The GlucoPure Grades - Välkommen -...
Transcript of The GlucoPure Grades - Välkommen -...
Nordic SEPAWA conference 2015
04/05/2015 – Dr. F. Schinle
Marketing & Application
BU ICS
Industrial & Home Care
The GlucoPure Grades
A New Generation of sugar
surfactants for home care applications
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure is renewable. More than 95% of Renewable Carbon Index
2
100% renewable glucose 100% renewable, RSPO certified
fatty acid esters or triglycerides
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Product Range
3
Product GlucoPure Foam GlucoPure Deg GlucoPure Wet
Active Matter 40% 60% 50%
C-chain basis RBD Coco Oil C12/14 Methylester C8/10 Methylester
Applications HDWL HDWL
HSC
Bathroom cleaner
Benefits
Superior foaming properties
Excellent formulation stability
Superior foaming properties
Excellent formulation stability
High concentrated, contains
Ethanol
Strong wetting properties
High Soap Scum removal
HIGHLY
RENEWABLE
EXCELLENT
AQUATOX PROFILE
MILD TO
THE SKIN
HIGH
PERFORMANCE
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Nordic SEPAWA conference 2015
04/05/2015 – Dr. F. Schinle
Marketing & Application
BU ICS
Industrial & Home Care
Discover GlucoPure Foam & Glucopure DEG
Marketing & Application, BU ICS, Industrial & Home Care
What is precious to the consumer?
5
High performance at
affordable cost
A pleasant skin feeling after
manual dishwashing
More sustainable and effective
alternatives in the market
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Challenges for the experts
6
Performance Soil and hard water easily break foam and
diminish the detergent’s performance
Flexibility
Viscosity in concentrated formulations is
hard to control and hard to balance with
cold cloud point
Mildness Most surfactants are harsh to hands
Green Current green raw-materials are not
effective enough
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Product Range
7
Product GlucoPure Foam GlucoPure Deg GlucoPure Wet
Active Matter 40% 60% 50%
C-chain basis RBD Coco Oil C12/14 Methylester C8/10 Methylester
Applications HDWL HDWL
HSC
Bathroom cleaner
Benefits
Superior foaming properties
Excellent formulation stability
Superior foaming properties
Excellent formulation stability
High concentrated, contains
Ethanol
Strong wetting properties
High Soap Scum removal
HIGHLY
RENEWABLE
EXCELLENT
AQUATOX PROFILE
MILD TO
THE SKIN
HIGH
PERFORMANCE
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Grades are ecosafe. Excellent aqua-toxicological profile
No aquatox labelling under GHS for GlucoPure Deg & Foam
GlucoPure allow formulations with lower aquatic toxicity consistent with upcoming
EU regulations (2015)
8
Properties Cocamidopropyl
Betaine Coco Betaine Lauramine Oxide
GlucoPure Deg &
GlucoPure Foam
Readily
biodegradable Yes Yes Yes Yes
RCI (%) 63 75 86 >95
GHS
Labelling
H 412
Harmful for aquatic
organisms, long term
effect
H 412
Harmful for aquatic
organisms, long
term effect
H 400
Very toxic for aquatic
organisms
H 411
Toxic for aquatic
organisms, long term
effect
No aquatox label
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure is mild. Zein Test shows that GlucoPure is even milder than Betaines
9
0
100
200
300
400
500
Sodium DodecylSulfate
CocamidopropylBetaine
GlucoPure Foam Lauryl Glucoside
Ze
in v
alu
e (
mg
N /
10
0 m
L)
Zein Test
The lower
the milder
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Foam enables high performance, highly renewable
and low aquatox profile hand dishwashing liquids
10
Recipe (%a.i.) A B C D
Sodium Laureth Sulfate (2EO) 18 18 18 18
Cocoamidopropyl Betaine 12 6 - -
GlucoPure Foam - 6 12 -
Lauryl-Polyglycoside - - - 12
Renewable % of surfactants (RCI) 69% 76% 83% 85%
GHS Labelling of the co-surfactant H 412 H 412 No aquatox No aquatox
All formulations with 7.0% Ethanol and water IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.
