TX PRESENTATION 1

TUBACEX CNFIA Erdos, 2015

Quality materials product ion for the Fert ilizer Industry 为化肥工业生产高质量的材料

TX PRESENTATION 2

AN INTEGRATED GLOBAL GROUP 一个完整的全球性集团

TUBACEX TODAY 今天的TUBACEX

TUBACEX – A STRONG GROUP TO YOUR SERVICE TUBACEX –一个为你服务的强大集团

Pipes & Tubes fit t ings

管道和管件

Master distributor主分配装置

Commercial network 商务网络

Steel billets & bars

钢坯和钢棒

Extrusion facilit ies

挤压工艺设施

Cold Finishing facilit ies

冷精整设施

TX PRESENTATION 3

Facilities•56 MVA EAF 56兆伏安电弧炉•60 MT AOD60吨氩氧脱碳转炉•2000MT Forging Press2000吨锻压设备•Blooming Mill 初轧机

Facilit ies: more t han 10 Mills worldwide 世界范围10+生产装置

Melting Shop

Facilities•1600 Mt Piercing Press1600吨冲孔机•4.100 Mt Extrusion Press4100吨挤压机•Stretch Reducing Mill张力减径机•11 Cold Pilger Mills11台冷轧管机

Facilities•1200 Mt Expanding Press1200吨扩孔压力机•2 Extrusion Press 2台挤压机(2000&3300 tons) (2000和3300吨)•Stretch Reducing Mill张力减径机•8 Cold Pilger Mills8台冷轧管机•5 Cold Drawing Benches5台冷拔牵引台

Facilities•Weld Mills焊接厂•Cold Drawing Benches冷拔牵引台

Fa

FacilitiesFittings Division – 4 plants管件部分 – 4个工厂Pipes Division – 3 plants管材部分 – 3个工厂JSI Mill in China for nuclear ApplicationsJSI工厂在中国，核能应用

TX PRESENTATION 4

TUBACEX TODAY

Warehouses 仓库

Sales representat ion 销售代表

Manufactures 制造工厂

Sales offices 销售办公室

SALEM TUBE

CANADA

USA

TUBACEX AMERICA

MEXICO

ARGENTINA

CHILE

BRAZIL

SPECIAL STEELS DO BRAZIL

MOROCCO

SOUTH AFRICA

AUSTRALIA

INDONESIA

SINGAPUR

TAIWAN

JAPÓN

S.KOREACHINA

JSI

INDIAUAE

RUSSIA

ACERALAVATTI LLODIOTTI AMURRIOTTI OCTGTTATSS

CZECHIA

POLAND

COTUBESTUBOS MECANICOS

SBERSBER PUIBF

AUSTRIA

ITALY TURKEY

UK

SWEDEN

FINLAND

FRANCE

MIS

GERMANYNETHERLANDS

GEOGRAPHIC STRATEGY. Tubacex presence TUBACEX的地理战略

Tubacex has a global presence with sales in 100 countries with a wide commercial network and manufacturing facilit ies located in Europe and America

TUBACEX在世界100多个国家具有广泛的商务销售网络，同时在欧洲和美洲有生产设施及装置

TX PRESENTATION 5

EXPERIENCED & LOOKING Ahead 经验与展望

Tubacex/Schoeller Bleckmann Edelstahlrohr has supplied HE-tubing for many Urea HP- strippers, carbamate condensers and scrubbers during the last 40 years. Tubacex/Schoeller Bleckmann Edelstahlrohr 在过去40年中已为许许多多的尿素高压汽提塔、甲铵冷凝器和洗涤器提供热交换器管材。

Currrently producing 25.22.2 strippers and Carb. Condenser tubing for Stamicarbon projects and qualification finished with Casale and Saipem/Snamprogetti. 目前正在为斯塔米卡帮生产25.22.2材质的汽提塔和甲铵冷凝器，卡萨利和塞班/斯纳姆的认证已经结束并通过。

Tubacex offers: Tubacex可以提供：

Complete range of dimensions for tubing , piping & fit t ings. 全尺寸范围的管材、管道和管件

Mill capabilities: Seamless tubes/pipes from OD 6 to 42”. Fit t ings from ½” to 72” 尺寸范围：无缝管材/管道外径6-42英寸，管件1.2-72英寸

