Ultra Pure Water Chemical / Waste Process
Transcript of Ultra Pure Water Chemical / Waste Process
Ultra Pure Water
3 Separation SystemsYour Purification Partner
Electro-deionization (EDI) combines two, well established,
water treatment methods; electro-dialysis and ion exchange
bymeans of ion exchanger resins. This technique makes it possible
anode to remove dissolved salts without chemical regeneration, at
low cost in terms of the energy used.
ELECTRO DEIONIZATION
Before being fed into the electro-deionization module the
permeate produced by the reverse osmosis system is divided into
three sub-streams. The EDI feed water is passed through the diluate
chambers, which, are filled with ion exchange resin. Through the
action of the electric field the anions migrate through the resin bed in
the direction of the anode. As a result they pass through the anion-
permeable membrane and arrive in the adjacent stream of
concentrate. The cations migrate through the resin bed in the
direction of the cathode, pass through the cation-permeable
membrane, and so likewise enter the stream of concentrate. With
the concentrate stream, the ions are expelled from the module. The
electrolyte stream flushes out the gases that are created at the
electrodes, along with the ions, and carry them cut of the module.
As a result of the electrical voltage, water splitting occurs in the
resin bed of the diluate chamber The H+ and OH- ions that are
needed for the regeneration of the exchange resin are created.
These regenerate the resin bed on an ongoing basis. In this way
continuous operation can be maintained, without any need to switch
oft the system for regeneration purposes.
Description of the EDI process
Steam generators
Laboratories
Pharmaceutical industry
Semiconductor industry
Optics industry
Glass costing
Metal processing industry
Applications requiring ultra-pure water
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Areas of application
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Chemical / Waste Process
Waste Water Treatment
Plating Bath Purification
Plating Rinse Recycling
Precious Metal Recovery
Ultra Pure Water
3 Separation SystemsYour Purification Partner
105, Vakharia Industrial Estate
Ram Mandir Road, Goregaon (W)
Mumbai - 400104, INDIA.
Tel : +91-22-32201863
Cell: +91-98923 45754
www.separationsystems.in
3 Separation SystemsYour Purification Partner
Waste Water Treatment
Flow Diagram
Equalization & Neutralization
Precipitation & Coagulation
Flocculation
Clarifier, Inclined Plate:
Filter PressSand/Carbon
Filter
FLOW CHART OF WASTE WATER TREATMENT
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Automotive part suppliersJewelry mfgMachine tool mfg.Metal forming such as stamped metal parts that require plating of various types. Building materials, cadmium plated nuts, bolts etc.. AerospaceWire forming - nails, screws etcAppliance makersElectronics – gold and silver plating of electrical connectors etc.
Electroplating shops, captive or independent
Typical industries include:
Hormon Free Dairy
el baT r uoY ot hserF
smraF lac
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Enviromental Justice
Natural Resourse
Stewardship
Social Environmental
Energy Effieciency
Incentives for use of
natural resourses
Envireonmental Economic
Education
Community
Social Cost Savings
Economic Growth
Research &
Development
Economic
Sustainability
Natural Resource Use
Ennironmental Managament
Pollution Prevention
Envirenmental
Business Ethics
Fair Trade
Economical-Social
ter Ma aw naet gs ea mW ent
Energy Efficiency
PACKAGED SYSTEMS :
3 Separation Systems has a great deal of experience and technical knowledge in designing custom packaged systems for your
wastewater treatment needs. We dedicate a great deal of time and effort to ensuring that the system we recommend will be a
great fit for your application, and will be cost effective as well.
Fully engineered skid mounted treatment systems are an excellent choice for fully automatic, reliable wastewater treatment
in a compact, easy to install and use package.
Systems can be configured for a wide variety of wastewater conditions, making them the most versatile systems available.
Treatment systems come complete with all the components integrated and skid mounted to make a complete wastewater
treatment system. The integral chemical mixing and separation chambers, automatic pH adjusting system, chamber mixers,
chemical pumps, sludge dewatering, and system control panel are included.
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Chemical Reaction Systems :
We manufactures following reaction systems.
pH adjustment
pH neutralization
multi-stage chemical reaction systems
flash mix and flocculation systems
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Advanced Wastewater Treatment Solutions :
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Disinfection
Activated Carbon
Filtration
Ion Exchange
3 Separation SystemsYour Purification Partner
Plating Bath Purification / Recovery
Chromic Acid Bath Purification
Chromic Acid Rinse Water Recycle
Nickel & Copper Recovery
Precious Metal Recovery
Spent Pickling Bath Purification
Chromic acid baths are used in metal working plants for plating and
passivation of metal surfaces. A typical spent chromium plating bath
contains about 300 g/L of chrmic acid and 25 g/L of Cu+2, Fe+3 and Cr+3
cause of the dissolution of a small amount of the metal piece being plated
results in high current densities, decreased bright range,?increased
tendency to burn, rough and pitted deposits. Even chromic baths used for
aluminum are also can be treated cause they are having concentration of
100 g CrO3/L and 10 g Al2O3/L. This baths treated with ion exchange
systems will have longer running life results in overall economic of the
plant.
These rinse water contain about 20 to 200 ppm of chromates with
metal impurities(Cu+2, Fe+3 and Cr+3) at 5 to 50 ppm levels. This chromic is
recovered with ion exchange system to get it back to the main plating bath
while effluents are converted into clean demineralized water which will be
taken back to the rinsing tank.
In all plating shops where Ni & Cu plating is carried out, these is wasted
in terms of rinse and waste water. The concentration of these metals can be
found in the ppm level to gms level for different industries in generally
acidic forms. This are treated to take the metal back to the main plating
bath.
The high price of noble or precious metals such as gold, platinum and
silver makes a high dent to the economic of such plants. Systems are very
small and compact in design with high efficiency to reduce the leakage to
ppt levels. The metal is then recovered by incineration in powder form.
The hydrochloric acid used for the pickling process gets contaminated
with Fe2+ and Zn2+ .At these chloride concentrations Zn2+ forms anionic
complex, ZnCl4. Iron(Fe2+) forms such complexes but at very high HCl
concentrations (>9N) while Fe3+ forms such complexes at 1.5 N HCl. The
purification process will be double benefit since it produces ferric chloride
which can be used for waste water treatment and HCl is recovered for bath.
Reduces Metal purchases
Reduce waste treatment costs
Lower operating costs
Increase productivity
Reduce power usage by 25%
Eliminate defects
Provide consistent bath performance
Improve quality
99% recovery from rinses
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Benefits
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IX column
Acid dosing station
Caustic dosing station
Dilution pump
Valves and fittings
Instrumentation and
automatic control
Feed pump
General Systems IncludesSpent Pickling Bath Purification
Copper Recovery
Nickel Recovery
Chromic Bath / Rinse Water Recycle
Precious Metal Recovery