Thesis Optical and acoustical properties of band gap materials.pdf
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Optical and acoustical properties of band gap materials.
ABSTRACT
This thesis deals with the propagation properties of the electromagnetic and the
elastic waves in artificial crystals which are called photonic and phononic crystals,
respectively.
In the first part, the three dimensional photonic crystals formed by microspheres
with Ag nano particles coating are studied. The light can be reflected by crystals due
to the partial band gap of the photonic crystals arranged in face-centered cubic
structure. The results reveal that the reflectance is wavelength dependant and can be
enhanced by suitable Ag coating on the microspheres.
In the second part, the bulk elastic waves propagating in two-dimensional and
three-dimensional phononic crystals are studied experimentally and theoretically. The
two-dimensional phononic crystals are constructed using steel cylinders. The
cylinders are arranged periodically in water. The three-dimensional phononic crystal
consists of close-packed periodic arrays of spherical beads of steel embedded in an
epoxy matrix. The forbidden band gap can be observed in the experimentalmeasurement of the transmission spectra. The results agree with the theoretical
calculations. The defect modes in two-dimensional phononic crystals are also studied.
The results show that the bulk elastic waves could be well controlled and confined by
the phononic crystal structures.
The propagation of acoustic waves in a square-lattice phononic crystal slab
consisting of a single layer of spherical steel beads in a solid epoxy matrix is studied
experimentally and theoretically. The transmission and the field image of acoustic
wave are investigated. The transmission attenuation caused by absorption and bandgap effects is measured as a function of frequency and propagation distance. We also
demonstrate experimentally that the acoustic waves are well confined and propagate
inside a line-defect waveguide.
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Mr. BAHRAM
DJAFARI-ROUHANI
Abdelkrim Choujaa
Abdelkrim Khelif Vincent Laude Choujaa
Khelif
Laude
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Hichem Karim
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Contents
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iii
Contents. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
List of Figures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viiiList of Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xvi
1 Introduction to photonic and phononic crystals 1
2 Introduction to photonic and phononic crystals 4
2.1 History and development of photonic crystals . . . . . . . . . . . . . . . 4
2.1.1 Photonic crystals in Nature . . . . . . . . . . . . . . . . . . . . . 5
2.1.2 Defects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
2.1.3 Photonic crystal fiber . . . . . . . . . . . . . . . . . . . . . . . . 13
2.1.4 Colloidal microsphere base photonic crystal . . . . . . . . . . . . 15
2.2 History and development of phononic crystals . . . . . . . . . . . . . . . 17
2.3 Elastic wave propagation in materials . . . . . . . . . . . . . . . . . . . 26
2.4 Theoretical methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
2.4.1 Finite-Difference Time-Domain method . . . . . . . . . . . . . . 29
2.4.2 Finite element method . . . . . . . . . . . . . . . . . . . . . . . 32
3 Optical properties of metallodielectric opals 34
3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
3.2 Plane Wave Expansion (PWE) . . . . . . . . . . . . . . . . . . . . . . . 35
3.3 Fabrication of opals and experimental samples . . . . . . . . . . . . . . . 37
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3.3.1 Experiment setup . . . . . . . . . . . . . . . . . . . . . . . . . . 41
3.3.2 Experimental results . . . . . . . . . . . . . . . . . . . . . . . . 43
3.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
4 Bulk waves in two dimensional water-steel and three dimentional epoxy-steel
phononic crystals 49
4.1 Introduction to this chapter . . . . . . . . . . . . . . . . . . . . . . . . . 49
4.2 Two-dimentional water-steel phononic crystals . . . . . . . . . . . . . . 50
4.2.1 The geometric and elastic properties of the structure . . . . . . . 504.2.2 Experimental setup . . . . . . . . . . . . . . . . . . . . . . . . . 53
4.2.3 Triangular lattice structure . . . . . . . . . . . . . . . . . . . . . 55
4.2.4 Honeycomb lattice structure . . . . . . . . . . . . . . . . . . . . 63
4.2.5 Discussion of complete band gap in triangular and honeycomb
lattice . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
4.3 Line defect waveguide . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
4.4 Three-dimensional epoxy-steel phononic crystals . . . . . . . . . . . . . 75
4.4.1 Structure and experimental setup . . . . . . . . . . . . . . . . . . 75
4.4.2 Complete band gaps . . . . . . . . . . . . . . . . . . . . . . . . 78
4.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
5 Square lattice steel-epoxy phononic crystal slab 83
5.1 Introduction to this chapter . . . . . . . . . . . . . . . . . . . . . . . . . 83
5.2 Introduction to the experiment method . . . . . . . . . . . . . . . . . . . 845.2.1 Fabrication and properties of the structures . . . . . . . . . . . . 84
5.2.2 Optical characterization setup . . . . . . . . . . . . . . . . . . . 87
5.2.3 Principle of laser interferometer . . . . . . . . . . . . . . . . . . 89
5.3 Complete band gap characterization . . . . . . . . . . . . . . . . . . . . 90
5.4 Attenuation behavior versus propagation distance . . . . . . . . . . . . . 93
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5.5 Line defect waveguide . . . . . . . . . . . . . . . . . . . . . . . . . . . 97
5.6 Unusual refraction effect . . . . . . . . . . . . . . . . . . . . . . . . . . 101
5.7 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
6 General Conclusion 106
Bibliography 109
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List of Figures
2.1 From left to right diagram, PCs are in one, two, and three dimensions. The
red and yellow colors indicate the different refraction index. (http://ab-
initio.mit.edu/photons/) . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
2.2 Somewhere in a beam of sunlight in the Amazon basin, the three-inch
wings of a morpho butterfly glow with deep blue iridescence. Then the
morpho shifts its wings and, as if a switch flipped, shows its other self,
dull brown. [1] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
2.3 High-resolution SEM images showing the fine structure of the scales with
rounded ends: (a) blue (BL) male, blue region; (b) blue (BL) male, blue-
violet region; (c) brown (BR) male.[2] . . . . . . . . . . . . . . . . . . . 6
2.4 (a)Sea mouse, (b) its iridescent threads (c) SEM cross-section of a spine.[2]
7
2.5 The opal is the example of photonic band structures in mineral worlds.[2] 8
2.6 Cross-sectional micrograph of the 2D PC. The holes were formed in a
1.85m thick Si core layer. TheSiO2layer was2m thick. [3] . . . . . 9
2.7 (a) Scanning electron micrograph top view of 38 period triple-line-defect
linear waveguide. The defect hole diameter is 0.8 times of lattice constant
(352nm). The rectangular boxes indicate the interfaces between the ridgeand the photonic band gap waveguide. (b) Scanning electron micrograph
image of the Y-splitter sample, which consists of a 120o Y- splitter and
two60o bends (indicated by the red circles). (c) Infrared camera image of
the two Y-splitter outputs at = 1650nm. They are both Gaussian-like
and equally bright, indicating a near 50/50 splitting ratio.[4] . . . . . . . 11
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2.8 Five photonic crystal cavities coupled together lithographically by ar-
rangement in the same slab.[5] . . . . . . . . . . . . . . . . . . . . . . . 12
2.9 Scanning electron microscope image of the end of a photonic crystal fiber,
showing the central core where a hole has been omitted. [6] . . . . . . . 13
2.10 Scanning electron micrograph image of the inner cladding and core of the
airsilica microstructure fiber. [7] . . . . . . . . . . . . . . . . . . . . . 142.11 Optical spectrum of the continuum generated in a 75-cm section of mi-
crostructure fiber. The dashed curve shows the spectrum of the initial
100-fs pulse. [7] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
2.12 SEM image of a6 10m2 region of the surface of a sample made from415 nm spheres. [8] . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2.13 SEM images of the photonic crystals after different heating durations.
(A) More than 15 layers of microspheres were orderly packed. (B) The
thickness of the opals is about 17m. (C) The thickness of the opals is
about78m. (D) The thickness of the opals would be more than200m.
