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www.entrepreneurindia.co Top Business Ideas of Profitable Manufacturing of Adhesives, Glues and Resins. Adhesive Factory/Plant

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Top Business Ideas of Profitable

Manufacturing of Adhesives, Glues

and Resins.

Adhesive Factory/Plant

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An adhesive or glue is a material, usually in a liquid or semi liquid state,

that adheres or bonds items together. Adhesives come from either

natural or synthetic sources. The types of materials that can be bonded

are vast but they are especially useful for bonding thin materials.

Adhesives cure (harden) by either evaporating a solvent or by chemical

reactions that occur between two or more constituents. Animal glues are

essentially high polymer proteins; these glues find application in a wide

range of industrial uses. Fish glue as the name indicates, is obtained as

the byproduct of the fish skin industry, was the first liquid glue that

reached commercial importance and was forerunner of all household

glues.

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Resins are used in the manufacture of adhesives, paints and number of

other products. Polyesters are thermosetting and thermoplastic resins for

various applications. Due to high cost they are used with other resins for the

application of adhesives. Polyamide resins used in adhesives can be divided

into four used classes; thermoset adhesives, nylon epoxy adhesives,

thermoset plastic adhesives and thermoplastic thermoset adhesives. The

adhesives industry has found its place in many industries and will surely

spread to many other fields. It is used in building, electrical, automobile,

aircraft and aerospace industries. The future advancement and

consumption are practically beyond mental comprehension.

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Even today, as ones surroundings are observed, the use of adhesives,

glues and resins are associated with almost every product that is

marketed. While use of all adhesives has increased, the greatest gain has

occurred in the synthetic resin category. The synthetic resin adhesive is

the most important for packaging uses. Pressure sensitive adhesive is a

fast growing segment of the industry. This field includes products

designed for the industrial trade but which can, by minor modification, be

marketed through the hardware dealer and variety store. Adhesives for

this growing market range from the simplest glues and mucilage for

furniture making and repair, to metal to metal bonding for frame

construction.

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Adhesives are the most adaptable bonding agents available in the market,

which remained unaffected by the recent global slowdown due to their

application in a wide variety of end-user industries. The major allied

industries for adhesives include packaging, woodworking and

construction industry. India adhesives market has recorded strong growth

during the period FY’2010-FY’2015 and is expected to sustain its rapid

growth during the next five years.

The adhesive industry was dominated by a few industrialized countries.

Now, a significant portion of new demand is being generated by emerging

countries such as China. The next major growth country could be India.

Market fragmentation continues as new adhesive demand is generated

from a supply and demand standpoint.

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The demand growth is also supported by the emergence of new market

applications that result from changing substrates and evolving assembly

processes. Increasing use of adhesives in automotive manufacturing

contributes to overall growth in the global adhesive resins market. The

construction sector, automotive market, and medical adhesives market have

all seen growth or resurgence that is contributing to a projected increase in

the world-wide market for adhesive resins. Adhesives offer distinct

advantages over mechanical fastening, sewing, and thermal bonding.

Adhesives can bind diverse materials, distribute stress evenly across a joint

and reduce cost. In addition, adhesive bonds are often more aesthetically

pleasing and contribute to the value of consumer products.

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Asia-Pacific is the biggest and the fastest growing region due to the

growing demand for adhesive resins in India, China, Japan, South

Korea, and Australia. North America is a matured market and is

expected to grow with a CAGR till 2020. The adhesive resin market

demand, in terms of value and volume, depicts the current and

future projections according to the parallel economic and industrial

outlook.

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Some of the fundamentals of the book are glues of animal origin, fish glues,

manufacture of animal glues, casein glues and adhesives, spray dried

melamine formaldehyde resins, epoxy resin adhesives, specialty epoxy

resins & derivatives, polychloroprene resin adhesives, phenolic resin

adhesives, resorcinolic adhesives, ethylene copolymer hot melt adhesives,

isocyanate adhesives, polyamide adhesives, rosin adhesives, silicone

adhesives and sealants, applications in pressure sensitive adhesives, starch

adhesives, acrylic adhesives and sealants, pressure sensitive adhesives,

amorphous polypropylene and petroleum resin, alkyd resins, use of alkyds in

trade sales finishes, etc.

The present book covers manufacturing aspects of various adhesives, glues

and resins. This will be very helpful to new entrepreneurs, technocrats,

technical institutes and existing units.

