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Transcript of The Annual Report on Monitoring and Assessment: Ukraine, 2009 RAC PMA (UkrSCES) Istanbul, 2010 Sep...
The Annual Report on Monitoring and Assessment: Ukraine, 2009
RAC PMA (UkrSCES)
Istanbul, 2010 Sep 15
2
Main goals
General Information about Ukrainian Regional Monitoring System of Black Sea (2009)
State of the Environment Proposals
3
Ukrainian Monitoring System
4
5
Ukrainian Monitoring SystemNumber/List of monitored parameters (2009/2008)
ParameterSamples numbers
(2009/2008)Parameter
Samples numbers
(2009/2008)
Hydrochemicals (water) Metalls (water)
Temperature 77/115 Fe 136/68
Salinity 150/183 Mn 0/0
pH 226/182 Zn 2/0
O2 211/167 Co 0/0
TSS 178/73 As 2/0
Transparency 10/0 Hg 2/0
BOD5 149/68 Cu 2/0
TOC 15/0 Cd 2/0
H2S 0/19 Pb 2/0
P(PO4) 183/130 Ni 2/0
6
Ukrainian Monitoring SystemNumber/List of monitored parameters (2009/2008)
ParameterSamples numbers
(2009/2008)Parameter
Samples numbers
(2009/2008)
Hydrochemicals (water)Other organic pollutants
(water)N (NH4) 190/106
N (NO2) 192/130 Phenols 48/68
N (NO3) 194/130 Detergents 149/68
Ntotal 43/63 TPHs 143/68
SiO4 14/0 Cs-137 2/0
7
Ukrainian Monitoring System
Chlororganic pesticides PCBs total
DDT 17/8 Ar1254 8/8
DDD 17/8 Ar1260 8/8
DDE 17/8 PCB(4 ind.) 9/8
Lindane 17/8 PCB(7 ind.) 8/8
α-HCH 17/8 PCB(10 ind.) 17/8
β-HCH 17/8
HCB 17/8 Other organic pollutants
Heptachlor 17/8 Phenols 25/8
Aldrin 17/8 TAHs 9/8
Dieldrin 8/8 TPHs 25/8
Endrin 8/8 TOC 17/8
Number/List of monitored parameters (2009/2008)
(bottom sediments)
8
Ukrainian Monitoring System
PAHs (bs)
Naphthalene 17/8
2-Methylnaphtalene 0/8
1-Methylnaphtalene 0/8
Acenaphthylene 17/8
Fluorene 17/8
Acenaphthene 17/8
Phenanthrene 17/8
Anthracene 17/8
Fluoranthene 17/8
Pyrene 17/8
Benzo[a]antracene 17/8
Chrysene 17/8
Benzo(b)fluoranthene 17/8
Benzo(k)fluoranthene 17/8
Benzo[a]pyrene 17/8
Dibenzo[a,h]anthracene 17/8
Indeno(1,2,3-c,d)piren 17/8
Benzo(ghi)perilen 17/8
Number/List of monitored parameters (2009/2008)
(bottom sediments)
9
Ukrainian Monitoring SystemNumber/List of monitored parameters (2009/2008)
(bottom sediments)
Metalls
Zn 25/8
Co 17/8
As 25/8
Hg 25/8
Cu 25/8
Cd 25/8
Pb 25/8
Ni 17/8
Al 17/8
10
Data were reported to the Ministry of Environment Protection of Ukraine.
Financing assured by Ministry of the Environment Protection of Ukraine, National Academy of Science of Ukraine, Ministry of Transport of Ukraine
11
Ukrainian Monitoring SystemNational institutions involved in 2008
• UkrSCES - the Ukrainian Scientific Center of Ecology of the Sea, Ministry of the Environment Protection (Department of Analytical Research and Organization of Monitoring, head Yuriy Denga,)
• SEINWRBS - State Ecological Inspection of Environmental Protection of the Black sea's North-West Region, Ministry of the Environment Protection (Department of Analytical Control, head Evgeniy Patlatiuk).
