYSICAL HAZARD: 1 Personal Protection: See Section 8 WARNING: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Moderate respiratory tract irritation. Skin contact: Moderate skin irritation. Eye contact: Moderate eye irritation. Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Principal hazard of

ingestion is aspiration into the lungs and subsequent pneumonitis.


Existing conditions aggravated by exposure:

Eye, skin, and respiratory disorders.

See Section 11 for additional toxicological information.

4. FIRST AID MEASURES

Inhalation: Remove to fresh air. If discomfort persists seek medical attention.

Skin contact: Wash with soap and water. If symptoms persist, obtain medical attention.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Ingestion: Do not induce vomiting. Get medical attention immediately.

5. FIRE-FIGHTING MEASURES Flash point: >93°C (>200°F)

Autoignition temperature: Not determined

Flammable/Explosive limits-lower %: Not available

Flammable/Explosive limits-upper %: Not available

Extinguishing media: Carbon dioxide (CO2). Foam. Dry chemical.

Special fire fighting procedures: None

Unusual fire or explosion hazards: None

Hazardous combustion products: Oxides of carbon. Oxides of nitrogen.

6. ACCIDENTAL RELEASE MEASURES

Environmental precautions: Prevent further leakage or spillage.

Clean-up methods: Remove all ignition sources. Soak up with inert absorbent. Store in a closed container until ready for

disposal.

7. HANDLING AND STORAGE

Handling: Keep away from heat, spark and flame. Avoid contact with skin and eyes.

Storage: Keep in a cool, well ventilated area.

Incompatible products: No special restrictions on storage with other products.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering controls: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below

established exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).

Skin protection: Neoprene or oil resistant gloves

Eye/face protection: Safety goggles or safety glasses with side shields.

See Section 2 for exposure limits.


9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Silver Odor: Hydrocarbon-like Vapor pressure: <5 mmHg @20°C (68° F) pH: Not applicable Boiling point/range: Not available Melting point/range: Not available Specific gravity: 1.25 Vapor density: Not available Evaporation rate: Not available Solubility in water: Insoluble Partition coefficient (n-octanol/water): Not determined VOC content: 12.96%; 162 grams/liter

10. STABILITY AND REACTIVITY

Stability: Stable.

Hazardous polymerization: Will not occur.

Hazardous decomposition products: None reasonably foreseeable

Incompatability: Strong oxidizing agents.

Conditions to avoid: None known.

11. TOXICOLOGICAL INFORMATION

Carcinogen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen

Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5

No No No

Graphite 7782-42-5

No No No


No No No


No No No

Aluminum 7429-90-5

No No No


No No No


Known Carcinogen Group 1 Yes

Literature Referenced Target Organ & Other Health Effects


Hazardous components Health Effects/Target Organs

Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5

Irritant

Graphite 7782-42-5

Lung


Irritant, Eyes, Corrosive


Irritant

Aluminum 7429-90-5

Central nervous system, Irritant, Lung


Irritant


Some evidence of carcinogenicity, Lung, Immune system

12. ECOLOGICAL INFORMATION

Ecological information: Not available

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

EPA hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

U.S. Department of Transportation Ground (49 CFR): Proper shipping name: Unrestricted Hazard class or division: None Identification number: None Packing group: None

International Air Transportation (ICAO/IATA): Proper shipping name: Unrestricted Hazard class or division: None Identification number: None Packing group: None

WaterTransportation (IMO/IMDG): Proper shipping name: Unrestricted Hazard class or division: None Identification number: None Packing group: None Marine pollutant: None


15. REGULATORY INFORMATION United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None. CERCLA/SARA Section 302 EHS: None. CERCLA/SARA Section 311/312: Immediate Health Hazard CERCLA/SARA 313: Aluminum (CAS# 7429-90-5) (dust and fumes only).

California Proposition 65: No California Proposition 65 listed chemicals are known to be present.

Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. WHMIS hazard class: D.2.A, D.2.B

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: New information added in section(s): 2

Prepared by: Regulatory Affairs

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

SECTION 3 - INSTALLATION

GENERAL

This section describes the recommended installation procedure for the Vacu-Flo Degasser. Instructions include site preparation, equipment leveling, feed and discharge connections, and electrical connections.

SAFETY

Read and understand ALL safety information presented in this manual before installing and operating this equipment. Refer to Section 2 for a summary of Warnings affecting installation, operation, and maintenance of this equipment.

Before beginning the installation, review the information presented in Equipment Handling later in this section. Pay particular attention to the information concerning “lift points” and the use of spreader bars before lifting or moving the equipment.

Failure to observe proper equipment handling procedures may result in serious personal injury or death and/or damage to the equipment.



INSTALLATION SEQUENCE

Following is the sequence of steps for installing the Vacu-Flo Degasser. The sequence may vary depending on the user’s facilities and previous experience with this type of equipment.

1. Read and understand all safety information in Section 2 before installing and operating this equipment.

2. Position the degasser downstream of the shale shaker and upstream of any secondary solids control equipment such as desanders, desilters, mud cleaners, and centrifuges.

