TIG welding – Method and Application - Electro- · PDF fileTIG welding – Method...

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1 TIG welding – Method and Application TIG welding Definition The designation TIG comes from USA and is an abbreviation of Tungsten Inert Gas. Tungsten - also called wolfram - is a metal with a fusion point of more than 3300oC, which means more than double the fusion point of the metals which are usually welded. Inert Gas is the same thing as inactive gas, which means a type of gas that will not to combine with other elements. In Germany this method is called WIG welding, the W meaning wolfram. TIG welding is the international standardised designation for this welding method. According to DS/EN 24063 this welding process has number 141. The Principle of TIG Welding TIG welding is an electric arc welding process in which the fusion energy is produced by an electric arc burning between the workpiece and the tungsten electrode. During the welding process the electrode, the arc and the weld pool are protected against the damaging effects of the atmospheric air by an inert shielding gas. By means of a gas nozzle the shielding gas is lead to the welding zone where it replaces the atmospheric air. TIG welding differs from the other arc welding processes by the fact that the electrode is not consumed like the electrodes in other processes such as MIG/MAG and MMA. If it is necessary to use filler material, it is added either manually or automatically as a bare wire. TIG welding Principle Feeding of filler material

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TIG welding – Method and ApplicationTIG weldingDefinitionThe designation TIG comes from USA and is anabbreviation of Tungsten Inert Gas.

Tungsten - also called wolfram - is a metal with afusion point of more than 3300oC, which meansmore than double the fusion point of the metalswhich are usually welded.

Inert Gas is the same thing as inactive gas, whichmeans a type of gas that will not to combine withother elements.

In Germany this method is called WIG welding,the W meaning wolfram.

TIG welding is the international standardiseddesignation for this welding method.

According to DS/EN 24063 this welding processhas number 141.

The Principle of TIG WeldingTIG welding is an electric arc welding process inwhich the fusion energy is produced by an electricarc burning between the workpiece and thetungsten electrode.

During the welding process the electrode, the arcand the weld pool are protected against thedamaging effects of the atmospheric air by aninert shielding gas.

By means of a gas nozzle the shielding gas is leadto the welding zone where it replaces theatmospheric air.

TIG welding differs from the other arc weldingprocesses by the fact that the electrode is notconsumed like the electrodes in other processessuch as MIG/MAG and MMA.

If it is necessary to use filler material, it is addedeither manually or automatically as a bare wire.

TIG welding Principle

Feeding of filler material

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Automatic feeding of filler material

The TIG ArcAs mentioned before the fusion energy in TIGwelding is produced in the arc burning betweenthe tungsten electrode and the workpiece.

The wire feeding can be done manually ormechanically.

In DC TIG welding the tungsten electrode isusually connected to negative polarity and theworkpiece to positive polarity.

According to the theory of electrons thenegatively charged electrons and positivelycharged ions will migrate when the arc is ignited.

The electrons will migrate from the negative poleto the positive pole while the ions will travel inthe opposite direction.

In the arc there will therefore be a collisionbetween the electron and the ions and thiscollision produces heat energy.

Migration of electrons and ions in TIG welding

The flow of electrons from the point of theelectrode takes place at a very high speed andwhen it hits the workpiece a substantial amount ofheat energy is produced.

When the flow of ions hits the point of theelectrode there is not produced a similar amountof hear energy.

The total produced heat energy is distributed byapprox. 30% to the point of the electrode that isconnected to the negative pole and approx. 70% tothe workpiece connected to the positive pole.

Alternating CurrentAlternating current is characterised by the fact thatthe voltage changes polarity a certain number oftimes, usually 100 times per second.

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Heat distribution at TIF welding

The electrode has positive polarity in a semi-period and in the same semi-period the workpieceis negative.

In the next semi-period the polarity is reversed,which means that the heat energy distributes with50% on the electrode and 50% on the workpiece.

ApplicationAdvantagesThe TIG welding process has a very large area ofapplication due to its many advantages, e.g.:• It provides a concentrated heating of the

workpiece.• It provides an effective protection of the weld

pool by an inert shielding gas.• It can be independent of filler material.• The filler materials do not need to be finely

prepared if only the alloying is all right.• There is no need for after treatment of the

weld as no slag or spatter are produced.• Places of difficult access can be welded.

Areas of applicationTIG welding is often used for jobs that demandhigh quality welding such as for instance:• The offshore industry• Combined heat and power plants• The petrochemical industry• The food industry• The chemical industry• The nuclear industry

Materials for TIG weldingThe most important area of application is:• Welding of thin materials in stainless steels• Aluminium• Nickel• Nickel alloys

The increasing demands to the weld quality hasmade TIG welding very popular for welding ofsmaller tube dimensions as well as root runs inboth non-alloyed and alloyed materials in heavierplates.

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The below table shows which materials can beTIG welded and the recommended types ofcurrent and polarity.

Material Type ofcurrent

Electrodepolarity

Unalloyedsteels

= -

Low-alloyedsteels

= -

Chromium/nickel steels

= -

Chromiumsteels

= -

Copper alloys = -Nickel alloys = -Titanium = -Lead = -Alluminiumalloys

~

Magnesiumalloys

~

Legend: = DC, ~ AC, - negative, + positive

Direct current with negative polarity on theelectrode is used for TIG welding of mostmaterials.

Welding aluminium and magnesium is usually notpossible with direct current. The reason for this isthat a strong layer of oxide, which is difficult tobreak through due to its high fusion point, coversthese materials.

Therefore aluminium, magnesium and their alloysare usually welded with alternating current whichis capable of breaking the oxide layer.

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TIG Welding Equipment

ConfigurationIn order to handle the TIG welding process andmake it work to its full capability you needequipment consisting of different parts with theirown separate function.

The TIG welding equipment chiefly consists of:• A TIG torch that is the tool the welder uses to

control the arc.• A power source which is capable of providing

the necessary welding current.• A TIG unit with incorporated control systems

that make it possible to adjust the weldingcurrent, arc initiation etc.

• A shielding gas cylinder with pressurereducing valve and flowmeter.

1 Cable for welding current2 Cable for welding current3 Control cable for TIG unit4 Shielding gas5 Cable for welding cable for TIG

torch6 Control cable for TIG torch7 Welding cable with +polarity

Example for configuration of welding equipment

Many TIG welding machines are constructed insuch a way that the power source and the TIG unitare one unit.

Power source and TIG unit in one unit

TIG TorchThe main purpose of the TIG torch is to carry thewelding current and shielding gas to the weld.

TIG Torch

The TIG torch is constructed on the basis of thewelding handle and a torch head that is coatedwith an electrically insulated material.

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The torch handle is usually fitted with a switch toturn the welding current and the shielding gas onand off.

1. Torch head2. Handle3. Control switch4. Electrode cap5. Sealing ring6. Electrode collet7. Heat shield8. Collet body9. Gas nozzle

Drawing of TIG welding torch

The electrode collet is split in order it cancompress to fit tight around the electrode whenthe electrode cap is tightened.

In order to avoid a too heavy current load on theelectrode the torch is constructed in a way that thecurrent transfer to the electrode takes place veryclose to the electrode point.

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The long torch cap, shown on the drawing, can beexchanged by a shorter version in order for thetorch to be used at restricted areas.

However, the cap is usually so long that it cancover an electrode of normal length.

TIG torches are available in many different sizesand designs according to the maximum requiredcurrent loads and the circumstances under whichthe torch is to be used.

The size of the torch will also depend on itscooling capacity during welding.

Cooling of the TIG TorchSome torches are constructed in such a way that itis the flowing shielding gas that cools the torch.However, the torch also gives off heat to thesurrounding air.

Other torches are constructed with cooling tubes.Water-cooled torches are mainly used for weldingwith larger current intensities and AC-welding.

Usually a water-cooled TIG torch is smaller thanan air-cooled torch designed to the samemaximum current intensities.

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Some of the new TIG torches also have a triggeron the torch handle for control of the weldingcurrent during welding.

The Gas NozzleThe function of the gas nozzle is to lead theshielding gas down around the welding zone andthereby replace the atmospheric air.

The gas nozzle is screwed onto the TIG torch so itcan be exchanged if required. It is usually made ofa ceramic material able to stand the massive heat.

The size of the gas nozzle is often indicated by anumber that refers to the interior diameter of theorifice in 1/16”.

ExampleA gas nozzle no. 4 has an interior diameter of4/16” corresponding to 6.4 mm.

Common gas nozzle and gas nozzle with gas lens

Gas LensAnother type of gas nozzle is the gas lens which isconstructed in a way that the shielding gas passesthough a wire grid in order to make the flow ofgas more stable at a longer distance.

Flow of shielding gas

The advantage of the long gas flow is the fact thatthe electrode can have a longer stick-out thusallowing the welder to have a better view of theweld pool. By means of a gas diffuser it is alsopossible to reduce the consumption of shieldinggas.

