Unit 2: Chemical Bonding Chemistry2202 1. Outline Bohr diagrams Lewis Diagrams Types of Bonding ...

Unit 2: Chemical Bonding

Chemistry2202

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Outline

Bohr diagrams Lewis Diagrams Types of Bonding

Ionic bonding Covalent bonding (Molecular) Metallic bonding Network covalent bonding

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Types of Bonding (cont’d) London Dispersion forces Dipole-Dipole forces Hydrogen Bonding

VSEPR Theory (Shapes) Physical Properties

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Bohr Diagrams (Review)

How do we draw a Bohr Diagram for - The F atom? - The F ion?

Draw Bohr diagrams for the atom and the ion for the following:

Al S C l Be

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Lewis Diagrams

LD provide a method for keeping track of electrons in atoms, ions, or molecules

Also called Electron Dot diagrams the nucleus (p+& n0) and filled energy

levels are represented by the element symbol

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Lewis Diagrams

dots are placed around the element symbol to represent valence electrons

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Lewis Diagrams

eg. Lewis Diagram for F

F•

• ••••

•

lone pair

lone pair

lone pair

bonding electron

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Lewis Diagrams

lone pair – a pair of electrons not available for bonding

bonding electron – a single electron that may be shared with another atom

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Lewis Diagrams

eg. Lewis Diagram for C

C•

• ••

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Lewis Diagrams

eg. Lewis Diagram for P

P•

• •••

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Lewis Diagrams

eg. Lewis Diagram for Na

Na•

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Lewis DiagramsFor each atom draw the Lewis diagram

and state the number of lone pairs and number of bonding electrons

Li Be Al Si

Mg N B O

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Lewis Diagrams for Compounds draw the LD for each atom in the

compound The atom with the most bonding

electrons is the central atom Connect the other atoms using single

bonds (1 pair of shared electrons) In some cases there may be double

bonds or triple bonds

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Lewis Diagrams for Compounds eg. Draw the LD for:

PH3

CF4

Cl2O

C2H6

C2H4

C2H2

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Lewis Diagrams for Compounds eg. Draw the LD for:

NH3 SiCl4 N2H4 HCN

SI2 CO2 N2H2 CH2O

POI CH3OH

N2 H2 O2

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Lewis Diagrams for CompoundsA structural formula shows how the atoms are connected in a molecule.

To draw a structural formula: replace the bonded pairs of electrons

with short lines omit the lone pairs of electrons

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Why is propane (C3H8) a gas at STP while kerosene (C10H22) a liquid?

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Why is graphite soft enough to write with while diamond is the hardest substance known even though both substances are made of pure carbon?

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Why can you tell if it is ‘real gold’ or just ‘fool’s gold’ (pyrite) by hitting it with a rock?

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‘As Slow As Cold Molasses’

‘All Because of Bonding’ 20

‘liquids’ @ -30 ºC

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Bonding

Bonding between atoms, ions and molecules determines the physical and chemical properties of substances.

Bonding can be divided into two categories:

- Intramolecular forces

- Intermolecular forces

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BondingIntramolecular forces are forces of attraction between atoms or ions.

Intramolecular forces include:

1. ionic bonding

2. covalent bonding

3. metallic bonding

4. network covalent bonding

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BondingIntermolecular forces are forces of attraction between molecules.

Intermolecular forces include:

5. London Dispersion Forces

6. Dipole-Dipole forces

7. Hydrogen Bonding

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Ionic and Covalent Bonding

ThoughtLab p. 161

Identify #’s 1 - 6

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Ionic Bonding Occurs between cations and anions –

usually metals and non-metals. An ionic bond is the force of attraction

between positive and negative ions. Properties:

conduct electricity as liquids and in solution hard crystalline solids high melting points and boiling points brittle

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In an ionic crystal the ions pack tightly together.

The repeating 3-D distribution of cations and anions is called an ionic crystal lattice.

Ionic Bonding

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Each anion can be attracted to six or more cations at once.

The same is true for the individual cations.

Ionic Bonding

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Ionic Bonding

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Covalent Bonding

Occurs between non-metals in molecular compounds.

Atoms share bonding electrons to become more stable (noble gas structure).

A covalent bond is a simultaneous attraction by two atoms for a common pair of valence electrons.

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Covalent Bonding

Molecular compounds have low melting and boiling points.

Exist as distinct molecules.

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Covalent Bonding

Molecular compounds do not conduct electric current in any form

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Property Ionic Molecular

Type of elements

Force of Attraction

Electron movement

State at room temperature

Metals and nonmetals

Non-Metals

Positive ions attract negative ions

Atoms attract a shared electron

pairElectrons move

from the metal to the nonmetal

Electrons are shared

between atoms

Always solids Solids, liquids, or gas

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Property Ionic Molecular

Solubility

Conductivity in solid state

Conductivity in liquid state

Conductivity in solution

Soluble or low solubility

Soluble orinsoluble

None None

None

None

Conducts

Conducts

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Metallic Bonding (p. 171) metals tend to lose valence electrons. valence electrons are loosely held and

frequently lost from metal atoms. This results in metal ions surrounded by

freely moving valence electrons. metallic bonding is the force of attraction

between the positive metal ions and the mobile or delocalised valence electrons

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Metallic Bonding

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Metallic Bonding This theory of metallic bonding is called

the ‘Sea of Electrons’ Model or ‘Free Electron’ Model

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Metallic Bonding This theory accounts for properties of metals

1. electrical conductivity

- electric current is the flow of electrons

- metals are the only solids in which electrons are free to move

2. solids- Attractive forces between positive cations

and negative electrons are very strong

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Metallic Bonding3. malleability and ductility- metals can be hammered into thin

sheets(malleable) or drawn into thin wires(ductile).