Pp. 11-15, 2002) – adapted with 0.3 g HDWL/L
Number of Washed Plates
Plate Test (IKW I - Carbohydrate)
CAB
CAB +
GlucoPure GlucoPure APG
32 34 31 16
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
11
Recipe (%a.i.) A B C D
Sodium Laureth Sulfate (2EO) 18 18 18 18
Cocoamidopropyl Betaine (CAB) 12 6 - -
GlucoPure Foam - 6 12 -
Lauryl-Polyglycoside (APG) - - - 12
Renewable % of surfactants (RCI) 69% 76% 83% 85%
GHS Labelling of the co-surfactant H 412 H 412 No aquatox No aquatox
Plate Test (IKW II - Grease)
Number of Washed Plates
GlucoPure Foam enables high performance, highly renewable
and low aquatox profile hand dishwashing liquids
All formulations with 7.0% Ethanol and water IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.
Pp. 11-15, 2002) – adapted with 0.3 g HDWL/L
26 25 22 14
CAB
CAB +
GlucoPure GlucoPure APG
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Concentrated HDWL can be formulated with low VOC
content, keeping viscosity and cold cloud point under control
12
Recipe (%a.i.) A B C D B’ C’ D’
Sodium Laureth Sulfate (2EO) 18 18 18 18 18 18 18
Cocoamidopropyl Betaine 12 6 - - 6 - -
GlucoPure Foam - 6 12 - 6 12 -
Lauryl-Polyglycoside - - - 12 - - 12
Ethanol 7 7 7 7 5.5 4 4
Viscosity (mPas) 2400 500 80 150 2000 2250 2250
Cold Cloud Point (°C) 0,6 -0,8 -5,1 0,6 -2,0 -3,2 2,4
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Foam offers high performance at low aquatic
toxicity by replacing amine oxides in >95% RCI formulations
13
Plate Test (IKW I - Carbohydrate)
Number of Washed Plates
AO +
GlucoPure
AO +
APG GlucoPure APG
No solvent and no NaCl added IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.
Pp. 11-15, 2002)
32 24 29 16
Recipe (%a.i.) A B C D
Sodium Laurylsulfate 8 8 8 8
Lauramine Oxide (AO) 3 3 - -
GlucoPure Foam 4 - 7 -
Lauryl-Polyglycoside (APG) - 4 - 7
Renewable % of surfactants (RCI) >95% >95% >95% >95%
GHS Labelling of the co-surfactant H 400 +
H 411
H 400 +
H 411
No
aquatox
No
aquatox
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Foam offers high performance at low aquatic
toxicity by replacing amine oxides in >95% RCI formulations
14
Plate Test (IKW II - Grease)
Number of Washed Plates
AO +
GlucoPure
AO +
APG GlucoPure APG
No solvent and no NaCl added IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.
Pp. 11-15, 2002)
23 18 21 11
Recipe (%a.i.) A B C D
Sodium Laurylsulfate 8 8 8 8
Lauramine Oxide (AO) 3 3 - -
GlucoPure Foam 4 - 7 -
Lauryl-Polyglycoside (APG) - 4 - 7
Renewable % of surfactants (RCI) >95% >95% >95% >95%
GHS Labelling of the co-surfactant H 400 +
H 411
H 400 +
H 411
No
aquatox
No
aquatox
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Formulations with GlucoPure Foam can be thickened by
NaCl keeping the cold cloud point at a very low level
15
Recipe (%a.i.) C D C’ D’
Sodium Laurylsulfate 8 8 8 8
GlucoPure Foam 7 - 7 -
APG - 7 - 7
Sodium chloride - - 1,1 1,25
Viscosity (mPas) 20 20 1950 1850
Cold Cloud Point (°C) -11,6 -0,5 -4,9 1,5
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Challenges for the experts
16
Performance Soil and hard water easily break foam and
diminish the detergent’s performance
Flexibility
Viscosity in concentrated formulations is
hard to control and hard to balance with
cold cloud point
Mildness Most surfactants are harsh to hands
Green Current green raw-materials are not
effective enough
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Solution GlucoPure: the novel mild sugar surfactants with high performance and high renewable content
17
Challenges Solution
Performance Soil and hard water easily break foam and
diminish the detergent’s performance
Flexibility
Viscosity in concentrated formulations is
hard to control and hard to balance with
cold cloud point
Mildness Most surfactants are harsh to hands
Green Current green raw-materials are not
effective enough
High foam mileage in hard and soft water
Easy viscosity adjustment and excellent
cold temperature stability
Very mild surfactant to human skin
Excellent eco-toxicological profile
Renewable content of 95% based on
carbon atoms
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Nordic SEPAWA conference 2015
04/05/2015 – Dr. F. Schinle
Marketing & Application
BU ICS
Industrial & Home Care
Discover GlucoPure Wet
Marketing & Application, BU ICS, Industrial & Home Care
What is precious to the consumer?
