Title Cover

Author(s)

Citation The Review of Physical Chemistry of Japan (1966), 36(1)

Issue Date 1966-10-30

URL http://hdl.handle.net/2433/46872

Right

Type Others

Textversion publisher

Kyoto University

Vol. 36, 1966

The Review of Physical e strv ~Jap ol. 36 No VYI~

No.

19661

1

RMVIEVYoR

THE

ru~sic~~ OF IAPAN

CN~~IISTRY

Founded ie 1926

CONTENTS

Jiro Osogf, Kiyoahi Shimizn aad Hidato Takizawa: Effect of Pressure on the

Dissociation of Electrolytic Solution (III)-Electrical Conductivity of Hesam-

mine Cobalt (III) .Sulphate at Highf Pressures ................:........................

Jiro Osvgi, Tetuo Mizakami and Tadafumi Tachibana :: The Effect of Pressure on

the Keto-enol Equilibriaof Acetone. and Cyclohesanone ................:.............

Jiro Oavgi and-Himihiko Hara : _Efiecl of Pressure on the Electrical Conductivity

of Organic'Substances (I) Pyrolyud Polyavyloai[rile. .............................

Jiro Oaugi and Kimihiko Hara : High-pressure Melting fn Polyethylene ..............

Jiro Oaugi, Ryosuke Namikawa and Yoahiyvki Tanskal Chemical. Reaction at

High Temperature (III) Reaction of Silicon and Pliosphorus at High Tempera-

1

g

Lure and High Pressure

I{lyoshi Kitamara : Inacfival

of Bacterial N-Protein

za

29

35

Klyoshi IS:itamara : Inactivation of Enzymes under High Presu~e (II) Inactivation

of Bacterial N-Proteinase and ~-Amylase. of Barley under High Pressure ......... 44

J1ro Osugi and KiyoshI Shimizn, Yoshiyolci Taos]reand Kosaku Kadono: Pre-

paration and Chemical Properuesof Cubic Boron Arsenide, BAs ..................... 54

THE PHYSICOCHEMICAL SOCIBTY OF JAPAN

The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)

THE REVIEWOF PHYSICAL CHEMISTRY OF JAPAN

(BtJtsttri-Kagaku no Shinpo)

President: Shinkicbi Horiha, Professor Emecitus; M. J. A.

Members of Council:

Aauma Okuda (Chic()

J: Osugi %. %odera

R Goto

T. Yamamoto

T. Fujinaga

S. Tasaka

Board of lidltora:

j. Osugi (Chief)

Y. Rachi

H. Takagi

H. HatBna

W. Jono

R. Gota

E. Suito

Kyoto Uaiverrily

I. Tsujikewa

A. %aji

A. Saika

W: Jooo (Associate) UniversUy of Xobe

R. Goto ( n )Kyoto Univasify

E.-$uito ( n ) Kyofo l/niversily

Secretary(

S. Shida

T. %itagawa

)d. Tamura

H._Matsuyama- .

T. Makila

R Susuki

K_ Hirota

S. Seki

T. Ishiao

T, Imoto

R.:Fujishiro

O. Toyama

S. Ono

5. Tsuchihashj

5. Hasegawa

H. Togawa

R.Shimiau

T. Fujiwara

Tokyo Insfifu/e of Technology

Yokokama Universiy

Xyofo Univenily

Dothislsa Univenily

Kyoto Techeical Ursiveisiry

Ritrumeikaa Univenity '

Univerryy aJ Osaka

University aJ Osako

Bimefi Institute of Terhnology

Muaicipal Universily.aJ Osaka

MuniciyaJ Urtivarsily- of Osaka

PnfeUUrol Univeaity of Osaka

Profedvsal University aJ Osako

University of Kohe

Okayoma. University

Dorhisko Unioersity

M. Sata

The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)

:October 30, 1966

CommmloaNoae to the Editor shoud be addresud-to Soardofliditors, The Physico-Chemical Society

of Japan, College of Science BYoto University, &yoto,-Jepaa

Bnsfness Correspondences should be addressed to; Secretary,'The Physico=Chemical Society of Japan,

College of Science, Ryoto University, Ryoto, Japaa.

Pnrehnae Order should be addressed to::Ma~usen,-Co.; Ltd., Nihonbaahi, Chuo-ku, Tokyo, Japan.