(E) This shows that the surface of the photonic crystals in (D) is well
packed in the FCC structure. [9] . . . . . . . . . . . . . . . . . . . . . . 17
2.14 Band structure for a period array of aluminum cylinders in nickel back-
ground. The inset shows the unit cell [10]. . . . . . . . . . . . . . . . . 20
2.15 Dark and white represent positive and negative vibrations, respectively.
(a) Experimentally observed patterns of liquid surface waves. Black areas
in the middle stands for the slab of copper cylinders. (b) Simulated results.Parameters used in simulations are the same as in experiment. Red dots
denote copper cylinders. [11] . . . . . . . . . . . . . . . . . . . . . . . . 25
2.16 Radiation amplitude field distribution over the phononic crystal: (a)by
experiment and (b) by simulation. [12] . . . . . . . . . . . . . . . . . . . 27
2.17 The diagram of the computational space . . . . . . . . . . . . . . . . . . 31
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3.1 SEM picture of pure PMMA microspheres. . . . . . . . . . . . . . . . . 38
3.2 SEM picture of PMMA microspheres with10wt%Ag nanoparticles. . . . 39
3.3 SEM picture of PMMA microspheres with20wt%Ag nanoparticles. . . . 39
3.4 The diagram of the first Brillouin zoom of FCC structure. . . . . . . . . . 40
3.5 Photonic band structure of the PMMA microspheres in fcc lattice. . . . . 41
3.6 The setup of supercontinuum source. . . . . . . . . . . . . . . . . . . . . 41
3.7 The spectrum of light is indicated by red line. Blue line indicates the dark
noise. The unit of intensity axis is arbitrarily unit. . . . . . . . . . . . . . 42
3.8 The experiment setup of (a)10o to45o (b) normal incident opal reflective
spectra measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43
3.9 The reflection spectrum of sample with incident angle0o. . . . . . . . . 44
3.10 The reflection spectrum of sample with incident angle10o. . . . . . . . . 44
3.11 The reflection spectrum of sample with incident angle25o. . . . . . . . . 45
3.12 The reflection spectrum of sample with incident angle35o. . . . . . . . . 45
3.13 The reflection spectrum of sample with incident angle45o. . . . . . . . . 46
3.14 (a)Reflection peak wavelength and (b) the coefficient of the microspheres
for different incident angles. . . . . . . . . . . . . . . . . . . . . . . . . 47
4.1 Two-dimensional phononic crystal used in the experiments. . . . . . . . . 51
4.2 The definition of the lattice directions. K and M are the two highest
symmetric directions in (a) the triangular and (b) the honeycomb structure. 52
4.3 Gap maps for (a) the triangular lattice and (b) the honeycomb lattice as a
function of the cylinder radius to lattice constant ratio. . . . . . . . . . . 53
4.4 The experimental setup . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
4.5 Signal intensity in the time domain with (blue dash line) and without (red
solid line) a phononic crystal structure. . . . . . . . . . . . . . . . . . . . 54
4.6 Reference spectra of two tranducers couples with central frequency is
450kHz (blue line) and 900kHz (red line). . . . . . . . . . . . . . . . . . 55
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4.7 Band structure of the infinite triangular-lattice phononic crystal composed
of steel cylinders in water, plotted along the -K-M-path of the first
irreducible Brillouin zone. . . . . . . . . . . . . . . . . . . . . . . . . . 56
4.8 (a) Real part of the pressure field in water for the eigen mode labeled
A in Fig.4.7. (b) and (c) are the real part of x and y displacement field
respectively in the steel cylinders for the eigen mode labeled B in Fig.4.7. 57
4.9 TheM direction transmssion spectrum of triangular lattice with 5, 6 and
7 layers. The insert at the doen left is the definition of layer. . . . . . . . 58
4.10 (a) Experimental (thick red solid line) and theoretical (thin blue solid line)
transmission through a triangular-lattice phononic crystal of steel cylin-
ders in water, along the M direction. (b) Band structure of the infinite
phononic crystal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
4.11 Real part of the pressure field in water for the eigenmode labeled C in
the band structure. The arrow shows the direction of incidence of waves
launched by the transducer. . . . . . . . . . . . . . . . . . . . . . . . . 60
4.12 TheK direction transmssion spectrum of triangular lattice with 5, 6 and
7 layers. The insert at the doen left is the definition of layer. . . . . . . . 61
4.13 (a) Experimental (thick red solid line) and theoretical (thin blue solid line)
transmission through a triangular-lattice phononic crystal of steel cylin-
ders in water, along the K direction. (b) Band structure of the infinite
phononic crystal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
4.14 (c) Real part of the pressure field in water for the eigenmode labeled D inthe band structure. The arrow shows the direction of incidence of waves
launched by the transducer. This mode belongs to a deaf band and is not
excited by a plane-wave transducer. . . . . . . . . . . . . . . . . . . . . 62
4.15 K direction transmission spectrum for the honeycomb lattice with 5, 6
and 7 layers. The inset at the down left is the definition of the layer. . . . 64
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4.16 (a) Experimental (thick red solid line) and theoretical (thin blue solid line)
transmission through a honeycomb-lattice phononic crystal of steel cylin-
ders in water, along the K direction. (b) Band structure of the infinite
phononic crystal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
4.17 Real part of the pressure field in water for the eigenmode labeled E in
the band structure. The arrow shows the direction of incidence of waves
launched by the transducer. This mode belongs to a deaf band and is not
excited by a plane-wave transducer. . . . . . . . . . . . . . . . . . . . . 66
4.18 The M direction transmssion spectrum of honeycomb lattice with 5, 6
and 7 layers. The insert at the doen left is the definition of layer. . . . . . 67
4.19 (a) Experimental (thick red solid line) and theoretical (thin blue solid line)
transmission through a honeycomb-lattice phononic crystal of steel cylin-
ders in water, along the M direction. (b) Band structure of the infinite
phononic crystal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
4.20 Real part of the pressure field in water for the eigenmode labeled F in
the band structure. The arrow shows the direction of incidence of waves
launched by the transducer. This mode belongs to a deaf band and is not
excited by a plane-wave transducer. . . . . . . . . . . . . . . . . . . . . 68
4.21 The (a) 1 line, (b) 2 lines and (c) 3 lines defect waveguides in triangular
lattice. The red dash circles indicate the position of steel cylinders that
was removed. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
4.22 The experimental transmission spectra (solid line) of 1 line defect waveg-uide with length 15mm, 25mm and 35mm. The dash line shown the trans-
mission spectrum for the triangular lattice K direction for the perfect
structure. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
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4.23 The experimental transmission spectra (solid line) of 2 line defect waveg-
uide with length 15mm, 25mm and 35mm. The dash line shown the trans-
mission spectrum for the triangular lattice K direction for the perfect
structure. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
4.24 The experimental transmission spectra (solid line) of 3 line defect waveg-
uide with length 15mm, 25mm and 35mm. The dash line shown the trans-
mission spectrum for the triangular lattice K direction for the perfect
structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
4.25 The experimental (red solid line) and theoretical (blue dash line) trans-
mission spectra of (a) 1 line, (b) 2 lines and (c) 3 lines defect waveguide. . 74
4.26 Experiment setup of acoustic wave field inside waveguide. . . . . . . . . 75
4.27 The acoustic wave real part images of (a) 2 lines and (b) 3 lines defect
waveguides. The frequency of the wave is 950kHz. . . . . . . . . . . . . 75
4.28 Structure orientation with [100] and [111] direction. . . . . . . . . . . . . 76
4.29 The picture of the 3-D phononic crystal with top surface perpendicular to
(a) [100] and (b) [111] directions. . . . . . . . . . . . . . . . . . . . . . 77
4.30 Experimental set-up used to measure the transmission spectra of phononic
crystals using acoustic transducers in acoustical contact with the phononic
crystal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
4.31 The transmission of [100] direction. . . . . . . . . . . . . . . . . . . . . 79
4.32 Transmission in the [111] direction. . . . . . . . . . . . . . . . . . . . . 80
4.33 Transmission in the [110] direction. . . . . . . . . . . . . . . . . . . . . 80
5.1 Pictures of the structures which edge is parallel to (a)X and (b) M
direction. (c) Definition of the lattice direction. . . . . . . . . . . . . . . 85
5.2 The fabrication process of the phononic crystal slab structure. . . . . . . . 86
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5.3 Sketch of the experiment. Waves are excited in the phononic crystal slabs
using an ultrasonic transducer through a prism with an incidence angle of
30 degrees. The phononic crystal slab is formed by a one layer thick array
of spherical steel beads with a diameter of 4 mm arranged according to a
square lattice in an epoxy matrix. . . . . . . . . . . . . . . . . . . . . . . 88
5.4 Principle of the laser interferometer. . . . . . . . . . . . . . . . . . . . . 89
5.5 (a) Scanning region position. (b) Measured transmission spectrum (left
hand side) and computed band structure (right hand side) in theX direction 91
5.6 (a) Scanning region position. (b) Measured transmission spectrum (left
hand side) and computed band structure (right hand side) in the M direction 92
5.7 Dependence of the displacement amplitude with frequency and propaga-
tion distance measured for (a) theX and (b) theM oriented phononic
crystal slabs. The white lines in the gray maps on the left mark the com-
plete band gap frequency range, while the black cycles indicate the po-
sition of steel beads. The illustrations in the left side of these two color
maps indicate the scanning region. . . . . . . . . . . . . . . . . . . . . . 93
5.8 The graphs (a) and (b) are extracted from the data in Fig. 5.7(a) and
5.7(b), respectively, and show line scans at three particular frequencies.
