nn rrrrn A rrnr* xr i r A n ~ r n ~ r u e PANC un h Y X UQI C U ~ T NGH!_A VIET NA-M_ DV N l V A I V L V fi L V L \ U L \ U l l y - Y L . V **VL1

DQc l$p - Tv do - Hqnh phlic ~ 8 : 22/20 151TT-BKHCN

H i NGi, ngiy 1 1 thring 1 1 nlim 201 5

THONG TU V; vitc ban hanh va thvc hien "Quy chuhn thugt gu6c gia

ve xHng, nhien lieu dilizen vP nhi8n ligu sinh hpc"

Clin cti Ludt TiEu chudn vh Quy chukn kjj thudt ngiy 29 thdng 6 nlim 2006 vh Nghj #inh sd 127/2007/ND-CP ngiy 01 thbng 8 ndm 2007 ctia Chinh phli guy dinh chi tiit thi hhnh m@t sb diiu ctia Ludt Ti& chudn v i Quy chudn kjj thudt;

Ciin cli Nghj djnh sd 20/2013/ND-CP ngiy 26 thdng 02 nlim 2001 ctia I "

Chinhphli quy djnh chtic nling, nhiem vg, guyin hqn vh co. criu t6 chtic ctia B@ Khoa hoe vh C6ng nghe;

The0 d; nghj ctia ~ 6 n ~ cgc mrdng ~ 6 n ~ cvc TiEu chudn Do l u h g chdt luqng v i Vg trudng Vg Phhp chk

B@ hrdng B@ Khoa hoe v i C6ng nghe ban hhnh Th6ng tu v i viec ban hinh v i thvc hien 'Quy chudn kjj thudt gudc gia vk xdng, nhiin lieu digzen v i nhizn lieu sinh hoe".

£lieu 1. Ban hknh kkbm the0 ThBng tu niy Quy chuhn @ thuat qubc gia vk xhg , nhien lieu diezen va nhien lieu sinh hoc (QCVN 1 :20 15BKHCN).

Biiu 2. ThBng tu nay cb hi@ luc thi hAnh kkd tir ngay 0 110 1/20 16.

Bieu 3. ThBng tu nay thay thk ckc ThBng tu sau:

1. Th6ng tu s8 2012009lTT-BKHCN ngAy 300/12009 cfia Bo t n r h g Ba Khoa hoc v& CBng nghe vk viec ban h h h VA thuc hien "Quy chuh ky thuat qu6c gia vk x h g , nhisn lieu diezen 2012 cfia Bo t n r h g Bo Khoa hoc va CBng nghe vB nhien lieu sinh hoc";

2. ThBng tu s8 14120 12lTT-BKHCN ngiy 121712012 cua Ba trutmg Ba Khoa hoc vA CBng nghe v& viec sira dbi, b6 sung ~ i k u 1 ThBng tu s6 2012009lTT-BKHCN ngiiy 301912009 cCa BQ t n r h g Be Khoa hoc vB CBng nghe vk vi&c ban hknh v i thuc hien "Quy c h u b kk thu& qu8c gia vk x k g , nhien lieu diezen v i nhien lieu sinh hoc";

3. ThBng tu s8 3012014lTT-BKHCN ngay 1511 012014 cua Ba tn rhg B6 Khoa hoc v l CBng nghe v6 vigc sua dai, b6 sung mat sb quy dinh cGa Quy

* c h u b i j thust qubc gia QCVN 1:2009/BKHCN v& xgng, nhien lieu diezen vB nh ih lieu sinh hoc ban h a kkbm the0 ThBng tu s6 2012009l'IT-BKHCN ngay 301912009 cfia Bij t m h g Bo Khoa hoc v& C6ng nghe.

Bieu 4. C b co quan, t6 chuc, cii n h h c6 hoat dong lien quan din viec nhap khku, sin xu&, ch& bikn, pha ch&, phPn ph6i va ban 1e va cac 1od xiing, nhien lieu diezen vB nhien lieu sinh hoc phiii thuc hien c8c quy dinh tai

Quy chuan ky thuet qu6c gia v$ xgng, nhi&n lieu diEzen va nhien lieu siidi hpc ban hanh kem the0 ThGng tu nay.

~ i & u 5. ~ 8 n ~ cyc t n r h g ~ 8 n ~ cpc Ti6u chuan Do l u h g c h i t llogmg, Thu tnrbng cac co quan, t8 chirc, ca nhfin c6 liZn quan chju trach nhiem thi hanh Th6ng tlo nay./.

KT. BO T R U ' ~ G Noi nhgn: - Thi~ tuong CP (dk bao cao); - Cac Ph6 Th6 tuang CP (dk bao cao); - Cac Bo, ca quan ngang Ba, ca quan thuac CP; - UBND chc tinh, t h h h ph6 truc thuac TW; - Vien Kikm sat nh2n d2n tbi cao; - Toi i n nhfin d2n tbi cao; - CBng bao VPCP; - Cuc Kikm tra VBQPPL (BQ Tu phap); - Luu: VT, TDC.

C6NG HOA XA HOI C H ~ NGHiA VlET NAM

QCVN I :2015/BKHCN

QUY CHUAN KY THUAT QUOC GIA VE XANG, NHIEN LIEU DIEZEN

VA NHIEN LIEU SlNH HOC

National technical regulation on gasolines, diesel fuel oils and biofuels

QCVN 1 :20151BKHCN

Lwi noi diu

QCVN 1 :20151BKHCN thay th6 QCVN 1 : 20091BKHCN.

QCVN 1:2015/BKHCN do Ban soan th io Quy chub kF thuat

qu6c gia v& x5ng d i u va nhiGn lieu sinh hoc bi6n soan, ~ 6 n g cuc

Tieu chub Do lvwng ~ h A t Ivwng trinh duy$t va dvwc ban hanh the0

Th6ng t v s6 2212015rTT-BKHCN ngay 11 thang 11 n5m 2015 clja

B6 trulbng Ba Khoa hoc va Cdng ngli$.