3. Be sure the unit is secure and level at installation site.

4. Locate degasser suction pipe in first compartment downstream of sand trap. Install end of 8-inch suction pipe at least 3’ below normal operating level of mud in tank. For best results install suction pipe 6” above bottom of tank and with run as short as possible.

5. Install eductor at next compartment downstream, allowing no more than 25’ from degasser discharge to eductor inlet. Install 8” discharge pipe level or with a slight downhill slope.

6. Install eductor discharge pipe at least one foot below the normal operating level of mud.

15 Aug 10 3-1

Degasser

INSTALLATION

INSTALLATION SEQUENCE (CONT’D)

7. Feed eductor with a centrifugal pump, sized to provide a 75’ head at the eductor inlet. Install centrifugal pump suction pipe as recommended by the pump manufacturer. Use a 6” feed pipe to eductor nozzle with a maximum length of 20’, and keep bends in pipe to a minimum.

8. Connect a 1-1/2” vent line from the vacuum pump outlet manifold to a safe area.

9. Connect electrical power supply to the equipment.

10. Refer to Section 4 for startup and operating instructions.

STORAGE

Storage Before Use

If the degasser will not be installed immediately, it should be covered with a tarpaulin (tarp). If unit is stored outdoors, use a UV-resistant tarp, or UV-resistant shrink wrap. Install vents when using shrink wrap.

To prevent motor damage during the storage period, perform the following precautionary activities:

1. Every 3 months, check insulation resistance of the pump motor windings using a megohmmeter (Megger). Periodically measure and record the readings in a log. Investigate any significant drop in resistance immediately. Resistance must be 1k Ohms minimum per volt of rated voltage.

2. Repeat insulation resistance test before placing equipment in service.

3. Rotate the motor shaft 10 full turns at least once every 2 months to decrease the likelihood of bearing deterioration during storage.

Note! Do not lubricate bearings during storage. Motor bearings are packed with grease at the factory and can be damaged by excessive grease.

Storage After Use

WARNING! BEFORE PREPARING THE DEGASSER FOR STORAGE, SHUT DOWN, DISCONNECT, AND LOCK OUT AND TAG OUT ELECTRIC POWER.

Prior to an idle period of any duration the unit must be drained and thoroughly cleaned inside and out to prevent damage from hardening of built-up mud.

After cleaning the unit, proceed as follows:

1. Drain the liquid trap and gas filter.

2. Lubricate the three-way valve control arm.

3. Cap both inlet connections and outlet flange.

3-2 15 Aug 10 Degasser

INSTALLATION

SITE PREPARATION AND CLEARANCE REQUIREMENTS

Prior to placement of equipment, verify that electricity and water are available at the installation site and that feed and discharge lines are provided. Also ensure that clearances around the equipment are adequate. Prepare the installation site as follows:

1. Verify that access cover can be opened for inspection, adjustment, and maintenance.

2. Check that feed and discharge lines are properly sized for the equipment (refer to general assembly drawing in Section 8 for feed and discharge sizes.

3. Verify that available electric power supply at the site agrees with electric power requirements of the equipment.

MOVING/POSITIONING THE EQUIPMENT

The degasser is normally shipped fully assembled with the eductor strapped to the same skid. A label indicating the weight of the unit is affixed to the equipment.

While the machine is still mounted on the wooden shipping skid, the unit should be transported on the ground using a forklift. After the machine is removed from the shipping skid, either a forklift or overhead-lifting device may be used.

WARNING! USE SPREADER BARS TO PREVENT DAMAGE WHEN LIFTING THE EQUIPMENT.



WARNING! DO NOT REMOVE ORANGE SHIPPING BRACKETS UNTIL EQUIPMENT HAS BEEN POSITIONED AT FINAL INSTALLATION SITE.

WARNING! WHEN USING AN OVERHEAD LIFTING DEVICE, USE ALL FOUR LIFT POINTS PROVIDED DO NOT ATTEMPT TO LIFT MACHINE USING FEEDER LIFTING LUGS.

15 Aug 10 3-3 Degasser

INSTALLATION

Equipment Hoisting

Four lift points are attached to the skid-base to allow attachment of an overhead-lifting device (Figure 3-1). Lift points are labeled “LIFT HERE ONLY”. DO NOT attempt to lift the assembly by the lid of the vessel or any other non-designated portions of the unit. Use of spreader bars is recommended.

Figure 3-1 Hoisting Degasser

Positioning

Position the degasser with sufficient space around unit to allow access to various components by operators and maintenance personnel.

Typical operation and maintenance functions include the following activities:

Opening the access cover

Removal, replacement, and adjustment of the vacuum pump drive belt

Connection and disconnection of inlet and discharge lines

Access to electrical junction box

Access to vacuum pump air connections and oil reservoir


INSTALLATION

Leveling

The degasser must be properly leveled as shown in Figure 3-2 to allow for proper operation of the three-way valve float. The equipment must be leveled along the length and width of the unit. A 4-foot level is recommended. Shim the equipment as required to level the unit.