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Table of Contents

ADHESIVES

1. Glues of Animal OriginPropertiesMethods of ManufactureCommercial Grades and SpecificationsMethods of AnalysisSamplingProcedureIdentificationPhysical MeasurementsDetermination of Other Constituents

2. Fish GluesIntroductionManufacturing ProcessProperties

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Applications & FormulationsRubber-to-SteelStrawboard-to-SteelRubber-or Cork-to-PlywoodPaper-to-SteelStraight Line Gluing

3. Animal GluesIntroductionChemical CompositionManufacture of Animal GluesPropertiesLiquid Animal GluesFormulation & ApplicationsMethods of Application

4. Casein Glues and AdhesivesIntroductionProperties

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Casein Blend GluesLime free Casein AdhesivesApplicationsCasein Adhesives for Bonding PaperCasein Adhesive for Binding Dissimilar Materials

5. Blood Albumen GluesIntroductionSolubility CategoriesPropertiesBlood-Soybean Flour CombinationsMold ResistanceApplication

6. Amino Resin AdhesivesIntroductionManufacturing TechnologyUrea Adhesive for PlywoodUrea Adhesive for Particle Board

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Spray Dried Melamine-formaldehyde ResinsFoundry ResinAniline-Formaldehyde Resinà Represents benzene ringSulfonamide-Formaldehyde ResinsApplicationsAdhesives for Hardwood PlywoodSand Core BinderWater Proof Corrugated BoardCompounding and Formulation

7. Cyanoacrylate AdhesivesIntroductionBonding with CyanoacrylatesAdhesive PropertiesApplications

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8. Epoxy Resin AdhesivesIntroductionChemistryEpoxy Novolac ResinsFlexible Epoxy ResinsEpoxidized OlefinsSpeciality Epoxy Resins & DerivativesEpoxy Esters of RosinEpoxy Esters of Styrenated RosinEpoxy Esters of Disproportionated RosinEpoxy Novolac EstersEpoxy Ester of Maleopimaric AcidCompoundingCuring AgentsDiluentsModifiersFlexibilizersFillersAcceleratorsSpeciality AdditivesManufacture of Adhesives

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9. Phenolic Resin AdhesivesIntroductionResole resinNovalac ResinsManufactureApplications and FormulationsContact AdhesivesAdhesive CompoundingNitrile/Phenolic Contact AdhesivesStructural AdhesivesVinyl/PhenolicEpoxy/PhenolicHot Melt AdhesivesHot Melt Vinyl Film to Wood Laminating AdhesivesPressure Sensitive Adhesives (PSA)

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10. Polychloroprene Resin AdhesivesIntroductionTypes of PolychloropreneApplications and FormulationsApplications

11. Polyester Resin AdhesivesIntroductionLinear PolycarbonatesPolymerized OilsAlkyd ResinsUnsaturated Polyester AdhesivesAdhesives for Flexible Printed CircuitAllyl Ester Adhesives

12. Polyethyleneimine in AdhesivesIntroductionApplicationsGeneral AdhesivesTie Coat Adhesives

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13. Polysulfide Sealants and AdhesivesIntroductionPolysulfide SealantsChemistryCompoundingCuring AgentRetarderReinforcementAdhesion AdditivesPrimersImproved Heat ResistanceApplicationsAdhesives from Polysulfide Liquid PolymerEpoxy Resin Reactions

14. Resorcinolic AdhesivesIntroductionResorcinol-Phenol Formaldehyde ResinsModified Resorcinol Resins

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Aspects of Adhesion MechanismFormulation of Glue MixturesLaminating

15. Ethylene Copolymer Hot Melt AdhesivesIntroductionCrystallinityCompatibilityPressure Sensitive TackHot Melt Adhesive FormulatingBook Binding AdhesivesCarton and Case Sealing AdhesivesCarpet ApplicationShoe AdhesivesPressure Sensitive Adhesives (PSA)Furniture Adhesives

16. Furan Resin AdhesivesIntroduction

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IntroductionAdvantages of Isocyanate AdhesivesDisadvantages of IsocyanatesApplicationsTypes and uses of Isocyanate based Adhesive System

18. Lignin AdhesivesIntroductionFormulations

19. Polyamide AdhesivesIntroductionClass I: Thermoset Adhesives Containing Liquid Polyamide Curing AdhesivesClass II: Nylon-Epoxy ResinsClass III: Thermoplastic Hot Melt Polyamide AdhesivesClass IV: Thermoplastic-Thermoset Adhesives

