The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF)...
-
Upload
audrey-gregory -
Category
Documents
-
view
218 -
download
0
Transcript of The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF)...
![Page 1: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/1.jpg)
Chem 1311 A D. G. VanDerveer/T. F. Block Fall, 2001 Tentative Syllabus
Date Lecture Reading1 Problems
M August 20 Introduction OFB, sec. 7-1 to 7-4 W August 22 Chemical Equilibrium OFB, sec. 7-5 to 7-7 OFB Ch 7, # 2, 4, 6, 8,
12, 18, 20, 27, 30 F August 24 Chemical Equilbirium OFB, sec. 8-1 to 8-3 OFB Ch 7, # 40, 42, 48,
53, 56, 60, 62 M August 27 Bronsted-Lowry Theory OFB Ch 8, # 4, 6, 10, W August 29 Bronsted-Lowry Theory OFB, sec. 8-4 OFB Ch 8, # 16, 20, 22 F August 31 Hydrolysis OFB, sec. 8-5 OFB Ch 8, # 26b, 28,
32, 38 M September 3 Labor Day W September 5 Buffers OFB, sec. 8-6 OFB Ch 8, # 46, 50 F September 7 Titrations OFB, sec. 8-7 M September 10 Polyprotic Acids
W September 12 Review F September 14 EXAM I
M September 17 Exam Return and Review
Norman, Ch. 5; OFB, sec. 8-8
W September 19 Lewis Acids and Bases; Acid and Base Anhydrides
OFB, sec. 9-1 to 9-3
F September 21 Solubility Product OFB, sec. 9-4 M September 24 Effect of pH on
Solubility OFB, sec. 9-5
W September 26 Complex Ions and Solubility
OFB, sec. 20-1 and 20-2
F September 28 Symmetry and Structure OFB, sec. 20-3 and 20-4 M October 1 Crystal Structure and
Defects
W October 3 Lattice Energy OFB, sec. 21-2 and 21-3 F October 5 Silicate Minerals OFB, sec. 21-4 and 21-5 M October 8 Ceramics W October 10 Review F October 12 EXAM II M October 15 No School Norman, Ch. 1 and 2;
OFB, sec. 18-1; Winter, Ch. 3
W October 17 Exam Return and Review
F October 19 MO Theory Winter, Ch. 4; OFB, sec. 3-6 and 18-2
OFB, Ch. 18, #2, 4, 6. 8, 10, 12, 14, 16, 18
M October 22 VSEPR And Hybrid Orbitals
Winter, Ch. 5 and 6 OFB, Ch. 18, #20, 22, 24, 26, 31;Winter, sec. 4.4, #1(first 6 only) and 2
W October 24 MO’s for Polyatomic Molecules
Winter, sec. 5.7, #1 and 2; sec. 6.8, #3
The Reading isfor the next class.
Problems are forthat day’s class.
Problems for eachweek (MWF) aredue the followingMonday.
![Page 2: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/2.jpg)
Reaction quotient
PCPD
PAPBa b
c d
Q = or[C]c[D]d
[A]a[B]b
![Page 3: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/3.jpg)
Reaction quotient
PCPD
PAPBa b
c d
Q =
PA , PB, etc. not at equilibrium
![Page 4: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/4.jpg)
Reaction quotient
PCPD
PAPBa b
c d
Q =
Q will go to the value of K as
the partial pressures go to
equilibrium
![Page 5: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/5.jpg)
Q vs K can
predict where
the reaction is
in respect to
equilibrium.
![Page 6: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/6.jpg)
PCPD
PAPBa b
c d
K =
PCPD
PAPBa b
c d
Q =
Q < K
aA + bB cC + dD
![Page 7: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/7.jpg)
PCPD
PAPBa b
c d
K =
PCPD
PAPBa b
c d
Q =
Q < K
aA + bB cC + dD
Too much reactant,not enough product.
![Page 8: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/8.jpg)
PCPD
PAPBa b
c d
K =
PCPD
PAPBa b
c d
Q =
Q < K
Q > K
aA + bB cC + dD
aA + bB cC + dD
![Page 9: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/9.jpg)
PCPD
PAPBa b
c d
K =
PCPD
PAPBa b
c d
Q =
Q < K
Q > K
aA + bB cC + dD
aA + bB cC + dD
Too much product, not enoughreactant.