The Power SourceThe power sources for TIG welding generallyhave an open circuit voltage of about 70 to 80 V.

For welding with direct current a power source isused that rectify the alternating current of themains supply of 400 V to the suitable output forthe TIG process and at the same time changes thecurrent intensity to the level set by the welder onthe welding machine.

Modern welding machines are capable of weldingof welding either in a DC mode or some unitsprovide both AC and DC modes.

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TIG BoxesThe control system of the TIG equipment can beeither very simple or very advanced with manydifferent functions.

In its most simple version only the weldingcurrent is controlled and the shielding gas isturned on/off by a small valve on the TIG torch.

The more advanced TIG boxes are capable ofcontrolling the shielding gas so it is lead to thewelding place before the arc is ignited, anddelaying the interruption of the shielding gas afterthe welding current is cut off.

This means that the tungsten electrode and theweld pool are also protected from the atmosphericair during the cooling period.

Furthermore, the TIG box usually has an ignitionfacility in order to avoid having to scratch theelectrode against the workpiece and thusdamaging the electrode point.

This ignition facility can be a high frequency unit(HF) which increases the frequency to 2 to 4million periods per second and the voltage toseveral thousand volts.

The high frequency and the voltage make itpossible to produce a spark between the electrodepoint and the surface of the workpiece thattransfers the arc.

High frequency ignition

Another type of control of the ignition can be anincorporated unit which is capable of limiting theshort-circuit current at the moment of ignition, sothat when welding starts the point of the tungstenelectrode can be placed directly on the workpiecewithout sticking. The control then increases thewelding current intensity when the electrode islifted from the workpiece thus igniting the arc.

This kind of control has several names as forinstance LIFTARC or LIFTIG.

Ignition with the LIFT method.

Other possibilities for control of the ignition are:• Slope control that makes it possible to pre-

program the increase of the welding currentwhen welding starts and the decrease of thewelding current when welding stops. Slopecontrol is especially important at the end ofwelding to help eliminate porosity and shrinkholes.

Slope facility

Current pulsation means that two welding currentlevels are pre-programmed. These are pulsecurrent and base current.

The base current is only large enough to maintainthe arc.

The fusion of the base material then takes placewhen the pulse current is present and the weldpool cools when the base current is present but thearc is maintained.

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The pulse and base current periods are alsocontrollable.

When welding is done with pulsing welding modethe weld is in principle a row of spot weldsoverlapping to a larger or smaller extentdepending on the welding speed.

Example of a weld with pulsing arc

Many double-current machines are equipped witha control function which makes it possible tomodify the curve of the alternating current inorder to make more square, and also modify thebalance between the positive and the negativesemi-periods.

Example of a modified AC curve

These control possibilities are very advantageouswhen TIG welding aluminium, magnesium andtheir alloys.

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TIG Welding – Grinding of Tungsten ElectrodesElectrodes for TIG WeldingFor TIG welding the applied electrode is mainlymade of tungsten.

Pure tungsten is a very heat resistance materialwith a fusion point of approximately 3,380oC.

By alloying tungsten with a few per cent of ametal oxide the conductivity of the electrode canbe increased which has the advantage that it canthereby resist a higher current load.

The alloyed tungsten electrodes therefore have alonger lifetime and better ignition properties thanelectrodes of pure tungsten.

The most frequently used metal oxides used foralloying of tungsten are:• Thorium oxide ThO2• Zirconium oxide ZrO2• Lanthanum oxide LaO2• Cerium oxide CeO2

Colour Indications on TungstenElectrodesAs the pure tungsten electrodes and the differentalloyed ones look the same, it is impossible to tellthe difference between them. Therefore a standardcolour indication on the electrodes has beenagreed.

The electrodes are marked with a particular colouron the last 10 mm.

The most commonly used types of tungstenelectrodes are:• Pure tungsten is marked with green colour.

This electrode is especially used for ACwelding in aluminium and aluminium alloys.

• Tungsten with 2% thorium is marked with redcolour. This electrode is mostly used forwelding of non-alloyed and low-alloyed steelsas well as stainless steels.

• Tungsten with 1% lanthanum is marked withblack colour. This electrode is equally suitedfor welding of all TIG weldable metals.

Electrode DimensionsTungsten electrodes are available in differentdiameters from 0.5 to 8 mm.

The most frequently used dimensions for TIGwelding electrodes are 1.6 - 2.4 - 3.2 and 4 mm.

The diameter of the electrode is chosen on basis ofthe current intensity, which type of electrode thatis preferred and whether it is alternating or directcurrent.

Grinding AngleAn important condition for obtaining a good resultof TIG welding is that the point of the tungstenelectrode must be ground correctly.

When welding is done with direct current andnegative polarity, the electrode point should beconical in order to obtain a concentrated arc thatwill provide a narrow and deep penetrationprofile.

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The following thumb rule indicates the relationbetween the diameter of the tungsten electrodeand the length of its ground point.

A small pointed angle gives a narrow weld pooland the larger the pointed angle the wider theweld pool.

Example of grinding of tungsten electrodes forDC welding

The pointed angle also has an influence of thepenetration depth of the weld.

Connection between the pointed angle and theweld pool

Blunting the electrode point to make a flat areawith a diameter of about 0.5 mm can increase thelifetime of the tungsten electrode.

Flat electrode point

For AC TIG welding the tungsten electrode isrounded as during the welding process it is soheavily loaded that it is melted into a half globularform.

Tungsten electrode for AC welding

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Grinding of the TungstenElectrodeWhen grinding the electrode its point must pointin the direction of the rotation of the grinding discso the grinding traces will lie lengthways theelectrode.

Wrong grinding Right grinding

In order to obtain an extra fine grinding of theelectrodes, the use of a grinding machineespecially for the grinding of electrodes can beadvantageous.

Such machines have a rotating diamond coateddisc which makes very fine grinding traces.Usually these machines are equipped with adevice for fixation of the electrodes with anadjustable grinding angle adding to a uniformgrinding.

Tungsten grinding machine

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TIG Welding - Shielding Gas

GasesThe shielding gas has several functions. One ofthem is to replace the atmospheric air so it will notcombine with the weld pool and the incandescenttungsten electrode.

Furthermore, the shielding gas also plays animportant role in connection with the transfer ofcurrent and heat in the arc.

For TIG welding two of the inert gases used areargon (Ar) and helium (He) of which argon is themore frequently used.

The two inactive shielding gases can be mixedwith each other or each of them mixed with a typeof gas which has a reducing effect.

To say that a gas is reducing means that it cancombine with oxygen.

In connection with TIG welding the two reducinggases, hydrogen (H2) and nitrogen (N2) are used.

The shielding gas can be chosen on the basis ofthe material to be welded.

Non

-allo

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and

low

-al

loye

d st

eels

Stai

nles

s ste

els

Nic

kel-a

lloye

d

Cop

per-

allo

yed

Alu

min

ium

-allo

yed

Ar x x x x x

Ar/H2 x x

Ar/He x x x

He x x

The choice of the correct shielding gas.

For protection of the backside of the weld it canbe advantageous to use a mixture of the reducinggases, N2/H2, the so-called backing gas.

The shielding gases are supplied in cylinders ofsteel painted in standardised colours in order tomake them easily recognisable. For this purposethe colour of the actual cylinder and the colour ofits shoulder area is used.

Colour of thecylinder

Colour of theshoulder

Ar Turquoise Turquoise

Ar/H2 Turquoise Red

Ar/He Turquoise Brown

He Brown Brown

N2/H2 Light grey Red

Colour indications on shielding gas cylinders

Pressure Reducing Valve andFlowmeterThe pressure in the steel cylinders is between 200and 300 bar. In order to use the shielding gas thehigh pressure must be reduced to a suitableworking pressure.

A pressure-reducing valve is used to reduce thepressure. The pressure-reducing valve is usuallyfitted with a gauge where the actual cylinderpressure can be read.

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In order adjust the required gasflow for the TIGwelding the drawing below shows a pressure-reducing valve with incorporated flowmeter.

Pressure reducing valve with flowmeter

In the flowmeter there is a small ball which iselevated by the flowing gas thus making itpossible to read the gas flow in litres per minute.

Please note that the measuring meter of theflowmeter must be placed vertically and that theflowmeter is designed for the used type ofshielding gas or else there is a risk for errorreadings.

Not all pressure-reducing valves are equippedwith a flowmeter. Some types have a workinggauge with a litre scale, or use a separateflowmeter.

Pressure reducing valve with working manometerwith a litre scale

A flowmeter, which measures directly on the gasnozzle, can be used to control that the requestedamount of shielding gas exists at the opening ofthe gas nozzle.

Direct measurement on the gas nozzle

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The amount of shielding gas depends on theinterior diameter of the gas nozzle.