- metallic bonding is non-directional such that layers of metal atoms slide past each other under pressure.

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Network Covalent Bonding (p. 199)

occurs in 3 compounds (memorize these) diamond – Cn

carborundum – SiC quartz – SiO2

large molecules with covalent bonding in 3-d

each atom is held in place in 3-d by a network of other atoms

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Network Covalent bonding Properties:

the highest melting and boiling points the hardest substances brittle do not conduct electric current in any

form

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Strongest

1. Network Covalent (Cn ,SiO2 , SiC)

2. Ionic bonding(metal & nonmetal)

3. Metallic bonding (metals)

4. Molecular (nonmetals)Weakest

MP

& B

P decreases

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Valence Shell Electron Pair Repulsion theory (VSEPR)

The shape of molecules is caused by repulsion between valence electron pairs around the atoms in a compound.

Repulsion between valence electron pairs force them to move as far away from each other as possible.

Valence Shell Electron Pair Repulsion theory (VSEPR)

To determine molecular shapes, count the # of bonds and # of lone pairs on the central atom(s).

We will examine 5 molecular shapes

1. Tetrahedral (4 bonds; 0 lone pairs)

2. Pyramidal (3 bonds; 1 lone pair)

3. V-shaped (2 bonds; 2 lone pairs)

4. Trigonal Planar (3 bonds; 0 lone pairs)

5. Linear (2 bonds; 0 lone pairs)

For each molecule below draw the Lewis diagram and the shape diagram. HOCl H2Se H2O2

NBr3 C2F4 C2H6

CHCl3 CH3OH PBr3

I2 SiH4 HCN

SiH2O C2H2

Electronegativity - EN - p. 174 EN measures the attraction that an atom

has for shared electrons. A higher EN means a stronger attraction or

electrostatic pull on valence electrons EN values increase as you move:- from left to right in a period- up in a group or family

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Electronegativity & Covalent Bonds

Increases

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Electronegativity & Covalent Bonds polar covalent bond

- a bond between atoms with different EN- the bonding pair is attracted more

strongly to the atom with the higher EN

ClH

δ−δ+

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bond dipole

nonpolar covalent bond- a bond between atoms with the same

EN- the bonding pair is shared equally

between the atoms

Complete: #’s 7 – 9 on p.178

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Electronegativity & Covalent Bonds

Electronegativity & Covalent Bondspolar molecule

- a molecule in which the bond dipoles do not cancel each other

- a polar molecule has a molecular dipole that points toward the more electronegative end of the molecule.

eg. HCN

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CH

Electronegativity & Covalent Bondsnonpolar molecule

- a molecule in which the bond dipoles cancel each other

OR

- there are no bond dipoles

eg. CO2 PH3

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Electronegativity & Covalent BondsTo determine whether a molecule is polar:

- draw the Lewis diagram & shape diagram

- draw the bond dipoles & determine whether they cancel

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Intermolecular Forces

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Strongest

1. Network Covalent (Cn ,SiO2 , SiC)

2. Ionic bonding(metal & nonmetal)

3. Metallic bonding (metals)

4. Molecular (nonmetals)Weakest

MP

& B

P decreases

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To compare mp and bp in covalent compounds you must use:

- London Dispersion forces (p. 204)

(in all molecules)

- Dipole-Dipole forces (pp. 202, 203)

(in polar molecules)

- Hydrogen Bonding (pp. 205, 206)

(when H is bonded to N, O, or F)

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Intermolecular Forces (p. 202)

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Intermolecular Forces Covalent compounds have low mp and

bp because attractive forces between molecules are very weak.

Intermolecular forces were studied extensively by the Dutch physicist Johannes van der Waals

In his honor, two types of intermolecular force are called Van der Waals forces.

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Intermolecular Forces Intermolecular forces can be used to

account for the physical properties of covalent compounds.

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Intermolecular Forces

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F F

FF


• LD forces exist in ALL molecular elements & compounds.

•The positive charges in one molecule attract the negative charges in a second molecule.

• The temporary dipoles caused by electron movement in one molecule attract the temporary dipoles of another molecule.

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The strength of these forces depends on:a)the number of electrons

more electrons produce stronger LD forces that result in higher mp and bpeg. CH4 is a gas at room temperature.

C8H18 is a liquid at room temperature.C25H52 is a solid at room temperature.Account for the difference.

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Two molecules that have the same number of electrons are isoelectronic

eg. C2H6 and CH3F

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b) shape of the molecule molecules that “fit together” better will experience stronger LD forces

eg. Cl2 vaporizes at -35 ºC while C4H10 vaporizes at -1 ºC. Use bonding to account for the difference.