Figure 3-2 Degasser Leveling

INLET CONNECTIONS

Victaulic® connectors (6” for the Vacu-Flo 500 and 8” for the Vacu-Flo 1200) degasser are provided for the inlet connection(s). Two inlets are provided to permit the degasser to be installed in either left or right orientation; the unused connection must remain capped.

For safety and efficiency, the suction line should be placed downstream of the sand trap. The end of the suction line must be submerged 3’ to 4’ below the minimum mud level (Figure 3-3). For best results, connect suction line as close as possible to the degasser but no more than 5’ from the inlet.

Figure 3-3 Typical Degasser Flow Diagram


INSTALLATION

EDUCTOR CONNECTIONS

Connect the degasser’s 8” outlet flange to the eductor inlet. Outlet piping from the degasser to the eductor should be no longer than 25’ and run level or at a slight downward slope toward the eductor. The eductor’s discharge line must be submerged 1’ to 2’ below the minimum mud level.

The eductor requires connection of a customer-supplied centrifugal pump to its nozzle. The pump draws fluid from the de-gassed mud tank (same as eductor discharge) and delivers it to the nozzle.

CENTRIFUGAL PUMP INSTALLATION REQUIREMENTS

The centrifugal pump must be sized to provide the required 75’ head at the eductor’s nozzle. Due to differences in piping design, the pump size, impeller, and horsepower requirements will vary. The following requirements apply to the centrifugal pump installation:

Locate pump suction line at the upstream end of the compartment where the eductor is located.

The suction line can slope slightly upward to the pump inlet or run level to pump.

Suction screen area should be more than three times the cross-sectional area of the suction line.

For pump startup and to facilitate maintenance, pump isolation valves are required on the pump suction and discharge lines. The valves should be located at a distance from the pump connection flanges of at least three times the suction line diameter.

Avoid all unnecessary turns and bends in the inlet and discharge lines.

Provide electrical service with correct wire size and adequate protection, including thermal overloads, for safe operation of the pump. If motor turns in opposite direction, shut down power and reverse leads to starter switch.

WARNING! TO AVOID SERIOUS PERSONAL INJURY BE SURE POWER TO EQUIPMENT IS LOCKED OUT, TAGGED OUT, AND DE-ENERGIZED BEFORE BEGINNING ELECTRICAL INSTALLATION.

WARNING! MOTOR MUST BE OPERATED AT THE DESIGNATED SUPPLY VOLTAGE AND FREQUENCY.

WARNING! A FUSED-DISCONNECT PRIMARY POWER SUPPLY WITH SUFFICIENT INTERRUPTING CAPACITY TO CLEAR THE MAXIMUM FAULT CURRENT CAPABILITY OF THE SYSTEM IS REQUIRED.

WARNING! ELECTRICAL CONNECTIONS MUST BE MADE IN ACCORDANCE WITH THE NATIONAL ELECTRICAL CODE (NEC) AND ALL APPLICABLE LOCAL CODES. FAILURE TO COMPLY MAY RESULT IN AN UNSAFE CONDITION THAT COULD INJURE PERSONNEL OR DAMAGE EQUIPMENT. ENSURE THAT ALL ELECTRICAL AND CONDUIT CONNECTIONS ARE SECURE.


INSTALLATION

ELECTRICAL POWER CONNECTIONS

The electrical connections should be performed only by trained, qualified personnel familiar with high-voltage applications and knowledgeable of National Electrical Code (NEC) standards and other applicable state or local codes for installation of industrial equipment. A fused disconnect is required for primary power supply.

The degasser is factory-wired to operate at a single voltage and frequency (either 50 or 60 Hz) only. Refer to Section 8 for the wiring schematic for the machine’s power requirements. The fused disconnect and wiring to the equipment shall be suitably sized and in accordance with NEC standards and all applicable state and local codes.

Make the following electric power connections:

1. Install a fused disconnect device having sufficient interrupting capacity to clear the maximum fault current capability of the power supply system.

2. Remove the plug from hole at top of the electrical junction box, install appropriate feed-through into the hole, and attach rigid conduit. Pass three-phase cable through the conduit and into the junction box.

3. Connect three-phase power leads to the terminals at the top of the starter block as shown in Figure 3-4.

Figure 3-4 Electrical Connections


INSTALLATION

ELECTRICAL POWER CONNECTIONS (CONT’D)

WARNING! BEFORE OPERATING THE DEGASSER, CONNECT FLOAT CONTROL ARM TO THREE-WAY VALVE USING HARDWARE FURNISHED.