TEE

Published lry

PHYSICO-CHEMICAL SOCIBTY OF JAPAN

(Nippon Butsuri-Kegaku Kenkyu Rai)

College oC Science„%yotoUniversity; Ryoto, Japan

Printed~by RAWAKITA INSATSU Cl).,-Ryoto, Japan

The Review of Physical Chemistry of Japan bol 36 No 1 (1966)

~r

~..

Many of fashions

to today

started

our

in

labs.

'S

S

K uAApAY..

1 /OW$_~. ~ ~ ~a 'Y ,- :- ~.~ ~ ,_,ti~",g .n

*'~~ 6: ' ~ ~ "r {~ • n y

~" ~x' .. ~~~ dt~ _ ...,, y~

-.. ... _ . ~~i. ...i~

.... ~ ; . Tha Review of Physiczl chemistry ofJaperll 36 No 1 (1966)

The

.~;t '

F

~~~~;

NVorld.

~. ~~r

,. ~-. _ ,

,..~. ..~~ ~ , .~ ~: ~~ ~ - ~. t ~ ,~. ~jM-Lei.i ,..

.r:

-;contributing

duction, the

K

--~

,,.

<:, ~- .,

~'~~.

- .,: .

r. h9w'tFie.cler.'tiig$t kn_g,'~rlio~, contriba#ing 'to the . tlereasg of ~~` ~~~ duction, the mode~i ~ ' 'h~ of 1

- ~:..

betterment of peopl~ , ~yy liv techniques are Iicens~fiY!;'apd products :have been

.,v~y.,~r: ~~ exported to more tli~n; 3'0.'cguntries.

These include urea, ammonium sulphate, synthetic

resins and plastics, and "other chemicals. ri:

T®1~0 K®ATSIJ ~' Nndu~tr~'se~; lnc .

Mitsui Daini Bekkdh, 2;4ghome,~NifiOnhas~~'.~Nongaku-Cha, Chuo•ku, Tokyo Cahle address : "TDATSU/ND TDNYD" -

• r.

~i a

' ~ ~ 'j

t.~~i f ~ . -!I~~aFF:j s~̂I~ ~ o~ic:~tCoa#eu~+:is~c~~ ~~I

._iagricislt~i a~'=pru-: ndustrfes' ~riii'<'the °_n :: es. Toyo,,Koatsu . - '

The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)

mix'

y, .-

~~~.~.=

~; ~' ~~: h ~~

~~ -~

r{rt:@~ y

c .~r..y..m.-,.- uax._...

® '~

`_~

NISSO(Ingredient

NI-CHLONCalcium Hypochlorite 70°/, min, granular & tablet)

;/Visso

• Sodium Cyanide

• Sodium Hydrosulphite

• TDI (Tolylene Diisocyanate)

• PPG (Polypropylene Glycol)

• Sulfisoxazole (Sulphafurazole)

• Benzoyl Peroxide (21.22%)

Manufarturer& Exporter of Chemicals

NIPPON SODA CO., LTD, Head Offfee : Otemachl, Tokyo, Japan

Cable Address : "SODANIPPOH" TOKYO

~u? .]1The Review of Physical Chemistry of Japan Vol.

L

36 No. 1 (1966)

I. Ca!*, Ready For Use The Tri-band ESR

I~ ~'~.... with Unique Linear Field Sweep Unit !

The JES36S is a new versatile ESR instrument with excellent features :- Super Sensitivity

Ultra Resolution Easy Operation Valuable Attachments

Tri~Measurement at X, K & Q Bands The JES-38S which is provided with a unique low~impedanee magnet, a direct read~aff circuit of the magnetic field and a linear field sweep method has the following records.

~~~-

;~...~-

=Y

-~

._

l

•Specifications (at X-Band measurement) Detection Sensitivity• • • • 1 x 10~~ spin/gauss

(100 kc modulation) 1 x 10'=spin/gauss

(80c/s modulation)Resolution 1x10-s or more

Standard Frequency•••9,400 Mc (X-band)Cavity Resonator

Variable Range

of Mag. Field

you (cylinder) Versatile type

500.13,000 Bauss

(18.000 gauss with the auxiliary pole piece)

ESR Signal of Crs' in single crystal of ruby N. B.: Absorption slgnais distinctly aDDeer in a

wide range by the linear field sweep unit.

JAPANELECTRONOPTICS LABORATORY CO.,lTO. New Tokyo Bldg., Tokyo, Japan

I

I

i

i

The Review of Physical Chemistry of Japan Vol. 36 No 1 (1966)

;~~~

VERYHIGH

.:

PRESSURE _--

..

EQUIPMENT

rte.

"GIA•• Equipment , Nh(e lype Very Nigh Prosmn Equ(pmsnl, Anrll Foes IOmmX/Omm, 70101 Ws(gh1 8 ton

~`

,_

_' P

p. ~~. Tim iT 1

.'p