316L UG, 25.22.2, 2906… Urea materials. 316L尿素级、25.22.2\2906 … 尿素材料

We are a fully integrated manufacturer, from the need to the solut ion, From the steel grade to the final tube

我们是一个全面的制造商，从需求到解决方案，从材质到最终管产品

TUBACEX in the FERTILIZERS Indust ry 化肥工业中的TUBACEX

TX PRESENTATION 6

APPROVED BY ALL UREA LICENSORS 所有知名尿素技术转让商均已认证

Tubacex is approved for the supply of 25.22.2 and 316L UG materials (+any std. grade) to: Tubacee 已被认证允许提供25.22.2和316L尿素级材料（任一标准）给：

Stamicarbon 斯塔米卡帮

Saipem/Snamprogetti Technology塞班 /斯纳姆技术

Casale 卡萨利

Toyo 东洋

Both Tubing and Piping. 包括管件和管道

TUBACEX in t he FERTILIZERS Indust ry 化肥工业也中的TUBACEX

TX PRESENTATION 7

Example of some Urea-Fertilizer projects deliveried during last years过往这些年中在尿素化肥项目上一些业绩

+ more than 60 projects deliveried 60多个项目的业绩

END USER COUNTRY/DESTINY ENGINEERING CONTRACTOR CUSTOMER DESCRIPTION

2015

OCI NETHERLANDS SITECH MCL NITRIC ACID HE

UNKNOWN INDONESIA STAMICARBON SCHOELLER-BLECKMANN NITEC GMBH HP SCRUBBER

PHOS-AGRO CHEREPOVETS RUSSIA STAMICARBON SCHOELLER-BLECKMANN NITEC GMBH HP CARB CONDENSER

CROATIA KUTINA AUSTRIA STAMICARBON SCHOELLER-BLECKMANN NITEC GMBH CARB CONDENSER

BAYER GERMANY BAM - APPARATEBAU GMBH

2014

DNEPROAZOT UKRAINE STAMICARBON DNEPRAZOT, PJSC /PRIVATBANK REPLACEMENT HEAT EXCHANGER

DNEPROAZOT UKRAINE STAMICARBON DNEPRAZOT, PJSC /PRIVATBANK HEAT EXCHANGER MAINTENANCE

KHORASAN PETROCHEMICAL COMPANY IRAN STAMICARBON SCHOELLER-BLECKMANN NITEC GMBH STRIPPER HEAT EXCHANGER

KHORASAN PETROCHEMICAL COMPANY IRAN STAMICARBON SCHOELLER-BLECKMANN NITEC GMBH SCRUBBER & LIQUID DIVIDER

UNKNOWN ITALY SPH STAHL-PARTNER-HAMBURG GMBH

BASF GERMANY ETTORE ZANON S.P.A.

UNKNOWN ITALY SPH STAHL-PARTNER-HAMBURG GMBH

2013

UNKNOWN RUSSIA ALISON MILEUZ MINERAL FERTILAZINGS PLANTS

INDORAMA ELEME FERTILIZER AND CHEMICALS LIMITED NIGERIA INDORAMA… INDORAMA… IEFCL FERTILIZER PROJECT (VIA COTUBES)

UNKNOWN ITALY ETTORE ZANON S.P.A. NITRIC ACID PRODUCTION Vessel

IOWA FERTILIZER COMP USA THYSSENKRUPP UHDE FBM-KNM FZCO

IOWA FERTILIZER COMP USA THYSSENKRUPP UHDE F.B.M. HUDSON ITALIANA Spa

2012

MELEUZ MINERAL FERTILIZERS OJSC (MEMY) RUSSIA ALISON INDUSTRIAL CO ALISON INDUSTRIAL CO MILEUZ MINERAL FERTILAZINGS PLANTS,

UZCHEMSANOYAT UZBEKISTAN TIKO MV STEEL GROUP CHIRCHIK UREA PLANT UZBEKISTAN

Tubing 25.22.2

Long t erm experience in t he Fert ilizer Market 在化肥市场的长期经验

TX PRESENTATION 8

Long t erm experience in t he Fert ilizer MarketResume of Urea-Fertilizer piping orders deliveried during the last years 近年尿素化肥管道订单一览