![Page 10: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/10.jpg)
PCPD
PAPBa b
c d
K =
Q =Q > K
aA + bB cC + dD
aA + bB cC + dD
Q < K
Q < K
Large vs c dPCPD
c dPCPD
a bPAPB
a bPAPB
![Page 11: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/11.jpg)
Q =c dPCPD
a bPAPB
![Page 12: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/12.jpg)
Exercise page 291
P4 2 P2
K = 1.39 @ 400oC
1.40 mol P4
1.25 mol P2
Volume = 25.0 L
![Page 13: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/13.jpg)
P4 2 P2
Q = (PP )2
2
PP4
![Page 14: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/14.jpg)
P4 2 P2
Q = (PP )2
2
PP4
P =nRT
V
T = 673 K
V = 25.0 L
R = 0.0820578 L atm mol-1 K-1
![Page 15: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/15.jpg)
P4 2 P2
Q = (PP )2
2
PP4
PP =nRT
V4
=(1.4)(0.0820578)(673)
25.0= 3.09 atm
![Page 16: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/16.jpg)
P4 2 P2
Q = (PP )2
2
PP4
PP =nRT
V2
=(1.25)(0.0820578)(673)
25.0= 2.76 atm
PP =nRT
V4
=(1.4)(0.0820578)(673)
25.0= 3.09 atm
![Page 17: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/17.jpg)
P4 2 P2
Q = (PP )2
2
PP4PP =
2
2.76 atm
PP =4
3.09 atm
=(2.76)2
3.09=
![Page 18: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/18.jpg)
P4 2 P2
(PP )2
2
PP4PP =
2
2.76 atm
PP =4
3.09 atm
=(2.76)2
3.09=
2.46Q =
Q =
K = 1.39
![Page 19: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/19.jpg)
P4 2 P2
(PP )2
2
PP4PP =
2
2.76 atm
PP =4
3.09 atm
=(2.76)2
3.09=
2.46Q =
Q =
K = 1.39
P4 2 P2
![Page 20: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/20.jpg)
Converting between partial
pressures and concentrations.
![Page 21: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/21.jpg)
Converting between partial
pressures and concentrations.
Concentration = moles
V
![Page 22: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/22.jpg)
Converting between partial
pressures and concentrations.
Concentration = moles
V
PV = nRT
![Page 23: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/23.jpg)
Converting between partial
pressures and concentrations.
Concentration = moles
V
For gas ‘A’ [A] =nA
V
PV = nRT
![Page 24: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/24.jpg)
Converting between partial
pressures and concentrations.
Concentration = moles
V
For gas ‘A’ [A] =nA
V=
PA
RT
PV = nRT
![Page 25: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/25.jpg)
Converting between partial
pressures and concentrations.
Concentration = moles
V
For gas ‘A’ [A] =nA
V=
PA
RT
PA = RT[A]PV = nRT
![Page 26: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/26.jpg)
PA = RT[A]
2 NO2(g)N2O4(g)
![Page 27: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/27.jpg)
PA = RT[A]
2 NO2(g)N2O4(g)
Pref = 1 atm
![Page 28: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/28.jpg)
PA = RT[A]
2 NO2(g)N2O4(g)
Pref = 1 atm
PN O2 4
/Pref
(PNO2
/Pref)2= K
![Page 29: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/29.jpg)
PA = RT[A]
2 NO2(g)N2O4(g)
Pref = 1 atm
4
/Pref
(PNO2
/Pref)2= K
PN O2
PN O2
4
= RT[N2O4]
![Page 30: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/30.jpg)
PA = RT[A]
2 NO2(g)N2O4(g)
Pref = 1 atm
4
/Pref
(PNO2
/Pref)2= K
PN O2
PN O2
4
= RT[N2O4]
PNO2
= RT[NO2]
![Page 31: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/31.jpg)
2 NO2(g)N2O4(g)
4
/Pref
(PNO2
/Pref)2= K
PN O2
PN O24
= RT[N2O4]
PNO2
= RT[NO2]
[N2O4](RT/Pref)
[NO2]2(RT/Pref)=
[N2O4]
[NO2]2
xRT
Pref
)(-1
K =
![Page 32: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/32.jpg)
2 NO2(g)N2O4(g)
[N2O4](RT/Pref)
[NO2]2(RT/Pref)= xK =
[N2O4]
[NO2]2
[N2O4]
[NO2]2
= K RT
Pref
)(
RT
Pref
)(-1
![Page 33: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/33.jpg)
[N2O4]
[NO2]2= K RT
Pref
)(
aA + bB cC + dD
c
= K[C]c[D]dPCPD
PAPBa b
d
[A]a[B]b
= K ( RTPref
)a+b-c-d
?