• SEINBAS - State Ecological Inspection of Environmental Protection of the Black and Azov Seas, Ministry of the Environment Protection (Department of Analytical Control)
12
Quality Assurance /Quality Control
The three laboratories: department of analytical research of UkrSCES, department of analytical control of SEINWRBS and department of analytical control of SEINBAS which are involved in the international marine monitoring system are accredited by the Ukrainian standardization organization.
13
Quality Assurance /Quality Control
RAC PMA in 2009 takes part in the Black Sea intercomparison exercises:
QUASIMEME Intercalibration Exercise, Round 56 and 57 (nutrients in water, trace metals and organic pollutants in bottom sediments).
MEL Monaco, IAEA-451 (organic pollutants in biota) and IAEA-452 trace metals in biota).
14
International Projects
http://www.cadses.net/projects/apprpro.html
UkrSCES
1.In 2009 a “Spatial Planning in Coastal Zone” (PlanCoast) EU funded project was completed by the UkrSCES (2007 -2009).
2.European Community Grant “Upgrade Black Sea Scene scientific network”.
3.European Community Grant (Cooperation in the Black Sea protection. Georgia, Moldova, Russia, Ukraine) – 2008-2009, Pilot project: Karkinitskyi Bay GIS-mapping.
4.Contract: TACIS/2005/109245 “Supplies for the Caspian and Black Sea Environmental Projects – Georgia, Kazakhstan, Moldova, Russian Federation, Turkmenistan and Ukraine”.Publication reference: EuropeAid/122682/C/SUP/MULTI.http://plancoast.sea.gov.ua/
15
Names of authors of the annual report
provided and names of those providing data
The annual report has been prepared by:
Viktor Komorin, Yuri Denga, Irina Orlova, Vladimir Ukrainsky, Svetlana Kovalishina, Richard Lisovsky, Tatiana Gavrilova, Eduard Kostilev
The data have been provided by:
Yuri Denga, Vladimir Ukrainsky, Svetlana Kovalishina, Tatiana Gavrilova, Eduard Kostilev, Evgeny Patlatuk
16
State of the Environment
17
1. Material and methods:
• 42 stations have been sampled in Ukrainian part of Black Sea•the salinity, T°C, pH, and DO, were measured using a Neil Brown Instruments Systems (STD) with a General Oceanic rosette and Niskin bottles at several water layers. It also provided water samples for further analysis of BOD5, nitrite-N, nitrate-N, ammonia-N, Ntotal, Porg, Pmin, Ptotal, Corg, seston, as well as concentration of aliphatic and aromatic hydrocarbons, heavy metals, and pesticides, which were also measured in bottom sediments. •Sediment samples were obtained with a Petersen’s bottom sampler (0.25 m2) and subsampled from the uppermost 3 cm of the sediment column for grain-size, geochemical, and biological analyses. Grain-size study of the sediments was performed by wet sieving and pipette analysis as described in Rukhin (1969). •Biological samples were obtained by thimble with an inlet of 12.5 cm, washed on the deck through 1 mm and 67 µm sieve, stored in 4 % formalin solution buffered with sea water, and stained in the laboratory with buffered Rose Bengal over 48 hours. •Zoo- and phytoplankton were collected by Jedi trap.