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20. Polyimide AdhesivesIntroductionAdhesive and Bonding TechnologyFoam System

21. Rosin AdhesivesIntroductionApplicationsFormulationsSolvent AdhesivesEmulsion AdhesivesHot Melt AdhesivesMethods of manufacture

22. Silicone Adhesives and SealantsIntroductionChemistryOxime silaneProperties

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Rheological CharacteristicsThermal StabilityWeathering CharacteristicsAdhesion CharacteristicsApplicationsIndustrialConstruction

23. Tannin AdhesivesIntroductionFormulation

24. Terpene Based AdhesivesIntroductionChemistryBeta-pinene resinsDipentene resinsAlpha-pinene resinsPhysical characteristics of resins

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Pressure sensitive adhesivesHot melt adhesivesAnalytical methodsCommercial resins and their usesCommercial productionApplications in pressure sensitive adhesivesApplications in hot melt adhesives

25. Starch AdhesivesIntroductionUnmodified StarchesHigh Strength AdhesiveCheap Diluted AdhesiveNon-weather Proof Corrugated Board AdhesiveWater Resistant Corrugated Paper Box AdhesiveFinal MixtureAcid Modified or Thin Boiling Starch AdhesiveOxidised Starch AdhesivesDextrin Based AdhesivesProperties

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26. Acrylic Adhesives and SealantsPolymerizationSolution PolymerizationProperties of the productEmulsion polymerizationProperties of the dispersionPropertiesFormulations and ApplicationsAdhesives to paper coated with PVDCDelayed tack adhesiveAdhesives for LaminatingLaminating Plasticized PVC film to textilesLaminating PVC film to particle boardLaminating plasticized PVC film to split leatherHigh temperature &pressure laminationFlocking AdhesivesBuilding AdhesivesAdhesives for plasticized PVC floor tilesAdhesives for ceramic tiles

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Pressure-Sensitive AdhesivesFlame Resistant & Pressure Sensitive AdhesiveAcrylic SealantsAqueous Acrylic SealantsSolvent-Based Acrylic Sealants

27. Pressure Sensitive AdhesivesAdhesive Strip for Antomotive TrimEva-Trialkyl Cyanurate Copolymer AdhesiveCarboxylate Polymer Based AdhesivesFumaric Diester Vinyl Acetate Polymer

28. Hot melt AdhesivesIntroductionAdvantagesDisadvantageFormulationsEthylene-vinyl Acetate

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Amorphous polypropylene and Petroleum ResinIsopropenyltoluene Copolymers as TackifiersChlorinated Polyphenyl, ChlorinatedPolyisoprene and Nitroso CompoundCarpet Backing FormulationOther Polyolefin CompositionsAmorphous Polyolefin and Styrene ButadieneBlock CopolymersMethylstyrene Tert Butyl Styreneolefin terpolymersAlkoxystyrene-Acrylonitrile, CopolymersBoric Acid as Viscosity Stabiliser in Ethylene-Propylene AdhesivesThermoplastic Polymer and Chelate of AminoaceticAcidCoal Tar Pitch and Ethylene-Acrylic-Acid CopolymerWater-Moistenable Vinyl Pyrrolidone-VinylacetateProduct

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RESINS

1. Alkyd ResinsIntroductionClassificationSynthesisEtherificationAddition reactions of unsaturated monobasicfatty acidsAddition reactions with other unsaturated alkyd ingredientsReactions during coating formation with dryingalkydsReactions during coating formation in alkyd blendsRaw materialsManufactureHealth and SafetyQuality Control and SpecificationsAnalysis

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CalculationsUsesUse of Alkyds in Trade-Sales FinishesMethods of AnalysisDetermination of CompositionChemical MethodsDetermination of Properties and Impurities

2. Acrylic Modified Alkyd ResinsTraffic paintsIndustrial applicationsConclusion

3. Alkyd-Amino Combinations Based on Neem OilAim of present investigationUses of oils in surface coatingsNeem oilAlkyd resinsAmino resins

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Experiments & ResultsPreparation of alkyd resinAlkyd resin preparationPreparation of amino resinTesting of performances of resin samplesDiscussionAnalysis of neem oilPreparation of alkyd from neem oilPreparation of urea formaldehyde resinPreparation of thiourea formaldehyde resinPreparation of various samples (mixtures)Performances of various resin samplesScratch hardnessConclusion

