UNSATURATED POLYESTER RESINS€¦ · UNSATURATED POLYESTER RESINS Information contained in this...
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MATERIALSAFETYDATASHEET UNSATURATEDPOLYESTERRESINS Noliabilitycanbeacceptedforclaims,lossesordemandsarisingoutofthecontentsofthis publication. Informationcontainedinthispublicationaregiveningoodfaithwithoutwarrantyorguarantee. CRYSTICRESINSINDIAPRIVATELIMITED 19/6,MATHURAROAD,FARIDABAD HARYANA,INDIA-121006 EMAIL: |web:www.crysticresins.com [email protected] 1.SUPPLIERSDETAILS ManufacturersCrysticResinsIndiaPrivateLimited, 19/6MathuraRoad,Faridabad, Haryana,India–121006 TelephoneNumber+91-129-4004813/2283948(Day) ProductDescriptionSolutionofunsaturatedpolyesterresininstyrenemonomer. 2.HAZARDSIDENTIFICATION ToxicbyInhalation,incontactwithskin,byeyeingestionandifswallowed. 3.INFORMATIONONINGREDIENTS IdentificationofthepreparationHalogenfreefireretardantUnsaturatedpolyesterresininstyrene. ChemicalsNameCAS-NoEINECS-NoClassWeight% RESINSOLUTIONINSTYRENE100-42-5601-026-00-0R10Xn;R2056 (proprietary)(forstyrene)(Xi;R36/38) 4.RECOMMENDEDFIRSTAIDTREATMENT Ingestion Donotinducevomiting.Consultadoctorimmediately. SkinContact Itisrecommendedthatcleanragsorpaperandproprietaryskincleansersbeusedtoremovepolyesterresin. Skincontaminatedwithaccelerator,shouldbethoroughlywashedwithsoapandwater.Solventsshould InhalationofNoxiousFumes Removetheaffectedpersontofreshair;keephimwarmandquiet;getmedicalattention.Resuscitateifbreathing fails.
Transcript of UNSATURATED POLYESTER RESINS€¦ · UNSATURATED POLYESTER RESINS Information contained in this...
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
Noliabilitycanbeacceptedforclaims,lossesordemandsarisingoutofthecontentsofthispublication.Informationcontainedinthispublicationaregiveningoodfaithwithoutwarrantyorguarantee. CRYSTICRESINSINDIAPRIVATELIMITED19/6,MATHURAROAD,FARIDABADHARYANA,INDIA-121006EMAIL: |web:[email protected]
1.SUPPLIERSDETAILSManufacturersCrysticResinsIndiaPrivateLimited,19/6MathuraRoad,Faridabad,Haryana,India–121006TelephoneNumber+91-129-4004813/2283948(Day)ProductDescriptionSolutionofunsaturatedpolyesterresininstyrenemonomer.2.HAZARDSIDENTIFICATIONToxicbyInhalation,incontactwithskin,byeyeingestionandifswallowed.3.INFORMATIONONINGREDIENTSIdentificationofthepreparationHalogenfreefireretardantUnsaturatedpolyesterresininstyrene.ChemicalsNameCAS-NoEINECS-NoClassWeight%RESINSOLUTIONINSTYRENE100-42-5601-026-00-0R10Xn;R2056(proprietary)(forstyrene)(Xi;R36/38)4.RECOMMENDEDFIRSTAIDTREATMENTIngestionDonotinducevomiting.Consultadoctorimmediately.SkinContactItisrecommendedthatcleanragsorpaperandproprietaryskincleansersbeusedtoremovepolyesterresin.Skincontaminatedwithaccelerator,shouldbethoroughlywashedwithsoapandwater.SolventsshouldInhalationofNoxiousFumesRemovetheaffectedpersontofreshair;keephimwarmandquiet;getmedicalattention.Resuscitateifbreathingfails.
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
Informationcontainedinthispublicationaregiveningoodfaithwithoutwarrantyorguarantee.Noliabilitycanbeacceptedforclaims,lossesordemandsarisingoutofthecontentsofthispublication. CRYSTICRESINSINDIAPRIVATELIMITED19/6,MATHURAROAD,FARIDABADHARYANA,INDIA-121006EMAIL: |web:[email protected]
Itisimportantwhensummoningmedicalattentionthatthedoctororhospitalbefullyadvisedindetailofthenatureoftheproduct.EyeContactFlushtheeyewithcopiousamountsofcleanwaterforatleasttenminutes.Getimmediatemedicalattention.General5.EMERGENCYACTION/FIREMEASURES
Thespentabsorbentshouldbecollectedanddisposedofinthepropermanner.approvedlandfill.Largespillagesofresinsolutionandacceleratorsshouldbecontainedinthesmallestareapossible.Sand,earthorinertabsorbentshouldbeusedtoabsorbthematerial.
