THE CO2 PILOT AT LACQ - IEAGHG 2/1stOCC_IEAGHG... · 2013. 7. 25. · THE CO2 PILOT AT LACQ CO2...
Transcript of THE CO2 PILOT AT LACQ - IEAGHG 2/1stOCC_IEAGHG... · 2013. 7. 25. · THE CO2 PILOT AT LACQ CO2...
THE CO2 PILOT AT LACQCO2 CAPTURE, TRANSPORTATION, INJECTION and STORAGE
READY FOR START UP
Nicolas AIMARD Claude PREBENDE TotalNicolas AIMARD, Claude PREBENDE Total Denis CIEUTAT, Ivan SANCHEZ-MOLINERO, Remi TSIAVA Air Liquide
1st Oxyfuel Combustion Conference1st Oxyfuel Combustion Conference
Cottbus, Germany 9th September 2009
What is Total’s direct share of GHG emissions?
Total operates a daily production of more than 2,5 Mboe/d worldwideTotal supplies 2% of heating and automotive fuels used worldwideCO2 emissions to the atmosphere are about 60MtCO2 equivalent per year
Our objective is to keep strengthening our portfolio while contributing to energy efficiency and limitation of CO2 emissions
21st OCC Cottbus 9th September 2009
Why is Total involved in Carbon Capture and Storage (CCS) ?
Carbon Capture and Storage is considered as a breakthrough technology to be promoted for high CO2 emissions facilities and a promising solution for the O&G industry
• Extra Heavy Oil and Oil Sands fields development• Very acid gas fields development (high CO2 content i.e. >10%)• Large LNG facilities• Non conventional resources (oil shales)• Non conventional resources (oil shales)
31st OCC Cottbus 9th September 2009
Oil sands production in Alberta (Canada)
SAGD
For the production of 100,000 bbl/d bitumen
Min. overburden100mMin. overburden100mMin. overburden100m
and Steam/Oil=2.5
G ti f 39600 t/d HP t 100 b 312°C
500 to 1000m
~5m
500 to 1000m
~5m
500 to 1000m
~5m
Generation of 39600 t/d HP steam 100 bar , 312°C (1044MWth) by combustion of Natural Gas 2000t/d
Emission of 5500tCO2/d without Capture
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CO2 Capture : Post- combustion vs Oxycombustion
energy Flue Gas
Steam for production
energyBOILER AmineS bbiair
ExhaustN2 O2Post combustion
CO2
steam
Natural gas
BOILER Scrubbingair CO2
Storage
Steam for production
Compression4.2 GJ/tCO2
energy CoolingDehydration
air Air SeparationUnit
O2
N2BOILER CO2
Steam for productionOxycombustion
power air H2ONatural gas
Flue Gas Recycle
StorageCompression
220kWh/tO2
w/o captureEnergy
Efficiency w/ capturePost-combustion
85%
61%
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Efficiency w/ captureOxycombustion 73%
Oxy-Combustion Capture and Storage pilot plant at Lacq
DEMONSTRATE TECHNICAL FEASIBILITY & RELIABILITYOF AN INTEGRATED CO2 CAPTURE, TRANSPORTATIONAND STORAGE SCHEME FOR STEAM PRODUCTION
1
DESIGN AND OPERATE A 30 MWth OXYCOMBUSTION2TIVE
S
GAS BOILER2
DEVELOP AND APPLY GEOLOGICAL STORAGEOB
JEC
T
DEVELOP AND APPLY GEOLOGICAL STORAGE QUALIFICATION METHODOLOGIES AND MONITORING TECHNIQUES
3
MA
IN O
PREPARE FUTURE LARGER SCALES AND LONG TERMSTORAGE PROJECTS4
M
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General Process Scheme
to Utilities
P50°C
STEAM 40t/h60bar450°C
STEAM 40t/h60bar450°C
4 oxyburners
QuenchBoiler32MW
Fuel GasFG
Power220°C
27 Bar
50°C4 oxyburners
Dehydration
Water to
O2
240 tpd
H20 < 50 ppm
Transport
FGR
Recycle ratio FGR/FG = 2 to 3
A
treat
N2
240 tpd95 to 99.5 %
TransportCO2>85%
27 km
Power
FGR/FG 2 to 3
SU
AirInjection &Storage
50 Bar
N2 for sorbents regeneration
Power
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Air4500 m150°C
Oxy burner developmentOxy-burner development
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AIR LIQUIDE Oxy-burner Principle
No external oxygen mixing
Advantageous on: flame stability, turndown ratio, difficult fuels.difficult fuels.