4. Amino ResinsIntroductionRaw materialsChemistry of resin formation

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Typical resin formulations and techniquesUrea formaldehyde resinsHigh solids urea-formaldehyde adhesive resinProtective coating resin with high mineral spiritstoleranceMethylated urea formaldehyde textile resinsUrea-formaldehyde particle board adhesiveMelamine-formaldehyde resinsButylated melamine protective coating resinChlorine resistant melamine resinTrimethoxymethyl melamineHexamethoxymethyl melamineMelamine resin molding powderMelamine resin acid colloidControl of the extent of the reactionFree formaldehyde estimationViscosity testsSolubility testsCure tests

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Urea versus melamine resinsPackage stabilityCompetitive product analysisChemical modification for water soluble productsChemical modification for oil soluble productsEthyleneureaMethylated uron textile resinsUron resinsGlyoxal resinsMiscellaneous resinsAmino resins in the paper industryFormulations for regular and HE colloidsToxcityMethods of AnalysisCompetitive Product Analysis

5. Carbohydrate Modified Phenol-formaldehyde ResinsIntroductionResearch on Carbohydrate Modified Resins

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Carbohydrate-Modified Base-Catalyzed PF resinsBonding Veneer PanelsBonding Flakeboard PanelsCarbohydrate-Modified PF Resins Cured atNeutral ConditionsBonding Veneer PanelsColor of BondlineConclusions

6. Epoxy ResinsIntroductionSynthesis of Resin IntermediatesCycloaliphatic epoxiesEpoxidized polyolefinsEpoxidised oils and fatty acid estersAliphatic-cycloaliphatic glycidyl type resinsEpoxy novolac resinsResins from phenols other than bisphenol AResins from aliphatic polyolsResins from long chain acids

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Fluorinated epoxy resinsEpoxy resins from methylepichlorohydrinMiscellaneous epoxy resinsEpoxy estersWater borne epoxy resins and derivativesDiluents and modifiersEpoxide reactions and curing mechanismsCuring of epoxy esters

7. Hydrocarbon ResinsTypes of Hydrocarbon ResinsRaw MaterialsProperties of Hydrocarbon ResinsMethods of ManufactureCommercial Resin Types and SpecificationsMethods of AnalysisAnalysis of Raw MaterialsDetermination of Chemical PropertiesDetermination of Physical Properties

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8. Polyurethane ResinsChemistryRaw materialsIsocyanatesTolylene diisocyanate (TDI)4,4' diphenylmethane diisocyanate (MDI)Hexamethylene diisocyanate (HDI)Other diisocyanates used in coating systemsHydroxy componentHazards of isocyanatesClassification of polyurethanesUrethane oils and urethane alkydsMoisture-cured urethanesDrying timeCatalystsSolventsPigmentationAdditives

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Film properties and usesTypical formulationsManufactureBlocked isocyanate systemsTwo-component catalyst-cured polyurethanesTwo-component polyol type polyurethanes

9. Phenolic ResinsThe Chemistry of Phenolic ResinsThe Structure of Phenolic ResinsFormation of phenol alcoholsFormation of methylene bridgesFormation of dibenzyl ethersFormation of quinone methidesRaw MaterialsPhenolsAldehydesHexamethylenetetramine (HMTA)Fillers for Phenolic Moulding Powders

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Types of fillerThermal DegradationModified and Thermal-resistance ResinsEtherification reactionsEsterification reactionsHeavy metal modified resinsChemical ResistanceResistance to microorganismOil Soluble Phenolic ResinsComposite Wood MaterialMoulding CompoundsHeat and sound insulation materialsIndustrial laminates and paper impregnationCoatingsFoundry resinsPhenolic resin as ion-exchange resinAbrasive materialsFriction materialsPhenolic resin in rubbers and adhesives

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Niir Project Consultancy Services (NPCS) can provide Process Technology Book on

Top Business Ideas of Profitable

Manufacturing of Adhesives, Glues and

Resins. Adhesive Factory/Plant

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Contact us

NIIR PROJECT CONSULTANCY SERVICES

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Email: [email protected] , [email protected]

Tel: +91-11-23843955, 23845654, 23845886

Mobile: +91-9811043595

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