THREE-WAY VALVE CONTROL ARM

For protection during shipment, the control arm is not connected to the valve. The control arm is restrained by a tie wrap (Figure 3-5), which must be removed to permit connection to the valve. Before operating the degasser, attach the control arm to the three-way valve as follows:

1. Remove the 5/16” bolt and nut from the control clevis at the top of the valve.

2. Remove and discard the plastic tie wrap retaining the valve control arm.

3. Swing notched end of the control arm down into control clevis, and reinstall nut and bolt.

4. Check for and remove any obstruction of valve’s atmospheric vent.

Figure 3-5 Three-Way Valve Control Arm Connection

MACHINE STARTUP

Refer to Section 4 for startup and operating procedures.


SECTION 4 - OPERATING INSTRUCTIONS


GENERAL

This section includes initial and normal startup shutdown procedures for the Vacu-Flo Degasser, as well as emergency shutdown.

OPERATING SAFETY

WARNING! BEFORE OPERATING THE DEGASSER, REMOVE WIRE TIE FROM 3-WAY VALVE CONTROL ARM AND CONNECT ARM TO VALVE USING 5/16” BOLT AND NUT.

WARNING! ALL OPERATING AND MAINTENANCE PERSONNEL MUST READ AND UNDERSTAND ALL SAFETY INFORMATION IN THIS MANUAL BEFORE WORKING WITH THE EQUIPMENT.

WARNING! VACUUM PUMP HOUSING BECOMES HOT DURING OPERATION AND MAY CAUSE SEVERE BURNS. DO NOT TOUCH PUMP HOUSING DURING OR IMMEDIATELY AFTER PUMP HAS BEEN OPERATING.

WARNING! OIL IN VACUUM PUMP BECOMES HOT DURING OPERATION. SEVERE BURNS MAY RESULT FROM HOT OIL IF PLUG IS REMOVED BEFORE OIL HAS COOLED. DO NOT REMOVE OIL FILLER PLUG DURING OR IMMEDIATELY AFTER PUMP HAS BEEN OPERATING.

WARNING! DO NOT OBSTRUCT OR PLUG ATMOSPHERIC PORT ON 3-WAY VALVE.

INITIAL STARTUP

The initial startup procedure should be used when the equipment is being started for the first time, or when equipment has been returned to use after an extended period out of service.

1. Verify that all operators and maintenance personnel have read and understand all operating and safety information in Section 2.

2. Confirm that equipment has been installed in accordance with Section 3.

3. Check that services and utilities are available in accordance with Section 3.

4. Check that 3-way valve control arm is properly connected, and confirm that control arm and valve spool move freely. Correct any binding.

5. Check for and remove any obstruction to atmospheric port of three-way valve.

6. Check oil level in vacuum pump by removing oil filler plug (Figure 4-1) and checking that the oil is at the top thread of the filler hole. Replenish if necessary, and re-install plug.

OPERATING INSTRUCTIONS

4-2 15 Aug 09

INITIAL STARTUP (CONT’D)


Figure 4-1 Vacuum Pump Oil Filler Plug Location

7. Remove top of liquid trap, and check that float valve closes. Correct any binding or defect.

8. Turn compressor belt wheel manually through several revolutions to confirm free movement.

9. Be sure that all operators and maintenance personnel are clear of equipment before applying electric power to vacuum pump and centrifugal pump.

10. Press START button on the electrical junction box to turn on the vacuum pump and begin drawing mud into the degasser vacuum chamber. Check that vacuum pump turns in proper direction (top of motor drive belt moves toward pump).

Note! If rotation is opposite, connections are reversed. Refer to Section 3 - Installation for proper connection procedure.

11. Close suction and discharge valves on centrifugal pump, and then open suction valve only.

12. Turn on electric power to centrifugal pump.

13. Slowly open the centrifugal pump discharge valve to begin pumping mud to degasser.

14. Check that vacuum gage rises, and verify that vacuum reaches and maintains a reading of 15” to 24” of mercury (0.50 to 0.80 atmospheres).

Note! Chamber pressure will vary between low and high values, depending on mud weight and degasser location.

OPERATING INSTRUCTIONS


NORMAL STARTUP AND OPERATION

The following procedure shall be performed at each machine startup:

1. Be sure that all operators and maintenance personnel are clear of the equipment before applying electric power to vacuum pump and centrifugal pump.

2. Press START button on the electrical junction box to turn on the vacuum pump and begin drawing mud into the degasser vacuum chamber.

3. Open suction and discharge valves on centrifugal pump.

4. Turn on electric power to centrifugal pump.

5. Confirm that vacuum gage rises, and verify that vacuum reaches and maintains a reading of 15 to 24 in. Hg (0.50 to 0.80 atmospheres).

Note! Chamber pressure will vary between low and high values, depending on mud weight and degasser location.

ABNORMAL OPERATION

Periodically, during degasser operation a gas kick or surge will occur. This surge causes the discharged mud from the degasser to have a substantially higher density than the feed mud. The level of density fluctuation depends on the size and duration of the kick. Normally, continued operation of the degasser will restore the mud to a density consistent with drilling requirements. During large gas kicks, however, the mud should be circulated through a mud/gas separator before being discharged to the surface pits.