QCVN 1 :20151BKHCN

QUY CHUAN KP THUAT QUOC GIA

VE XANG, NHIEN LIEU OIEZEN VA NHIEN LIEU SlNH HOC

National technical regulation on gasolines, diesel fuel oils and biofuels

1. QUY D!NH CHUNG

1 .I. Pham vi di iu chinh

1.1.1. Quy chuan ky thuat nay quy djnh mivc giwi han d6i vwi cac chi tieu

kv thuat lien quan d6n an toan, s6c kh6e, m6i trwwng va cac y6u chu v& q u i n Iy 0

ch i t luwng d6i vwi cac loai x ing, nhien lieu diezen va nhien lieu sinh hoc, bao gbm:

- Xgng kh6ng chi, x5ng E5, x i ng E10;

- Nhien lieu diezen, nhien lieu diezen 65;

- Nhien lieu sin h hoc g6c: Etanol nhien lieu va nhien lieu diezen sinh hoc g6c

61 00.

1.1.2. Quy chusn ky thugt nay kh6ng ap dung d6i vwi cac loai nhien lieu

siv dung trong nganh hang kh6ng va muc dich qu6c phong.

1.2. D6i twwng ap dung

Quy chuan ky thuat nay ap dung dki vbi cac cw quan, t6 chivc, ca nhiin co

hoat dong lien quan d6n viec nhgp kh$u, s i n xui t , pha ch6, phiin ph6i va ban lit cac loai

xing, nhi611 lieu diezen va nhien lieu sinh hoc tai Viet Nam.

1.3. Giai thich tiv ngk

Trong Quy chuan ky thugt nay, cac tiu ng0 dwwi d i y dvwc hi& nhv sau:

1.3.1. Xiing khbng chi

H6n hwp d5 bay hwi clja cac hydrocarbon I6ng co ngubn g6c tiv dhu m6 vwi khoing

nhiet do s6i th6ng thvwng tiu 30 O C d6n 215 OC, thvwng co chiva lvwng nh6 phu gia

phlj hwp, nhvng kh6ng co phu gia chiva chi, dvwc siv dung lam nhien lieu cho dong cw

d6t trong.

QCVN 1 :20151BKHCN

H6n hwp clja x5ng kh6ng chi va etanol nhien lieu, co ham Ivwng etanol tiu 4 %

ddn 5 O/O theo th6 tich, ky hieu la E5.

1.3.3. Xang E l 0

H6n hwp c i a x2ng kh6ng chi va etanol nhien lieu, co ham Ivwng etanol tiu 9 %

d6n 10 O/O the0 th6 tich, ky hieu la E10.

1.3.4. NhiQn lieu diQzen (DO)

~ 6 n hqp hydrocacbon 16ng co ngu8n g6c tir d5u m6 vwi khoing nhiet do s6i

trung binh phh hwp d6 s b dung lam nhien lieu cho dong cw diezen lam viec theo

nguyen Iy t y chay khi nen dvwi ap su5t cao trong xylanh.

1.3.5. Nhien lieu di6zen B5

H6n hwp clja nhien lieu diezen va nhien lieu diezen sinh hoc g6c, co ham Ivwng

metyl este c i a axit beo (FAME) tir 4 O h d6n 5 O/O the0 th6 tich, ky hi& la 65.

1.3.6. NhiQn lieu sinh hoc g6c

1.3.6.1. Etanol nhi6n lieu

Etanol nhien lieu g8m etanol nhien lieu kh6ng bi6n tinh va etanol nhien lieu

bidn tinh. - 1.3.6.1.1. Etanol nhien lieu khbng bi6n tinh

Etanol co cac tap chht th6ng thvtrng s5n sinh trong qua trinh s5n xu&

nhien lieu (k6 c5 nvwc).

1.3.6.1.2. Etanol nhiQn lieu bibn tinh

Etanol nhien lieu kh6ng bi6n tinh dvqc pha them cac c h i t bidn tinh nhv xsng,

naphta vwi ham lvgng tir 1,96 % d6n 5,O % th6 tich.

* 1.3.6.2. NhiQn lieu diezen sinh hoc &c

Nhien lieu dvqc chuy6n hoa t k nguyen lieu sinh hoc ( d i u thwc v$t hoac m&

dong v$t), co thanh phan chi r~h la metyl este clja axit beo mach dai, chva pha tron vwi

cac loai nhien lieu khac, s12 dung d6 pha tron thanh r~hien lieu cho dong c o diezen,

ky hi@ la 6100.

QCVN 1 :20151BKHCN

2. QUY D!NH KV THUAT

2.1. X ing kh6ng chi, x5ng E5, x ing E l 0

2.1.1. Xiing kh6ng chi

Cac chi ti6u kv thu$t cw b i n va phlvwng phap thG tlvwng ivng clja x2ng kh6ng chi

duwc quy djnh trong B5ng 1.

Bang 1 - Chi tieu chi t lulwng cw ban cGa xing kh6ng chi

I -- - -

I Ten chi tieu 1 Mivc 2 MILc 3 1 Mivc 4 I Phwvng phPp thiv I

I 1. Tri s5 6ctan (RON) min. 1 90192195 1 92/95/98 1 92/95/98 TCVN 2703 (ASTM D 2699) 1 J 2. H i m lvqng chi, glL max. 0,013 1 0,013 1 0,005 1 TCVN 7143 (ASTM D 3237) 1

3. Thanh phan cat phin doan: - Digm s6i d iu , OC

- 10 % th6 tich, OC max.

- 50 % th6 tich, OC

- 90 % t h i tich, OC max.

- Digm s6i c h i , OC max.

- C$n cubi, % th6 tich max.

4. Ham lvwng Iuu huynh, mglkg max. ,

I TCVN 6701 (ASTM D 2622); 1 1 TCVN 7760 (ASTM D 5453) 1

I

Bao cao

70

max. 120

190

215

-- 200

500

5. Ham lwwng benzen, 1 TCVN 31 66 (ASTM D 5580); I

% the tich max 1 2,5 2,s i 1,O TCVN 6703 (ASTN D 3606) 1 I

6. Hydrocacbon tholm, % the tich max. 1 40 1 40 1 40 TCVN 7330 (ASTM D 1319)

Bao cao

70

70-120

190

210

2,o

150

7. Ham lvwng olefin, % th6 tich TCVN 7330 (ASTM D 131 9)

8. Ham Iuwng oxy, % khoi Ivwng max. 2,7 2,7 2,7 TCVN 7332 (ASTM D 481 5)

-- --

9. ~ 6 n g ham luwng kim loai (Fe, Mn), mglL max. 5 5 5 TCVN 7331 (ASTM D 3831)

Bao cao

7 0

70-120

190

21 0

2,o

50

10. Ngoai quan Trong suat, kh6ng

ph5n lwp va kh6ng

co tap ch i t

Trong suBt, kh6ng

ph5n Iwp va kh6ng

co tap chat

Trong subt,

kh6ng ph5n Iwp va kh6ng

co tap ch i t

TCVlV 7759 (ASTM D 4176)

QCVN I :2015/BKHCN

2.1.2. Xang E5

2.1.2.1. Cac chi tieu ky thuat cw b5n va phulwng phap thljl tluwng ivng clja x3ng E5

dulwc quy djnh trong B5ug 2.