Indicated values for the amount of shielding gas.

A too large amount of gas increases the outflowspeed in the gas nozzle. This may cause air to bewhirled into the shielding gas due to the injectoreffect.

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TIG Welding - Personal Safety

Heat and Welding Light

The light emitted from the arc is very damaging tothe eyes and may cause “arc eyes” which feelslike having sand in the eyes. The heat emissionmay cause cataracts, which is a destruction of theeyeball. The light from the arc is very damagingto the skin and may cause the same symptoms as aserious sun burn on the uncovered skin.

Protection against Light andHeat

Welding HelmetThe welding shield protects the face and the eyesfrom heat and light and is available as a handshield or welding helmet. The shields are fittedwith dark, graded filter lens that reduces the lightand protects the eyes from the arc radiation. Infront of the dark filter is a clear cover protectingthe dark one.

Types of Shielding FiltersThe types of the shielding filters have beenstandardised by the British or European standardsbut are usually supplied according to Germanstandard (DIN), Deutsche Industrie Norm. Thetype of the filter should be chosen according tothe strength of the arc, the light in the room andthe welder’s eyes. The area surrounding thewelding area must also be a suitable shade so thatthe light emitted from the arc does not disturb thewelder, but not so dark that it makes it difficult tosee the surroundings of the weld zone when thearc is established.

For arc welding the following density of weldingfilters are recommended. These recommendationsare meant as guidelines. New examinationmethods have established those welding filterswith a density of > DIN 5 provides protection ofthe eye.

Less than 100 A DIN 7- 9100 to 300 A DIN 10-11More than 300 A DIN 12-14

Shielding of the Working PlaceBy shielding off his working place the welder canprotect other persons in the room from thewelding light. Even at a distance of 10 metres thearc may cause “arc eyes”, if you look directly intoit.

Working ClothesWorking clothes protect the skin against the lightand heat radiation.

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Working GlovesThe working gloves protect the hands and wristsagainst heat and light. The gloves are usuallymade of leather and the top should be at least 120mm long. The gloves should be kept dry due tothe electrical safety (electrical leak resistance isgreatest at dry gloves).

Arc Eyes

EffectFlashes from the arc and reflections from shinyobjects can cause “arc eyes”. The cornea dries upand may burst. Arc eyes feel very uncomfortable,like having sand in the eyes. Normally arc eyes donot cause lasting damage, but repetitive exposureto welding light may cause a reduction of thevision power.

TreatmentCold packs offers palliation and certain ointmentswill provide a local anaesthetic. If the painpersists you should see a doctor who canprescribe an eye lotion that palliates the pain.When using such ointment or lotion willanaesthetise the eye so that grinding dust mayenter the eye without being noticed.

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Pressure Gas Cylinders

AppellationChemical

designationAreas of application Colour of bottle Connecting thread

Cylindri-cal part

Shoulderpart

Acetylene(gas)

C2H2 Welding, cutting and the like Reddish brown RG inside right

Argon Ar Shielding gas welding of allmetals

Light grey 24, 32 WG outside right14 thread/inch

Hydrogen H2 Reduction- and shielding gas forchemical- and metal-workingindustry. Generator cooling.Plasma welding and -cutting

Light grey 21, 8 WG outside left14 thread/inch

Air – Compressed airInhalation

Black WhiteBlack

RG inside right

Nitrogen N2 Gaseous: Shielding gas formetal-working industry,chemical industry, food industryand electro industry.Liquid: Cooling and freezing

Green Black 24, 32 WG outside right14 thread/inch

OxygenTechnical

O2 Gas weldingFlame cutting

Light blue White 21, 8 WG outside right14 thread/inch

Oxygen,Technical

O2 Welding, cutting and the like Light blue White 21, 8 WG outside right14 thread/inch

Cylinders under pressure must be secured againstoverturning, rolling, falling and heat (sunexposure and heat from boiler systems). Theymust be easily accessible and easy to remove incase of fire. At entrances where pressurecylinders are kept there must be a sign shownindicating hazards.

Transport of cylindersCylinder should be handled in a safe and propermanner using the appropriate trolleys etc.

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Electric Safety in TIG Welding

Electric current and risks

Electricity is a good servant, but a hard master.The electrical danger of electric arc welding isusually quite small if the necessary safetyregulations are observed.

Open Circuit VoltageWelding equipment must observe the allowedpresent open circuit voltages as indicated in thecurrent electrical regulations.

Equipment for manual or semiautomaticoperation:• Alternating current - 80 V (effective value)• Direct current ripple voltage > 10% 80 V

(effective value)• Direct current ripple voltage < 10% 100 V

(mean value)• Transportable equipment for private use - 70

V (effective value)

Mains Voltage Supply230 or 400 V is highly dangerous, but normally itis unlikely to get into contact with the mainvoltage supply.

Defective InsulationDefective insulation of the main supply may causeleaks and dangerous contacts.

Earth ProtectionAll machines should be earthed especially oldermachines which may not be double insulated.

Maintenance of the Welding EquipmentThe operator should carry out daily housekeepingchecks on the welding equipment to pick upnormal wear and tear. Equipment should also bemaintained on a regular basis to ensure that it issafe to use and kept it in peak operating condition.

Electrical Safety in TIG Welding

Power SourcePower sources with both direct and alternatingcurrent are often used for TIG welding. The opencircuit voltage of these power sources is oftenwithin the same range as that of equipment forused for ordinary arc welding with coatedelectrodes.

The welding machine is often equipped with ahigh frequency facility for ignition of the arc.

If the machine is not equipped with a highfrequency facility it can be used according to thesame regulations as equipment for ordinary arcwelding with coated electrodes. If however, theequipment is fitted with a high frequency facilitythe electric hazards are increased and it shouldtherefore only be operating in a dry environment.

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Primary ConnectionMains ConnectionFitting of the mains connection on machines suchas welding machines must only be done by acompetent person.Two errors often occur when mounting weldingmachines:• Incorrect connection of the cables• Missing or incorrectly fitted cable gland.

An incorrect connection can occur when e.g. athree-pole cable is connected to the three clampsof the welding machine. A phase and an earthconnection could be mistaken, so that the machinecasing could be alive, and it would then be highlydangerous to touch the machine.

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Secondary Connection

Cables and ConnectionsAll cables and connections must be insulated. Thismeans that all connections should be made withinsulating straight-through joints and not like it isoften seen, with metal cable rings tightenedtogether with a bolt screw.

If the insulation of the cable is ruined, the cablemust be discarded or the insulation repaired. Inelectric arc welding it is important that the cablecross-section is sufficiently large throughout theentire circuit.

Too thin cables with torn cores or poor switchesmay cause both an unstable welding current andunintentional heating which may have disastrousconsequences.

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TIG Welding - Fumes Production

General Information of WeldingFumes and TIG WeldingAt a first glance there are no fumes production orvery little fumes to be seen when TIG welding.But that should not lead us to think that TIGwelding does not produce any unhealthysubstances.

Different factors influence on the concentration ofunhealthy substances in the inhaled air, e.g. thecurrent intensity, the steel quality (unalloyed, low-alloyed and high-alloyed steels) and the cleaningof the materials of for instance cutting lubricantsand anti-corrosives.

Welding Fumes and GasesNitrous GasesWhen welding with shielding gas smallerconcentrations of nitrous gases are produced. Thegases are produced because of the stronggeneration of heat, which is a result of thechemical reaction between nitrogen and oxygen.

Nitrous gases is a common name for a group ofelements which are also called nitric oxides ofwhich there are several different ones.

Only two of these have a fixed TLV (ThresholdLimit Value). The TLV of nitrogen oxide (NO) is25 PPM. The TLV of nitrogen dioxide (NO2) is 3PPM.

If nitrogen oxide and ozone is mixed (as it is thecase when TIG welding) they produce nitrogenpentoxide which is more toxic that the othernitrous gases.

Nitrous gases only feel faintly irritating and it istherefore harder to discover in due time. Whenexposed to concentrations more than the TLV thissubstance may cause instant and highly dangerousdamages to the lungs, e.g. pulmonary oedema andthe pulmonary disease emphysema.

OzoneOzone is produced when the oxygen of the air isexposed to ultraviolet radiation, as is the case withTIG welding. There are only a few differentwavelength ranges within the UV-radiation thatcan produce ozone. The most efficient part of thewavelengths between 130 and 175 nm will becompletely absorbed in the closest air layerimmediately outside the shielding gas, and largeamounts of ozone is produced. This is happeningbecause of the high absorption in the oxygen. Inthe shielding gas there is no absorption andtherefore no production of ozone. The TLV ofozone is 1.0 PPM.

Opposite the nitrous gases, ozone can be detectedby its very characteristic smell. Even in lowconcentrations ozone feels strongly irritating onthe eyes and respiratory passages. It may causeheadaches and fatigue and after a longer period ofexposure the pulmonary function will be reduced.