19
Easy removal of soap scum
More sustainable and effective
alternatives in the market
The surfaces in my bathroom
always looking new
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Challenges for the experts
20
Mildness Most bathroom cleaners are harmful to
plastic and metal surfaces
Green Best co-surfactants for this market are not
green
Performance
Soap scum is a tough soil to remove
The removed soil easily redeposits on the
surface
Flexibility Bathroom cleaners have a low pH
Foam control is key
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Product Range
21
Product GlucoPure Foam GlucoPure Deg GlucoPure Wet
Active Matter 40% 60% 50%
C-chain basis RBD Coco Oil C12/14 Methylester C8/10 Methylester
Applications HDWL HDWL
HSC
Bathroom cleaner
Benefits
Superior foaming properties
Excellent formulation stability
Superior foaming properties
Excellent formulation stability
High concentrated, contains
Ethanol
Strong wetting properties
High Soap Scum removal
HIGHLY
RENEWABLE
EXCELLENT
AQUATOX PROFILE
MILD TO
PLASTICS
HIGH
PERFORMANCE
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Grades are ecosafe. Excellent aqua-toxicological profile
No aquatox labelling under GHS for GlucoPure WET
GlucoPure allow formulations with lower aquatic toxicity consistent with upcoming
EU regulations (2015)
22
Properties Cocamidopropyl
Betaine Coco Betaine Lauramine Oxide GlucoPure WET
Readily
biodegradable Yes Yes Yes Yes
RCI (%) 63 75 86 >94
GHS
Labelling
H 412
Harmful for aquatic
organisms, long term
effect
H 412
Harmful for aquatic
organisms, long
term effect
H 400
Very toxic for aquatic
organisms
H 411
Toxic for aquatic
organisms, long term
effect
No aquatox label
Marketing & Application, BU ICS, Industrial & Home Care
23
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates GlucoPure Wet
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
GlucoPure Wet - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
00:00
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
24
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates GlucoPure Wet
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
GlucoPure Wet - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
02:30
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
Marketing & Application, BU ICS, Industrial & Home Care
25
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates GlucoPure Wet
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
GlucoPure Wet - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
05:00
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
Marketing & Application, BU ICS, Industrial & Home Care
26
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates GlucoPure Wet
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
GlucoPure Wet - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
07:30
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
27
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates GlucoPure Wet
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
GlucoPure Wet - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
10:00
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
GlucoPure Wet is compatible with the materials
common in bathrooms – in contrast to ethoxylates
*Stress-corrosion cracking of plastic material (DIN 53449-T)
28
Material APG Ethoxylates GlucoPure Wet
0-7d 7-14d 0-7d 7-14d 0-7d 7-14d
ABS Acrylnitrile-Butadiene-
Styrene Copolymer
PC Polycarbonate
(transparent)
PMMA Polymethylmethacrylate
(transparent)
POM1 Polyoxymethylen (grey)
POM2 Polyoxymethylen (white)
Stress-corrosion test*
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Challenges for the experts
29
Mildness Most bathroom cleaners are harmful to
plastic and metal surfaces
Green Best co-surfactants for this market are not
green
Performance
Soap scum is a tough soil to remove
The removed soil easily redeposits on the
surface
Flexibility Bathroom cleaners have a low pH
Foam control is key
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015
Marketing & Application, BU ICS, Industrial & Home Care
Solution GlucoPure: the novel mild sugar surfactants with high performance and high renewable content
30
Challenges Solution
High wetting power
Excellent soap scum dispersion
GlucoPure Wet works from pH 3 to 10
Adjustable foaming profiles
No corrosion on metal surfaces
Excellent compatibility with a variety of
plastic surfaces
Excellent eco-toxicological profile
Renewable content of 95% based on
carbon atoms
Mildness Most bathroom cleaners are harmful to
plastic and metal surfaces
Green Best co-surfactants for this market are not
green
Performance
Soap scum is a tough soil to remove
The removed soil easily redeposits on the
surface
Flexibility Bathroom cleaners have a low pH
Foam control is key
GlucoPure Grades – Nordic SEPAWA conference 04/05/2015