NospecialoradditionaldrillsarerequiredwithregardtoPolyesterresinsSmallFiresDrypowderandfoamextinguishersaresuitablefordealingwithminoroutbreaksoffireinvolvingpolyesterresinsolutionsandpolyesterresins.LargeFiresIngeneralonlyprofessionalfirefighterscandealwithlargefires.SpillageSmallspillagesofresinsolutionsandacceleratorsmaybecleanedupusingcleanrag,paperorinertabsorbent.Thesematerialsmustsubsequentlybedisposedofcarefullybycontrolledincinerationor6.RECOMMENDEDPRECAUTIONFORUSAGEUsageSpecificproductdataisgenerallyavailableforuserstodeterminetheusestowhichaproductmaybeput.Itistheusersresponsibilitytodeterminetheprecautiontobetakenusingtheinformationprovidedbythesupplier.Ingeneralthefollowingcommentswillapplytoallresinsystemsandmostusesituations.
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
Informationcontainedinthispublicationaregiveningoodfaithwithoutwarrantyorguarantee.Noliabilitycanbeacceptedforclaims,lossesordemandsarisingoutofthecontentsofthispublication. CRYSTICRESINSINDIAPRIVATELIMITED19/6,MATHURAROAD,FARIDABADHARYANA,INDIA-121006EMAIL: |web:[email protected]
LightingDiffuseddaylightlightingispreferredforworkareasprovidednodirectsunlightisallowedtofallupontheresinorresinsystemsincethiswillcauseprematuregelation.VentilationandExtractionTemperatureandStabilityPolyestersresinsensitivetotemperature.Whenmixedreadyforusewithcatalystsand/oraccelerators,theyaremoresensitiveandmaygelinrelativelyshorttimesatcomparativelylowworkareatemperatures.Catalystandacceleratorconcentrationsaffectthestabilityoftheresinsystem.Workareatemperaturesandcatalystandacceleratorconcentrationsmustthereforebeinaccordancewiththesuppliers’recommendationsforeachparticularapplication.Temperaturesofandaround25°Careconsideredsuitableforworkareaswhereresinsandresinsystemsareused.
MixingItisessentialthatresins,catalystsandacceleratorsarekeptapartuntilrequiredformixing.Itisessentialalsotokeepmixturesapartfromtheirconstituentelements.Undernocircumstancesmustcatalystsandacceleratorsbemixeddirectlytogetherastheycanreactwithexplosiveviolence.Itisthereforestronglyrecommendedthataclearlabelingandstoragesystemisdesignedandused.Resinmixescontainingcatalystandacceleratorshouldneverbeleftunsupervisedintheworkareaandparticularlytheymustneverbeleftovernight.
Workareamusthavegoodventilationtoremovevapors,fumes,anddustassociatedwiththeresinsandcuringsystems.Positiveextractionandparticulatecollectionatrespiratoryzonelevelshouldensureeffectiveventilation.Itisrecommendedthatextractionandcollectionequipmentishousedoutsidetheworkarea.