Bang 2 - Chi ti6u ch6t I v y g cw ban cua xHng E5

T9n chi tieu 1 Mivc2 1 Mipc 3 MiYc4 Phrsong ph lp thb I 1. Trj s6 actan (RON) min.

2. Ham llvgng chi, g/L max.

3. Thanh ph$n cat ph5n doan: - 0i6m s6i dau, OC

- 10 % the tich, OC max.

- 50 % the tich, OC

- 90 % the tich, OC max.

- ~ i e m s6i cuai, OC max.

Bao cao

70

max. 120

190

215

92/95/98

0,013

Bao cao

70

70 - 120

190

21 0

92/95/98 TCVN 2703 (ASTM D 2699)

TCVN 2698 (ASTM D 86)

Bao cao

7 0

70 - 120

190

21 0

TCVN 6701 (ASTM D 2622): 1 TCVN 7760 (ASTM D 5453) 1

- Can cuai, % the tich max.

5. Ham lvpng benzen, TCVN 3166 (ASTM D 5580); % the tich max. TCVN 6703 (ASTM D 3606)

2,o

7. Ham llvwng olefin, I % the tich max. ( 38

4. Ham llvwng llvu hujlnh, mg/kg max.

1 6. Hydrocacbon thom, I YO the tich max. 1 40 40 4 0 TCVN 7330 (ASTM D 131 5)

I 8. Ham Ivwng oxy, % khbi lvwng

2,o

I

TCVN 7330 (ASTM D 131 9)

500

2,o

TCVN 7332 (ASTM D 481 5)

150 50

9. Ham llvqng etanol, % the tich 1 4 - 5 4 - 5 4 - 5 TCVN7332(ASTMD4815)

Trong suat, kh6ng

phin lwp va kh6ng

co tap ch i t

10. ~ 8 n g ham lulwng kim loai (Fe, Mn), mg/L max. 5

Trong suBt,

kh6ng ph5n Iwp va kh6ng

co tap chat

11. Ngoai quan

.

TCVN 7331 (ASTM D 3831 )

Trong suat, kh6ng

ph5n lwp va kh6ng

co tap ch i t

TCVN 7759 (ASTiv1 D 41 76)

2.1.2.2. Etanol nhikn lieu dung 66 pha trOn vwi x8ng khBng chi ph5i phu hqp vwi

cac quy djnh trong di6m 2.3.1 k h o i n 2.3 Muc 2 c l ja Quy c h u i n kv thugt nay.

QCVN 1 :20151BKHCN

2.1.3. X ing E l 0

2.1.3.1. Cac chi ti& ky thu$t col b i n va phuwng phap thiv tuolng ivng clja x i n g E l 0

duwc quy djnh trong B5ng 3.

Bang 3 - Chi ti6u chi t llvwng cw b5n clja xHng E l 0

Ten chi tieu 1 Mivc2 Mivc3 M(vc4 Phrvongphipthiv ~ 1 0, 1. Trj 56 Bctan (RON)

1 2. Ham lwqng chi, g/L max. TCVN 7143 (ASTM D 3237) 1 TCVN 2698 (ASTILI D 86) 3. Thanh phan c$t

phin doan: - Diem s6i dau, 'C Bao cao

7 0

Bao cao

7 0

70 - 120

Bao cao

7 0

70 - 120

190

21 0

1 - 10 Oh the tich, OC max. n

- 50 Oh the tich, OC I

, max. 120

1 1 - Can cuhi, % thd tich m a x 2.0 1 2,O 2,O , I

- 90 Oh the tich, OC max.

- ~ i e m s6i cu6i, OC max.

/ 4 Ham lvqng llvu huQnh, I mg/kg max. 1 500 150

TCVN 6701 (ASTM D 2622); ~ 5 0 I TCVN 7760 (ASTM D 5453) 1

190

21 5

5. Ham llvwng benzen, % th6 tich max. 1 2.5 / 2.5

190

21 0

6. Hydrocacbon thwm, % thd tich max. 1 40 1 40

1,o

4 0 ) TCVN 7330 (ASTM D 131 9) ' TCVlV 31 66 (ASTM D 5580); TC\/N 6703 (ASTM D 3606)

7. Ham lvqng olefin, Oh th6 tich max. 1 38 1 30

1 30 1 TCVN 7330 (ASTM D 1 31 9)

8. Ham lvqng oxy, 1 Oh kh6i lvqng max. 3.7 1 3,7 3,7 1 T cvN 7332 (AsTM D 481 5)

9. Ham lvqng etanol, 1 Oh thd tich 1 9 - 10 9 - 1 0 1 9 - 1 0 1 TCVN7332(ASTMD4815)

10. Ham lvwng nvwc, % the tich max. ASTM E 203

11. ~ 6 n g ham lvwng kim loai (Fe, FAn), mg/L max. 5

Trong suat, kh6ng

ph in 16p va kh6ng

co tap ch i t

5

Trong suat,

kh6ng ph in Iwp va kh6ng

co tap chat

5

Trong su6t,

kh6ng ph in lwp va kh6ng

co tap chat

TCVN 7331 (ASTM D 3831)

TCVN 7759 (ASTM D 41 76) 12. Ngoai quan

QCVN I :20151BKHCN

2.1.3.2. Etanol nhien ligu dung d& pha tran vwi x8ng kh6ng chi p h i i phu hwp vwi

cac quy djnh trong di6m 2.3.1 kho5n 2.3 Muc 2 clja Quy chusn ky thugt nay.

2.2. Nhien lieu diezen, nhien lieu dienen B5

Cac chi ti& ky thugt cw b i n va phlrwng phap thiv twwng k n g clia nhien lieu diezen

dlrwc quy djnh trong B5ng 4.