NORMAL SHUTDOWN

The normal shutdown procedure is to be used for controlled stopping of operation. Normal shutdown is performed for routine activities such as cleaning, lubrication, inspection, or other routine procedure.

1. Press STOP button on the electrical junction box to stop the vacuum pump.

2. Turn off electric power to the centrifugal pump.

3. Close the centrifugal pump discharge valve.

4. Close the centrifugal pump suction side valve.

5. Open fused disconnect that supplies electric power to the machine.

EMERGENCY SHUTDOWN

To immediately stop the machine in case of emergency, open the fused disconnect supplying electric power to the machine.

SECTION 5 - MAINTENANCE

15 Oct 09 5-1 Degasser

GENERAL

Proper maintenance will ensure maximum life and trouble-free operation. While the maintenance schedule presented in this section is not rigid, modifications should be based on experience with operating the equipment at your facilities. A maintenance log should be kept to help establish a routine maintenance schedule, as well as to monitor and adjust the schedule as necessary throughout the equipment’s life.

Consider the following factors when establishing a maintenance schedule:

Duty cycle

Ambient temperature

Operating environment

ROUTINE MAINTENANCE

The following maintenance routine must be performed at least daily, or each shift if possible. These activities may be performed while the degasser is operating.

DAILY MAINTENANCE

Item Action

Three-way valve control arm Check for free movement and lubricate.

Liquid trap Drain liquid, if required (Figure 5-1).

Gas filter Drain condensate.

Note: Moving three-way valve control arm downward will facilitate drainage by opening vacuum line to atmosphere.

Vacuum pump Check oil level, and replenish if necessary (refer to Vacuum Pump Maintenance).

MAINTENANCE

ROUTINE MAINTENANCE (CONT’D)

Figure 5-1 Daily Maintenance Items

VACUUM PUMP

The table below contains the recommended maintenance schedule for the vacuum pump. For additional maintenance instructions such as troubleshooting and parts replacement, refer to the manufacturer’s literature in Section 10.


5-2 15 Oct 09

MAINTENANCE

VACUUM PUMP MAINTENANCE

ACTIVITY INTERVAL

Change oil Every 500 hours or 3 months, whichever comes first, and whenever contaminated. Fill with ISO-100, SAE 30W non-detergent oil; in Arctic climates use SA 32W

Inspect/clean/replace valves Every 2000 hours or 12 months, whichever comes first

Cylinder cooling fins Clean monthly

Drive belts Check tension. Proper tension is indicated by slight bowing at bottom of belts (see Figure 5-2)*.

* If more accurate measurement of belt tension is desired, refer to manufacturer’s documentation in Section 10.

Figure 5-2 Visual Check of Vacuum Pump Drive Belt Tension


MAINTENANCE

VACUUM PUMP MOTOR

Inspection

Clean and inspect motor approximately every 500 hours of operation or every 3 months, whichever comes first, using the following procedure:

1. Clean the motor and ventilation openings. Check that motor interior and exterior are free of dirt, oil, grease, water, or other contaminant. Proper ventilation prevents overheating and premature failure.

2. Using a megohmmeter (Megger), check insulation resistance of motor winding periodically, and immediately investigate cause of any significant drop in insulation resistance.

3. Check that all electrical connections are secure.

Bearing Lubrication

The motor bearings should be lubricated every 12,000 hours. The recommended lubricant is Exxon Mobil Polyrex EM grease; however, the following lubricants are also approved for motor lubrication: Pennzoil Pen 2 Lube, Rykon Premium #2, Texaco Polystar, and Chevron SRI.

Refer to the manufacturer’s documentation in Section 10 for additional lubrication and maintenance information.

EDUCTOR

The eductor has no moving parts and requires no maintenance other than an occasional check for leaks and obstructions lodged in the jet pump nozzle. However, through normal use the internal surfaces of the eductor will wear, decreasing operating efficiency. Repair or replace the pump when it can no longer maintain required head pressure.

TROUBLESHOOTING

The troubleshooting chart lists troubles, possible causes, and remedies for degasser malfunctions. Problems are generally revealed by low mud density in the degasser discharge tank. If mud density measures low, isolate and correct the problem as described in the troubleshooting chart. Before performing electrical continuity checks, shut down, lock out, and tag out electric power to degasser.

WARNING! TO AVOID SERIOUS PERSONAL INJURY BE SURE EQUIPMENT IS LOCKED OUT, TAGGED OUT, AND DE-ENERGIZED PRIOR TO PERFORMING MAINTENANCE AND/OR ADJUSTMENTS.

5-4 15 Oct 09

MAINTENANCE


DEGASSER TROUBLESHOOTING

TROUBLE POSSIBLE CAUSE REMEDY

Improper installation Refer to Section 2. Degasser not operating properly.

Incorrect startup procedure

Shut down unit and restart per Section 4.

Degasser vacuum chamber not sealed

Missing/damaged cover or flange gaskets; loose hose fittings

Check all entry and exit openings on vessel for an air-tight seal. Repair or replace as needed.