18
2. General
Long-term dynamic of the average annual temperature of air in Odessa
19
2. General – T° C, Salinity
Vertical distribution of water temperature on the north-western Black Sea shelf
Vertical distribution of salinity in the north-western Black Sea shelf
20
2. General – Transparency (Secci), TSS
Average value of Secci (suface layer)
1,9 1,75
12
0
2
4
6
8
10
12
14
Danube delta Kerch Peninsula Backgroundstation
m
Average value of TSS (suface layer)
3,26 3,26
2,112,58
12,91
0
2
4
6
8
10
12
14
Od
ess
are
gio
n
Da
nu
be
de
lta
Cri
me
an
Pe
nin
sula
Ke
rch
Pe
nin
sula
Ba
ckg
rou
nd
sta
tion
mg
/L
Average value of TSS (bottom layer)
22,12
3,88
0
5
10
15
20
25
Danube delta Kerch Peninsula
mg
/L
21
Average value of O2 (bottom layer)
248,2
291,6
268,7
220
230
240
250
260
270
280
290
300
Danube delta NWS open sea Kerch Peninsula
uM
2. General – Oxygen, BOD-5
Average value of O2 % (bottom layer)
79,8
88,1
90,7
74
76
78
80
82
84
86
88
90
92
Danube delta NWS open sea Kerch Peninsula
%
Average value of BOD5 (suface layer)
59,8 58,2
48,9
0
10
20
30
40
50
60
70
Odessa region CrimeanPeninsula
Kerch Peninsula
uM
Average value of O2 (suface layer)
329,1
302,8275,5
250,1
317,7
255
0
50
100
150
200
250
300
350
Od
ess
are
gio
n
Da
nu
be
de
lta
NW
S o
pe
nse
a
Cri
me
an
Pe
nin
sula
Ke
rch
Pe
nin
sula
Ba
ckg
rou
nd
sta
tion
uM
22
3. Eutrophication
Average value of NH4 (suface layer)
0,62
6,86
0,781,47
2,29
6,09
0
1
2
3
4
5
6
7
8
Od
ess
are
gio
n
Da
nu
be
de
lta
NW
S o
pe
nse
a
Cri
me
an
Pe
nin
sula
Ke
rch
Pe
nin
sula
Ba
ckg
rou
nd
sta
tion
uM
Average value of NO2 (suface layer)
0,33
0,07 0,090,18
0,910,87
00,10,20,30,40,50,60,70,80,9
1
Od
ess
are
gio
n
Da
nu
be
de
lta
NW
S o
pe
nse
a
Cri
me
an
Pe
nin
sula
Ke
rch
Pe
nin
sula
Ba
ckg
rou
nd
sta
tion
uM
Average value of NO3 (suface layer)
8,77
57,25
17,2
0,410,520,370
10
20
30
40
50
60
70
Od
ess
are
gio
n
Da
nu
be
de
lta
NW
S o
pe
nse
a
Cri
me
an
Pe
nin
sula
Ke
rch
Pe
nin
sula
Ba
ckg
rou
nd
sta
tion
uM
Average value of NH4 (bottom layer)
0,57
0,24
2,29
0
0,5
1
1,5
2
2,5
Danube delta NWS open sea Kerch Peninsula
uM
Average value of NO2 (bottom layer)
0,87
0,180,1
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1
Danube delta NWS open sea Kerch Peninsula
uM
Average value of NO3 (bottom layer)
57,25
0,4 10
10
20
30
40
50
60
70
Danube delta NWS open sea Kerch Peninsula
uM
23
3. Eutrophication
Average value of PO4 (suface layer)
1,51
1,11
0,36
0,22
0,4
1,18
0
0,2
0,4
0,6
0,8
1
1,2
1,4
1,6
Od
ess
are
gio
n
Da
nu
be
de
lta
NW
S o
pe
nse
a
Cri
me
an
Pe
nin
sula
Ke
rch
Pe
nin
sula
Ba
ckg
rou
nd
sta
tion
uM
Average value of Ptotal (suface layer)
1,91
1,41,261,21
0
0,5
1
1,5
2
2,5
Danubedelta
NWS opensea
KerchPeninsula
Backgroundstation
uM
Average value of PO4 (bottom layer)
0,47
0,31
1,51
0
0,2
0,4
0,6
0,8
1
1,2
1,4
1,6
Danube delta NWS open sea Kerch Peninsula
uM
Average value of Ptotal (bottom layer)
1,91
1,291,53
0
0,5
1
1,5
2
2,5
Danube delta NWS open sea Kerch Peninsula
uM
24
3. Eutrophication
Relations of average concentrations of organic forms of nitrogen (а) and phosphorus (б) to their mineral forms
in surface waters in winter time of 2009
25
3. Eutrophication
Long-term changes of hydrochemical state of the surface waters of the Odessa Bay
26
3. Eutrophication
Distribution of average annual concentration (mg/l) chlorophyll-a in surface waters ACHB in 2009 according to satellite observations
(OBPG MODIS spatial discreteness of 4 km).