Bang 4 - Chi tieu chat luqng ccr ban cua nhien lieu diezen

Ten chi tieu

1. Ham llrwng llru huynh,

max.

3. Nhiet do cht tai 90 J/o th6 tich thu h6i, OC max. 1 360 360 355 1 TCVN 2698 (ASTM D 86)

M6c 2

2. Xetan min.

- Trj s6 xetan

- Chi s6 xetan I )

4. Di8m chwp chay c6c kin, OC min. TCVN 2693 (ASTM D 93)

500

M 6 c 3

46

4 6

I 6. Di&m d6ng dac 2'. OC rnax I + 6 I + 6 I + 6 I TCVN 3753 (ASTM D 97) I

350

5. Do nhwt dong hoc tai 40 OC, mm2/s 1 2.0 - 4.5 2,O - 4.5 1 2,O - 1,5 TCVN 3171 (ASTM D 445)

7. Ham Iuwng nuwc, max. 1 200 1 200 200 TCVN 3182 (ASTM D 6304)

IMCc 4

48

4 8

,-

5 0

') C6 th8 B p dung chi 56 xetan thay cho tri s6 xCtan, n6u kh6ng c6 s l n dong cw chuan dB xac djnh trj s6 xQtan va kh6ng s b dung phu gia c5i thien trj s6 xQtan.

Phwwng phap thb

TCVN 6701 (ASTM D 2622);

TCVN 7760 (ASTM D 5453);

TCVN 31 72 (ASTM D 4294) I 50

50

8. Ham Iuwng chat thwm da vong (PAH), % kh6i Iuqng max.

*' VBO mOs d6ng, & cac tinh, th inh ph6 phia BBC, c i c n h i s i n xuat, kinh doanh ph in ph6i nh'ibn lieu ph i i d i m b i o cung cap nhien lieu diQzen c6 di6m d6ng dgc thich hqp sao cho nhien lieu kh6ng g i y i n h hlr&ng d6n s y van hanh clja dong cw tai nhiet do m6i truwng.

h

TCVN 7630 (ASTM D 61 3)

TCVN 3 1 80 (ASTM D 4737) 1

- 11 1 1 I ASTM D 51 86; ASTM D 6591

QCVN 1 :20151BKHCN

2.2.2. Nhien lieu diezen B5

2.2.2.1. Cac chi tieu kj? thugt cw b i n va phvwng phap thG tvwng ivng c i a

nhien lieu diezen B5 dvwc quy dinh trong Bang 5

Bang 5 - Chi tieu c h i t lwwng cw ban cua nhien lieu diezen B5

I T6n chi ti6u

2. Tri sb xetan min. 1 , 46 1 48 1 50 TCVN7630(ASTMD613) 1

1. Ham lwqng lwu hujlnh,

mg/kg max.

A -- - -

3. Nhiet do cat tai 90 % 1 the tich thu h6i, OC max. 1 360 1 360 355 1 TCVN 2698 (ASTM D 86)

Mwc2 Ml ic3

4. ~ i e m chwp chay c6c kin, OC min. 1 55 55 1 55 1 TCVN 2693 (ASTM D 93)

Ml ic4 Phwwng phap thiv 1 500

5. DO nhwt dong hoc tai 40 OC, mm2/s TCVN 3171 (ASTM D 445)

350

6. D i i m ddng dac ", OC max. t--

1 6. tidm luqng chat thwm , da vong (PAH), O h kh6i lwwng max.

5 0

7. Ham lwqng nvwc, mg1k.g max.

TCVN 6701 (ASTM D 2622);

TCVN 7760 (ASTM D 5453);

TCVN 3 1 72 (ASTM D 4294)

+ 6

I I 200

1 200 1 200

,--

+ 6

TCVN 31 82 (ASTM D 6304)

9. Ham lvqng metyl este axit beo (FAME), % th6 tich

') V i o mlia d6ng, b cac tinh, th inh phb phia ~ a c , cac n h i s i n xu&, kinh doanh ph in phbi nhien lieu ph i i d5m b i o cung cap nhien lieu diezen co di&m d6ng dac thich hwp sao cho nhien lieu kh6ng gay i n h hwbng d&n s y van hhnh clja dong cw tai nhiet do m6i trvwng.

4 - 5

10. Bn dinh oxy hoa, f mgI100 mL 25 ~ 25 25

2.2.2.2. Nhien lieu diezen sinh hoc g6c dung d& pha tron vwi nhien lieu diezen

ph5i phu hqp vwi cac quy djnh trong di6m 2.3.2, kho5n 2.3, Muc 2 clja Quy chuin kj? thuat

nay.

+ 6

4 - 5 4 - 5

ASTM ASTM D D 7462; 7545

TCVN 3753 (ASTM D 97) I

TCVN 8147 (EIV 14078)

QCVN I :2015/BKHCN

2.3. Nhien lieu sinh hoc g6c dung d& pha trQn xing E5, xing E l 0 va nhien lieu

diezen B5

2.3.1. Etanol nhien lieu

2.3.1.1. Etanol nhien lieu khBng bi6n tinh

C5c chi tieu kj i thuat cw b i n va phulwng phap t he tvwng Gng c i a etanol nhien lieu

khdng bi6n t inh duwc quy djnh trong B5ng 6.

Bang 6 - Chi tieu ky thugt cda etanol nhien lieu khBng bi6n tinh

2.3.1.2. Etanol nhien lieu bi6n tinh

Ten chi ti6u

1. Ham lulwng etanol, % the tich min.

2. Ham lulwng metanol, % th6 tich max.

3. Ham lulwng nvwc, % th6 tich max.

4. Do axit (tinh the0 axit axetic CH,COOH), % kh6i lvwng (mglL) max.

5. Ham lwwng clorua v6 cw, mg/L (mglkg) max.

2.3.1.2.1. Cac ch i tieu kj? thugt cw b i n va phvwng phap thiv tvwng Gng clja etanol

nhien iieu bi6n t inh duwc quy djnh trong B i n g 7.