![Page 34: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/34.jpg)
[C]c[D]d
[A]a[B]b
= K ( RTPref
)a+b-c-d
Exercise page 297
CH4 + H2O CO + 3 H2
K = 0.172
[H2]=[CO]=[H2O]= 0.00642 mol L-1
![Page 35: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/35.jpg)
[C]c[D]d
[A]a[B]b
= K ( RTPref
)a+b-c-d
CH4 + H2O CO + 3 H2
K = 0.172
[H2]=[CO]=[H2O]= 0.00642 mol L-1
(0.00642)4
[CH4](0.00642)= 0.172 ( RT
Pref
)-2
![Page 36: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/36.jpg)
[CH4]= 0.172 ( RT
Pref
)-2
CH4 + H2O CO + 3 H2
[CH4] =
K(RT)-2 = 3.153 x 10-5
(0.00642)3
(0.00642)3
3.153 x 10-5= 8.39 x 10-2 mol L-1
![Page 37: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/37.jpg)
Le Chatelier’s Principle
![Page 38: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/38.jpg)
Le Chatelier’s Principle
A system in equilibrium that is
subjected to a stress reacts in a
way that counteracts the stress.
![Page 39: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/39.jpg)
Le Chatelier’s Principle
Any system in chemical equilibrium, as a result
of the variation in one of the factors determining
the equilibrium, undergoes a change such that, if
this change had occurred by itself, it would have
introduced a variation of the factor considered
in the opposite direction.
![Page 40: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/40.jpg)
Le Chatelier’s Principle
Any system in chemical equilibrium, as a result
of the variation in one of the factors determining
the equilibrium, undergoes a change such that, if
this change had occurred by itself, it would have
introduced a variation of the factor considered
in the opposite direction.
![Page 41: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/41.jpg)
Le Chatelier’s Principle
A system in equilibrium that is
subjected to a stress reacts in a
way that counteracts the stress.
Stress = a factor affecting equilibrium
![Page 42: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/42.jpg)
Stress = a factor affecting equilibrium
K =[C]c[D]d
[A]a[B]b
Anything causing a change in the concentration (or partial pressure) ofa reactant or product is a stress.
![Page 43: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/43.jpg)
Factors affecting equilibrium:
![Page 44: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/44.jpg)
Factors affecting equilibrium:
temperature
![Page 45: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/45.jpg)
Factors affecting equilibrium:
temperature
pressure
![Page 46: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/46.jpg)
Factors affecting equilibrium:
temperature
pressure
volume
![Page 47: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/47.jpg)
Factors affecting equilibrium:
temperature
pressure
removal or addition of product
volume
![Page 48: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/48.jpg)
Factors affecting equilibrium:
temperature
pressure
removal or addition of reactant
volume
removal or addition of product
![Page 49: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/49.jpg)
Removal or addition of a reactant
or product.
![Page 50: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/50.jpg)
Removal or addition of a reactant
or product.
Increases or decreases concentration.
![Page 51: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/51.jpg)
PA[A]
PB [B]
Removal or addition of a reactant
or product.
Increases or decreases concentration.