+ more than 60 orders

of Piping systems since 2004 for Snamprogetti,

Stamicarbon, Toyo or Casale Projects

从2004年起为斯纳姆、斯塔米卡帮、东洋或卡萨利等60多个

项目管道系统订单。

YEAR COUNTRY/DESTINY END USER/PROJECT CUSTOMER ENGINEERING CONTRACTOR2015 CHINA WUHAN TIANJIN PETRO PIPE Co, Ltd. HFEC

2015 AUSTRIA BHDT GmbH UNKNOWN

2015 ITALY T.A.L. S.P.A. TUBI ACCIAIO LOMBARDA UNKNOWN

2015 BELGIUM GEMACO S.A. UNKNOWN

2015 AUSTRIA INDONESIA SCHOELLER-BLECKMANN NITEC GMBH STAMICARBON

2015 RUSSIA PHOS-AGRO SCHOELLER-BLECKMANN NITEC GMBH STAMICARBON

2015 BELGIUM STOCK GEMACO S.A. UNKNOWN

2015 BELGIUM GEMACO S.A. UNKNOWN

2015 AUSTRIA SBN PIPING UNKNOWN

2015 GERMANY YARA BHDT PIPING UNKNOWN

2014 CZECH REP R.F. PROFI S.R.O. UNKNOWN

2014 GERMANY SPH STAHL-PARTNER-HAMBURG GMBH UNKNOWN

2014 CZECH REP PACOVSKE CS STEEL A.S. UNKNOWN

2014 BELGIUM GEMACO S.A. UNKNOWN

2014 ITALY TAL PIPING UNKNOWN

2014 Sabah Ammonia Urea MITSUBISHI HEAVY INDUSTRIES,LTD. SAIPEM /HALDOR TOPSOE

2014 TAF PROJECT MITSUBISHI HEAVY INDUSTRIES,LTD. SAIPEM /HALDOR TOPSOE

2013 INDONESIA PT PUUL PUSRI 2B VAN LEEUWEN PIPE&TUBE (S) PTE LTD. TOYO ENGINEERING

2013 BELGIUM PIPING STOCK GEMACO S.A. UNKNOWN

2013 ITALY STOCK RACCORTUBI S.P.A. SAIPEM

2013 BELGIUM STOCK GEMACO S.A. UNKNOWN

2013 TAF PROJECT MITSUBISHI HEAVY INDUSTRIES,LTD. SAIPEM /HALDOR TOPSOE

2012 BELGIUM STOCK GEMACO S.A. UNKNOWN

2012 BELGIUM GEMACO S.A. UNKNOWN

2012 ALGERIA ALGERIA OMAN FERTILISER PROJECT MITSUBISHI HEAVY INDUSTRIES,LTD. SAIPEM /HALDOR TOPSOE

2012 UREA CASALE S.A. CASALE

2012 TAF PROJECT MITSUBISHI HEAVY INDUSTRIES,LTD. SAIPEM /HALDOR TOPSOE

2012 UKRAINE ODESSA PORT PLANT PROJECT MATERIALS EN ODESSA PORT PLANT

2012 SAUDI ARABIA SAFCO RACCORTUBI SAFCO V UREA STAND ALONE PROJECT JUBAIL2011 BELGIUM GEMACO S.A. UNKNOWN2011 BELGIUM GEMACO S.A. UNKNOWN2011 QATAR QAFCO 5 PROJECT GLOBAL SUPPLIES (UAE) FZE UNKNOWN2011 QATAR QAFCO 5 PROJECT SAIPEM SPA SAIPEM2011 QATAR QAFCO-6 SAIPEM SPA SAIPEM2011 ALGERIA ALGERIA OMAN FERTILISER PROJECT MITSUBISHI HEAVY INDUSTRIES,LTD. SAIPEM /HALDOR TOPSOE2011 TAF PROJECT MITSUBISHI HEAVY INDUSTRIES,LTD. UNKNOWN2010 ITALY VRV SPA UNKNOWN

Piping 316L UG 316L尿素级管道

L

TX PRESENTATION 9

Tubacex has been supplying Tubing for vessels since the 1970´s. 从70年代开始Tubacex一直在提供管材

Measurements made in real on stream Heat Exchangers support the quality of the material supplied.本真测量在热交换器生产中使用，为所提供材料的高质量提供了保障

Long t rack records + looking ahead R&D st ructure 长期业绩和研究发展体系展望

Tubacex R&D Department is currently studying the behaviour of these materials to upgrade the corrosion resistance. Tubacex研究发展部门目前正在研究这些材料的性能特点以使其耐腐能力升级