BPng 7 - Chi tieu ky thugt cua etanol nhign lieu bi6n tinh n

Mwc

99,O

0,5

1 ,o

0,007 (56)

8 (10)

Phwwng phap thiv

TCVN 7864 (ASTM D 5501)

TCVN 7864 (ASTM D 5501)

TCVN 7893 (ASTM E 1064)

TCVlU 7892 (ASTM D 1613)

ASTM D 7319; ASTM D 7328

Phwwng phap thiv

TCVN 7864 (ASTM D 5501)

TCVN 7864 (ASTM D 5501)

TCVN 7893 (ASTNI E 1064)

TCVN 7892 (ASTNI D 1613)

ASTM D 7319; ASTM D 7328

Ten chi ti6u

1. Ham lulwng etanol, % th6 tich min.

2. Ham lwwng metanol, % the tich max.

3. Ham lulwng nwwc, % th6 tich max.

4. Do axit (tinh the0 axit axetic CH3COOH), % kh6i lulwng (mg1L) max.

5. Ham lulwng clorua v6 cw, mg1L (mglkg) rnax.

M Ci~c

92, l

0,5

1 ,o

0,007 (56)

8 (1 0)

QCVN I :20151BKHCN

2.3.2. Nhi6n lieu di6zei sinh hoc g6c

Cac chi ti&u ky thugt c a b5n c ~ i a nhien lieu diezen sinh hoc g6c dvqc quy dinh

,trong B5ng 8.

Bang 8 - Chi ti6u kji thu@ cua nhien lieu dikzen sinh hoc g6c

-. 2.4. Phu gia

Ten c h i tieu

1. Ham lwwng metyl este axit beo (FAME), % kh6i llvwng min.

2. Nwwc va cgn, % the tich max.

3. E)Q nhbt dong hoc tai 40 OC, mm2/s

4. Tro sulfat, % kh6i llrwng max.

5. Luu hujlnh, % kh6i Ivqng max.

6. Trj s6 xetan min.

7. Trj s6 axit, mg KOHlg max.

8. on dinh 6xy hoa, tai 11 0 OC, h min.

9. Glycerin t v do, % kh6i llvqng max.

2.4.1. Cac loai phu gia s& dung d6 pha x ing kh6ng chi, x ing E5, xing E10,

nhi6n lieu di6zen va nhien lieu di6zen B5 phsi d5m b5o phu hwp vwi cac quy djnh v&

an toan, sljlc kho6, m6i trwang va kh6ng dwwc gay hw h6ng cho dong cw va he th6ng

tan tr0, v$n chuy6n va ph2n ph6i nhi6n lieu.

2.4.2. Viec S& dung phu gia khbng th6ng dung d6 s5n xuAt va pha ch6 x5ng

kh6ng chi, x3ng E5, x i n g E10, nhien lieu di6zen va nhi6n lieu diezen B5 ph5i dvwc

d ing ky va chAp thugn theo quy djnh tai Thbng tw 15/2009/TT-BKHCN ngay 02/6/2009

cfia Ba trveng Be Khoa hgc va C6ng nghe v& viec hwwng dsn trinh tv , thfi tuc d ing ky

viec SG dung phu gia kh6ng thbng dung d6 s5n xu6t1 pha ch6 x i n g va nhien lieu diezen.

Mwc

96,s

0,050

1,9 - 6,O

0,020

0,005

48

0,50

1

Phwwng phap thw

TCVN 7868 (EN 141 03)

TCVN 7757 (ASTM D 2709)

TCVN 3171 (ASTM D445)

TCVN 2689 (ASTM D 874)

TCVN 7760 (ASTM D 5453) -

TCVlV 7630 (ASTM D 613)

TCVN 6325 (ASTM D 664)

TCVN 7867 (ASTM D 6584)

TCVN 7866 (ASTM D 495'1)

10. Glycerin tBng, % kh8i Ivwng max. 0,240

I TCVN 7895 (EN 141 12)

11. Phospho, % kh6i llvwng max.

0,020

0,001

TCVN 7867 (ASTM D 6584)

QCVN I :20151BKHCN

2.4.3. Xing klidng chi, x ing E5, x ing E l 0 co chiva hqp ch i t oxygenat nhul la phu gia

thi ham lvqng cac hwp ch i t oxygenat trong x ing khdng chi, xang E5, x ing E l0 phai

tu5n thlj quy djnh trong B5ng 9.

Bang 9 - Cac hwp chat oxygenat 'I

1 2. lso-butyl ancol, % thk tich max. 1 10,O ( 1 3. Tert-butyl ancol, % th6 tich max. 1 7,O

Phvwng phap thiu

TCVN 7332 (ASTM D 481 5)

Ten chi tieu 1 Mivc

I Rieng MTBE, % th6 tich max. 1 , 10,O

1. Iso-propyl ancol, % the tich max. 10,O

1 6. Keton, % th6 tich KPH 3'

7. Cac loai este, % th& tich KPH 3,

5. Metanol , % th6 tich

I ) Cac hwp chit oxygenat co th& dung 6 dang don I6 hogc 6 dang h6n hwp vwi th6 tich n im trong gihi han quy djnh va t6ng ham lwwng oxy phG hwp vCri quy djnh d6i vwi cac loai x5ng.

C6 nhiet do sbi 5 210 OC.

KPH 3,

3' Khbng phat hien I 1

Msu cac loai nhi6n lieu d& xac djr-th cac chi tieu quy djnh trong Quy chuan ky thugt

nay dlrqc lay theo TCVN 6777:2007 (ASTM D 4057-06) SGn ph im dzu md -

Phwng phap lay rnau thrj cbng hogc TCVN 6022:2008 ( IS0 3171:1988) c h i t Idng

d6u rnd - ~ 6 y rnsu t y dong trong du&ng Bng va theo Hvwng dsn p hvcrng phap I Ay m Au

xGng dAu clja T6ng cuc Ti6u chuin Do lvbng Ch i t Ivwng.

3.2. Phwwng phap thw

3.2.1. Cac chi ti& clja xang khdng chi, xang E5, xang E l 0 quy djnh tai kho5n 2.1

Muc 2 cfia Quy c h u h ky thugt nay dvqc xac djnh theo cac phvwng phap sau:

QCVN 1:20151BKHCN

- TCVN 2703:2013 (ASTM D 2699-12) Xac djnh tri s6 dc tan nghien cGu cho

nhien lieu dong cw danh lea.

- TCVN 7143:2010 (ASTM D 3237-06~') X i n g - Phvwng phap xac dinh

ham lvpng chi bbng quang ph6 hdp thu nguyen tiu.

- TCVN 2698:2011 (ASTIbl D 86-10a) S i n p h i m d6u m6 - Phuwng phap

xac djnh thanh ph6n c i t Iv ap sudt khi quy&n.