Iron OxideIron is the most important element in steel. Theheating of iron produces fumes with a content ofiron oxide. Inhalation of large amounts of ironoxide may cause reduced pulmonary function.

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ManganeseManganese is set free by welding in steels withmanganese e.g. non-alloyed and low-alloyedsteels. Manganese influences on the brain causingsymptoms such as headaches, weakness, loss ofappetite and sleeping problems.

Manganese is harmful to the respiratory passagesand increases the risk of pneumonia. Highconcentrations may cause metallic fumes fever.

ChromiumChromium is set free during welding in low- andhigh-alloyed steels. A distinction is drawnbetween chromium 3 and chromium 6:

The threshold limit value of chromium 3 is 0.5mg/m3.The threshold limit value of chromium 6 is 0.02mg/m3.

Both chromium 3 and chromium 6 may causeallergy e.g. as a rash in the face when welding instainless steels. Chromium 6 causes seriousirritations to the respiratory passages and maycause sores in the oral cavity, nasal cavity andthroat. There is also a risk of chronic bronchitis.Chromium 6 is also suspected to be carcinogenic.

NickelNickel is set free during welding in low- and high-alloyed steels.

The threshold limit value of nickel is 1 mg/m3(difficulty soluble combinations). The thresholdvalue of nickel is 0.1 mg/m3 (solublecombinations).

Nickel is a highly allergy-causing agent that alsocauses rashes and asthma-like diseases. Nickel isalso suspected to be carcinogenic.

Hygienic Limit Values

Threshold Limit Values (TLV)The Danish National Labour Inspection has set upthreshold limit values of the highest permissibleconcentrations of harmful elements in the inhaledair in order to protect the welders among others.The TLV indicates the highest permissible meanvalue of harmful elements in the inhaled airduring one day. The concentration is either

indicated in PPM (parts per million) cm3/m3 or inmg/m3.

The TLVs are based on the present knowledge ofthe influences of the elements. If new knowledgemakes it appropriate, the present TLVs will berevised. TLVs are not to be considered strict limitsbetween harmful and not harmful concentrations,as such limits do not exist. It should not beconsidered adequate to merely reducing the airpollution to the level of the TLVs.

Even though a concentration of a particular airpollution corresponding to the TLV of the elementin question will normally be harmful to the health,it should nevertheless always be a goal to keep theconcentrations of the air pollution as far below theTLVs as possible.

Exceeding the Threshold Limit ValuesIn general the TLVs indicate the highestpermissible mean concentrations of an 8-hourworking day. This means that brief exceeding ofthe TLVs is permitted if the concentrations areotherwise so far below the TLV that the time-weighed mean value lies below the TLV.However, gratuitous high, brief exceeding of theTLVs is not permitted even though the meanvalue of a whole day’s work is kept below thelimit.

How long time and how large exceeding that ispermitted must be considered in each case andshould be evaluated by the Danish NationalLabour Inspection.

The below table shows the exceeding which canbe tolerated in periods up to 15 minutes under theprecondition that the weighed mean value doesnot exceed the TLV. The below figures are meantas a thumb rule only.

Permitted exceedingGV < 1 3 X GV

1 < GV < 10 2 X GV10 < GV < 100 1.5 X GV

100 < GV < 1.000 1.25 X GV

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When calculating the allowed exceedingaccording to the below table, the unit PPM is usedfor gases, and vapours and the unit mg/m3 forparticles (dust, fumes and mists).

A substance of TLV = 1 PPM is therefore alloweda maximum of 1 x 3 = 3 PPM for a period of 15minutes. A substance of TLV = 10 PPM isallowed a maximum of 10 x 2 = 20 PPM. Andfinally a substance of TLV = 50 PPM is allowed amaximum of 50 x 1.5 = 75 PPM. The allowednumber of exceeding the TLV per day isdetermined by the fact that the time-weighedmean value must be less than the TLV.

Threshold LimitValue

PPM mg/m3

Iron oxide - 3.5Crome 3 - 0.5Crome 6 - 0.02Manganese - 1.0Nickel, difficultdecomposablecombinations

- 1.0

Nickelcombinations,decomposable

- 0.1

Nitrogen oxide 25.0 30.0Nitrogendioxide

3.0 5.6

Ozon 0.1 0.2

Table of TLVs

How to Prevent Air PollutionProcess VentilationProcess ventilation is one the most importanttechnical means of reducing the pollution of theair in the workshop. However, it is not themeaning that in every connection ventilationshould be regarded the ultimate means forimprovement of the working environment. It maybe that in spite of a thoroughly considered andwell done ventilation system it is not possible tosolve the present environmental problem.Therefore it is important to evaluate all thedifferent possibilities for preventing theproduction and spreading of unhealthy airpollution before you start on the technicalventilation examinations.

Ventilation can be divided into two main groups:• Comfort ventilation• Process ventilation

Process ventilation aims at creating a safe andhealthy environment while the purpose of comfortventilation is to increase the well-being in order toobtain the best possible conditions of a goodworking environment. As previously mentioned itis process ventilation that should make certain thatundesirable influences in the form of air pollutionare prevented.

Process ventilation can be divided into three grossgroups:• Local exhaust ventilation of the welding place• Local exhaust ventilation of the welding cabin• General ventilation system

In order to remove the welding fumes aseffectively as possible it is necessary to use allthree types of ventilation.

Welding is not to take place unless adequatemeasures have been taken against the air pollutionthat is a result of welding.Where it is practically possible, the unhealthy airpollution must be removed before it reaches theinhalation range of the welder and leadimmediately into free air.If at indoor jobs it is not possible to remove thefumes immediately at the place of production,mechanical ventilation of the room must beestablished so that the content of pollutingsubstances in the inhaled air does not exceed thehygienic limit value of the mixture.

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Local Exhaust Ventilation of the Welding PlaceLocal exhaust ventilation of the welding place is atype of ventilation that removes the pollution fromits place of production. This type of exhaustventilation offers valuable advantages, because itsignificantly reduces the requirements to thegeneral ventilation system and it also normallyoffers an improved environment in comparisonwith a general ventilation system without furtherexhaust systems.

The actual exhaust unit are available in manydifferent designs e.g. a swivel arm or flexiblehoses which at all times can be adapted to thewelding or cutting job in question.

A common demand for all suitable local exhaust unitsis that they are efficient, easy to operate, produces littlenoise and do not disturb the working process. If thesedemands are not met, the exhaust unit will not be usedand the investment will be wasted.

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Local exhaust ventilation of the welding cabinIn addition to the ventilation described above,local exhaust ventilation systems are also used atstationary welding cabins. This type of exhaustventilation ventilates the individual welding areawithout directly removing the fumes from thewelding place. It can be a welding table with anexhaust unit in the tabletop that is often made witha grid or with exhaust in the back or top plates.

General ventilationGeneral ventilation systems are designed to ensurea satisfactory working environment in the room.

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TIG Welding - Filler Materials - Welding Techniques

Filler Materials

During welding the torch are guided forward at alateral perpendicular angle of 80 to 90o in thewelding direction.

The filler wire are fed in step with the progressingwelding in an angle of about 10 to 20o to the basematerial.

The welding method is much like that ofMIG/MAG welding, leftward welding with smalldipping movements.

During welding it is important that the filler wireis kept strictly within the gas flow from the gasnozzle.

This will prevent the melting and still hot wirefrom oxidising in connection with the atmosphericair.

Every form of oxidation and pollution of the fillerwire will cause a contamination of the weld pool.

It is therefore very important that the welder onlyuses clean filler materials that are not dirty, greasyor moist.

Mostly grease and dirt will come from using dirtygloves. It is therefore a good idea to clean thefiller wire with for instance acetone immediatelybefore the welding starts.

Grease and moisture both on the filler wire and onthe base material may cause serious weldingerrors such as porosities, hydrogen cracks, etc.

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Types of Errors in TIG Welding of Butt Welds

IntroductionThe technological development means thatincreasingly heavier demands are made on thesteel materials and therefore new materials ofimproved tensile strength are being developedcontinuously.

The use of these new materials make it possible toreduce the dimensions of the materials so thatwhen previously you had to use 8 mm plates younow only use 6 mm plates to obtain the samestrength.

When making a butt weld if the materialdimension is reduced the area of the welding isalso reduced.

The development causes an increasing demand tothe quality of the individual weld and of thewelded construction in general.

The increasing demands of welding means thatTIG welding is in use more frequently.

The quality demands will in the first place bemade on the engineers, the welding techniciansand the welder.The engineer is responsible for the design of theconstruction.

The welding technicians are responsible forchoosing the correct welding method, elaborationof the welding procedure specification and theinternal control.

The welder carries out the actual welding job andhe is therefore responsible for the quality of thewelds.

Even though all parties involved are very carefulwith their jobs, welding errors will occur.