Flow rate through degasser exceeds rated capacity

Decrease head (pressure) to jet pump nozzle until flow rate is within degasser operating range.

Gas-containing mud coming out degasser discharge

Upper piping in degasser chamber partially filled with solids

Remove side inspection cover and thoroughly clean circular leaves and piping.

Eductor not operating correctly

Check/clear obstruction in centrifugal pump suction pipe.

Inspect eductor venturi surfaces for excessive wear and obstructions. Repair or replace as needed.

Insufficient head (pressure) supplied to eductor

Inspect centrifugal pump for adequate capacity or wear to determine if pump is capable of producing required head (pressure). Repair or replace pump as needed.

Low flow rate through degasser

Degasser suction opening partially blocked

Turn off unit. Thoroughly clean suction pipe and pit to remove large debris. If necessary shorten suction pipe to avoid drawing sediment off tank bottom.

Degasser suction pipe not fully submerged in liquid

Either raise liquid level in tank or lengthen suction pipe to avoid the intake of air.

Insufficient tank vacuum

Three-way valve not operating correctly

Remove degasser side inspection cover, and clean float assembly and surrounding area. Check float for freedom of travel throughout entire operating range. Inspect integrity of float ball and associated linkage, and repair/replace if necessary.

Manually cycle three-way valve to check for freedom of operation and no leakage in the closed position. If necessary, disassemble valve and clean all internal components. Inspect seals for excessive wear, and replace if necessary.

MAINTENANCE

5-6 15 Oct 09

DEGASSER TROUBLESHOOTING

TROUBLE POSSIBLE CAUSE REMEDY

Motor/vacuum pump operating incorrectly

Check belt tension and condition; tighten or replace as needed.

Inspect vacuum pump per manufacturer’s recommendations (refer to Section 10). Repair/replace worn components as needed.

Check supply voltage and current draw of each phase of the vacuum pump motor during normal operation. Measured values should agree with those on the motor nameplate.

Insufficient tank vacuum (Cont’d)

Water trap full or requires maintenance

Open water trap drain valve and completely empty trap. Check inlet line for debris or, in cold environments, ice. Remove any obstructions.

Inspect water trap float valve; clean and lubricate guides or repair if necessary.

PARTS REPLACEMENT

Defective parts should be replaced as soon as possible to prevent further damage to the equipment. Refer to the applicable general assembly drawings and accompanying parts lists in Section 8 for Derrick component locations and part numbers. Refer to Section 10 for supplier component data.

To facilitate pump maintenance, Derrick offers repair parts kits containing all components required for most pump repairs. The following kits are available directly from Derrick:

G0008950 Kit, Repair, Valve/Gasket, V255 Pump

G0008951 Kit, Repair, Ring/Gasket, V255 Pump

G0008952 Kit, Repair, Bearing/Connecting Rod, V255 Pump

RECOMMENDED SPARE PARTS

Following is a list of recommended spare parts to support one Vacu-Flo 1200 Degasser for two years. However, since all potential part replacements cannot be predicted, the complete spare parts inventory should be based on the user’s experience with similar equipment.

Consider the following factors when establishing a spare parts inventory:

Duty cycle

Ambient temperature

Operating environment

MAINTENANCE


Recommended Spare Parts - Vacu-Flo 1200 Degasser

Part No. Description Consumable 2-Yr Qty

10669-00 Eductor Assembly No 1

6186-08 Rod, Liquid Trap No 1

G0007067 Pendant, Local On/Off Control No 1

HYT-E716X1300 Hose, Hydraulic, 1” ID X 13” Lg No 2

HYT-E716X8500 Hose, 1” NPT With Swivel X 85” Lg No 1

PP1137 Drive Belt, Vacuum Pump Yes 2

PP1140 Float Ball, Liquid Trap, 5” No 1

PP1141 Float Ball, Tank, 12” No 1

PP1491 Valve, 3-Way No 1

TIW-002777 Valve insert No 1

WLK-FRP-95-209 Air Filter Element Yes 1

SECTION 8 - REFERENCE DRAWINGS


This section contains Derrick engineering drawings for your equipment. These drawings are included to provide assistance in troubleshooting, repair, and parts ordering.