Improved operating safety: dedicated pure oxygen circuit all along distribution system.
Additional flexibility to adjust FGR rate.Flue gas recycle Flue gas recycle
OxygenOxygen
Fuel Fuel
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Synthetic air type AIR LIQUIDE oxy-burner
Oxy-Burner design
No Oxygen/FGR MixingOxygen and FGR can be adjustedMass flows and velocities effect on:
Fl I iti
FGR2nd O2
1st O2
Fuel gas
Flame IgnitionFlame stability Turn down ratio
Heat profile the best criteria for boiler
2
Pilot
prevampingSafety operation
Feasibility Design
Manufacturing
InstallationSpecificationsRequirements
• PRA, HAZOP• Pilot test
• Safety studies•Operating proceduresB ifi ti /Commissioning
qLab testsCalculations
•Modeling/Simulations•Burner specs•Drawings
•Burner specifications/•Customization
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1 MW Burner8 MW Burner
Experimental Results at 1 MWth Test Rig
FGR=0
FGR=1
Flame stability performance h dwas unchanged
O2 in the near burner region can increase flame stability
FGR=1.5FGR=3.4
y
Use of FGR has not impacted on flame stability
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Oxycombustion yand CO2 storage pilot plant
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Air Separation Unit by cryogenic distillation
Standard ASU packaged plant
240 t/day of oxygen
95% to 99,5% oxygen purity
Nitrogen for CO2 dehydration molecular sieves regeneration
151st OCC Cottbus 9th September 2009
Industrial steam boiler in oxycombustion mode
OXYFIRING started on 3rd July
Flue Gas Recycle O
OXYFIRING started on 3rd JulyNow 500h
y O2 from ASUO2
to burnersto burners
161st OCC Cottbus 9th September 2009
in charge of boiler revamping works
Wet scrubbing of high CO2 content flue gas
wet CO2
Flue gas ( ~ 48% H2O, 48% CO2) @ 200°C and atm pressure
1. Venturi scrubber1. Venturi scrubber Flue gas outlet @ 90°C
2. QuenchW t d d
Quench
Water condensed Flue gas outlet @ 50°C
Venturi Scrubber
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Transportation and injection into a gas depleted reservoir
5 kmCity of PAU
L
WH50 barg
Pont d’As
Saint-FaustLacq
ROUSSE-1
Baysères27barg Existing right of way
Injection well
Typical CO2 compositionCO2: 92.0 %O2: 4.0%
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O2: 4.0%Ar: 3.7%N2: 0.3%
Pilot phase: 120,000 T CO2 injected for 2 years85,000 Sm3/d
Rousse 1 work over with SMP 101 drilling rig
D h lDownhole sensors along the tubing along optic fiber
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CO2 injection into Rousse depleted gas reservoir
Jurassic fractured dolomitic reservoir (i d)
Injection wellS N
(in red)
Thick cap rock (in green and orange)
Tertiary Pyrenean compressive
phase
Depth # 4500m/MSLTemp. # 150°CInitial P = 485 barg
Upper Cretaceous
Pre-Pyrenean Initial P = 485 bargCurrent P # 30 bargInitial CO2 = 4,6%
Low Cretaceous
Rousse depleted gas field
Pre-Pyrenean Extensive
phase
Existing unique well RSE 1 producing since 1972
Initial H2S < 1%No aquifer
depleted gas field
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Existing unique well RSE-1 producing since 1972Well work over required
CO2 Monitoring planInjection phasej p
• Flowrate & composition of injected gas
• P and T borehole and reservoir pressure (optical fibre)
• Microseismic monitoring of reservoir and caprock
baseline before injection
G i ti t th f• Gas migration at the surface : • soil gas survey (baseline before injection)• surface detectors on well pad
• Aquifer sampling
Post injection phase
• P and T bottom hole and reservoir pressure
• Microseismic monitoring of reservoir and caprock
• Gas migration at the surface
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• Aquifer sampling
A major stake: demonstrate that CO2 can be stored safely and permanently into Rousse(Rousse aerial view)
RSE-1
RSE-3
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Public consultation and dialogue was required
Objectives: Share the opportunity of having such project in that area and