Stripper: 0.065 mm/y

Carb. Condenser: <0.035 mm/y

On Stream AVERAGE CORROSION RATES

Quality materials product ion for the Fert ilizer Industry 为尿素工业生产优质材料

TX PRESENTATION 10

PRODUCTION in our Special Tube Mill in Aust ria 位于奥地利的我们特殊管工厂的生产状况

Quality materials product ion for the Fert ilizer Industry

More than 150 years of experience in iron and steel processing 在钢铁加工方面150多年的经验

More than 50 years of experience in stainless steel incl. duplex/Sduplex/HiNialloys. 在不锈钢包括双向钢/多向钢/高镍合金方面50多年的经验

State of the art plant designed for Umbilicals

and Fertilizer Tubing 为脐带管和化肥管材设

计的最先进工厂

Started 5 years ago5年前开始投产

Top quality Process顶级质量的工艺

Tubacex/Schoeller Bleckmann Edelstahlrohr site in Ternitz/Austria 位于奥地利Ternitz的Tubacex/Schoeller Bleckmann Edelstahlrohr工厂

EXTRUSION挤压

DEGASSING & PICKLING脱气和酸洗

WATER QUENCHING水淬火

SWING SAW 产品剪切

INDUCTION REHEATING 感应加热

EXPANDING热膨胀

FURNACE HEATING 炉子加热

STRAIGHTENING拉直

HOLLOWS 管产品

COLD MANUFACTURING & FINISHING 冷加工和完成

INDUCTION HEATING 感应加热

Hot manufacturing General Process 热加工一般工艺

PILGER & DRAWING MACHINES 冷轧和拉拔机

CUTTING + TESTING 剪切和探伤

SBER hot forming / main steps SBER热成型 / 主要步骤

Induction heating感应加热Heating the billets up to 1000 - 1250 °C 坯料加热至摄氏1000-1250度

1

Expanding / Piercing presses膨胀穿孔工艺

Press force: 1.200 &. 1.600 ton 压力：1200吨 和 1600吨re-heating (induction coils) 再加热（感应线圈）

2

Extrusion presses 挤压

Press force: 2.000 ton 压力：2000吨Press force: 3.600 ton 压力：3600吨Press force 4.100 ton 压力：4100吨

Water quench or stretch reducer 水淬火或张力减径机

3

Special Tube Mill Investment 特殊管工厂投资

State of the Art Plant located in Austria 于奥地利的最先进工厂started 5 years ago, 始于5年前specially designed for demanding special tubes like Fertilizer Industry HE tubing 为化肥工业热交换管材特别设计的

Key issues for Quality assurance in Fertilizer tubing

化肥用管材质量保证的关键因素

Cold pilger method 冷轧方法

Tube cleaning 管子清洁

Annealing 退火

NDT 无损探伤

Tubacex Quality Dept. Tubacex质监部门

Cold pilger / schematic view冷轧 / 图解视图

Figure 2Longitudinal section through the forming section in a cold pilger mill 冷轧厂成形部分的纵剖面

Figure 3Cross section (A-A) through the forming section in a cold pilger mill 热成形部分的横切面

Roll 辊

Mandrel 芯棒

Shell 表壳

Finished Tube管成品

ET AT

Feeding & turning

Cold Pilger Development 冷轧管的发展“ Influence of geometric parameters to tube and tool“

几何参数对管子和工具的影响

• Reduction limit / elongation limit

减径极限 / 拉长极限

• Q-factor Q-因素

• calibration shape 产品成型计算

– over the rolling length 滚动长度线

– cross-section 横截面

• slip coefficient 滑移系数

Simulation of the pilger mill rolling process 轧管厂轧制工艺模拟

(cold working 冷加工)

Process analysis工艺分析

45,0)( ×−−

=eODfinaltubODhollow

ODODSF pinionroll

outgoingoutgoing

ingoingingoing

outgoingingoing

WTHODWTHOD

WTHWTH

Q−−=

ln

ln

dissolving oil

removeparticles

Chemicalcompound

Single Tube cleaning 单管清洁

watertreatmentplant

solventtreatmentplant

Several steps for the cleaning procedure assure the highest quality of the Urea tubes: 清洁过程中的几个关键步骤，确保尿素用管的最高质量