The chosen frequencies lie before the complete band gap, inside it, and
above it. The blue cycles indicate the position of steel beads. . . . . . . . 95
5.9 Dependence of the displacement amplitude with frequency and propaga-
tion distance measured for the pure epoxy slabs with 4mm thickness. . . . 965.10 The picture of the line defect waveguide . . . . . . . . . . . . . . . . . . 97
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5.11 Experimental transmission through a line defect waveguide managed along
theX direction of the phononic crystal slab and the corresponding theo-
retical band diagram. On the left, the transmission spectrum of waveguide
is shown with a red line, while the transmission spectrum of the perfect
phononic crystal slab in X direction is shown in blue line. The right
hand side is theoretical band diagram of the waveguide. The complete
band gap frequency range is located between the two gray areas. The
illustrations in the left side indicates the scanning region. . . . . . . . . . 99
5.12 Spatial scanning region of displacement field of acoustic waves in the line
defect waveguide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
5.13 Real part of the displacement field of acoustic waves frequency within
complete band gap in the defect line waveguide. The wave frequencies at
275 kHz, 300 kHz and 325 kHz, respectively. The white circles indicate
the positions of the steel beads. . . . . . . . . . . . . . . . . . . . . . . . 100
5.14 Real part of the displacement field of acoustic waves in the defect line
waveguide at a frequency of 135 kHz. The white circles indicate the po-
sitions of the steel beads. . . . . . . . . . . . . . . . . . . . . . . . . . . 101
5.15 (a)Experimental set up for negative refraction. (b) Illustration of the neg-
ative refraction effect. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
5.16 Real part of the displacement field with frequenies (a) 133 kHz and (b)
380 kHz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
5.17 Real part of the displacement field with frequencies (a) 280 kHz and (b)300 kHz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
5.18 Real part of the displacement field with frequencies (a) 333 kHz and (b)
340 kHz. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
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List of Tables
2.1 Band-structure-related properties of three periodic cyctem. [10] . . . . . 19
4.1 Material constants of the phononic crystal constituents. cSand cLare the
velocities for shear and longitudinal waves, respectively, is the mass
density, and ZL is the acoustic impedance for longitudinal waves. . . . . . 524.2 Material constants of the phononic crystal constituents. cSand cLare the
velocities for shear and longitudinal waves, respectively, is the mass
density, and ZL is the acoustic impedance for longitudinal waves. . . . . . 78
5.1 Material constants of the phononic crystal constituents. cSand cLare the
velocities for shear and longitudinal waves, respectively, is the mass
density, and ZL is the acoustic impedance for longitudinal waves. . . . . . 87
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Chapter1 General Introduction
Since the first experiment of X-ray refraction experiment is observed in 1962, the the-
ories of solid state were developed rapidly. In the solid state theories, the electrons are
considered as rather wave than particle. In the crystalline solid, the periodic potential
applied to the electron wave and causes some energy gaps. The electron waves with fre-
quencies within those gaps can not existence inside the solid. The same methods can beapplied to traditional waves as electromagnetic waves or acoustic waves. The first con-
cept was presented in 1987 for electromagnetic waves and in 1993 for acoustic waves.
The analogy energy gaps in traditional wave are called forbidden band gaps or complete
band gaps. The structures, which can generate complete band gaps for electromagnetic
and acoustic waves, are called photonic and phononic crystals, respectively. The elec-
tromagnetic or acoustic wave with frequencies with in the complete band gaps can not
propagate inside the crystals. As the crystalline solid with periodic potential, the photonicand phononic crystals are periodic structure geometrically. The optical and elastic param-
eters are periodically varying inside the photonic and phononic crystals, respectively.
This thesis presented the studies in photonic and phononic crystals. The works are
cooperated by Department of Optics and Photonics, National Central University, Taiwan
and Institude FEMTO-ST, Universit de Franche-Comt, France. Three major subjects
are presented in this thesis. First subject focuses on the optical properties of three-
dimensional photonic crystal. Second subject includes the studies of the acoustic bulk
waves in two and three-dimensional phononic crystals. Finally, the third subject includes
the studies of Lamb wave mode in phononic crystal slab which is consisted of plate and
plannar periodic structure is studied.
We presented in the studies of three-dimensional photonic crystals a method to en-
hance the reflectance of the artificial opal. The experiment is demonstrated by coating
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Ag nanoparticles on the polymethylmethacrylate microspheres to form a metallodielec-
tric artificial opal. The diameter of microspheres is 320nm. The angle-resolved reflection
spectra of the metallodielectric opals are studied. The experimental results are verified
by the three dimensional theoretical band structures which can predict the band gap fre-
quency range corresponding to different incident directions. By a suitable coating of
Ag nanoparticles on the microspheres, the reflectance of the opals is enhanced without
changing the reflection wavelength. This metallodielectric material can be used as the
high reflectance mirror. The device works in visible light wavelength range.
In the chapter of acoustic bulk waves, two-dimensional phononic crystals with tri-
angular and honeycomb lattices are investigated experimentally and theoretically. The
structures used in our experiment are composed of arrays of steel cylinders immersed in
water. The geometrical parameters of these two structures are the same. The measured
transmission spectra revealed the existence of complete band gaps but also of deaf bands.
Band gaps and deaf bands are identified by comparing band structure computations, ob-
tained by a periodic-boundary finite element method, with transmission simulations, ob-
tained using the finite difference time domain method. The appearance of flat bands and
the polarization of the associated eigenmodes is also discussed. Triangular and honey-
comb phononic crystals with equal cylinder diameter and smallest spacing are compared.
As previously obtained with air-solid phononic crystals, it is found that the first com-
plete band gap opens for the honeycomb lattice but not for the triangular lattice, thanks to
symmetry reduction.
Three-dimensional epoxy-steel photonic crystals are studied experimentally also inthis chapter. The structures used in our experiment are composed of face-center cubic
package spherical steel beads embedded in an epoxy matrix. The complete band gaps
are identified by measuring the transmission in different orientations of structure. A large
complete band gaps for longitudinal waves are observed. The60% relative width of the
band gap is larger than expected based on the contrast in material properties. The cou-
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pling between shear and longitudinal polarizations is proposed to be the mechanism for
enlarging the band gap by comparing with the steel beads in water matrix case.
Finally, the propagation of acoustic waves in a square-lattice phononic crystal slab
consisting of a single layer of spherical steel beads in a solid epoxy matrix is studied ex-
perimentally. The acoustic wave, which is guided between two surfaces of slab, is plate
mode, also called Lamb wave mode. The three dimensional confinement and control of
acoustic waves is achieved by the single layer periodic structure and the two face of slab,
so this kind of structure is also called quasi-three dimensional phononic crystal structure.
Acoustic waves are excited by an ultrasonic transducer and fully characterized on the slab
surface by laser interferometry. The transmission and field image of acoustic wave are
investigated. A complete band gap is found to extend around 300 kHz, in good agreement
with theoretical predictions. The transmission attenuation caused by absorption and band
gap effects is obtained as a function of frequency and propagation distance. Well confined
acoustic wave propagation inside a line-defect waveguide is further observed experimen-
tally. An unusual refraction effect is observed in the wave frequencies near the higher
band edge of complete band gaps.
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Chapter2 Introduction to photonic and phononic
crystals
2.1 History and development of photonic crystals
The wave propagation inside periodic structure can be traced to X-ray refraction ex-
periment. The first experiment of X-ray diffraction by crystal is observed. The experiment
of X-ray introduced the concept of forbidden band. After, the theories of solid-state and
semi-conductor were developed widely. The concept was applied to the case of electro-
magnetic waves and elastic waves.