- TCVN 6701:2011 (ASTM 2622-1 0) San phsm d6u m6 - Phvwng phap

xac djnh Ivu huynh b i n g ph6 huynh quang bvwc song tan xa tia X.

- TCVN 7760:2013 (ASTM D 5453-12) Hydrocacbon nhe, nhien lieu dong cw ,--- danh lea, nhign lieu dong cw diezen va dsu dong cw - Phuwng phap

xac djnh t6ng lvu huynh b3ng ph6 huynh quang tiu ngoai.

- TCVN 3166:2008 (ASTM D 5580-02) Phvwng phap xac Qnh benzen, toluen,

etylbenzen, p/m-xylen, o-xylen, cac c h i t thwm C9 va ngng hwn va t6ng cac

chdt thwm trong xGng thanh phsm bdng s i c ky khi.

- TCVN 6703 (ASTM D 3606) X2ng may bay va x i n g 6 t8 thanh phsm -

Xac Qnh ham lvwng benzen va toluen bsng phvwng phap sac ky khi.

- TCVN 7330:2011 (ASTM D 1319-10) SBn p h i m d6u m6 dang I6ng -

P h m g pAap xac Qnh hydrocacbon b i n g h i p phu chi thj huynh quang.

r.

- TCVN 7332:2013 (ASTM D 4815-09) X5ng - Xac dinh hwp chdt MTBE, ETBE,

TAME, DIPE, rvwu tert-Amy1 va wwu tiu C1 d6n C4 bbng phvwng phap sac ky

kh i.

- TCVN 7331:2008 (ASTM D 3831-06) XGng - Phvwng phap xac dinh

ham lvwng mangan b i n g quang phd h i p thu nguygn tiv.

- TCVN 7759:2008 (ASTM D 4176-04~'), Nhien lieu chlvng cat - Xac d,nh

nuwc t v do va tap chdt dang hat ( P h m g phap yuan sat b i n g mat thvwng).

- ASTM E 203-08 Test method for water using volumetric Karl Fischer

titration (Phvwng phap xac djnh nuwc bbng chusn d6 th6 tich Karl Fischer).

3.2.2. Cac chi tigu clia nhien lieu diezen va nhign lieu digzen B5 quy djnh tai

kho5n 2.2 Muc 2 clia Quy c h u h kji thugt nay dvwc xac djnh the0 cac phvcrng phap

sau:

13

QCVN 1:20151BKHCN

- TCVN 6701:2011 (ASTM 2622-10) S i n ph6m d4u m6 - Phuwng phap

xac dinh luu huynh b i ng ph8 huynh quang buwc song tan xa tia X.

- TCVN 7760:2013 (ASTM D 5453-12) Hydrocacbon nhe, nhien lieu dong cw

danh /$a, nhien lieu dong cw diezen va d4u dong cw - Phuwng phap xac @nh

t8ng luu huynh bsng ph8 huynh quang t$ ngoai.

- TCVN 3172:2008 (ASTM D 4294-06) D ~ U m6 va san ph6m dau md -

Phuwng phap xac dinh luu huynh bsng ph6 huynh quang tan xa n3ng Iuwng

tia X.

- TCVN 7630:2013 (ASTM D 613-10a) Nhien lieu diezen - Phuwng phap

xac djnh trj s6 xetan. n

- TCVN 3180:2013 (ASTM D 4737-10) Nhien lieu diezen - Phuwng phap

tinh toan chi s6 xetan bsng p h m g trinh b6n bi6n s6.

- TCVN 2698:2011 (ASTM D 86-10a) San p h i m dau m6 - Phuwng phap

xac djnh thanh phan tit w ap su i t khi quygn.

- TCVN 2693:2007 (ASTM D 93-06) SAn phdm dau mo - Phuwng phap

xac dinh di6m chwp chay b&g thi6t bj thfi c6c kin Penski-Martens.

- TCVN 3171:2011 (ASTIV D 445-1 1) chat long d i u m6 trong su6t va kh6ng

trong su6t - Phuwng phap xac djnh do nhwt dong hoe (va ti'nh toan do nhwt

dong Iyc).

?

- TCL'N 3753:2007 (ASTM D 97) S i n phAm ddu md - P h m g phap xac djnh

di6m d6ng dgc.

- TCVN 3182:2008 (ASTM D 6304-04ael) San phdm d6u m6, dau b6i trwn

va phu gia - Xac dinh nuwc b i n g chu in do dien luwng Karl Fischer.

- ASTM D 51 86 Standard Test Method for Determination of Aromatic Content

and Polynuclear Aromatic Content of Diesel Fuels and Aviation Turbine

Fuels by Supercritical Fluid Chromatography (NiiSn lieu diezen va nhiGn lieu

tube bin hang kh6ng - Xac djnh ham l w g c h i t thwm va ch4t thwm da nhBn

b ing szc ky ch6t 16ng si6u tbi han).

- ASTNl D 6591 Standard Test Method for Determination of Aromatic Hydrocarbon

types in Middle Distillates High Performance Liquid Chromatography Method wifh

Refractive Index Detection (Phuong phap xac dinh cac loai hydrocarbon thwm

QCVN 1 :20151BKHCN

trong nhiGn lieu chu'ng cdt trung binh b ing sac ky ldng hi& n3ng cao vtri

detector chi s8 khljc xa).

- TCVN 8147:2009 (EN 14078:2003) San phdm d6u m6 dang ldng - Xac dinh

esfe metyl axit beo (FAME) trong phdn c i t gi0a - P h m g phap ph8

hang ngoai.

- ASTM D 7462-1 1 Standard Test Method for Oxidafion Stability of Biodiesel

(B100) and Blends of Biodiesel with Middle Distillate Petroleum Fuel

(Accelerated Method) [NhiGn lieu diezen sinh hoc g8c (B100) va hdn hqp

nhien lieu diezen sinh hoc v&i nhiGn lieu chung cdt trung binh - Xac dinh

do an dinh oxy hoa ( P h m g phap t2ng tdc)]. F-

- ASTM D 7545-14 Standard Tesf Mefhod for Oxidafion Stability of Middle

Distillate Fuels-Rapid Small Scale Oxidation Test (RSSOT) [NhiGn lieu

chung cdt trung binh - Xac djnh do 6n dinh oxy hoa b i n g phep thljl oxy hoa

tg le nhd (RSSOT)].