Therefore the welder is not necessarily to blamefor the errors, but it is a fact that errors do occur inthis process.

The following sections will deal with the errors onwhich the welder has influence when TIG weldingbutt welds.

Designations and Definitions ofWelding Errors DS/ISO 6520DS/ISO 6520 is a present Danish and internationalstandard indicating designations and definitions oferrors that occur in welding.

The standard lists all types of errors includingthose that cannot be controlled visually.

The types of errors are divided into the followingsix main groups:• Cracks• Porosities• Inclusions• Lack of fusion and lack of penetration• Imperfect shape• Various errors that do not belong to any of the

above groups

The standard indicates the different types of errorsin columns with explanations and illustrations.

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Column 1 Indicates every type of error by anumber.

Column 2 Indicates a group of letters that refersto the radiographic evaluation IIW(International Institute of Welding.

Column 3 Indicates the designation of the errorin Danish, English and French. TheGerman designation is in appendix B.

Column 4 Indicates the explanation in English.Column 5 Indicates the explanation in Danish.Column 6 An illustration of the error when

further explanation is necessary.

DS/ISO 6520 does not provide any requirementsfor the size of the errors and is therefore not suitedfor an evaluation of the weld.

The visual evaluation with indication of themarking is made according to DS/R 325.

The marking of the radiographic evaluation can begiven on the basis of the IIW’s radiographicevaluation table.

Welding ErrorsCracksCracks in connection with TIG welding are rarelyseen, but may occur both as vertical or horizontalcracks.

The cracks can occur in the weld metal, the heat-affected zone or in the parent metal.

Error type no. 100

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The most frequent type of cracks in TIG weldingare cracks in the ending crater, the so-called cratercracks.

Error type no. 104

The reason for the formation of cracks can be:• Wrong or no use of the slope-down facility• Too small or too few stitches• Wrong welding order• Too rapid cooling of the weld zone• Wrong or no pre-heating and post heating

treatment

CavitiesAccording to DS/ISO 6520 cavities are defined ascavities in the weld due to entrapped gases.

Cavities are often found in TIG welds due to themany possibilities for this error to occur.

Error type no. 200

The reason for the formation of porosities can be:• Lacking or impure shielding gas• Inadequate cleaning of the groove edges and

filler material• Incorrect adjustment of the flow of shielding

gas• Wrong inclination of the torch• Wrong size of gas nozzle• Too quickly an interruption of the shielding

gas by the end of a weld• Draught caused by a wrongly placed exhaust

unit• Leaking hose connections• Inadequate airing of the TIG torch before

welding

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Shrinkage CavityA shrinkage cavity is a cavity that occurs by theend of a weld.

Error type no. 202

This error occurs when the weld metal solidifiestoo quickly.

It can be avoided by a gradually slope down of thewelding current which makes the weld metalsolidify less quickly.

Metallic InclusionInclusions of tungsten are a particular problem forTIG welding.

An inclusion of tungsten in the weld may causethe formation of cracks as tungsten has anotherexpansion coefficient than steel.

Error type no. 304

The reasons for these inclusions of tungsten canbe:• The point of the tungsten electrode has

touched the weld pool or the groove edges.• The point of the electrode has a wrong

sharpening angle.• The type and dimension of the electrode are

incorrect.• Too long stick-out.

Lack of Fusion and PenetrationLack of fusion and penetration is an error whichoccurs when the fusion between the weld metaland the parent metal or between the weldingpasses are inadequate.Lack of fusion may also occur in the bottom run.The error is not very frequent in TIG welding dueto the large penetration ability of this method.

Error type no. 400

Lacks of fusion and penetration may be causedby:• Too small current intensity• Wrong inclination angle of the TIG torch• Too much feeding of filler wire• Too large dimension of filler wire

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Lack of fusion at the root of the weldThis error occurs when the penetration of the rootrun is incomplete. The error is not very commonin TIG welding due the large penetration ability ofthis method.

Error type no. 402

Lack of fusion at the root of the weld can becaused by:• Wrong adaptation of the weld preparation.• Too large “root nose” (insufficient blunting of

the bottom of the V-prep by grinding)• Too small welding current intensity• Wrong inclination angle of the TIG torch• Too large wire dimensions

UndercutAn undercut usually appears in the zone betweenthe weld metal and the parent metal and can occurboth on the front and the backside.

Error type no. 501

Undercuts can be caused by:• Too high welding current intensity• Too long arc• Wrong inclination angle of the TIG torch• Lack of filler wire• Feeding of filler wire at the wrong place

Excess of Weld MaterialThe excess of weld material will cause a weaknessof the welded construction similar to the effects ofundercut.

Furthermore, there is used an excessive amount offiller wire which means unnecessary weldingcosts.

Error type no. 502

Excess of weld material is mostly due to anexcessive feeding of filler wire.

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Excessive PenetrationExcessive penetration is an error which occurswhen the weld metal protrudes through the root ofa weld made from one side where it weakens thestrength of the weld where the weld metal and theparent metal meet.

Error type no. 504

Excessive root penetration can be caused by:• Too high welding current• Too large “root nose” (insufficient blunting of

the bottom of the V-prep by grinding)• Wrong feeding of filler wire• Too hot welding of middle and closing runs

Incompletely Filled PreparationIncomplete filling of the preparation is a channelin the weld metal due to insufficient deposition ofweld metal.

Error type no. 511

Incompletely filled weld preparation can becaused by:• Insufficient feeding of filler wire• Wrong feeding of filler wire• Too hot welding

Root ConcavityA shallow groove due to shrinkage of a butt weldat the root when the weld metal solidifies.

Error type no. 515

Root concavities can be caused by:• Insufficient feeding of filler wire• Excessive heating when welding middle and

closing runs

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Metallurgy - Stainless Steels

GenerallyStainless steels include all the types of steel whichare made corrosion-resistant by alloying the steelwith different alloying elements.

However, corrosion-resistant steels can “corrode”under the influence of different substances.

The term “stainless steel” may therefore seem amisnomer, which is why the term ”stainless steel”will be used as the term for the whole group ofsteels in which chromium is alloyed for itscorrosive-resistant properties.

In the following section the chemical names of anumber of alloying elements are used. Below is alist of their chemical designation and names:

Cr ChromiumC CarbonTi TitaniumNb NiobiumN NitrogenMo MolybdenumTa Tantalum

Types of Stainless SteelsStainless steels are alloys of iron, chromium,nickel, manganese, molybdenum, titanium,niobium, carbon and others just to mention themost important ones.

Stainless steels can be divided into three maingroups and in addition a smaller group as shownin the below table.

The division is based on the crystal structure.

As you can see there are in principle two groups:• Chromium-alloyed types• Chromium-nickel-alloyed types

Of the chromium-nickel-alloyed types themartensitic ones are hardenable due to therelatively high carbon content. The other typescannot be hardened by heat-treatment.

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Chromium-alloyed Steels

Martensitic Stainless SteelsThis group of steels has a carbon content from 0.1to 1.0%. The Cr content varies from 13 to 18%.

These steels are maraging and air-hardenable.This means that the steels cannot be weldedwithout pre-heating and the following tempering.These steels therefore belong to the machinesteels.

These steels are spheroidizable and in thatcondition workable by cutting. They obtain aconsiderable strength in heat-treated condition andalso an improved corrosion-resistance.

These steels are used for machine parts that areexposed to corrosion, e.g.:• Valve shafts• Pump shafts• Knives, etc.

Machine steels are steel types that are used formachine components such as:• Axles• Gear wheels• Valves, etc.

Normally the requirement for the weldability ofthese steels is not very great as they as oftenjoined together in other ways.

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Spheroidizing (softening)Steels with a large content of cementite or alloyedsteels with a large content of carbide are onlydifficulty weldable by cold deformation andcutting which is caused by the great hardness andplate-shaped formations of the carbides. Whenforging or welding, during which the steel isheated to more than A3-Acm temperature, thisstructure is changed into a structure with plate-shaped perlite and grain boundary carbides whichcannot be cut by cutting tools without great wearon the tools.

The steel is spheroidized at a temperature belowthe A1 temperature. The spheroidization meansthat the carbide plates transform into ball-likeformations.

Usually, this heat-treatment is carried out at thesteel mill.

When machining the spheroidized material thehard balls are pressed into the softer ferrite basematerial.

The hardness has decreased and the ductility hasincreased.

Ferritic Cr-alloyed stainless steelsThese steels are ferritic at all temperatures if thepercentage of C and the percentage of Cr arebalanced to each other. The content of Cr mayvary from 12 to 30%.

If the percentage of Cr is 27% a content of C until0.25% is allowed. If the content of Cr is 13% theC percentage must not exceed 0.05%, see thedrawing on the next page.

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The ferritic steels are harder to weld than theaustenitic steels as there is a risk of cracks in theheat-affected zone (HAZ) due to the grainformation.