Number Title Equipment

10310-00-009 Vacu-Flo 1200 Degasser 1200

7098-00-001 Vacu-Flo 500 Degasser 500

10667-00-012 Parts List 1200

6303-00-002 Parts List 500

SK10669-00 Eductor Pipe Assembly 1200

SK11935-00 Eductor Pipe Assembly 500

6187-00-001 Plug Assembly 500 & 1200

SK6186-00 Liquid Trap 500 & 1200

6188-00-007 Electrical Parts List 500 & 1200

13716-00 Wiring Schematic, 240/480Vac, 60Hz 500 & 1200

13716-00-001 Wiring Schematic, 190/380/400Vac, 50Hz 500 & 1200

13716-00-002 Wiring Schematic, 575Vac, 60Hz 500 & 1200

13716-00-003 Wiring Schematic, 415Vac, 50Hz 500 & 1200

14684-00 Wiring Schematic, Explosion-Proof Control Panel W/Magnetic Starter

500 & 1200

PE-S-014-09 Thermal Unit Selection Table 500 & 1200

PE-S-014-09 rev. 01/15/08

Derrick®, Flo-Line®, FLC 2000™, Flo-Line Scalper™, Pyramid®, Sandwich Screens®, DE-1000™, Hi-G™, Vacu-Flo™, GBG™, PMD™, PWP™, SWG™, DC™, DF™, DX™, and GS™, are trademarks of Derrick Corporation. (F:\ENG\DOCS\PES014.DOC)

RECOMMENDED THERMAL UNIT SELECTION TABLE

FOR DERRICK®

SUPPLIED MANUAL STARTERS

DERRICK VIBRATING MACHINES

575V.A.C. 60Hz 1.5HP = SQD-B3.30 or FUR-H19 460V.A.C. 60Hz 1.5HP = SQD-B4.15 or FUR-H21 F, FX, K, KX, L, LX, T, TX 230V.A.C. 60Hz 1.5HP = SQD-B10.2 or FUR-H26 MOTORS 215V.A.C. 60Hz 1.5HP = SQD-B10.2 or FUR-H27 440V.A.C. 50Hz 1.5HP = SQD-B3.70 or FUR-H19 380V.A.C. 50Hz 1.5HP = SQD-B4.15 or FUR-H21 220V.A.C. 50Hz 1.5HP = SQD-B8.20 or FUR-H26 575V.A.C. 60Hz 2.5HP = SQD-B6.25 or FUR-H24 460V.A.C. 60Hz 2.5HP = SQD-B7.70 or FUR-H26 E, EX, M, MX, SG, SGX 230V.A.C. 60Hz 2.5HP = SQD-B17.5 or FUR-H32 MOTORS 215V.A.C. 60Hz 2.5HP = SQD-B17.5 or FUR-H32 440V.A.C. 50Hz 2.5HP = SQD-B6.90 or FUR-H24 380V.A.C. 50Hz 2.5HP = SQD-B7.70 or FUR-H26 220V.A.C. 50Hz 2.5HP = SQD-B14.0 or FUR-H31 575V.A.C. 60Hz 3.0HP = SQD-B6.90 or FUR-H25 460V.A.C. 60Hz 3.0HP = SQD-B9.10 or FUR-H27 R, RX 230V.A.C. 60Hz 3.0HP = SQD-B19.5 or FUR-H33 MOTORS 215V.A.C. 60Hz 3.0HP = SQD-B19.5 or FUR-H34 440V.A.C. 50Hz 3.0HP = SQD-B7.70 or FUR-H26 380V.A.C. 50Hz 3.0HP = SQD-B9.10 or FUR-H27 220V.A.C. 50Hz 3.0HP = SQD-B17.5 or FUR-H32 575V.A.C. 60Hz 5.0HP = SQD-B11.5 or FUR-H29 460V.A.C. 60Hz 5.0HP = SQD-B15.5 or FUR-H32 A, C, N 230V.A.C. 60Hz 5.0HP = SQD-B36.0 or FUR-H40 MOTORS 215V.A.C. 60Hz 5.0HP = SQD-B36.0 or FUR-H40 440V.A.C. 50Hz 5.0HP = SQD-B12.8 or FUR-H30 380V.A.C. 50Hz 5.0HP = SQD-B15.5 or FUR-H32 220V.A.C. 50Hz 5.0HP = SQD-B32.0 or FUR-H37

DERRICK DEGASSER

575V.A.C. 60Hz 5.0HP = SQD-B8.20 or FUR-H28 460V.A.C. 60Hz 5.0HP = SQD-B10.2 or FUR-H30 230V.A.C. 60Hz 5.0HP = SQD-B19.5 or FUR-H38 415V.A.C. 50Hz 5.0HP = SQD-B11.5 or FUR-H31 380V.A.C. 50Hz 5.0HP = SQD-B19.5 or FUR-H32

DERRICK PRIMER

575V.A.C. 60Hz 1.5HP = SQD-B3.30 460V.A.C. 60Hz 1.5HP = SQD-B3.70 230V.A.C. 60Hz 1.5HP = SQD-B8.20 380V.A.C. 50Hz 1.5HP = SQD-B3.70

NOTE: IF MOTOR VOLTAGE OR HORSE POWER IS NOT LISTED, CONTACT ENGINEERING DEPARTMENT.

**** FOR MAGNETIC STARTER OVERLOAD INFO REFER TO THE ELECTRICAL PARTS LIST THAT IS FOUND ON THE EQUIPMENTS GENERAL ARRANGEMENT DRAWING.