3.2.3. Cac chi tieu cfia etanol nhi6n lieu quy djnh tai digm 2.3.1 kho in 2.3

Muc 2 clja Quy chu6n ky thuat nay dvwc xac djnh the0 cac phvwng phap sau:

- TCVN 7864:2013 (ASTM D 5501-1 23 Etanol nhien lieu bi6n tinh - Xac dinh

ham Iuqng etanol - Phuong phap s i c ky khi.

- TCVN 7893:2008 (ASTM E 1064-05) ~ h A t ldng hfiu c o - Xac dinh nlvCrc

/ - b2ng chusn do dien Iuqng Karl Fischer.

- TCVN 7892:2008 (ASTM D 1613-06) Dung m6i bay hoi va cac hoa ch i t

trung gian sljl dung trong son, vecni, son bong va cac s5n phdm likn quan -

Xac dinh do axit.

- ASTM D 7319-12 Standard Test Method for Determinafion of Existent and

Potenfial Sulfate and Inorganic Chloride in Fuel Efhanol by Direct Injection

Suppressed Ion Chromatography (Phluong phap xac Qnh sulfat co s i n va

fi&m tang va clorua v6 c o trong etanol nhien lieu b6ng sac ky khG ion bom

frvc tikp).

- ASTM D 7328-1 1 Standard Test Method for Defermination of Existent and

Potential lnorganic Sulfate and Total Inorganic Chloride in Fuel Ethanol by

Ion Chromatography Using Aqueous Sample Injection (Phwng phap

15

QCVN 1 :20151BKHCN

xac dinh sulfat c o s & ~ va ti6m tang va clorua v8 c o trong etanol nhien lieu

b i ng s i c ky ion sf i dung bom msu nu&).

3.2.4. Cac chi tieu clja nhiGn lieu diGzen sinh hoc g6c quy djnh tai di6m 2.3.2

kho in 2.3 Muc 2 cba Quy chub ky thuat nay dwgc xac djnh the0 cac phlvolng phap

sau:

- TCVN 7868:2008 (EN 141 03:2003) DSn xu i t m& va dau - Este metyl axit beo

(FAME) - Xac dinh ham luqng este va este metyl axit linolenic.

- TCVN 7757:2007 (AS-TM D 2709-06) Nhien lieu chung c6t trung binh -

Xac dinh nlvdvc va cgn b i n g phuong phap ly tsm.

,? - TCVN 3171:2011 (ASTM D 445-1 1) c h i t I6ng d6u m6 trong su6t va kh6ng trong

su6t - Phuong phap xac dinh do nhCrf dong hoc (va tinh toan do nhdvf dong Ivc).

- TCVN 2689:2007 (ASTM D 874-06) SBn phsm d8u m6 - D ~ U b6i tron va cac

phu gia - Xac Qnh tro sulfat.

- TCVN 7760:2013 (ASTM D 5453-12) Hydrocacbon nhe, nhien lieu dong co

danh Ifia, nhien lieu dong c o diezen va d i u dong c o - Phwng phap xac dinh

tBng luu hu)inh b ing huynh quang tf i ngoei.

- TCVN 7630:2013 (ASTM D 61 3-1 0a) Mhien lieu diezen - Phuong phap

xac dinh trj s6 xetan.

- TCVN 6325:2013 (ASTM D 664-1 1 a) S i n ph6m d6u m6 - Xac @nh tn s6 axit - .>

Phlmng phap chu6n do &en th6.

- TCVN 7895:2008 (EN 14112:2003) Dsn xu& m& va d8u - Este metyl axit

beo (FAME) - Xac dinh do 6n dinh oxy hoa (ph6p thl'r oxy hoa nhanh).

- TCVN 7867:2008 (ASTM D 6584-07) Este metyl diezen sinh hoc g6c 6100

-Xac dinh glycerin t v do va glyzerin tdng - P h m g phap s6c ky khi.

- TCVN 7866:2008 (ASTM D 4951-06) D8u b6i tron - Xac djnh ham I r m g

cac nguyen t6 phu gia b i ng quang ph8 phat xa nguy&n t f i plasma ket n6i

c i m Gng (ICP).

QCVN 1 :20151BKHCN

3.3. Xiu Iy k6t qua thiv nghiem

Viec XC~J Iy k&t q u i thG nghiem d6i vwi xsng, nhien lieu diezen va nhien lieu sinh hoc 66 danh

gia sy phlj hwp dvwc thyc hien the0 TCVN 6702:2013 (ASTM D 3244-07a) Xfi ly k i t qua

thr3 nghiem d6 xac Qnh s y phrj hpp vbi y6u c6u ky thu$t.

4. QUY DlNH QUAN LY

4.1. X5ng kh6ng chi, xgng E5, x5ng E10, nhien lieu diezen, hhien lieu diezen B5

nhgp khsu, s i n xuAt, pha ch6 trong nvwc ph i i dvwc danh gia chivng nhan sv phu hqp vwi

cac quy dinh ky thugt lien quan tai Muc 2 clja Quy c h u h ky thuat nay va thyc hien cac r'

thlj tuc the0 cac quy djnh quin Iy hien hanh trvwc khi dva ra lvu th6ng tren tl-~i trvwng.

4.2. Viec danh gia, chivng nhgn xgng khdng chi, x5ng E5, x5ng E10, nhien lieu

diezen, nhien lieu diezen B5 phlj hwp vwi cac quy djnh ky thuat tai Muc 2 clja Quy chusn

ky thuat nay do t6 chivc chivng nhan dvwc ~ 6 n g cuc Tieu chuin Do lvwng ChAt lvwng

chi djnh hogc thiva nhgn thyc hien.