The concepts of photonic crystals and photonic band gap were first presented by Eli
Yablonovitch and Sajeev Jhon in Physical Review Letters [13, 14] in 1987. They purposed
to suppress spontaneous emission and to achieve localization of light. Recently, photonic
crystals attracted much attention of researchers in not only optics but also chemistry,
physics, and microelectronics beacuse of the potential of light control. Photonic crystals
are potent to control the flows of photons. The purpose could be achieved by designing
the band gap frequency range properly.
Photonic crystals (PCs) are dielectric materials in which the refraction index is period-
ically modulated. The validity of Bloch-Floquet theorem for Maxwell equations implies
the existence of photonic bands, in analogy to electrons in crystalline solids. Photonic
crystal structures can produce complete band gaps of electromagnetic wave, in analogy
to energy gaps of electrons. The electromagnetic wave with frequencies within band gaps
range can not propagate inside photonic crystal structure. By introducing some defects or
deformations inside structures, the photonic crystals can be used to control the propaga-
tion direction and properties of light in many approaches.
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Figure 2.1: From left to right diagram, PCs are in one, two, and three dimen-
sions. The red and yellow colors indicate the different refraction index. (http://ab-
initio.mit.edu/photons/)
The photonic crystals types could be divided into one, two and three dimensional.
Fig. 2.1 indicates the three type of structure. In one dimensional structure, the refraction
index is periodically modulated along one dimension, as multilayer structure. Two di-
mensional structure could be achieved by arranging dielectric cylinders in air [15, 16, 17]
periodically or inverse [17, 18]. Three dimensional structure could be fabricated by pack-
aging dielectric cylinders or spheres. There are various techniques for the fabricationof three dimensional PCs [19]. For instance, silicon micromachining [20], wafer fusion
bonding [21], holographic lithography [22], self-assembly [23, 24], angled etching [25],
micromanipulation [26], glancing angle deposition [27] and autocloning [28].
2.1.1 Photonic crystals in Nature
Photonic crystals structure is not only artificial. It existed in nature also, in many
plants, animals and mineral. These photonic crystals periodic structures in nature causethe surface of materials to gleam colors when the light incident on them. The colors do
not result from the existence of pigment.
Here are some examples of the photonic crystals in nature. Fig. 2.2 shows the iri-
descent colors of butterfly wings caused by the periodic structures. The SEM picture of
butterfly wings are shown in Fig. 2.3. [1, 2]
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Figure 2.2: Somewhere in a beam of sunlight in the Amazon basin, the three-inch wings
of a morpho butterfly glow with deep blue iridescence. Then the morpho shifts its wings
and, as if a switch flipped, shows its other self, dull brown. [1]
Figure 2.3: High-resolution SEM images showing the fine structure of the scales with
rounded ends: (a) blue (BL) male, blue region; (b) blue (BL) male, blue-violet region; (c)brown (BR) male.[2]
Fig. 2.4 (a), (b) and (c) shows the colorful spine pf sea mouse and the SEM picture
of cross-section of a spine, respectively.[1, 29] Sea mouse is a marine worm and living
in moderately deep water. [1, 29, 30] Scientists discovered that the spine of sea mouse
consisted of an array of regularly arranged hollow cylinders (Fig. 2.4 (c)), and this simple
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structure gives rise to a spectacular iridescence. [30]
Figure 2.4: (a)Sea mouse, (b) its iridescent threads (c) SEM cross-section of a spine.[2]
Fig. 2.5 shows the picture of opal. This is the oldest and best-known example of
photonic crystals structure in mineral word. The colorful surface of opal is caused by thephotonic crystals structure also.
2.1.2 Defects
Electromagnetic waves with frequencies within the photonic crystal band gaps are
forbidden to propagate in the photonic crystal. However, suitable defects introduced into
the photonic crystal can act as waveguides or cavities for those electromagnetic waves.
Electromagnetic waves can be controlled (guided or confined) by those defects. Thecombination of those defects can act as the novel planar light wave circuit with higher
efficiency than traditional methods.
Some briefly introductions of the waveguide and cavity defects in photonic crystal are
presented in follow. Meadeet al[31] presented the waveguides and cavities in two dimen-
sional photonic crystal structure theoretically. Compare the results to conventional struc-
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Figure 2.5: The opal is the example of photonic band structures in mineral worlds.[2]
tures, the results of photonic crystal defects shown lower bend losses and higher Q values
than conventional bending waveguides and cavities, respectively. Mekiset al[32] demon-
strated highly efficient transmission of light around sharp corners in photonic bandgapwaveguides theoretically. The transmittance is higher than 95 %. High transmission is
observed even for90o bends with zero radius of curvature, with a maximum transmission
of98%as opposed to30%for analogous conventional dielectric waveguides. Tokushima
et al[3] demonstrated1.55m wavelength lightwave propagation through a 120o sharply
bent waveguide formed in a triangular-lattice two-dimensional photonic crystal which
was fabricated in a silicon-on-insulator (SOI) wafer with the top silicon layer of the wafer
used as a core layer. Fig. 2.6 shows the cross sectional micrograph of the structure.C. Martijn de Sterke et al [33] studied the the modes of coupled photonic crystal
waveguides. Liet al[34] employed a highly efficient transfer-matrix method to inves-
tigate the propagation loss in a photonic crystal waveguide without complete wave con-
finement because of limited cladding wall thickness. An anomalous loss phenomenon is
found where the loss for guided modes near the upper band edge can be several orders of
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Figure 2.6: Cross-sectional micrograph of the 2D PC. The holes were formed in a1.85m
thick Si core layer. TheSiO2layer was2m thick. [3]
magnitude smaller than that for modes in the middle of the band gap, and it is attributed to
a different localization degree of the guided mode at different frequency domains. Gersen
et al[35] presented a real-space observation of fast and slow pulses propagating inside
a photonic crystal waveguide by time-resolved near-field scanning optical microscopy.For a specific optical frequency, a localized pattern associated with a flat band in the dis-
persion diagram. During at least 3 ps, movement of this field is hardly discernible: its
group velocity would be at mostc/1000. They also measured the eigenfield distribution
and the band structure of a photonic crystal waveguide with a phase-sensitive near-field
scanning optical microscope [36]. Bloch modes are visualized in the waveguide. In the
band structure, multiple Brillouin zones due to zone folding are observed, in which pos-
itive and negative dispersion is seen. The negative slopes are shown to correspond toa negative phase velocity but a positive group velocity. Chienet al[37] introduced the
point-defect coupling under the tight-binding approximation to describe the behavior of
dispersion relations of the guided modes in a single photonic crystal waveguide and two
coupled identical photonic crystal waveguides.
Some optical devices consisted of photonic crystal waveguides were presented also.
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Linet al[4] reported a successful experimental realization of a photonic-crystal Y split-
ter operating at 1.6mwith a large splitting angle of120o and a miniature sizeof3mX3m. The device is based on a triple-line-defect in 2D photonic crystal slab
structure. The material of light-guiding layer is GaAs. Fig. 2.7 shows the SEM picture
of the devices. Sharkawy et al[38] presented an electro-optical switch implemented in
coupled photonic crystal waveguides theoretically. The device is designed in a square
lattice of silicon posts in air as well as in a hexagonal lattice of air holes in a silicon slab.
The switching mechanism is a change in the conductance in the coupling region between
the waveguides and hence modulating the coupling coefficient and eventually switching
is achieved. Wavelength-selective operation of an optical filter (add/drop) based on a
contra-directional photonic crystal waveguide coupler is demonstrated by Qiuet al[39]
experimentally and theoretically. The waveguides are defined as line defects in a two-
dimensional triangular photonic crystal fabricated in an InP/GaInAsP heterostructure.
Chien et al [40] demonstrated a dual-wavelength demultiplexer with a coupling length
of only two wavelengths and output power ratio as high as 15 dB. The fundamental mode
of the two coupled photonic crystal waveguides can be odd parity in a triangular photonic
crystal and their dispersion curves do intersect. Thus, the photonic crystal waveguides are
decoupled at the crossing point.
The optical cavity with high Q value could be used to confine light and is useful to fab-
ricate laser or other optical devices. Tayebet al[41] analyzed diffraction by a finite set of
parallel cylinders to study the influence of defects in a photonic crystal. They describedl
the near-field map, scattered field, and energy flow of the electromagnetic field and alsolocalized resonant modes. Schereret al[5] presented some examples of high-Q value op-
tical nanocavities in InGaAsP experimentally. The structures can be used to fabricate sur-
face plasmon enhanced light-emitting diode (LEDs) and vertical-cavity surface-emitting
lasers. The photonic crystal cavity are shown in Fig. 2.8
Robinsonet al[42] theoretically demonstrate a mechanism for reduction of mode vol-
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Figure 2.7: (a) Scanning electron micrograph top view of 38 period triple-line-defect
linear waveguide. The defect hole diameter is 0.8 times of lattice constant (352nm).