![Page 52: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/52.jpg)
![Page 53: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/53.jpg)
![Page 54: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/54.jpg)
K =[B]
[A]
![Page 55: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/55.jpg)
I2 + H2 2 HI
![Page 56: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/56.jpg)
I2 + H2 2 HI
PHI= 3.009 atm
PI2
= 0.4756 atm
PH2
= 0.2056 atm
![Page 57: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/57.jpg)
I2 + H2 2 HI
= 0.4756 atm
= 0.2056 atm
= 3.009 atm
PHI
PHI
( )2
PI2
PI2
( ) PH2PH
2
( )= K
![Page 58: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/58.jpg)
I2 + H2 2 HI
= 0.4756 atm
= 0.2056 atm
= 3.009 atm
PHI
PHI
( )2
PI2
PI2
( ) PH2PH
2
( )= K
(3.009)2
(0.4756)(0.2056)=
![Page 59: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/59.jpg)
I2 + H2 2 HI
= 0.4756 atm
= 0.2056 atm
= 3.009 atm
PHI
PHI
( )2
PI2
PI2
( ) PH2PH
2
( )= K
(3.009)2
(0.4756)(0.2056)= 92.60
![Page 60: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/60.jpg)
I2 + H2 2 HI
Increase PI2
to 2.00 atm.
![Page 61: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/61.jpg)
I2 + H2 2 HIK = 92.60
Start P 2.000 0.2056 3.009
P
2nd eq P
Increase PI2
to 2.000 atm
![Page 62: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/62.jpg)
I2 + H2 2 HIK = 92.60
Start P 2.000 0.2056 3.009
P
2nd eq P
Increase PI2
to 2.000 atm
-x -x +2x
![Page 63: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/63.jpg)
I2 + H2 2 HIK = 92.60
Start P 2.000 0.2056 3.009
P
2nd eq P
Increase PI2
to 2.000 atm
-x -x +2x
2.000-x 0.2056-x 3.009+2x
![Page 64: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/64.jpg)
I2 + H2 2 HIK = 92.60
Start P 2.000 0.2056 3.009
P
2nd eq P
Increase PI2
to 2.000 atm
-x -x +2x
2.000-x 0.2056-x 3.009+2x
92.6 =(3.009+2x)2
(2.000-x)(0.2056-x)=
![Page 65: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/65.jpg)
92.6 =(3.009+2x)2
(2.000-x)(0.2056-x)=
![Page 66: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/66.jpg)
92.6 =(3.009+2x)2
(2.000-x)(0.2056-x)=
(9.054 + 12.036x + 4x2)
(0.4112 - 2.2056x + x2)= 92.6
![Page 67: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/67.jpg)
92.6 =(3.009+2x)2
(2.000-x)(0.2056-x)=
(9.054 + 12.036x + 4x2)= 92.6
9.054 + 12.036x + 4x2 = 92.6 (0.4112 - 2.2056x + x2)
(0.4112 - 2.2056x + x2)
![Page 68: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/68.jpg)
92.6 =(3.009+2x)2
(2.000-x)(0.2056-x)=
(9.054 + 12.036x + 4x2)= 92.6
(0.4112 - 2.2056x + x2)
(0.4112 - 2.2056x + x2)
9.054 + 12.036x + 4x2 = 38.08 - 204.24x + 92.6x2
9.054 + 12.036x + 4x2 = 92.6
![Page 69: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/69.jpg)
9.054 + 12.036x + 4x2 = 38.08 - 204.24x + 92.6x2
88.60x2 - 216.276x + 29.023 = 0
x =-b b2 - 4 ac
2a
a b c
=
![Page 70: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/70.jpg)
9.054 + 12.036x + 4x2 = 38.08 - 204.24x + 92.6x2
88.60x2 - 216.276x + 29.023 = 0
x =-b b2 - 4 ac
2a
a b c
= 0.142 or 2.30
![Page 71: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/71.jpg)
Start P 2.000 0.2056 3.009
P
2nd eq P
-x -x +2x
2.000-x 0.2056-x 3.009+2x
0.142 or 2.30x =
I2 + H2 2 HI
![Page 72: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/72.jpg)
Start P 2.000 0.2056 3.009
P
2nd eq P
-x -x +2x
2.000-x 0.2056-x 3.009+2x
0.142 or 2.30x =
I2 + H2 2 HI
x = 2.30 would give a negative pressure for I2
![Page 73: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/73.jpg)
Start P 2.000 0.2056 3.009
P
2nd eq P
-0.142 -0.142 0.284
1.858 0.0636 3.293
0.142 or 2.30x =
I2 + H2 2 HI
![Page 74: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/74.jpg)
Calculate K with new partial
pressures.