provide technical information of the Lacq pilot itself Provide a better understanding of CCS technology context, issues
and therefore promote the CCS technology deployment Have all questions raised to propose answers at different steps Provide information on short and longer term scientific follow upProvide information on short and longer term scientific follow up
(dedicated scientific committee appointed with external experts) and monitoring Help identifying project possible contribution to local socio-
economic developmenteconomic development Demonstrate transparency and provide access to relevant
information
Total's approachTotal s approach Open dialogue with all stakeholders upstream permitting process Several public meetings open to public in 2007-2008 Transparency and access to detailed information, governance
L l f ll itt ith t k h ld
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Local follow up committee with stakeholders during construction, injection and monitoring phase
Project information also available onwww.total.com/corporate-social-responsibility
In order to ensure that the consultation process initiated by Total is useful to all concerned, and to guarantee a meaningful dialogue with all stakeholders, the Group undertakes to:
• Provide full, honest and clearly expressed information about the Provide full, honest and clearly expressed information about the project (characteristics, impact, surveillance and monitoring system, etc.) so as to facilitate the sharing of knowledge and to foster open discussion with all stakeholders.• Execute and report on the project with advice from a number of independent scientific and technical experts.• Provide answers to all questions asked by stakeholders or members of the public.• Publish minutes of all public discussion meetings as well as a summary of the consultation process, and take these into account in deciding final project details.• Provide stakeholders and general public with regular updates of project
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• Provide stakeholders and general public with regular updates of project progress and timetable.
A long process
2006 : Early presentations of the conceptJan – Oct 2007 : Formal information to the french administration, mayorsMarch 2007: Public meeting RousseNov 2007 : press conference and launch of the dialogue phaseNov – dec 2007: 3 public meetings (Jurançon, Pau, Mourenx)Apr 2008 : meeting with new mayor of JurançonApr – June 2008 : several meetings with small groupsApr – June 2008 : several meetings with small groupsMay 2008 : meeting with all mayors from Lacq to RousseJune – July 2008 : CLIS n°1 et 2July 2008 : working meetings with Jurançon y g gJuly – Sept 2008 : official public hearingsSept 2008 : CLIS n°3Dec 2008 : well pad open to the public – information letter to project neighboursFeb 2009 : CLIS n°4March 2009 : CLIS n°5May 2009 : Official permit to capture, transport, inject and store 120'000 t of CO2June 2009 : CLIS n°6
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June 2009 : CLIS n 6
Project schedule milestones
2006 2007 2008 2009 2010 2011Site screening and conceptual studies
Basic engineering studies
Detailed engineering and procurement
C t ti kConstruction works
Injection well work over
Injection
Base line surveys and monitoring
Information to stakeholders Public inquiry
P j t i f ti il bl
Permitting process with regulatory agencies
291st OCC Cottbus 9th September 2009
Project information available onwww.total.com/corporate-social-responsibility
CO2 injection
CO2 transportation Gas productionThank you for your attention
Compression
CO2 injection
CO2 capture
Lacq gas power plant
3
Commercial gas
4
UtilitiesBoiler oxycombustion
5
CO2 Transportation
7
89
4500
OxygenProduction
Unit Natural gas inlet
2
35
CO2
6
CO2 storage
10
4500 m Natural gasPurification / CO2 dehydration
Compression
Lacq gas production
CO2
4000 m
Rousse reservoir
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Lacq deep gas reservoir
1