The rectangular boxes indicate the interfaces between the ridge and the photonic band
gap waveguide. (b) Scanning electron micrograph image of the Y-splitter sample, which
consists of a120o Y- splitter and two60o bends (indicated by the red circles). (c) Infrared
camera image of the two Y-splitter outputs at = 1650nm. They are both Gaussian-like
and equally bright, indicating a near 50/50 splitting ratio.[4]
ume in high index contrast optical microcavities to below a cubic half wavelength. The
principle can be applied to nearly every existing microcavity resonator to enhance not only
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Figure 2.8: Five photonic crystal cavities coupled together lithographically by arrange-ment in the same slab.[5]
light emission but also nonlinear effects. Englundet al[43] observed a large spontaneous
emission rate modification of individual InAs quantum dots in a 2D photonic crystal with
a modified, high-Q single-defect cavity. The emission rate increase of up to 8 times than
quantum dots in a bulk semiconductor. Chaloupka et al [44] shown how to construct
circular photonic crystals and variable-size circular photonic crystals cavities, which can
support well-localized modes with high-quality factors by local density of states Istrate et
al[45] presented a method which can obtain the equivalent of the Fresnel coefficients for
photonic crystals by the band structure and Bloch modes. They used these coefficients to
derive the reflection of light from a photonic crystal of finite size and the resonant modes
of photonic crystal cavities. Xuet al[46] presented theoretically a nanowire-array-based
optical microcavity high Q values and small Veffcan find applications in fields such as
microlasers, compact nonlinear frequency conversion, alloptical signal processing, andquantum information processing. The material is consist of III-V and II-VI semicon-
ductor. OBrien et al[47] presented experimentally tunable optical delay in a coupled
resonator structure consisting of a chain of three heterostructure nanocavities. The speed
of light in the device is varied over a range from c/75 to c/120 using effective pump powers
below100W.
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2.1.3 Photonic crystal fiber
Optical fiber is a traditional and useful optical device. It is applied to optical commu-
nication, optical measurement, laser and many other categories. Many works presented
that by adding the photonic crystal structure in the core of optical fiber, the novel applica-
tion and phenomena could be observed.
In 1996, Knightet al[48] presented the photonic crystal fiber consists of a pure silica
core surrounded by a silica-air photonic crystal material with a hexagonal symmetry. The
fiber supports a single robust low-loss guided mode over a very broad spectral range ofat least from 458 to 1550 nm. Birks et al [6] presented an all-silica optical fiber by
embedding a central core in a two-dimensional photonic crystal with a micrometer-spaced
hexagonal array of air holes. An effective-index model confirms that such a fiber can be
single mode for any wavelength. The SEM picture of fiber is shown in Fig. 2.9.
Figure 2.9: Scanning electron microscope image of the end of a photonic crystal fiber,
showing the central core where a hole has been omitted. [6]
Ranka et al [7] demonstrated experimentally air-silica microstructure optical fibers
can exhibit anomalous dispersion at visible wavelengths. The output spectra of fiber
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extending from the violet to the infrared, by propagating pulses of 100-fs duration and
kilowatt peak powers through a microstructure fiber near the zero-dispersion wavelength.
Fig. 2.10 shows the Electron micrograph picture of fiber Fig. 2.11 shows the optical spec-
Figure 2.10: Scanning electron micrograph image of the inner cladding and core of the
airsilica microstructure fiber. [7]
trum of fiber. Also shown is the spectrum of initial pulse. Jhonson et al[49] presented
Figure 2.11: Optical spectrum of the continuum generated in a 75-cm section of mi-
crostructure fiber. The dashed curve shows the spectrum of the initial 100-fs pulse. [7]
present the light-propagation characteristics of OmniGuide fibers, which guide light by
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concentric multi-layer dielectric mirrors having the property of omnidirectional reflection.
The multi-layer dielectric acts one-dimensional photonic crystal structure. Shephardet al
[50] discussed the damage threshold and practical limitations of current hollow-core fibers
for the delivery of short optical pulses. Coen et al[51] presented the generation of a spa-
tially single-mode white-light supercontinuum has been observed in a photonic crystal
fiber pumped with 60-ps pulses of subkilowatt peak power experimentally.
2.1.4 Colloidal microsphere base photonic crystal
Recently, three-dimensional photonic crystal fabricated by microspheres attracted much
attenuation. The structure is also called artificial opal. The advantages of photonic crystal
based in colloidal microspheres are fabricated easily and with small size which can be
used to high frequency range.
In 1996, Tarhan et al[52] studied the photonic band structure of a polystyrene col-
loidal fcc crystal by transmission measurements. Mguezet al[8] investigated the optical
properties of packed monodisperse silica submicron spheres by means of optical transmis-sion measurements. The lattice parameters of these structures can be easily tuned through
the sphere size form 200 to 700 nm thus covering the whole visible and near infrared
spectrum. Fig. 2.12 shows the SEM picture of the structure. In almost the same time,
Bogomolovet al[53] reported on the photonic band gap phenomenon in the visible range
in a three-dimensional dielectric lattice formed by close-packed spherical silica clusters
experimentally. Manifestations of the photonic pseudogap have been established for both
transmission and emission spectra.Liet al[54] investegated the full band gap of inverse-opal (air-spheres in host) theo-
retically. They also found that, in the presence of disorder such as variations in the radii of
air spheres and their positions, the band gap reduces significantly. This imposes a severe
requirement on the uniformity of the crystal lattice. Lpez Tejeira et al[55] analyzed the
symmetry properties of eigenstates along the high-symmetry directions of close-packed
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Figure 2.12: SEM image of a610m2 region of the surface of a sample made from415 nm spheres. [8]
bare opals according to the group theory. The results shows that some bands cannot be
coupled with an external plane wave along several directions, because of symmetry rea-
sons, and is not expected to provide any observable features in the transmittance Wang
et al[56] studied the effect of different stacking sequences on the optical properties of
inverted opal photonic crystals composed of close-packed air spheres embedded in high
dielectric matrix of GaAs by electromagnetic wave multiple scattering technique. Chenet al [57] presented theoretically a method to reduce the propagation loss of Si-based
photonic crystal slab waveguides. The transmission are enhanced to twice by stacking
silica and polystryrene microspheres on the top of waveguides. Next year, they [9] pro-
posed a technique to fabricate a free-standing three-dimensional colloidal crystal by self-
assembling the colloidal microspheres with controllable thickness from the air and liquid
interface. The structures can be used for nano-photonic circuits, white-light LEDs or as a
photocatalyst. Fig. 2.13 shows the opal with different thicknesses.
Pavariniet al[58] presented a theoretical approach for the interpretation of reflectance
spectra of opal photonic crystals with fcc structure and (111) surface orientation. It is
based on the calculation of photonic bands and density of states corresponding to a spec-
ified angle of incidence in air and yield a clear distinction between diffraction in the
direction of light propagation by (111) family planes and diffraction in other directions
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Figure 2.13: SEM images of the photonic crystals after different heating durations. (A)
More than 15 layers of microspheres were orderly packed. (B) The thickness of the opals
is about17m. (C) The thickness of the opals is about 78m. (D) The thickness of the
opals would be more than200m. (E) This shows that the surface of the photonic crystals
in (D) is well packed in the FCC structure. [9]
by higher-order planes. The theoretical results were verified by reflectance measurements
on artificial opals made of self-assembled polystyrene spheres
2.2 History and development of phononic crystals
A phononic crystal is an artificial crystal which is composed of a finite-size periodic
array of sonic scatterers embedded in a homogeneous host material. The host material
may be solid [59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69] or fluid [61, 70, 71, 72, 73, 74,75, 76]. Phononic crystals can produce full band-gaps, or complete band-gaps, where any
sound wave is not allowed to propagate into the crystal. The theory of phononic crystals is
similar to that of photonic crystals. The analogy between behaivors of the electromagnetic
wave in photonic crystals and acoustic wave in phononic crystals were well discussed by
Miyashita [77].