RECOMMENDEDPRECAUTIONFORSTORAGETemperatureMaterialsshouldbestoredatatemperaturenohigherthan25°C.Unlessspecificallystatedthefollowingnotesrelatetopolyesterresins,theirsolutionsandaccelerator.Resinsolutionsandacceleratorsinhighlyflammablesolvents.Storage
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
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VentilationMaterialsshouldbestoredinawell-ventilatedarea.MixedStorageMaterialsshouldbestoredinawell-ventilatedarea.Resinsolutions,acceleratorsandcatalystsmustbestoredapartfromeachotherandalsoapartothermaterials.StorageprecautionItishighlyrecommendedthatallthematerialisstoredat stabletemperaturelessthan25°Cpreferablyindoorsandaway fromdirectsunlightforashelflifeof3monthsfromdateofmanufacture.Liquidpolyesterresinsareflammablebutnothighlyflammable.Mostresinshaveaflashpointof31°C(88°F).Resinsandacceleratorsshouldbekeptpreferablyinabrick-buildstoreconformingtothenormalfireregulations.Storageathighertemperaturesevenforonlyafewdayswillconsiderablyreducetheshelflife.Similarlyresinsstoredinglass,especiallyifexposedtodirectsunlight,willgelrapidly,ofteninaslittleastwodays.Asageneralguide,aslongastheresinsremainsapourableliquiditwillbeusable.Fireretardantandfilledresins:Itisstronglyrecommendedtomixresinthoroughlybeforeuseandifkeptunused,shouldmixwellonceevery10dayssinceitisafilledresinandtoavoidfillersettling.7.RECOMMENDEDPRECAUTIONFORHANDLINGHandlingProtectiveWearandHygieneCareshouldbetakentoavoidaccidentalsplashingofresin.Protectiveclothingsuchasaboilersuit,gloves,apronandgogglesoftheapprovedtypesmustbeworn.Barriercreamsmayalsobeusedandafterwardsremovedwithproprietarycleansingagents.Finally,washthoroughlywithsoapandwater.Acceleratorsshouldbehandledinthesamemanner.Smoking,eatinganddrinkingshouldbeforbiddeninareaswherepolyesterresinsbeingusedorstored.Contaminatedclothingshouldberemovedandcleansedbeforere-useandmustnotbeleftinclotheslockersorenclosedplaces.TrimmingCertainpolyesterresinsmaycontainadditives,whicharetoxicwheninhalede.g.antimonytrioxide,whichmaybepresentinreducedfirehazardpolyesters.Thereforeduringcuttingandgrindingoflaminatescareshouldbetakentoavoidinhalationbyprovidinggooddustextraction.Particularcareshouldbetakentoavoidthepresenceofanymeansofignitionwhenhandlingpart-filledoremptycontainersbecausesolventvapormaybuild-uptoexplosivelevelsintheairspace.Cleaningsolventsmaybemorehazardousthanthepolyesterresinsystemsandreferenceshouldbemadetothesuppliers.beforeuse.PartlyEmptyContainers
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
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8.CHEMICALPROPERTIES FlashPoint:32DegreeCelsius Watersolubility:immiscible Form:ViscousLiquid Relativedensity:(25degC)=1.10–1.3 Colour:clear,paleyellow,opaquewhite9.RECOMMENDEDGENERALPRECAUTIONS/EXPOSURECONTROLResinSolutionsHealthConsiderationsInformationwithregardtothemonomerscurrentlyusedforPolyesterResinsolutionsisreasonablywelldocumentedandrelativelyuncontroversial.Lesswelldocumentedandmedicallycontroversialaretheorganicmetalcompounds,theaminesandsomeofthefillers.100ppm-ThresholdlimitValueTheeffectsofstyrenevapourare:25ppm-odourisdetectable200-400ppm-transientirritatingeffectoneyesandnasalPassage400-1000ppm-increasingsystemiceffectssuchasdizziness,nauseaandheadaches1000ppm-canleadtounconsciousness5700ppm-saturatedvapourpressureat15CTheeffectsofmethylmethacrylateare:10000ppm-mightcausedeathinlessthananhour11500ppm-lowerexplosionlimit10ppm-odourisdetectable100ppm-ThresholdlimitValue
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
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10.STABILITYAttherecommendedstoragetemperaturethestabilityofthematerialsisgood.Heat,moistureandcontaminantswilladverselyaffecttheirstability.Oxidizingagentsandstrongacidssuchasorganicandinorganicperoxides,sulphuricacid,phosphoruspentoxide,ferroussaltsandcertainmetalhalidesareknowntopromotepolymerisation.Careshouldbetakentoensurethatsuchmaterialsdonotcontaminatepolyesterresinsolutions.Alkalicontaminantssuchassodiumhydroxidemayremoveinhibitorsfromresinsolutionsandthusincreasethepossibilityofuncontrolledpolymerisationoccurring.11.TOXICOLOGICALINFORMATION
ByInhalation
ByIngestionTheLD50forstyreneinratsis5g/kgandformethylmethacrylate9.4/kg.Bothmonomerswouldfallintotheslighttomoderatelytoxicclass.ByskinContactAlmostall‘chemicals‘particularlysolventsandmonomershaveabasicdermatitiseffectonhumanskin.Styreneandmethylmethacrylateremovethenaturallyoccurringprotectiveoilfromtheskinsurfacetherebyexposingittobacterialattack.