The formation of coarse grains cannot beprevented by heat-treatment because the steel isalso ferritic at high temperatures.

Small amounts of vanadium (V) and molybdenum(Mo) can counteract the formation of coarsegrains.

These steels cannot be martensitically hardened,but increase their strength by cold-deformation.

The steels are suitable for deformation shapingand are used for home appliances among otherthings.

Intergranular corrosion may appear in these steelsas a consequence of chromium-carbideprecipitation.

The precipitation of carbide will happen at atemperature of 900 to 1000oC.

The error cannot be rectified by means of a heat-treatment of these steels because a solution heat-treatment will cause a great growth of grains, andin spite of a quick chilling new carbideprecipitation will take place due to the fineconditions for diffusion in the cubic centeredspace lattice.

If the heat-treatment takes place at 700 to 800oCthere will, however, be a balancing of theconcentration of the remaining amount ofchromium in the a crystals.

Stabilising the steels with Ti and Nb can reducethe inclination of the ferritic steels to intergranularcorrosion.

Another way to avoid intergranular corrosion is touse ELI-steel which is steels with a very lowcontent of carbon 0.003% (C) and nitrogen (N),but the content of chromium then has to very highas both C and N have an austenitical effect, seethe Schaeffler diagram.

A long time heating from 550 to 800oC of ferriticchromium steels of more than 20% Cr will cause

brittleness due to the formation of the so-calledsigma-phase.

In this phase the material is brittle why itsductility is significantly reduced while the tensilestrength is increased. The phase is resoluble byheating to more than 800oC after which a quickchilling will prevent this phase from reappearing.

Chromium-Nickel AlloyedStainless SteelsFerrite-austenitic Stainless SteelsThese steels are alloyed with 18 to 26%chromium, 5 to 6% nickel and 0.03 to 0.15%carbon. The steels are more easily weldable thanthe purely ferritic ones and their corrosionresistance is more or less like that of the 18/8steel.

These steels have a significantly better impactstrength than the ferritic steels, but they can becold brittle. In some types there can be aformation of martensite during welding.

Due to the fine casting properties of these steels,they are often used for stainless foundry goodssuch as valves and similar products.

Austenitic Stainless SteelsOne of the first produced stainless steel had thefollowing analysis:C 0.12%Cr 18%Ni 8%This steel was called an 18/8 steel and it is fromthis type that later on there has been developed anumber of other types of stainless steels.

By adding up to 5% Mo together with a largercontent of nickel an improvement of thecorrosion-resistant properties was achieved.

This steel is monophase steel, which means that itis austenitic at all temperatures except that delta-ferrite can form in certain steels at hightemperatures.

The percentage of carbon must be low in theaustenitic steels as chromium is a very strongproducer of carbide, and as chromium-carbideformation is an undesirable element in moststainless steels.

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It is very difficult and expensive to diminish thecontent of carbon to such low a level andtherefore the steel is often alloyed with Ti and Nbwhich are strong generators of carbide, in order toavoid the formation of chromium carbides.stålet med Ti og Nb, som er stærke karbiddannere,så dannelsen af kromkarbider undgås.

The austenitic steel can be divided into fourgroups according to the alloying compositionparticularly with regard to the percentage ofcarbon:• Steels with a content of approx. 0.10% of

carbon• Steels with a content of approx. 0.06% of

carbon• ELC steels with an extra low percentage of

carbon, approx. 0.03%• Stabilising steel alloyed with Ti or Ni, carbon

content is approx. 0.06%

Carbon will combine with titanium or niobiumand thus prevent the generation of chromium-carbide.

Alloying of Mo will improve the corrosion-resistant properties against chlorides and dilutedacids.

In order to preserve the austenitic structure thecontent of Ni must be increased when the contentof Mo is increased.

Analysis - weight %

Cr Ni Mo Cu18 818 10 1,518 12 2,718 14 3,420 25 4,5 1,5

Examples of content of Cr-Ni-Mo in austeniticsteels

The Weldability of Austenitic SteelsAustenitic steels are easily weldable withoutgenerating martensite in the heat-affected zone(HAZ).

However, it has to be taken into consideration thataustenitic steels have a low thermal conductivity,approx. 40% lower than that of ordinary steel.

The thermal expansion coefficient is approx. 50%larger than that of ordinary steel.

These conditions mean a larger tendency totensions and distortions. If the percentage ofcarbon is sufficiently high there can be aprecipitation of chromium carbides in the HAZ,where the temperature rises to the range of 450 to800oC.

The precipitation mainly takes place in the grainboundaries of the austenite and it means that areasof gamma crystals near to the chromium carbidesbecome “de-chromed” and thereby loose theircorrosion resistance (See the section: Types ofCorrosion).

The content of carbon should be sufficiently largeto generate the chromium carbides. This is thecase in the before-mentioned groups 1 and 2, andtherefore these types of steels must undergo aheat-treatment after the welding process in orderto place the chromium content in the austenitegrains again.

This heat-treatment can be carried out at atemperature of 1,000 to 1,100oC at which thechromium carbides dissolves, and the chromiumcontent is evenly re-distributed in the gammacrystals.

The chilling to below 400oC should take placevery quickly to avoid the reformation of carbides.Even at such high heat-treatment temperature theaustenitic steel is not very inclined to grow grains.

When working with construction so large thatsuch heat-treatment is not possible, it is necessaryto choose a ELC steel group 3 which has a verylow content of carbon and therefore does notgenerate carbides.

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The Weldability of Stabilised SteelThe stabilised steels (group 4 acc. to page 45) canalso be welded without heat-treatment afterwards.

The steel can be alloyed with Ti, Ni, Cr or Tawhich has a greater affinity to carbon thanchromium. These elements consume the carbonand make the generation of chromium carbideimpossible.

Due to the difficulties of the above-mentionedheat-treatment, weldable stainless steels which donot require heat-treatment after welding (group 4steels with a carbon content less than 0.1%).

These steels are also suitable for applications athigher temperatures.

When alloying with stabilisers such as Ta, Ti orNb, stable carbides are generated preventing thegeneration of the undesirable chromium carbides.

The amount of stabilisers depends on the C-content.

The Ti-content should be 10 times the C-content,and the Ta-content, which normally replaces apart of the Nb-content, should be 20 times theamount of C.

Ti is not used in the filler material as it easilyoxidises and generates TiO. The filler material isnormally stabilised with Nb.

Ti holds important economic advantages, but isnone the less regarded less active than Nb. Ti hasthe disadvantage that it is difficult to obtain acompletely smooth surface by polishing.

The normal manufacturing of plates and profilescauses the carbon to link as titanium carbide, sothat the steels are usually resistant againstintergranular corrosion.

The stabilised steels are advantageous toconstructions under high pressure and hightemperatures as their creep strength and tensilestrength at high temperatures are better than thoseof non-stabilised steels. They are also more stableto intergranular corrosion at temperatures above400oC.

When stabilised steels are annealed for severalhours and slowly cooled they will not generatechromium carbides.

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Handling of Stainless Materials

Corrosion Resistance

The corrosion resistance is due to the formation ofa thin layer of metallic oxide on the surface and isconditional on the preservation of this layer. Inthis way the corrosion resistance will beintegrated into the material together with the othermaterial properties, and therefore the corrosionresistance also depends on how the materials aretreated.

The optimum corrosion resistance of stainlessmaterials is achieved when the surface ismetallically clean, which means that it is free fromtarnish, scales and similar polluting elements.

After-treatment of stainless materials is verycostly why it is important to protect the materialand handle it with great care as scratches andmarks significantly increases the costs of the after-treatment.

In order to protect stainless materials in the bestway, the first thing to do when a new job is startedshould be to paste a piece of paper or plastic foilonto the workpiece.

Furthermore, stainless materials should be keptseparated from other steel materials. Steel shelvescan be clad with wood or plastic in order to avoiddirect contact between the stainless materials andthe steel.

Tools used for treatment of stainless steel shouldbe polished and clean, e.g.:AnvilsStraightening platesStraightedgesHammers

It should also be avoided to work on both stainlesssteel and ordinary steels at the same time or in thesame area in order to prevent a pollution of thestainless material by steel particles or dust fromthe ordinary steel.

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Cleaning

Even the smallest impurities cause the formationof porosities.

Stainless steel is sensitive to undercuts especiallyif it is exposed to a dynamic load. It is thereforeextremely important when welding stainless steelthat all welding surfaces are completely clean. Alldirt and dust must be removed and if there isrolling lubricant or grease left on the material, itshould be removed by a solvent. Grease becomesliquid under the influence of the welding heat andhas a tendency to creep towards the weldinggroove. It is therefore important to degrease arather large area on both sides of the weldingzone.

Also the welding equipment such as cables,welding helmet, gloves, torch, rectifier, etc.should be clean in order not to contaminate thewelding zone during welding.