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2. Dipole-dipole Forces

- occur between polar molecules

- the δ+ end of one polar molecule is attracted to the δ- end of another polar molecule (& vice-versa)

eg. Which has the higher boiling point CH3F or C2H6 ?

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p. 202

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3. Hydrogen Bonds

- a special type of dipole-dipole force (about 10 times stronger) - only occurs between molecules that contain a H atom which is directly bonded to F, O, or N ie. the molecule contains at least one H-F, H-O, or H-N covalent bond.

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3. Hydrogen Bonds

-the hydrogen bond occurs between the H atom of one molecule and the N, O, or F of a second molecule.

eg. Arrange these from highest to lowest boiling point

C3H8 C2H5OH C2H5F

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p. 206

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NOTE: To compare covalent compounds you must use:

- London Dispersion forces

(all molecules)

- Dipole-Dipole forces

(polar molecules)

- Hydrogen Bonding

(H bonded to N, O, or F)

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Alchem worksheet pp. G32, 33

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p. 226 #13

Omit parts g), j) – o), q), u), & v)

- Answers on p. 815 for #13

- Incorrect answers

c), d), & s)

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p. 210

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Intermolecular Forces1. Use intermolecular forces to explain the following:

a) Ar boils at -186 °C and F2 boils at -188 °C .

b) Kr boils at -152 °C and HBr boils at -67 °C.

c) Cl2 boils at -35 °C and C2H5Cl boils at 13 °C .

2. Examine the graph on p. 210:

a) Account for the increase in boiling point for the hydrogen compounds of the Group IV elements.

b) Why is the trend different for the hydrogen compounds of the Group V, VI, and VII elements?

c) Why are the boiling points of the Group IVA compounds consistently lower than the others.

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3.Which substance in each pair has the higher boiling point. Justify your answers.

(a) SiC or KCl

(b) RbBr or C6H12O6

(c) C3H8 or C2H5OH

(d) C4H10 or C2H5Cl79

2. Examine the graph on p. 210:

a) Account for the increase in boiling point for the hydrogen compounds of the Group IV elements.

b) Why is the trend different for the hydrogen compounds of the Group V, VI, and VII elements?

c) Why are the boiling points of the Group IVA compounds consistently lower than the other compounds.

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p. 226 #’s 13 & 14

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Electronegativity

Electronegativity is a result of the space between the nucleus and the electrons

As the number of protons in the nucleus increases, the attractive force on the electrons increases, pulling them closer to the nucleus

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Electronegativity and Ionic Bonds Because the EN of metals is so

low, metals lose electrons to form

cations Nonmetals gain electrons to form

anions because the EN of nonmetals is relatively high

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Electronegativity and Ionic Bonds When ions form, the resulting

electrostatic force is an ionic bond

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Electronegativity and Covalent Bonds Atoms in covalent compounds can

either have: the same EN

eg. Cl2 , PH3, NCl3 different EN

eg. HCl

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Electronegativity and Covalent Bonds

Atoms that have different EN attract the shared pair of valence electrons at different strengths

The atom with the higher EN exerts a stronger attraction on the shared electron pair

eg. H2O

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Since the oxygen atom has a higher EN the bonding electrons will be pulled closer to the oxygen atom

This results in slight positive and negative charges within the bond.

These charges are referred to as “partial charges” and are denoted

with the Greek letter delta (δ). 87


The region around the oxygen atom will be slightly negative, and around the hydrogens will be slightly positive

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The symbol, δ+ represents a partial positive charge (less than +1) and δ− represents a partial negative charge (less than −1).

Since the bond is polarized into a positive area and a negative area the bond has a “bond dipole”.

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Electronegativity and Covalent Bonds The arrow points to

the atom with the higher EN.

p.178

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Electronegativity and Covalent Bonds Covalent bonds resulting from

unequal (electronegativities) sharing of bonding electron pairs are called Polar Covalent Bonds

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Electronegativity Homework

#’s 7, 8, & 9 - p. 178 #’s 1, 2, & 3 - p. 180

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Bond Energy (pp. 179-180)

1. Describe the forces of attraction and repulsion present in all bonds.

2. What is bond length?3. Define bond energy.4. Which type of bond has the most energy?5. How can bond energy be used to predict

whether a reaction is endothermic or exothermic?

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Test Outline Bohr Diagrams (atoms & ions) Lewis Diagrams (Electron Dot) Ion Formation Ionic Bonding, Structures & Properties Covalent Bonding, Structures & Properties

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Test Outline Metallic Bonding Theory& Properties Network Covalent Bonding & Properties Electronegativity Bond Dipoles & Polar Molecules VSEPR Theory LD, DD, & H-bonding Predicting properties (bp, mp, etc.)

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Unit 2: Chemical Bonding Chemistry2202 1. Outline Bohr diagrams Lewis Diagrams Types of Bonding ...

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Transcript of Unit 2: Chemical Bonding Chemistry2202 1. Outline Bohr diagrams Lewis Diagrams Types of Bonding ...