FireandExplosionThefireandexplosionhazardsassociatedwithpolyesterresinsolutionsarisefromtheirmonomercontent.ThemajorityofpolyesterresinsolutionsareclassifiedasHighlyFlammable.Theflashpointsofthetwomostcommonmonomersusedarestyrene31°Candmethylmethacrylate10°C.
Styrenehasapleasantodouratlowconcentrationintheatmospherebutbecomesincreasinglyunpleasantastheconcentrationincreases.Atlevelsof800ppmandabovestyreneisanimmediateandintolerableirritanttomucousmembranes.Asaconsequenceofthisintolerableirritationvoluntaryexposureattheselevelsisunlikelytocontinue.Methylmethacrylatehasasweetishpleasantodourandbehavessimilarlytostyreneatlowconcentrations.Athigherconcentrationitisrelativelylessharmfulthanstyrene.
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
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12.ECOLOGICALINFORMATIONNoexperimentalecologicaldataareavailableonthepreparationassuch.13.DISPOSALCONSIDERATIONS
bekeptawayfromnakedflames.Smokingshouldnotbeallowedinamouldingshop.Precautionarynoticesshouldbedisplayedinworkshops.Resin,curingagents,Crysticcleaner,acetoneandmostcleaningsolventsareflammableandmust
Fullycuredpolyesterresinsystemsmaybedisposedofasunnotifiablewaste.Resin,solutionsandacceleratorsmustbedisposedofinaccordancewithregulations.Mostpolyesterresinscontainmonomericstyrene,whichisagoodgreasesolventandmaycauseirritationtotheskin.Themosteffectivemethodofprotectinghandsistheuseofabarriercreamandthisisstronglyrecommended.Resincanberemovedfromthehandswithproprietaryresinremovingcreams,orwithacetonefollowedimmediatelybyawashinwarmsoapywater.Itispreferable,however,nottowashthehandinacetoneorothersolvent.Ifthesesimpleprecautionsaretakentherewillbelittlelikelihoodofskinirritationordermatitis.Insufficientconcentrationstyrenevapourisirritatingtotheeyesandrespiratorypassages.Workshops,therefore,shouldbewellventilated.Whenresinissprayedagauzemaskshouldbeworntoprotectthemouthandnose.Thisalsoappliestotrimmingoperationwhenresinandglassdustcancauseirritation.Catalystanacceleratormustneverbemixeddirectlywitheachother,sincetheycanreactwithexplosiveviolence.14.TRANSPORTINFORMATIONHazardIdentificationNo.:30MarinePollutantMarkAppliesClassNo.:3ClassNo.:3.3SubsidiaryHazardNo.:IMDGCodePage:3379EmergencyActionCode:3[Y]PackingGroup:IIIUnitedNationsNo.:1866UnitedNationsNo.:1866ShippingName:ResinSolutionShippingName:ResinSolutionPackingGroup:IIIIATAShippingName:ResinSolutionSpecialProvisions:185,187IATAClassno:Class3IATAsubsidiaryrisk:None
Road/Rail(CDGCPLRegulations1994.)Maritime(IMDGCode)&IATA
MATERIALSAFETYDATASHEETUNSATURATEDPOLYESTERRESINS
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15.REGULATORYINFORMATIONSupplyLabel:SymbolforHarmfulRiskPhrases:R10-FlammableR20-HarmfulbyInhalationR36/38-IrritatingtoeyesandskinSafetyPhrases:S23-Donotbreathefumes/vapoursS38-Incaseofinsufficientventilationwearsuitablerespiratoryequipment.S43-Incaseoffireusefoam,CO2ordryChemical.16.OTHERINFORMATIONTheinformationcontainedinthisMaterialSafetyDataSheet,asoftheissuedate,isbelievedtobetrueandcorrect.However,theaccuracyorcompletenessofthisinformationandanyrecommendationsorsuggestionsaremadewithoutwarrantyorguarantee.Sincetheconditionsofusearebeyondthecontrolofourcompany,itistheresponsibilityoftheusertodeterminetheconditionsofsafeuseofthisproduct.Theinformationinthissheetdoesnotrepresentanalyticalspecifications,forwhichpleaserefertoourtechnicaldatasheet.