4.3. Cac phvwng thivc danh gia chljlng nh$n s y phu hwp va nguyen tac ap dung

dvwc quy djnh tai f)i&u 5 v i Phu luc II c i a Quy anh v6 cbng b6 hpp chuin, cdng b6

hpp quy va phlvcrng thirc csnh gia s y phu hqp vbi ti& c h d n va quy chub ky thugt

ban hanh kem the0 Thong t v s6 2812012TTT-BKHCN ~igay 12/12/2012 clja BO Khoa hoc va

, C6ng nghe. Viec ap dung cu th6 nhv sau:

a) X3ng kh6ng chi, x5ng E5, x5ng E10, nhien lieu diezen, nhien lieu diezen 85

s i n xu&, pha ch6 trong nvwc phi i dvwc danh gia chivng nh$n s y phu hwp vwi Quy chusn

ky thugt nay the0 Phvwng .thivc 5 "ThG ngl-~iem nisu dai dien va danh gia qua trinh s i n xuit;

giam sat thdng qua thG nghiem msu lAy tai nwi s i n xuAt hogc tren thj trvwng k6t hwp v6i

danh gia qua trinh sin xuit" hoac Phvwng thivc 7 "ThG nghiem, danh gia sw phu hwp cGa 16

s i n phim, hang h6a";

b) X5ng khijng chi, xgng E5, xsng E10, nhien lieu diezen, nhien lieu diezen B5

nhgp kh6u phi i dwwc danh gia chivng nhgn sy phu hwp vwi Quy chilsn ky thuat nay the0

Phvwng thivc 7 "ThG nghiem, danh gia s y phlj hwp clja I6 s i n pham, hang hoa";

4.4. Xing kh6ng chi, x ing E5, xing E10, nhien lieu diezen, nhien lieu diezen B5

s i n xuit, pha ch6 trong nvwc phi i cBng b6 hwp quy the0 quy d/nh tai Th6ng t v s6

2812012iTT-BKHCN ngay 1211212012 clja Ba Khoa hoc va CBng nghe.

Xing kh6ng chi, x ing E5, xing E10, nhien lieu diezen, nhien lieu diezen B5

nhap khau phi i d ing ky ki6m tra nha nvwc v& ch%t Ivwng tai cw quan kigm tra the0 quy djnh

tai Th6ng t v 271201 2mT-BKHCN qgay 1211 21201 2 clja BG Khoa hoc va C6ng nghe.

4.5. Xing kh6ng chi, x ing E5, xing E10, nhien lieu diezen, nhien lieu diezen B5

nhap khAu, s i n xu%t, pha ch6 va lvu thbng tren thj trvwng ph i i d i m b i o chit Iwwng

phh hwp vwi Quy chuan kji thuat nay va chju sw ki6m tra nha nvwc v& chi t Iwwng the0

quy djnh clja phap lugt. . ,-

5.1. ~6 chivc, ca nh3n s i n xu&, pha ch6 va nhap kh5u x i ng kh6ng chi, x ing E5,

x5ng E10, nhien lieu diezen, nhien lieu diezen B5, etanol nhien lieu va nhien lieu

diezen sinh hoc g6c p h i i thvc hien c6ng b6 ti& chub ap dung vwi nei dung khdng

dvwc trai vwi Quy chub kji thuat nay, d i m b i o ch%t Ivwng phh hwp vwi quy djnh tai

Quy chuan kji thuat nay va ti& chuin d2 cdng b6 ap dung.

5.2. T6 chivc, ca nh in s i n xu&, pha ch6 x iqg kh6qg chi, x ing E5, x2ng E10,

nhien lieu diezen, nhien lieu di6zen B5 phi i thvc hien viec chivng nhan hwp quy v i c6ng b6 - hwp quy the0 quy djnh tai Quy chub kji thuat nay.

~6 chivc, ca nh in nhap kh6u xing kh6ng chi, x ing E5, x ing E10, nhien lieu diezen,

nhien lieu diezen B5 ph i i thvc hien viec cliivlig nhan hwp quy va d ing ky ki6m tra nha nvwc

v& ch%t Ivwng the0 quy djnh tai Quy chuin kji thuat nay.

5.3. ~6 chivc, ca nh2n ph in ph6i va ban I6 x ing khbng chi, x ing E5, x2ng E10,

nhien lieu diezen, nhien liei! diezen B5, etanol nhien lieu va nhien lieu diezen sinh hoc g6c

phi i d i m b i o chi t lwwng phil Iiwp vwi cac quy djl-~h tai Quy chu6n ka thuat nay.

5.4. Tai cac tram hogc cfia hang kir~h doanh nhien lieu hogc phvwrlg tien phin ph6il

ban I6 khac phi i ghi rb loai x ing valhogc nhien lieu diezen vwi cac th6ng tin sau:

- ~ 6 i vwi x ing khdng chi: trj s6 octan va mivc tieu chu%n nhien lieu phh hwp vwi

mivc tieu chuan khi t h i i

QCVN 1 :20151BKHCN

Vi du: RON90-ll; RON92-ll; RON95-ll; RON92-Ill; RON95-Ill; RON98-Ill;

RON92-IV; RON95-IV; RON98-IV

- D6i v&i xBng sinh hoc: trj s6 octan, tl;l Ie etanol nhi6n lieu dulwc ph6i tron va

mivc tieu chuhn nhien lieu phu hwp vwi mivc tieu c h u h khi th5i

Vi du: E5 RON92-11; E5 RON95-ll; E5 RON92-Ill; E5 RON95-Ill;

E5 RON98-Ill; E l 0 RON92-IV; E l 0 RON95-IV; E l 0 RON98-IV

- D6i vwi nhien lieu diezen: ky hieu nliien lieu diezen, ham Ivwng lvu huynh

Vi du: DO 0,05S; DO 0,035s; DO 0,005s

- 06i vwi nhien lieu diezen 65: ky hieu nhien lieu diezen, ky hieu 65 va - ham lvwng lvu huynh

Vi du: DO 65 0,05S; DO 65 0,035s; DO 65 0,005s

6.1. ~ 6 n g cuc Tiku chu in D o Ivwng ~ h $ t Ivwng co trach r~hiem hvwng d i n ,

kihm tra va ph6i hqp vwi cac cw quan chivc nBng lien quan t6 chivc viec thvc hien

Quy c h u i n ky thuat nay.

CBn cir vao yeu chu q u i n Iy, ~ 6 n g cuc Tieu chu2n D o Ivwng ~ h A t Ivwng c6

trach nhiem ki6n nghj 66 Khoa hgc va C6ng nghe sira d6i1 b6 sung noi durig - - Quy c h u h ky thu$t nay phu hwp v6i thvc ti&.

6.2. Khi cac vBn b5n quy pham phap lust, cac tai lieu vien dsn hogc hvwng d5n

quy dinh tai Quy chu in ky thu$t nay co s y thay d6i1 b6 sung hogc dvwc thay th& thi

thvc hien the0 cac van b5n mwi.1.