~~~

~?,~.

a.

;~.a=~..::,

S.H.P. Nleaaromenr Gauge, Fkrtdeaf Rad#anee Srm/n Gwg~ Type,

G/ihrafsd with the /Nas/er fro.-Piston Gauge !n Kobe Sfaal.

(Japanese PAT. Np.394153J

KOBE STEEL• MACHINERY DIVISION HEAD OFFICE: 36, 1•chome, Wakinohama-cha, Fukiai-ku,

Robe, Japan OVERSEAS OFFICES: New York, DussiddroT. New Delhi TOKYO OFFICE: Yanagiya Bldg., No. 2-l, Tori 2-Chome,

Chuo-ka, Tokyo, Japaa

Liquid Pressure up to 15,000kg/cm~

Solid Pressure up to 700,000kg/emT

for Production and Research Purposes

Super Hlgh Pressure Generator Unit Super High Praswra Reaction Vessel Super High Pressure Measurement Gauge Super High Prsswre Equipment

Other Malor Products

Fertllizar Plant, Cement Plont, Oxygen

Plant, Rolled Stsel Products, Steel

Castl ngs & Forgl ngs, Genera I I ndustrial Machinery, Light Metal Alloy Cas-

tings & Forgings, Titanium Products,

Arc Welding Electrodes, Small Tools, Non Ferrous Metals & Their Products,

Sugar Cane Milling Plant and others.

J

The Review of Physical Chemistry of Japan Vol.

I

36 No. 1 (1966)

~~.

.,,,

~' ._ ~>r v

Single crystals of HORIBr1 INSTRUMENTS, INC., offered as complete products ready to use which are free from impurity absorption. have squired worldwide reputations.

Our scintillators, such as NaI (Tl), CsI (TI) or CaI2 are also credited and used internationally by the nuclear scientists, for the established qualifies.

Limit of transparancy (microns)

Refractive index:

Soluhil ity '•

Specific gravity: gr/cm~

Melting point: °C

Maximum diameter: mm

Maximum height: mm

NaCI KCI KBr KI LiF AgCI KRS-5' KRS-6• CsI

~-IS X21 -~27 X31 ~fi x-30 X40 -y34 -y70

1.555 L499 L559 1.667 1.394 2.071 2.629 233fi 1.987

35.i 28.5 53.5 ] 27.5 0.27 8.9 x 10'5 0.07 032 44

2.1fi 1.59 2.75 3.13 2.64 S.Sfi i.7 7.19 4.53

801 77fi 730 680 843 455 4I5 424 621

120 120 120 120 100 60 60 60 60

IW 100 100 70 60 ]00 60 100 100

s KRS•5 is a compound single crystal of TII and TIBr,

and TIBr. ss g/100 gr water at normal temperature.

and KRS-fi is a compound single crystal of TICI

HORIBA IN STRUME NTS, ING.

Head office & Factory: \akagawara 1liyanohigashi-machi,

Kissyoin, I.Iinami-ku, Kyoto Tel : 37-gt21

Tokyo branch office: \o. 2-10, 1Fi=hihatchobori, Chuo-ku,

Tokyo Tel: ii2-7661

The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)

PRODUCTS FOR

PRODUCTS

TODAY

FOR TOMORROW

KA.TV`EGAFUCHI now serves more than 100 industries

varying from food to feed, soaps to textiles, electric wires

to plastics.

KA?tEGAFUCHI's variety of products include industrial

chemicals, polymers, oil & fat products and fermentation

products. Such diversified operation ranks KANEGA-

FUCHI aunique position in the industry.