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The concept of the phononic crystal is first presented by Kushwaha et al. [10] and
Economou and Sigalas [78] in 1993. They discuss classical wave propagation in periodic
structures. Classical waves include electromagnetic waves and elastic (acoustic) waves.
Kushwaha et al. list a comparison of ordinary crystals, dielectric composites and elastic
composites (Tab. 2.1). Tab. 2.1 clearly shows the analogy and difference between quan-
tum, electromagnetic and acoustic waves.
Kushwaha also studied theoretically the acoustic band gap of straight, infinite cylin-
ders embedded in an elastic background. First, the cylinder is made by Ni and the back-
ground is made by Al. In the second structure, the materials of cylinders and background
are exchanged. The band structure of the second structure is displayed in Fig. 2.14. This
is the first "band gap" results for acoustic waves.
Kushwaha and Halevi [79] then presented the acoustic band gap in periodic, binary
composites of long, elastic cylinders that form a hexagonal lattice. They concluded sev-
eral general rules for the occurrence of acoustic band gaps. First, the wave velocity in
the inclusion should be lower than that in the matrix material. Second, The diamond and
FCC structure are preferable, especially the FCC structure. Third, the difference between
acoustic wave velocity in inclusion and matrix should be large. Fourth, the difference
between the velocity of transverse and longitudinal wave should be as small as possible.
Lastly, The material density is also a key point to decide band gap effects. Further works
have shown that these rules are not absolute.
The geometric parameters of phononic crystals are directly dependent on the acoustic
wave length. For long wave length (low frequency), the size of unit cell (for example: theinset of Fig. 2.14) could be very large. The first experimental result of the acoustic band
gap measure is achieved by Martinez-Sala et al[80]. The experiment sample is a sculpture
in Juan March Fundation at Madrid. The sculpture is consisted of square array steel
cylinders with diameter 2.9cm. The acoustic wave frequency is 2 kHz. Afterwards, many
different composite materials were studied, for instance, carbon/epoxy and water/mercury
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Table 2.1: Band-structure-related properties of three periodic cyctem. [10]
Property "Electronic" Crystal "Photonic" Crystal "Phononic" Crystal
Material Crytalline Constructed of two di-
electric materials
Constructed of two
elastic materials
Parameters Universal constants,
atomic numbers
Dielectric constants of
constituents
Mass densities, sound
speeds of constituents
Lattice Con-
stant
1-5 0.1m - 1cm Mesoscopic or macro-
scopicWaves de Broglie (electrons)
Electromagnetic or
light (photons) E,B
Vibrational or sound
(phonons) u
Polarization Spin , Transverse: D =0( E= 0)
Coupled trans.-longit.
(u= 0, D= 0)Differential
equation
h2m
2+ V(r) =ih
t
2E ( E) =(r)c2
2Et2
2uit2
= 1{ xi
(ulxl
) +
xl
[(uixl
+ ulxi
)]}
Free particlelimit
W = h2
k2
2m = ck =cl,tk
Band gap Increases with crystal
potential; no electron
states
Increase with |ab|; no photons, no light
Increase with| ab|; no phonons, novibration; no sound
Spectral re-
gion
Radio wave, mi-
crowave, optical, x
ray
Microwave, optical 1GHz
[81, 82]. The first experiment result of a bulk acoustic wave complete band gap was
presented by Sanchez-Perezet al[73]. The results presented the complete band of two-
dimensional periodic array of rigid cylinders in air with square and triangular geometrical
configurations. The authors also observed the deaf band effect. Deaf bands are acoustic
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Figure 2.14: Band structure for a period array of aluminum cylinders in nickel back-ground. The inset shows the unit cell [10].
branches which exist in the band structure. But the modes of these branches cannot be
excited depending on the symmetry of the mode with respect to the source, hence they
do not transport acoustic energy through the crystal. At almost the same time, Montero
de Espinosa et al[83] presented the complete band gap effect of mercury cylinders in
aluminum matrix without deaf band.
Different kinds of material were also presented. For example, Wenet al[84] presented
the band structure of flexural waves in a periodic binary straight beam with different cross
sections. It is worth to mention that Liuet al[85] presented the locally resonant material
for which the size is 12 times smaller than the wave length. These results can be extended
to the large wave length range. The size of the unit cell can also be reduced.
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So far, the results were presented here are all in the case of acoustic bluk wave. The
acoustic bulk wave is an elastic wave propagating in an infinite solid material. Generally,
the studies of three-dimensional phononic crystals or two-dimensional phononic crystals
with the periodic structure in x-y plane and infinite in z-axis fall in this category.
Phononic crystals for surface acoustic waves and Lamb waves
In contrast to the bulk wave, there are some kinds of acoustic waves that are confined
at the surface or the interface of a material. Tanaka et al[86] present the theoretical eluci-dation of surface acoustic waves characteristics in 2D phononic crystals. They studied the
wave propagating on the surface perpendicular to the axes of elastic cylinders (z-direction)
forming a 2D lattice. The system occupying z>0 is periodic within the flat surface (z=0),
which is taken to be the x-y plane and homogeneous in the z direction. They also compare
the acoustic stop bands of surface and bulk modes in two-dimensional phononic crystal
[87]. Some examples of the acoustic surface wave researchs include different materials
and measurement techniques will be introduced below. Mesegueret al[88] studied thesurface-elastic waves attenuation by a periodic array of cylindrical holes. The experi-
ments were performed in a marble quarry by drilling cylindrical holes. The attenuation
spectra of the surface waves show the existence of absolute band gaps for elastic waves in
these semi-infinite two-dimensional crystals. Vienset al[89] presented the frequency gap
of surface acoustic wave in phononic structures multilayers which consisted of slots cut in
an aluminum substrate filled with a polymer. The complete band gap of surface acoustic
wave in water is presented by Jeong et al[90]. Dhar et al[91] studied the frequencies
dispersion of surface acoustic modes in aluminum-coated glass plates with square-wave
surface relief. The relief is fabricated by laser-based transient grating method. Profunser
et al[92] persented the imaging of ripples in one-dimensional phononic crystal consists
of of a grating of alternate copper and silicon oxide lines of thickness both deposited on
a silicon substrate by ultrafast optical pump and probe technique. The phononic crystal
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devices using surface acoustic wave are received much attenuation also [93, 94, 95]. The
functions included the applications in high frequency wave, filter devices and acoustic
mirrors or transducers.
Lamb waves have also received much attenuation recently, They can be generated in
the elastic plate with finite thickness in the direction perpendicular to the propagation sur-
face. The vibration exists on the two faces of the plate and the acoustic energy distributes
inside all the plate, not just near the surface. Like the surface acoustic wave, the propa-
gation direction of the Lamb wave is already fixed in the direction parallel to the material
surface. The wave can be further controled by adding a structure varying periodically
along the surface of material with phononic crystal effect. It means that the influence
of two-dimensional phononic crystals for surface acoustic waves or Lamb waves is like
the influence of three-dimensional phononic crystals for the bulk waves. Below are some
examples of phononic crystals for Lamb waves.
Hsuet al[96] studied theoretically the propagation for the lower bands of Lamb waves
in two-dimensional phononic-crystal plates consisting of square array of crystalline gold
cylinders in the epoxy matrix. The theory is based on Mindlins plate theory and on the
plane wave expansion method. Zhanget al[97] studied experimentally a new type of
phononic crystal produced by patterning holes on thin metal plates with optical charac-
terization. Khelifet al[98] examined theoretically the propagation of elastic waves in a
phononic crystal slab consisting of piezoelectric inclusions placed periodically in a host
material by finite element method. The system is composed of a square lattice of quartz
cylinders embedded in an epoxy matrix. Gaoet al[99] presented numerically the prop-agation of Lamb waves in one-dimensional quasiperiodic composite thin plates made of
tungsten and silicon resin arranged according to a Fibonacci sequence. The propagation
of Lamb waves in silicon plates coated by a very thin two-dimensional phononic film was
presented by Bonelloet al[100] by using a laser ultrasonics technique.
All the studies above considered a one dimensional structure or a two dimenstional
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structure with cylindrical inclusions. A phononic crystal slab with two dimensional spher-
ical inclusions will be presented later in chapter 3.
Guide and Cavity
To achieve acoustic wave control, the complete band gap effect can be extended to guiding
or confinement the acoustic energy by adding specific defects. Further, various applica-
tions can be developed by studying the interaction between these defect states.