SECTION 9 - INSTALLATION AND MAINTENANCE LOG


PURPOSE

This section should be used by operating and maintenance personnel to record historical information gathered during the installation and operation of the Derrick equipment. If properly kept, the log will be useful for altering maintenance intervals and intercepting trends that may indicate the need for changing operating procedures. Each entry in the log should be dated for future reference and tracking. If required, additional pages may be added to the log by copying a blank page or simply inserting ruled paper at the rear of the section.

Installation and Maintenance Notes:

INSTALLATION & MAINTENANCE LOG

9-2 15 Aug 09

INSTALLATION AND MAINTENANCE LOG



9-4 15 Aug 09

INSTALLATION AND MAINTENANCE LOG



9-6 15 Aug 09

SECTION 10 - SUPPLIER DATA


GENERAL

Documentation for Vacu-Flo Degasser components manufactured by outside suppliers is included in this section. For Derrick engineering drawings, refer to Section 8.

VACUUM PUMP

Component Description Document

I-R Air Compressor Instruction Manual Form SCD-454

I-R Air Compressor Parts List Form SCD-471

VACUUM PUMP MOTOR

Component Description Document

Baldor Motor M7044T-I Outline Drawing 36LYJ694

Baldor Motor Installation and Maintenance 5040-203

Baldor Motor Installation and Operation 400-504

Baldor Motor Performance Data M7044

Baldor Motor Wiring Data Drawing CD0005

AC & DC Motor Installation – Maintenance Instructions

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P.O. Box 2400Fort Smith, AR 72902–2400 U.S.A.(479) 646–4711

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Perform ance Data: M7 0 4 4 T- I

* For cert ified inform at ion, contact your local Baldor office.

Rat ing - Nom inals

Rated Output 5 HP

Volts 230/ 460

Full Load Amps 13.4/ 6.7

Speed 1750

Hertz 60

Phase 3

NEMA Design Code B

LR KVA Code K

Efficiency 87.5

Power Factor 80

Service Factor 1.00

Rat ing - Duty 40C AMB-CONT

Characterst ics

Full Load Torque 15 LB-FT

Break Down Torque 55.1 LB-FT 367 % of F.L. Torque

Locked-Roter Torque 39.3 LB-FT

Start ing Current (Am ps) 53.0

No-Load Current (Am ps) 2.98

Line- line Resistance @ 25° C

Tem perature Rise, C @ FL ( in deg) 64

Load Character ist ics - Tested

% of Rated Load 25 50 75 100 125 150 S.F.

Power Factor 43 66 77 82 85 86

Efficiency 80.8 87.0 88.0 87.5 86.3 84.6

Speed ( rpm) 1788 1777 1765 1751 1737 1722

Line Am peres 3.31 4.08 5.17 6.50 7.92 9.57

Page 1 of 1AC Motors: M7044T-I

11/24/2004http://www.baldor.com/products/perfdata.asp?1=1&pdf=brochure&1=1&catalog=M7044...

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Document No.: PE-S-071-03-03

http://dmc-sps/qc/Certificates/Origin Standard/PE-S-071-03-03.doc Revison Number 2 Revision Date: 29-December-2011

CERTIFICATE OF ORIGIN

Equipment: Degassers Model: Vacu-Flo™ 1200, ACD-1500 Characteristics: 0-600VAC, 50/60Hz, 3PH Derrick Corporation acknowledges that the above set-forth product is manufactured in the United State of America as of the date of this certificate. This certificate is governed by the applicable purchase order terms in effect at the time of Derrick Corporation’s original shipment of the referenced product.

Date: 29-December-2011 Signature: Jennifer J. Polanowski Derrick Corporation

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http://dmc-sps/qc/Certificates/Quality/PE-S-011-08-00.doc Revison Number 2 Revision Date: 29-December-2011

CERTIFICATE OF QUALITY

Equipment: Degassers Model: Vacu-Flo™ 1200, ACD-1500 Characteristics: 0-600VAC, 50/60Hz, 3PH Derrick Corporation acknowledges that the above set-forth product conformed to the requirements for the applicable purchase order at the time of its original shipment by Derrick Corporation in that all construction materials and components were new and unused, were manufactured for this product, and that it was free of any known defects as to their design, material and workmanship. This certificate is governed by the applicable purchase order terms in effect at the time of Derrick Corporation’s original shipment of the referenced product.


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http://dmc-sps/qc/Certificates/Shipping Final Inspection and Run Test/PE-S-070-04-00.doc Revison Number 2 Revision Date: 29-December-2011

SHIPPING FINAL INSPECTION

AND RUN TEST CERTIFICATE

Equipment: Degassers Model: Vacu-Flo™ 1200, ACD-1500 Characteristics: 0-600VAC, 50/60Hz, 3PH The product listed above was inspected and found to be in conformance with Derrick Corporation’s internal coating, run test, and assembly inspection documents that were required for the type of equipment manufactured in accordance with the Derrick quality system. This certificate is governed by the applicable purchase order terms in effect at the time of Derrick Corporation’s original shipment of the referenced product.


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