KA~IEGAFUCHI's research activities which enabled

successful achievement of today's products are continually

producing a flow of new products to meet the challenge

of tomorrow

i

~~ C ~

~. '

~~

~ ~~

:11!1

t

~ft 19f~~IR'~ a • I~~~~ • :~~r

PRINCIP~A"L~''PRODUCTS

•KAKEVINYL (PVC &

copolymer, PVC compound)

•KAA"E ACE-S (ABS resin)

•KANE ACE-B (PVC modifier)

•KANE PEARL (expandable

polystyrene beads) eKANEKALON (modacrylic

fiber)

• Electric wires & ables

o Caustic soda, FIydrochloric acid,

KAXECHLOR (transformer oil,

beat transfer medium), Butanol, Acetone

O Bakery }•east, RNP (ribo-

nucleo-protein), b1IKAMY- Peed (animal feed additives)

• illargarine. Shortening oil,

Soap, Glycerine

KANEGAFUCHI CHEMICAL INDUSTRY

14, 2-chome, Awezi-machi, Higashi-ku, Osaka, Japan

Cable address: CHEM[G-ANE

CO, LTD.

The Review of Physical Chemistry of Japan Vol. 36 No. 1 (1966)

ASAHI CHEMICAL INDUSTRY CO., LTD.

Capital: ~15,000A00.000

President: KAGAYAKI ;v1IYAZAKI

Head Office: 25, 1-c6ome. Dojima-hamadori, Kita-ku Osaka, Japan

Tokyo Office: 12, Lchome. Yurakucho, Chiyoda-ku Tokyo, Japan

Other Branch Offices: Nobeoka, Fuji, Fukuoka, Sapporo, Nagoya, Fukui, Kanazawa, New York

Plants: Nobeoka. Fuji, Kawasaki, Sakanoichi, Wakayama

Laboratories: Tokyo (Technical Research Laboratory) Takatsuki (Textile Research Laboratory)

Asahi's history dates as far back as 1923 when

the late Mr. Jun Noguchi, who was the firs[

president of the company, erected a synthetic ammonia plan[ in Nobeoka, present site of the

company's major plants. This is a memorable

plant in that the fist commercial production of synthetic ammonia in the world by the Casale

process was successfully started at this plant. Thereafter Asahi's production activity rontim

ved to expand, with the exception oC the war

years, into great many fields. Using ample elec-tric power from its own power plants and stand-

ing on the firmly established basis that primary

raw materials are available within the company.

Asahi has been producing chemical fibers, s}•n-

thetit resin, explosives, chemiral fertilizers, chemical seasoning, industrial nitrocellulose and

several scores of chemicals of ammonia, soda and

chlorine derivatives.

This fact points up to Asahi's special feature

as a chemical compan}•. Asahi ranks first in the

production of viscose rayon in Japan and its cuprammonium rayon capacity is largest in the world. Using acrylonitrile monomer produced

by Sohio process at its Kawasaki plant. Asahi

produces polyacrylic fiber "Cashimilon" by its own process. Production acrylonitrile monomer

and of polyazrylic 56er is also the largest in

Japan. Asahischemital seasoning(monosodium

glutamate) Asahi Aji, ranks second in output of similar chemical seasonings. Sun-Nitrq Asahi's

unique chemical fertilizer, is building up for it-

self aspectacular sales. Asahi's industrial nitro-

cellulose and electrolytic soda production is the

largest in Japan. Asahi is also at the top in pro-

duction volume of all the explosives manufac-

turers in Japan. Recently Asahi launched into

three new fields of operation, i. e. nylon 6, syn-

thetic rubber polybu[adiene "ASADENE" and

new building material "Silikaltsuiit".

At present. Asahi's products arc exported to

50 diKerent countries. Export of the process is

also making headway. 15'orthy of mention in

this connection is the export of viscose rayon

manufacturing techniques to Che Baroda Rayon

Corporation, India and Dawood Industries Lim-

ited, Pakistan, and of polyazrylic fiber manu-

facturing techniques to ANIC S. p. A., Italy.

Through all these activities, the excellence of

Asahis techniques is highly evaluated. Asahi now has many powerful affiliates, in-

cludiag Asahi-Dow Limited and Shin Nihon

Chemical Industry Co., Ltd. and is proceeding

on the road to further growth as a multiple-

purpose chemical compan}•.