With large plate construction the welder has towalk on the plates and also draw his weldingcables on the plates. Therefore it is important tokeep the floor clean, so that the welder will notimport the dirt from the floor onto the plates.

A painted floor is easier to keep clean than arough floor.

Before welding begins the welding zone and theover and underside of the workpiece should bebrushed with a stainless steel wire brush. This isdone in order to remove the oxide layer, whichalways exists on the surface of the material.

When TIG welding it is important to take care thatthe filler material is clean before welding isstarted. If necessary the filler material should becleaned by a cloth with solvent, polished by steelwool, or dipped into caustic soda and rinsed inwater. The filler material must be completely drybefore welding starts.

Welding Table and Fixtures

In order to avoid deformations and to ensure thatthe finished product has the correct shape afterbeing welded, it is important to clamp theindividual parts to the welding table and maybetack weld them.

For serial productions you often use clampingtools with easily adjustable clamps. Theadvantages of using fixtures cannot be emphasisedenough.

First and foremost the welds will have a betterquality and the welding costs reduced. Especiallyin serial production it pays to invest both moneyand thoughts on the fixtures. Furthermore, fixturesensure a uniform product when producing severalpieces of the same product.

The additional cooling effect provided by thefixtures will often be an advantage when weldingstainless steels.

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The Influence of the Alloying Elements

IntroductionStainless steel achieves its properties by thealloying of different elements to the steel.

Most alloys contain 70 to 75% or more iron whythe metallurgic properties of the iron must be veryimportant.

AlloyingElement

% Influence

Chromium 13-25-30

Makes the steel corrosionresistant. At least 13% Cr.

Nickel 0-25 Provides higher ductilityand heat-resistance to thesteel.

Carbon 0.02-1 Undesirable for welding.Molyb-denum

1-4.5 Provides acid-resistance.

Titanium 0.5 Stabiliser. Improveswelding properties.

Niobium 0.5 Stabiliser. Reducesdurability.

Ferrit Theremain-

ingpercen-

tage

Base material to which theelements are alloyed.

Table of important alloying elements and theirinfluence

Chromium (Cr)Cr increases the tensile strength by some 80N/mm2 per percentage of chromium. Due to itsinclination to generate carbides, Cr increases thehardness. Steels with more 12% Cr are corrosionresistant to water and certain acids. Cr increasesthe heat-resistance in particular together with Ni.

When oxidised Cr forms a tight oxide layer that isrelatively corrosion resistant and may cause thesteels to become ferritic at all temperatures.

Nickel (Ni)Ni is both ductile and strong, but as it is ratherexpensive it is only used to a limited degree. Niincreases the tensile strength by some 40 N/mm2per percentage. Ni reduces the critical coolingspeed. When alloyed by more than 25% of Ni,austenitic steels that are non-magnetic andcorrosion resistant are produced.

If the steel is also alloyed with Cr the desiredaustenitic state is obtained with a content of 8%Ni and 18% Cr (18/8 chromium-nickel steel).

Molybdenum (Mo)Mo increases the strength, ductility and heat-resistant properties of the steel. Mo is stronglycarbide generating and is used in high-speed steels(HS steels) and heat-treatment steels as itincreases the tempering resistance.

Mo in stainless steels provides an increasedcorrosion resistance against:• Sulphuric acid• Phosphoric acid• Formic acid• Various hot organic acids

Mo also protects against pitting corrosion inparticular for chlorous solutions.

Pitting is further described in the section “Typesof Corrosion”.

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Titanium (Ti)The advantages of using pure Ti lies in its finecorrosion resistance which is more or less thesame as that of stainless steel, and the goodstrength in relation to its weight.

However, these fine properties disappear at hightemperatures, at which Ti reacts strongly andgenerates chemical combinations with all gasesexcept the inert gases. For instance, will Ti “burn”in pure nitrogen at 800oC to titanium nitride underfierce heat-generation.

Ti is much used as an efficient deoxydation anddenitrating agent for instance in certain stainlesssteels with which it mainly combines carbon totitanium carbide, but also combines with theharmful nitrogen to titanium nitride.

Niobium (Nb)Nb is a strong carbide generator, and in austeniticChromium-nickel steels it prevents undesirableprecipitation of carbide of other elements.

Chromium-nickel AlloysIn the two-phase system iron-chromium thegamma area is ligated, and from approx. 12.5% ofchromium there will be only ferrite from thefusion temperature to room temperature (cubicalspace-centred grid structure).

When the content of nickel is increased thegamma area in to two-phase system iron-nickel isextended. From a given nickel content thestructure will become purely austenitic (cubicallysurface centred).

The elements that will be used for alloyingstainless steels in order to achieve certain specificproperties can be divided into two main groups:• Ferrite generating elements - Cr, Si, Al, Mo,

Nb, Ti, W and V• Austenite generating elements - Ni, Mn, C, Co

and N

Two-phase system, iron-nickel, iron-chromium

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Stainless Steel - Welding - Heat-Affected Zone

GenerallyThe tempering which is a consequence of thewelding process or other heat-treatment ofstainless steel, is a damage of the passive materialsurface that significantly reduces the corrosionresistance. This tempering is made of verychromium-rich high-temperature oxides that forma very brittle and leaking layer. The underlyingmaterial will thus be very poor in chromium andthe corrosion resistance will be reduced.

Rustfast materiale med kromoxidhinde

The chromium-oxides must be removed ormeasures should be taken to prevent theirformation. When welding with shielding gas theoxide formation can be significantly reduced bymeans of a gas diffuser or shoe that followsimmediately after the torch. The diffuser/shoe willprotect the heated weld seam at the same time asthe flowing argon or nitrogen mixture cools theweld seam. It goes without saying that the back ofthe weld is shielded.

It is mainly argon that is used as shielding gaswith manual TIG welding. The gas is connected tothe TIG torch and will protect the tungstenelectrode and flow over the weld pool shielding itfrom the oxygen in the air.

Argon, sometimes mixed with a small percentageof hydrogen, is often used to protect the back ofthe weld. A protection with formier gas is cheaperand in many cases a better choice. In order toavoid the harmful tempering of the steel it isnecessary to maintain the flow of gas until thetemperature is lower than 200oC.

Suitable back gas tools can contribute to a reducedconsumption of gas and an improved gas quality.

Flow of shielding gas in a piece of pipe

Flow of shielding gas in a pipe section

Blockade and supply of shielding gas

Construction of the back gas tool

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Guidelines for Welding of Stainless Steels

As there do not at present exist any normativeguidelines for welding of stainless materials, thefollowing points may serve as indicativeguidelines:

Welding Quality• The welding quality must meet the standard

demands to e.g. complete penetration.• The welding must be performed with skill and

with an even and consistent weld seam.• The transition area between the weld and the

parent metal should be even and the surfaceshould be smooth.

• The weld must appear without visible weldingerrors and discoloration due to a lack ofshielding gas.

Precautions• The filler material should be chosen so that

metallurgic and corrosion-connectedcomplications are avoided.

• The welding method and the weldingequipment must be suitable, so that thewelding zone will be homogenous and free ofheat cracks and welding errors.

• The back of the weld should be protected witha suitable back gas or a suitable backingmaterial, unless the undercut is ground off.

Cleaning• The surface must be metalically clean and free

of discoloration, welding and grinding spatterand glue residue.

• Marks caused by handling or treatment by e.g.the. bending press, and contamination frome.g. copper backing or clamps must beremoved.

• A suitable cleaning or passivating agentshould clean the entire workpiece includingthe undercut.

The Heat-Affected Zone (HAZ)

The HAZ areas around the weld seam that do notmelt are exposed to a fierce heating and thiscauses the micro-structure of the steel to change.The extent of these changes depends on thecomposition of the material and the speed bywhich the HAZ is heated. The cooling speed isalso important and it depends on the thickness ofthe material, the dimensions of the workpiece, theheat input produced by the welding process andthe cooling method.

1 Weld metal2 Incomplete3 Overheated4 Normalised5 Incomplete transformation6 Parent material

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A reduction of chromium due to carbidegeneration in the grain boundaries in austenitic

Cr/Ni steel (table)

Welding of Martensitic StainlessSteelsOf the stainless steels the martensitic steels are thelowest alloyed steels. Typical analysis is indicatedin the table on page 54, which is primarily basedon Swedish steel qualities. As this survey is notcomplete it is important to read the informationfrom the steel manufacturers and other steelnorms.

The martensitic stainless steels are generally lesssuitable for welding. When cooled from atemperature at more than 800oC it hardens byaircooling. The same conditions for cooling countfor the HAZ of welding, and thus martensite isgenerated. The accompanying volume changesresult in very strong strain. In combination withthe thermal strain this means that cracks easilyappear in the martensitic areas. The higher thecontent of carbon is the more important is thisproblem. Welding in steels with a carbon contentof more than 0.10 to 0.15% should be avoided.