The first study of a defect state of a phononic crystal was presented theoretically bySigalas[101] and Torreset al[102]. There are many theoretical and experimental studies
of different defects in numerous kinds of phononic crystals. Generally, the theoretical
methods used in these studies are based on the plane wave expansion or the finite differ-
ence time domain methods [103, 104]. The defect band in the band structure could be
calculted by plane wave expansion. The transmission can be predicted by finite differ-
ence time domain methods. Some examples are introduced here. Chandraet al[105] pre-
sented the acoustic wave propagation along waveguides in three-dimensional phononiccrystals by finite difference time domain methods. The phononic crystal is constituted
of lead spherical inclusions on a face-centered cubic lattice embedded in an epoxy ma-
trix. The cavity mode and sharp bending waveguide transmission were studied by khelif
et al[106, 107] in a two dimensional phononic crystal constituted by a square array of
circular parallel steel cylinders in water. Sharp bending and the coupling phenomenon
of joined parallel phononic crystal waveguides in two-dimensional steel/epoxy phononic
crystal was presented by Sun et al [108, 109]. Pennec et al[110] studied the coupling
effect between two continuum waveguides and two cavities inserted in a phononic crystal
composed of steel cylinders in water.
Based on these researches, functional and tunable phononic devices can be developed.
Waveguides with stubs which induce zeros of transmission were studied by Khelifet al
[62]. The device have potential applications in filtering and wavelength demultiplexing
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phenomena. A waveguide with tunable narrow pass bands is studied by khelifet al[63]
and Pennec et al [111]. Kafesaki et al [112] showed that the transmittivity (T) in the
waveguide as a function of frequency has an oscillating behavior with regions ofT 1and regions ofT 0. Wanget al[113] studied a quasi-one-dimensional waveguide withperiodical double stubs with tunable complete spectral gaps in the band structure.
Negative refraction in phononic crystal
Negative refraction received great attention in photonic crystal in recent years. Thesame effect is studied in phononic crystal also. The negative refraction effect can be used
to realize perfect imaging and superlenses. There are many theoretical studies based on
the multiple-scattering method. Liet al[114] presented the negative refraction effect in
two dimensional square lattice, rubber-coated tungsten cylinders placed in water. Zhang et
al[115] presented the All-Angle-Negative-Refraction (AANR) in phononic crystals with
steel cylinders in air background and water cylinders in mercury background. Far-field
images of two-dimensional, hexagonal arrays of steel cylinders in air, phononic crystalsuperlens are presented by Qiuet al[116].
Experimental observation of negative refraction of acoustic wave was realized by Feng
et al[117] in two-dimensional triangular sonic crystal constituted by drilling triangular
array of holes on aluminum plate. Hu et al [11] observated directly the point source
imaging in liquid surface waves. The phononic crystal is constituted by square lattice
copper cylinders. Fig. 2.15 shown the simulated and experimental results. Fig. 2.15 (a)
shown the patterns of liquid surface waves with different frequencies. The black areas
inside these figures marked the position of phononic crystal. The acoustic point source is
placed at the left side and near to the phononic crystal. Fig. 2.15 (b) shown the simulated
results with the same parameters as in experiment.
Ke et al [118] observed negative refraction behavior and imaging effect in a two-
dimensional phononic crystal which consists of a triangular array of steel rods immersed
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Figure 2.15: Dark and white represent positive and negative vibrations, respectively. (a)
Experimentally observed patterns of liquid surface waves. Black areas in the middle
stands for the slab of copper cylinders. (b) Simulated results. Parameters used in simula-
tions are the same as in experiment. Red dots denote copper cylinders. [11]
in water. The same effect was observed in three dimensional phononic crystals consist
of tungsten carbide beads surrounded by water, with the beads close packed in a face
centered cubic crystal structure, by Yanget al[119].
Other applications and studies
There are many other kinds of studies in phononic crystal. For instance, the tunneling
effect, high frequency phononic crystal and highly directional acoustic sources based on
phononic crystals.
The tunneling effect is one of the most striking phenomena in quantum mechanics.
Since the theory of photonic and phononic crystals is deduced from the "electric" crystal,the existence of tunneling effect with classical waves is possible. Yanget al[120] studied
experimentally and theoretically the tunneling effect in 3D phononic crystals, consisting
of fcc arrays of close-packed tungsten carbide beads in water. Qiuet al[121] found that
the resonant tunneling of longitudinal waves can be distinguished from those of transverse
waves in two-dimensional double phononic potential barriers.
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High frequency phononic crystals consisting of micro structures are achieved by mi-
cro fabrication processes or nano structures. Gorishnyyet al[122] demonstrated a new
method for fabrication and characterization of hypersonic phononic crystals by combi-
nation of interference lithography and Brillouin light scattering. The frequency range
extends to the GHz range. Lin et al[123] studied the characteristics of a nanoacoustic
mirror and a nanophononic cavity by femtosecond optical pulse. The first phononic band
gap frequency is centered at 280 GHz.
Recently, there have been some researches for highly directional acoustic wave sources
which can be applied as acoustic transducers. Qiuet al[124] demonstrated a highly di-
rectional acoustic source with a large radiation enhancement, operating at the band-edge
frequency of the phononic crystal by placing a line acoustic source inside a phononic
crystal with a square lattice. Wuet al[125] presented an optimal amplitude magnification
which is more than 86.5 times in comparison with the amplitude of the original source
freely radiating based on the planar resonant cavity of two-dimensional phononic crystals.
Fig. 2.16 displayed the experiment results which were presented by Ke et al [12]. The
structure they used is steel rods in water arranged in a square lattice. The results shown a
highly directional radiation with a half-power angular width of6o.
2.3 Elastic wave propagation in materials
This section is a brief introduction to acoustic wave propagation inside elastic materi-
als [126].
The propagation of acoustic waves affects the deformation of materials. The dis-
placement vector at each point of a material is presented by the vector u. The strain-
displacement relation can be expressed by:
Sij =1
2
uixj
+ujxi
(2.1)
The displacements of a material are accompanied with restoring forces which are
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Figure 2.16: Radiation amplitude field distribution over the phononic crystal: (a)by ex-
periment and (b) by simulation. [12]
called the stress field T. The inertial and elastic restoring forces in a free vibrating
medium are thus related through the translational equation of motion:
T= 2u
t2 (2.2)
Hookes Law states the strain is linearly proportional to the stress, or conversely, that
the stress is linearly proportional to the strain. In general, the stress can be expressed by :
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Tij =cijklSkl (2.3)
Wherei, j, k,l = x, y,zand with implied summation over the repeated subscriptsk
and l. The "microscopic spring constants" cijklare called elastic stiffness constants. These
stiffness constants are not all independent since
cijkl =cjikl =cijlk =cjilk (2.4)
and
cijkl =cklij (2.5)
Therefore, the stress field can be writen as:
Tij =cijklukxl
(2.6)
In isotropic material, The stress reduces to:
Tij =ullij+ 2uij (2.7)
where(r)and(r)are so-called Lam coefficients.
The relations above describe elastic wave propagation in media. The theoretical meth-
ods for calculating wave propagation inside inhomogeneous media are based on these
relations.
2.4 Theoretical methods
This section introduces some theoretical calculation methods for phononic crystas.
The methods include the Finite-Difference Time-Domain (FDTD) method and Finite El-
ement Methods (FEM). In our study, The FDTD method is used to compute the transmis-
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sion of phononic crystals; FEM is used to compute the band structure. FEM also is used
to calculate the eigen-modes of acoustic branches in the band structure.
2.4.1 Finite-Difference Time-Domain method
The Finite-Difference Time-Domain method used in phononic crystals was first de-
veloped by Sigalas and Garca [103, 104]. The FDTD method can handle inhomogeneous
mixed system cases such as fluids in solids or the converse. It is a code for the temporal
integration of incident wave packets for the full elastic equation that converges well in all
cases investigated. Compared to other methods, the FDTD method can calculate the wave
varying in the structure with time. The simulation is suited to finite dimension structures
and can be made most similar to the real experiment environment.
The propagation of elastic waves in isotropic inhomogeneous media is described by:
2ui
t
2 =
1
Tij
xj
(2.8)
Tij = ullij+ 2uij (2.9)
Sij = 1
2
uixj
+ ujxi
(2.10)
whereuiis theith component of the displacement vectoru(r),Tijis the stress tensor,
(r)and(r)are the so-called Lame coefficients, and(r)is the density.