![Page 75: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/75.jpg)
Calculate K with new partial
pressures.
(3.293)2
(1.858)(0.0636)=
![Page 76: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/76.jpg)
Calculate K with new partial
pressures.
(3.293)2
(1.858)(0.0636)= 91.77
K given = 92.60
![Page 77: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/77.jpg)
Changing volume of system
![Page 78: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/78.jpg)
Changing volume of system
V 1
P
![Page 79: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/79.jpg)
Changing volume of system
V 1
P
If V is reduced, P increases.
PV = nRT
![Page 80: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/80.jpg)
Changing volume of system
V 1
P
If V is reduced, P increases.
Le Chatlier’s principle requires that the
equilibrium shift so that P decreases.
![Page 81: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/81.jpg)
2 NO2(g)N2O4(g)
![Page 82: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/82.jpg)
2 NO2(g)N2O4(g)
An increase in pressure should
favor an increase in the product,
N2O4.
![Page 83: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/83.jpg)
2 NO2(g)N2O4(g)
An increase in pressure should
favor an increase in the product,
N2O4.
Each N2O4 produced means a loss of two NO2 molecules, a net loss of onemolecule and a lower pressure.
![Page 84: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/84.jpg)
2 NO2(g)N2O4(g)
A decrease in pressure favors a shift to
NO2.
![Page 85: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/85.jpg)
Raising or lowering the temperature
![Page 86: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/86.jpg)
Raising or lowering the temperature
Some reactions liberate heat to
form products.
![Page 87: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/87.jpg)
Raising or lowering the temperature
Some reactions liberate heat to
form products.
This is an exothermic reaction.
![Page 88: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/88.jpg)
Raising or lowering the temperature
This is an endothermic reaction.
Other reactions absorb heat to
produce products.
![Page 89: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/89.jpg)
Raising the temperature of an
endothermic reaction will favor
the formation of more product.
R P
![Page 90: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/90.jpg)
Raising the temperature of an
exothermic reaction will favor
the formation of more reactant.
R P
![Page 91: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/91.jpg)
NaOH(s) + H2O(l) Na+(aq) + OH-
(aq) + H2O(l)
![Page 92: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/92.jpg)
NaOH(s) + H2O(l) Na+(aq) + OH-
(aq) + H2O(l)
The solution of solid sodium hydroxide
into water is exothermic.
![Page 93: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/93.jpg)
K = [P]
[R]
![Page 94: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/94.jpg)
K = [P]
[R]
If a reaction is exothermic and the
temperature is raised, K will decrease.
![Page 95: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/95.jpg)
K = [P]
[R]
If a reaction is endothermic and the
temperature is raised, K will increase.
![Page 96: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/96.jpg)
Driving reactions to completion
![Page 97: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/97.jpg)
Driving reactions to completion
Completion = 100% yield of product
![Page 98: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/98.jpg)
Cl-(aq) + Ag+
(aq) AgCl(s)
![Page 99: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/99.jpg)
Cl-(aq) + Ag+
(aq) AgCl(s)
AgCl precipitates from the
solution.
![Page 100: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/100.jpg)
Cl-(aq) + Ag+
(aq) AgCl(s)
AgCl precipitates from the
solution.
As the AgCl precipitates,
product is removed from solution.
![Page 101: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/101.jpg)
![Page 102: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/102.jpg)
Cl-(aq) + Ag+
(aq) AgCl(s)
![Page 103: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/103.jpg)
N2 + 3 H2 2 NH3
All gases
![Page 104: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/104.jpg)
N2 + 3 H2 2 NH3
All gases
exothermic
![Page 105: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/105.jpg)
N2 + 3 H2 2 NH3
All gases
exothermic cool
![Page 106: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/106.jpg)
N2 + 3 H2 2 NH3
All gases
exothermic cool
![Page 107: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/107.jpg)
N2 + 3 H2 2 NH3
Although a lower temperature
favors more NH3 formed, the
lower temperature also leads to
a very slow reaction.
![Page 108: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/108.jpg)
N2 + 3 H2 2 NH3
An increase in pressure should favor product.
![Page 109: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/109.jpg)
N2 + 3 H2 2 NH3
An increase in pressure should favor product.