Furthermore, the austenite transformation will notbe complete when the carbon content is higher,and slow transformation residual austenite mayappear.

A preheating temperature at minimum 200oC isused for welding. It primarily serves to reduce the

thermal strain. If an improvement of the ductilityand a reduction of the hardness after welding aredesirable, the steel must undergo heat-treatment.

Welding of Ferritic StainlessSteelsThe ferritic steels do not harden when welded andthey are therefore easier to weld. The heating todegrees of 900 to 1000oC, which will take placein the HAZs during welding, will result in abrittleness of these zones due to the grainformation.

This grain formation may be accompanied bybrittle precipitations in the grain boundaries,which in some cases may cause intergranularcorrosion.

The above risk can be eliminated by heat-treatment, and at the same time the brittlenes willdisappear that comes from the precipitations ofgrain boundaries. The brittlenes that alone comesfrom the grain formation cannot be eliminated byheat-treatment. Cold working followed by a heat-treatment, a method that is hardly applicable inpractice, can only eliminate it.

Welding of Ferrite-austeniticStainless SteelsThese types of steel are more suitable for weldingthan the two above-mentioned. The inclination toprecipitation’s and grain formation in the HAZsdoes exist, but is less significant cf. the ferriticsteels.

Welding of Austenitic StainlessSteelsThis type of steel does not cause any weldingproblems, if the ordinary procedures are observedand the welder is adequately skilled.

As the steel is austenitic in the whole temperaturerange and does not harden during cooling, acooling after welding will reduce the formation ofgrain boundary carbides, intergranular corrosion,as can be seen from the illustration (ma104-02).

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TIG Welding in Stainless SteelTIG welding is an economically advantageous towelding of thinner stainless steels. It makes clean,smooth welds without porosities and craterspossible even without welding from the backside.

Welding is done in DC with negative polarity onthe electrode. The electrode is made of tungstenthat does not melt. A shielding gas, usually argon,shields the arc, the electrode and the weld pool.The welding torch is cooled either by thesurrounding air alone or by a water flow inside thetorch. The water and the shielding gas must bekept separated in order to avoid porosities.

There are many types of tungsten electrodesavailable. Normally you use a tungsten electrodealloyed with thorium as it is less inclined to causeinclusions of tungsten in the weld metal. It is alsoeasier to ignite and offers clean welds. Theelectrode is ground to a point in order to facilitatethe ignition. If it is polluted with weld metal oroxides, it will melt more readily, the welding willbe inferior and tungsten will be transferred to theweld pool. This issue is further described in thesection “TIG Welding - Tungsten Electrodes”.

The most common impurity in the shielding gas ismoisture. The dew point should be below -50oC.This is usually observed at the manufacturer, butif the cylinders are returned with open valves, themanufacturer’s care is of little use. Furthermore,all hose connections and similar things must betight and dry. The workpiece should be dry andclean. Finally, the weld and the electrode must beshielded by argon until they have cooled to below200oC.

By use of HF-ignition a contamination of the weldpool as the arc is ignited without touching theweld pool. Starting points, end craters andundercuts appear as errors. By equipping thewelding machine with a foot switch it is possibleto control the current during welding, whichmeans that, the undercuts and end craters can beavoided, and the penetration in the beginning ofthe weld can be increased. The end crater can beavoided by a gradual reduction of the current.When the current is reduced gradually the weldpool will become smaller and thus the deep crater,

which is also called the crater porosity and oftenends in a crack, is avoided. The ignition of the arcis further described in the section “TIG Welding -Ignition of the Arc”.

TIG welding is mostly used for thin materials. Ifthe weld requires more than three passes, viz.from 6 mm, MMA welding with a coatedelectrode or MIG welding can be used for filling.

Weld zone and Filler MaterialIf it is necessary to make an even weld backwithout the possibility of welding after, e.g. pipewelding, a careful preparation of the weld zone isvery important and the back of the weld should beprotected against oxidisation. The weld prep gapshould be uniform, but with a foot control askilled welder will be able to compensate forsmall variations.

The protection of the back of the weld can bedone with argon (Ar) or helium (He). However, itis cheaper to use a nitrogen-hydrogen mixture (N)(H) that also provides a back of weld withoutporosities and oxides. The absorption of nitrogen,even in the root pass, is so small that it lies withinthe diffusion of the analysis values.

A filler wire is used for filling the weld zone. Theweld prep gap is usually a bit smaller than thewire diameter.

Welding can be done without filler material. Thenthe butt edges must be placed up against eachother. In square butts filler material can be leftout, as the sinking of the surface is limited. In Vpreps only the bottom run can fuse together. Tofill the V prep you have to use filler material.

However, in full austenitic base material there isan increased risk of cracks as it is not possible toreduce the ferrite content by 5 to 10%. In generalthe filler material should be chosen in co-operation with the supplier of materials.

Another version of TIG welding is welding with apulsing arc, which means that the welding currentcomes in pulses. The peak current pulse makes apenetration of the weld seam, after which thecurrent falls to a lower value and the weld poolalmost solidifies. Then another peak current pulsefollows.

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The weld takes the form of an overlapping row ofspot welds. The weld pool is only molten for sucha short time that it cannot spread into the weldzone. Pulsed TIG welding can be used forautomatic welding in all positions withoutadjusting the current. Pulsed TIG welding isfurther described in the section “TIG Weldingwith Pulsing Arc”.

In all welding processes it is important to have anefficient shielding against the atmospheric air. Ifthis shielding is not adequate, important alloyingelements may burn off causing an inferior weldmetal. Elements that give off carbon must notexist in the weld material or the shielding gas asthey can increase the content of carbon in theweld metal. Moisture should be avoided as itcauses porosities.

When preparing the weld it is important thatgrease, discoloration’s, dirt and othercontamination’s are removed as they may cause acarburization of the weld metal.

Sigma-PhaseThe sigma-phase is a hard, brittle and non-magnetic combination precipitated under longtimeannealing at 600 to 900oC of chromium andchromium-nickel steels with a high content ofchromium. It consists of about 52% Cr and 48%Fe but may also contain other elements. Thecombination is generated at about 800oC at thequickest. At lower temperatures the precipitationspeed is usually so low that there is no risk of asigma-phase.

The sigma-phase is normally generated by delta-ferrite completely or partly transformed to sigma-phase and austenite.Weld metal with a high content of deltaferrite istherefore more sensitive than weld metal with alow content of deltaferrite.

When welding ferritic chromium steels andaustenitic chromium-nickel steels with a ferritecontent the ductility in the HAZ can be reducedby the welding heat because the sigma-phase ismade of ferrite.

Therefore it is important to avoid strain-freeannealing at temperatures from 600 to 900oC. Itmay happen that sigma-phase is made directlyfrom austenite, but it demands a long time ofannealing, e.g. in 25% Cr/20% Ni steel.

Weld metals with a higher content of Mo or Nb isvery inclined to generate sigma-phase. When themolybdenum content is more than 3%precipitation of sigma-phase has been known tohappen immediately after welding multiple-passes. Nb further increased this tendency.

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The above illustration shows the influence of thesigma-phase. The original ferrite content ofapprox. 16%, which is mostly desired to improvethe ductility, is reduced to approx. 4% byannealing at 800oC. The impact resistance fallsand the hardness increases.

Annealing at 950 to 1050oC can dissolve thesigma-phase, and hardness and impact resistancereturns to normal. For workpieces that work athigh operation temperatures there is no need tofear the sigma-phase, as the impact resistance attemperatures above 300 to 400oC is sufficientlyhigh, especially if the ferrite content is below 7 to8%.

Influence on the Corrosion Properties by WeldingWelding can reduce the corrosion properties ofstainless steel. It may reduce the durability of theworkpiece to such a degree that is becomesuseless.

It is therefore important that when elaborating thewelding procedures and methods these conditionsare taken into consideration.

For stainless steels it is the surface that determinesthe corrosion resistance. Especially the surfacearound the welds must be clean, smooth andmetallically shining, which means free of exteriorelements, slag, scales, tempering discoloration andoxides.

These latter dissolves easily in an aggressive agentand forms metallic salts which will cause seriouscorrosion to most steels.

It is therefore recommendable to give the welds anafter-treatment for instance with pickle togetherwith a mechanical surface treatment.

The recommendations of the steel manufacturersshould be observed in every respect.

When selecting a suitable stainless material and itssuitability to be a part of the present product, theprocedure of selection should begin with findingthe cheapest material that meets the mechanicalrequirements, and in which standard componentsit is supplied.

The corrosion resistance of the material in therelevant environment should be evaluated. For

this purpose the suppliers of steels haveinformation available.

If this information is not adequate, it is necessaryto find additional information in literature or tocarry out a number of tests to provide proofs ofthe suitability of the selected material.

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