27
3. Eutrophication
Trend of changes of Odessa Bay water quality according to index E-TRIX
28
3. Eutrophication
0
500
1000
1500
2000
2500
3000
I II III IV V VIVII
VIII IX X XIXII
month
bio
ma
ss,
mg
/m3
Bacillariophyta
Chlorophyta
Chrysophyta
Cryptophyta
Cyanobacteria
Dictyochophyta
Dinophyta
Euglenophyta
Haptophyta
biomass
winter
spring
summer
autumn
Seasonal fluctuation of phytoplanktonic amount (A) and biomass (B) in coastal waters of Odessa
0
500
1000
1500
2000
2500
3000
I II III IV V VIVII
VIII IX X XIXII
month
am
ou
nt,
mln
.ce
lls/m
3Bacillariophyta
Chlorophyta
Chrysophyta
Cryptophyta
Cyanobacteria
Dictyochophyta
Dinophyta
Euglenophyta
Haptophyta
amount
winter
spring
summer
autumn
29
3. Eutrophication
Seasonal fluctuation of zooplanktonic amount, ind/m3 in coastal waters of Odessa
1
10
100
1000
10000
I II III IV V VI VII VIII IX X XI XII
Month
Am
ou
nt,
ind
/m3
amount
meroplankton
holoplankton
Winter
77%
23%
Spring
45%55%
Summer
81%
19%
Autumn
39%61%
30
4. Pollution
Average concentration of total petroleum hydrocarbons in surface waters of NWS of the Black Sea and Kerch Strait
Hg Cd Cr Pb Cu As Zn
Kerch
NWSMAC0
5
10
15
20
25
30
35
40
45
50
mkg/L Kerch
NWS
MAC
TPHs
0
0,02
0,04
0,06
0,08
0,1
0,12
0,14
0,16
NWS Kerch MAC
mg/L
Average concentration of trace metals in surface watersof NWS of the Black Sea and Kerch Strait
31
Disaster in the Kerch Strait
• On 11 November 2007, a strong storm in the Kerch Strait (which connects the Sea of Azov with the Black Sea and separates Ukraine from the Russian Federation) resulted in thirteen vessels being sunk, stranded, or damaged and the incident caused loss of life, of property, and environmental harm.
32
Disaster in the Kerch Strait
• The four vessels that sank were: motor tanker Volgoneft-139 (Russian Flag), motor vessel Volnogorsk, motor vessel Nahichevan (Russian Flag), and motor vessel Kovel (Russian Flag).
• Russian motor vessel Volgoneft-139 initially leaked approximately 1,300 tones of fuel oil into the sea.
33
Average concentrations of organic pollutants in bottom sedimentsof the Black Sea
Pollution substances Unit Diapason ofconcentrations
Average value MAC
NWSopen sea
Kerch strait
Petroleum Hydrocarbons
TPHs, Simard eqv. mg/kg 100 - 250 182 162 50
ARHs, Ropme eqv mg/kg 4,8 - 18,8 10,0 14,3 5
Phenols mg/kg 0,43 – 1,0 0,72 0,85 0,05
Polycyclic Aromatic Hydrocarbons (PAHs)
Naphtalene µg/kg 7,4 - 90 50 34
Acenaphthylene µg/kg 1,8 – 7,0 4,5 5
Acenaphthene µg/kg 1,8 – 10,2 5,2 4,8
Fluorene µg/kg 30 - 79 40 45
Phenanthrene µg/kg 138-368 170 229 45
Anthracene µg/kg 0,9 – 9,7 4,2 7,3 50
Fluoranthene µg/kg 20 - 239 87 122 15
Pyrene µg/kg 10 - 127 54 75
Benzo(a)anthracene µg/kg 1,4 - 164 39 45 20
Chrysene µg/kg 6,5 - 107 45 61 20
34
Average concentrations of organic pollutants in bottom sedimentsof the Black Sea
Pollution substances Unit Diapason ofconcentrations
Average value MAC
NWSopen sea
Kerch strait
Benzo(b)fluoranthrene µg/kg 4,1 - 131 81 77
Benzo(k)fluoranthrene µg/kg 9,0 - 188 76 84 25