![Page 110: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/110.jpg)
N2 + 3 H2 2 NH3
Ultimate solution: react at high
Temperature to speed up reaction,
cool until NH3 becomes liquid.
Remove from reaction vessel and repeat.
![Page 111: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/111.jpg)
(time)
CONCENTRATION
![Page 112: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/112.jpg)
Heterogeneous equilibrium
![Page 113: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/113.jpg)
Heterogeneous equilibrium
Involves at least two phases.
![Page 114: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/114.jpg)
Heterogeneous equilibrium
Involves at least two phases.
What is the concentration of
a pure liquid or a pure solid?
![Page 115: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/115.jpg)
Concentrations are not a valid
way to define a pure liquid
or solid.
![Page 116: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/116.jpg)
Concentrations are not a valid
way to define a pure liquid
or solid.
Moles water
Liters solvent= ?
![Page 117: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/117.jpg)
The concentration of a pure liquid
or solid is defined as 1.
![Page 118: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/118.jpg)
Law of Mass Action
![Page 119: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/119.jpg)
Law of Mass Action
1. Gases enter equilibrium expressionsas partial pressures in atmospheres.
![Page 120: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/120.jpg)
Law of Mass Action
1. Gases enter equilibrium expressionsas partial pressures in atmospheres.
2. Dissolved species enter as concentrations in mol L-1.
![Page 121: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/121.jpg)
Law of Mass Action1. Gases enter equilibrium expressionsas partial pressures in atmospheres.
2. Dissolved species enter as concentrations in mol L-1.
3. Pure solids and liquids are represented by 1at equilibrium , a dilute solvent is 1.
![Page 122: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/122.jpg)
Law of Mass Action
1. Gases enter equilibrium expressionsas partial pressures in atmospheres.
2. Dissolved species enter as concentrations in mol L-1.
3. Pure solids and liquids are represented by 1at equilibrium , a dilute solvent is 1.
4. Partial pressures or concentrations ofproducts appear in the numerator, reactants inthe denominator. Each is raised to the powerof its coefficient.
![Page 123: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/123.jpg)
hemoglobin
![Page 124: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/124.jpg)
hemoglobinFe
![Page 125: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/125.jpg)
heme Fe
![Page 126: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/126.jpg)
Feheme + O2 Feheme O2
![Page 127: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/127.jpg)
Feheme + O2 Feheme O2
4 heme Fe sites to bond O2
![Page 128: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/128.jpg)
4 heme Fe sites to bond O2
Increase PO more Feheme O2
Feheme + O2 Feheme O2
2
![Page 129: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/129.jpg)
4 heme Fe sites to bond O2
Feheme O2
Feheme + O2 Feheme O2
Increase PO by changing local
atmosphere.
2
Increase PO more2
![Page 130: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/130.jpg)
4 heme Fe sites to bond O2
Decrease PO less Feheme O2
Feheme + O2 Feheme O2
2
![Page 131: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/131.jpg)
4 heme Fe sites to bond O2
Decrease PO less Feheme O2
Feheme + O2 Feheme O2
2
Decrease PO2
by going to
higher altitude.
![Page 132: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/132.jpg)
Feheme + CO Feheme CO
Feheme + O2 Feheme O2
![Page 133: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/133.jpg)
Feheme + CO Feheme CO
Feheme + O2 Feheme O2
PO2
= 0.20 atm
Affinity for CO over O2 factor of 200+.
![Page 134: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/134.jpg)
Feheme + CO Feheme CO
Feheme + O2 Feheme O2
PO2
= 0.20 atm
Affinity for CO over O2 factor of 200+.
CO 1 x 103 ppm < 1% PCO < 0.01 atm
![Page 135: The Reading is for the next class. Problems are for that day’s class. Problems for each week (MWF) are due the following Monday.](https://reader036.fdocuments.net/reader036/viewer/2022062409/5697bfbf1a28abf838ca30e5/html5/thumbnails/135.jpg)
Feheme + CO Feheme CO
Feheme + O2 Feheme O2
PO2
= 0.20 atm
CO 1 x 103 ppm < 1% PCO < 0.01 atm
Kheme-CO >> Kheme-O2