1.OD mechanical cleaning 外径的机械清洁

2.ID cleaning 内镜清洁

3.OD chemical cleaning 外径的化学清洁

4.Water and solvent treatment systems

Tubes handling with care 管子生产过程中的精心操作

In order to avoid any damage to the surface of the tubes:目的是避免管子表面的任何损伤

collecting of tubes in layers管产品要分层收集整理

prepared for the furnace要为热处理作好准备

lifting with unique stacker crane吊装要用专用塔式起重机

Bright annealing光亮退火

Purpose: 目的 removal of undesired chemical

compounds 去除不想要的化合物

strain softening 应变软化

setting of desired microstructure 固定想要的显微结构

forming of a homogeneous oxide layer 形成一个同质的氧化层

performed in a roller hearth furnace under controlled H2atmosphere在可控氢气环境下的辊底式炉中进行

NDT - non destructive testing 无损探伤

groundingbrushes 接地刷

Ultrasonic Test

超声波探伤

Positive materialidentification 阳性材料鉴别

Eddy currentTest

涡流探伤

centering and feed对中和进入

Individual Bar Code Marking 逐个棒材标号

EC – examination涡电流 – 检测

σ– Phase

Indication of 2% σ – phase

EC: 涡电流试验

- Differential examination for defects差别检验以发现不同的瑕疵

- Absolute test for sigma phase完全测试是为西格玛相

UT: 超声试验

- Defects: Longitudinal and Transversal发现问题：从纵切面 和 横切面

- Dimensional: OD, WT尺寸的：外径，壁厚

FERTILIZERS INDUSTRY

longitudinal inside 1

longitudinal outside 1

longitudinal inside 2

longitudinal outside 2

transversal 1

transversal 2

wall thickness

outer diameter

eddy current result

sigma phase

UT

EC

NDT single report无损探伤报告

Annealing continous tracking 退火连续跟踪

Quality assurance in line and after roduction

生产中和之后的质量保证

Continuous Material quality control: 连续不断的材料质量控制More than 50 parameters are controled along production to assure quality of the material. 整个生产过程中50多个参数被监控以保证材料质量

Tubacex Quality Department Tubacex质量部门

Quality in compliance with following specs:依从下列规格的质量：

Saipem SPC.CR.UR.510/520/521/529塞班 SPC.CR.UR.510/520/521/529----

Stamicarbon 18005 & A4 53961斯塔米卡帮 18005 & A4 53961--

Casale 8000-00MSM-001/007卡萨利 8000-00MSM-001/007-

Any std. Norm ASME/ASTM, EN, VdTUV...其它标准 ASME/ASTM, EN, VdTUV…------

Quality Laboratories (5 complete labs):质量实验室（5个完整的实验室）

Mechanical and technological test 机械和工艺测试Destructive tests 破坏测试Nondestructive tests 无损测试Metallographical tests 金相测试Corrosion tests 腐蚀测试

TX PRESENTATION 24

Conlusions 结论

Tubacex can supply all the range of dimensions of seamless steel materials to the Urea Fertilizers Market Tubacex可以提供尿素化肥市场所需的所有尺寸的不锈钢材料

tubing & piping (6mmOD to 42”), and fit t ings (from ½” to 72”) 管材和管道（6毫米到42英寸）

25.22.2, 316L UG, 2906… 25.22.2,316L 尿素级，2906…

Tubing is produced in a worldwide state-of-the-art plant in Austria. 管材生产于位于奥地利的最先进技术的工厂

Tubacex only produces high quality tubing, piping and fit t ings. Tubacex只生产高质量的管材、管道和管件

Quality materials product ion for the Fert ilizer Industry

Quality is determined at every stage of the complete process: 质量决定于工艺过程中的每个环节

Most suitable Melting and composition (HEAT cleanliness) 最适合的熔炼和成分（热清洁度 ）

Accurate Hot Extrusion Process (Temp. control) 精确的热挤压工艺（温度控制）

Analyzed Cold rolling Process (design parameters) 冷轧工艺分析（设计参数）

Unique Finishing Process (cleaning, annealing, handling) 独有的整理工艺（清洁、退火、操作）

Up to date NDT techniques at your service (UT, EC, PMI, traceability) 最新的无损测试技术随时为你服务（UT，EC，PMI，可追溯性）

TX PRESENTATION 25July 2013WWW.TUBACEX.COM

MANY THANKS FORYOUR ATTENTION

For further informat ion:Egoitz Lopategi

+34 680 42 16 50at the CNFIA 2015 booth