Benzo(a)pyrene µg/kg 4,8 - 86 35 46 25
Indeno(1,2,3cd)pyrene µg/kg 5,1 - 243 84 49 25
Dibenzo(a,h)anthracene µg/kg 1,0 - 36 14 10
Benzo(g,h,i)perylene µg/kg 6,1 - 250 85 51 20
35
Average concentrations of organic pollutants in bottom sedimentsof the Black Sea
Pollution substances
Unit Diapason ofconcentrations
Average value MAC
NWSopen sea
Kerch strait
Chlororganic Pesticides (CPs)
-HCH µg/kg 0 – 0,94 0,53 2,5
-HCH µg/kg 0 – 3,17 0,85 0,85 1,0
-HCH (Lindane) µg/kg 0 – 0,53 0 0 0,05
HCH total µg/kg 0 – 5,96 0,91 1,38 5
Hexachlorbenzene µg/kg 0,5 – 1,24 0,63 0,53 2,5
Heptachlor µg/kg 0 – 2,53 0,29 0,94 2,5
Aldrine µg/kg 0 – 1,77 0,26 0,66 2,5
DDE µg/kg 0,22 – 16,2 6,76 3,88
DDD µg/kg 0 – 4,97 1,74 1,16
DDT µg/kg 0 – 15,4 4,19 1,42
DDT total µg/kg 0,58 – 27,8 12,7 6,5 2,5
Polychlorinated biphenyl’s (PCBs)
Ar-1254 µg/kg 10,4 – 5420
Ar-1260 µg/kg 3,52 – 80,9
36
4. Pollution
Average concentration of oil hydrocarbons in bottom sediments
Average concentrations of PAHs in bottom sediments of Black Sea
TPHsAhs
MAC
NWS
Kerch
0
20
40
60
80
100
120
140
160
180
200
mg/kgMAC
NWS
Kerch
Nap
hta
len
e
Ace
nap
hth
ylen
e
Ace
nap
hth
ene
Flu
ore
ne
Ph
enan
thre
ne
An
thra
cen
e
Flu
ora
nth
ene
Pyr
ene
Ben
zo(a
)an
thra
cen
e
Ch
ryse
ne
Ben
zo(b
)flu
ora
nth
ren
e
Ben
zo(k
)flu
ora
nth
ren
e
Ben
zo(a
)pyr
ene
Ind
eno
(1,2
,3cd
)pyr
ene
Dib
enzo
(a,h
)an
thra
cen
e
Ben
zo(g
,h,i)
per
ylen
e
MA
C NW
S
Ker
ch
0
50
100
150
200
250
mkg/kg
MAC
NWS
Kerch
37
4. Pollution
Average concentrations of Chlororganic Pesticides s in bottom sediments of the Black Sea
a-H
CH
b-H
CH
l-H
CH
(L
ind
ane)
Hex
ach
lorb
enze
ne
Hep
tach
lor
Ald
rin
e
NWS
MAC0
0,5
1
1,5
2
2,5
mkg/kg
NWS
Kerch
MAC
HCH totalDDT total
MAC
Kerch
NWS
0
2
4
6
8
10
12
14
mkg/kg
MAC
Kerch
NWS
38
4. Pollution
Average concentrations of Trace Metals in bottom sediments of Black Sea
CdСo
HgCu
PbCr
ZnAs
Ni
NWS
KerchMAC
0
20
40
60
80
100
120
140
mg/kgNWS
Kerch
MAC
39
4. Pollution
Spatial distribution of the normalized concentration of sum oil hydrocarbons in bottom sediments of Kerch Strait
Tam an Peninsula
Tuzla sp it is land
Kerch Peninsula
1
1.3
1.6
1.9
2.2
2.5
2.8
3.1
3.4
40
5. Biota contamination
0 20 40 60 80 100
Malyi Fontan cape %
2009
2007
2005
Bioassay of marine environment quality of coastal and open parts of NWBS and of the Kerchenska Strait in 2005-2009 years: a - retention time of neutral red by the mussel hemolymph cells lysosomes in December, 2009 (in minutes); b - development of larvae of the Black Sea mussels (% anomalous and dead)
0
10
20
30
40
50
60
70
80
90
100
Tim
e, m
inut
es
Kerchenskastrait
MalyiFontan cape
Tendrowskabeak
41
Main Publications of the Monitoring and Assessment Results
Ukrainsky V.V., Popov Yu.I. Climatic and hydrophysical conditions of occurring of water hypoxia on the Black Sea northwest shelf// Marine Hydrophysical Journal. – 2009. – № 3. – С.19 – 29
Kukushkin A.S. Variability of water transparency distribution in the Karkinit Bay // Marine Hydrophysical Journal. – 2009. – № 2. – Р.67 – 79