The FDTD method uses discretization of the elastic wave equations in both the spa-
tial and time domains, sets appropriate boundary conditions, and explicitly calculates the
evolution of the displacement vectoru in the time domain. More specifically, real space
is discretized into a cubic grid. The separation distance between grids isx,yor z.
Propagation time is also discretized into many temporal steps with interval t. For exam-
ple, a function(x)is discretized using the method above. The differential of(x)with
respect toxcan be expressed as:
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(x)x
= (x + x,y,z) (x,y,z)x
(2.11)
For elastic wave equations, the displacement vectorucan be expressed by uxx+uyy+
uzz. The componentsux,uy anduzare spatially interlaced by half a grid cell; they can
be approximated by center differences in both space and time. The equation for the ux
displacement becomes:
ux(l ,m,n,k+ 1) = 2ux(l ,m,n,k) ux(l ,m,n,k 1) + t2
(l ,m,n)x
[Txx(l+12
, m , n, k) Txx(l 12
, m , n, k)]
+ t2
(l ,m,n)y[Txy(l, m +
1
2, n , k) Txy(l, m 1
2, n , k)]
+ t2
(l ,m,n)z
[Txz(l ,m,n +12
, k) Txz(l ,m,n 12
, k)] (2.12)
where theTxxcomponent of the stress tensor is given by
Txx(l+1
2, m , n, k) =
1
x[(l+
1
2, m , n, k) + 2(l+
1
2, m , n, k)]
[ux(l+ 1, m , n, k) ux(l ,m,n,k)]+
(l+ 12
, m , n, k)
y [uy(l+
1
2, m +
1
2, n , k) uy(l+1
2, m 1
2, n , k)]
+
(l+ 12
, m , n, k)
z
[uz(l+12
, m , n +1
2, k) uz(l+1
2, m , n 1
2, k)] (2.13)
where k is the index for the time step. In a similar way one can get the other components
of the stress tensor. The y component of the displacement vector is calculated at the
(l + 12
, m + 12
, n)grid point and the z component at the (l + 12
, m , n + 12
)grid point. That
way, we can get second order accuracy in our finite difference scheme.
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Figure 2.17: The diagram of the computational space
The computational space is sketched in Fig. 2.17. The computational cell contains
the phononic crystal structure in its central part. The structure consists of inclusions
embedded in a matrix of a different material. The inclusions form a lattice which we want
to study. On the left and right sides of the composite, we put a homogeneous material,
indentical to the matrix material of the composite. The acoustic wave is launched in the
homogeneous (excitation) region in the left of composite and propagates along the z axis.
The components of the displacement vector as a function of time are collected in the otherhomogeneous (detection) region on the other side of the composite. Periodic boundary
conditions have been used at the edges of cell along x and y directions. In order to close
the space along the z axis, Murs first order absorbing boundary conditions are applied at
two edges in z direction which are given by the following expression:
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ux(l,m, 1, k+ 1) = ux(i,m, 2, k) +c0t xc0t + x
[ux(l,m, 2, k+ 1) ux(i,m, 1, k)] (2.14)
forn = 1;c0is the longitudinal sound velocity of the matrix material forux,uyand
uz.
The time series results collected at the detection region are converted into the fre-
quency domain using a fast Fourier transform. By normalizing these results relative to the
incident wave, one can find the transmission coefficient.
2.4.2 Finite element method
The finite element method has more accuracy than the other methods in phononic
crystals with sharp spatial changes of impedance, e.x. air/solid. In our studies, it is the
major tool to calculate the band structures of bulk waves and Lamb waves in phononic
crystals.
In the finite element method, the phononic crystal is assumed to be infinite and ar-
ranged periodically along the surface. The whole domain is split into successive unit cells
containing one hole surrounded with the matrix material. Each unit cell is indexed by m
,p. The unit cell is meshed and divided into finite elements connected by nodes. Accord-
ing to the Bloch-Floquet theorem, all fields obey a periodicity law, yielding for instance
the following relation between the mechanical displacementsuifor nodes lying on the
boundary of the unit cell:
ui(x + ma1, y+pa2) = ui(x,y,z)exp[j(kxma1)] exp[j(kxpa2)] (2.15)
where kx and ky are the components of the Bloch wave vectors in the x and y di-
rections, respectively. a1anda2are the pitches of the array. Considering the periodical
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boundary conditions above allows us to reduce the model to a single unit cell which can
be meshed using finite elements. A mechanical displacement and electrical potential fi-
nite element scheme is used. Considering a monochromatic variation of mechanical and
electrical fields with a time dependence in exp(jt), whereis the angular frequency,
the general piezoelectric problem with no external applied force can be written:
Kuu 2Muu Ku
Ku K
u
=
0
0
(2.16)
whereKuuandMuuare the stiffness and mass matrices of the purely elastic part of
the problem,Kuand Kuare piezoelectric-coupling matrices, andKaccounts for the
purely dielectric problem.u and represent, respectively, all displacements and electrical
potential at the nodes of the mesh, gathered together in vector form. As the angular
frequencyis a periodical function of the wave vector, the problem can be reduced to the
first Brillouin zone. The dispersion curves are eventually built by varying the wave vector
on the first Brillouin zone for a given propagation direction. The full band structure is
then deduced using symmetries.
For our case, there are no piezoelectric-coupling and dielectric problems. The problem
can be reduced to:
Kuu 2Muu
(u) = 0 (2.17)
The band diagram is obtained by solving an eigenvalue problem inside the first irre-
ducible Brillouin zone.
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most important, because it is the most stable against disorder.
In this chapter, the synthesis and the angle-resolved reflectance spectra of metallodi-
electric opals by coating the Ag nanoparticles onto the dielectric micro-spheres are pre-
sented. The opals are made by polymethylmethacrylate(PMMA). With the suitable con-
centration of the Ag nanoparticles, the reflectance of the opals can be enhanced without
changing the photonic band gap of the PC structures. The results are presented experi-
mentally and theoretically. The theoretical band structure of microspheres is calculated by
plane-wave expansion method. It shows the relation between band gap frequency range
and light incident angle. The experimental one is measured the angle-resolved reflectance
spectra directally. The experiment setup will be presented in a later section.
3.2 Plane Wave Expansion (PWE)
Plane wave expansion [132] is widely adapted to calculate to band structure of pho-
tonic crystals. In order to verify to our experimental results, the band structure of our opal
are calculated by PWE also. Band structure is the dispersion relation of the periodicallyarranged dielectric structure. The band gap frequency range, phase and group velocity
can be extracted from band structure. A brief introduction of PWE is presented in follow
paragraph.
E(r, t) =1c
B(r, t)
t =(r)
c
H(r, t)
t (3.1)
H(r, t) =1c
D(r, t)t
= 0(r)
cE(r, t)
t (3.2)
where Eis the electric field, His the magnetic field, Dis the electric displacement
and Bthe magnetic induction.
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The time-indepent form could be get by set E, H, Dand Bas follow:
E(r, t) = E(r)eit (3.3)
H(r, t) = H(r)eit (3.4)
D(r, t) = D(r)eit (3.5)
B(r, t) = B(r)eit (3.6)
The magnetic permeability of the photonic crystal is equal to that in free space, i.e.,
(r) =0. The electric constant is assumed real, isotropic, and spatial periodically, i.e.,(r) =(r+ ai), i= 1, 2, 3, where ais the lattice vector of the photonic crystal.
According the description above, the equations 3.1 and 3.2 can be rewrite as:
1
(r) ( E(r)) =
2
c2E(r) (3.7)
( H(r, t)
(r) ) =
2
c2H(r) (3.8)
This is the Helmholtz equation of electromagnetic wave.
The Blochs theorem is applied to the equation above. Blochs theorem indicated that
The eigenfunctions of the wave equation for a periodic potential can be expressed as:
(r) = uk(r)eikr, whereuk(r) = uk(r+ a)and ais the lattice vector of the lattice of
periodic potential.
Because of(r) is periodical. Thus the Blochs theorem can be applied to the Helmholtz
equation of electromagnetic wave. The electric field and magnetic field are thus charac-
terized by a wave vector kin first Brillouin zone and band index as:
E(r) = Ekn(r) = ukn(r)eikr (3.9)
H(r) = Ekn(r) = vkn(r)eikr (3.10)
whereukn(r)andvkn(r)are periodic vectorial function.
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ukn(r+ ai) = ukn(r) (3.11)
vkn(r+ ai) = vkn(r) (3.12)
fori = 1, 2, 3.
Because of the spatial peridodicity