Demyshev S.G., Ivanov V.A., Markova N. V. Analysis of the Black Sea climatic fields below the main pycnocline obtained by assimilation of archival data on salin ity and temperature in the numerical hydrodynamic model // Marine Hydrophysical Journal. – 2009. – № 1. – Р.3 – 15
Samodurov A.S. Bottom boundary layer in the Black Sea: formation of station ary state // Marine Hydrophysical Journal. – 2009. – № 1. – Р.16 – 25
Ukraine’s Algae. Diversity, Nomenclature, Taxonomy, Ecology and Geography. Bacillariophyta. Eds.: P.M. Tsarenko, S.P. Wasser & E. Nevo, Ruggell, A.R.A. Gantner Verlag K.G., Terenko G. V., Vol. 2, 2009. - 414 p. (in English)
Vorobyova, L.V., Kulakova, I.I. Contemporary state of the meiobenthos in the western Black Sea. - Одесса, Астропринт. - 2009. - 126 p. (in English)
P.M.Tsarenko, S.P.Wasser and E.Nevo (Eds.)Algae in Ukraine: Diversity, Nomenclature, Taxonomy, Ecology and Geography. Vol.2. Bacillariophyta Ruggell (Liechtenstein): A.R.G. Gantner Verlag, 2009.-413 pp
Minicheva G.G., Kosenko M.N. Shvets A.V. Phytobenthos of the Large and Smoll Phyllophora Fields as a reflection of the contemporary ecological state of the northwestern Black Sea Marine Ecological Journal, v.8, #4, 2009
F.P.Tkachenko, I.P. Tretiak, E.F. Kostylev Macrophytobenthos of the Zernov Phyllophora Field in present conditions (the Black Sea, Ukraine). International Journal on Algae. Volume 11, Issue 1. 2009. - P. 64-72.
Mankovskiy V.I., Colov’ev M.V., Mankovskay E.V. Hydrooptical characteristics of the Black Sea: a handbook // Marine Hydrophysical Institute. – Sevastopol: -Hydrophysics, 2009. - 90 p.
Territorial planning of the seas coastal zone in Ukraine”, “Proposals for marine spatial planning in 12-miles zone for Odessa agglomeration based on principals of complex coastal zones management: “Maps of the coastal zone ecological sensitivity to oil pollution”.INTERREG III B CADSES, PlanCoast Project, UkrSCES, 2009, V.Borulko, O.Bon, V.Karamushka, R.Lisovsky, T.Gavrilova, D. Zabolotny, V. Zizak, M.Dimerly, A.Skachek, O.Bratchenko, O.Neprokin, O. Prudius, V.Semenov, print “Print Bistro”.
42
Proposals for desigion to the 20-th Meeting of AG PMA
Address to the governments of the Black Sea countries according to their responsibility for fulfilling the Black Sea Convention and other international documents on organizing and financing of the National Monitoring System of each Black Sea State as a component of the Regional Monitoring System.
Provide an International expedition covering the Black Sea in the whole within the framework of fulfilling regional monitoring.
Create a program for international inter-comparison exercises for chemical laboratories of National Centres on basis of RAC PMA (bottom sediments, mussels).
Organize education and training of the young scientists and specialists (the Young Professional Programme)
Implement the information management component of RAC PMA according to the signed TOR.
43
Thank you very much !!!
http://www.sea.gov.ua/