TCE - Gasification

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    tce GASIFICATION

    Peter Fagianoexplainshow the humble lumpof coal could be theanswer to securingdelivery of SouthAustralias futureenergy needs

    IN recent years, theres been tremendous

    volatility in the cost of crude oil,

    culminating in prices reaching US$147/

    bbl in July 2008. Due to the global recession,

    the price fluctuated downwards, but as a

    result of political instability in the Middle

    East and North Africa, the crude oil price

    currently sits around US$111/bbl. As its

    unlikely in the medium term that prices

    will stabilise or come down, many nations

    are seeking security of supply at more

    economic levels by diversifying their

    sources and type of energy supply.

    The situation is compounded by the fact

    that conventional cheap sources of oil are

    declining and hence international energy

    exploration and production companies are

    now seeking oil sources in areas of higher

    political risk, with higher exploration and

    production costs. This resulted in an 8%

    growth in the natural gas market in 2010.

    But what other options exist?

    The exploitation of the huge shale gas

    reserves in the US will mean that the country

    will now become an exporter of LNG asopposed to an importer.

    Nuclear is now facing many challenges as an

    energy alternative following the 2011 tsunami

    in Japan.

    Renewable energy sources such as biofuels

    and wind energy grew by 16% but overall

    represent less than 2% of the global energy

    consumption.

    Coal consumption grew globally in 2010

    at the same rate as natural gas with some

    48% of world demand being consumed in

    China. The growth in coal demand has not

    been solely for generation of electricity but

    also in the conversion of coal into synthetic

    transportation fuels and petrochemicals.

    energy in South Australia

    missing a trick?South Australia currently relies on

    importation of all of its transportation fuels

    primarily from Singapore with bulk fuel

    shipments arriving every three days at Coode

    Island Terminal.

    With synfuel production gaining pace in

    other areas around the world (see box), an

    opportunity to develop South Australias

    coal reserves for the production of electricity

    and synthetic transportation fuels lies onits doorstep in the form of the Arckaringa

    basin. Arckaringas coal assets of 7.8b t

    represent more than 10% of Australias total

    coal reserves and with this in mind, Altona

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    Synfuel from coal

    Synfuel plants are operational or are

    being built in North America, Europe

    and Asia.

    All international airlines that refuel

    in Johannesburg or Cape Town fly on

    50:50 synfuel:refinery aviation fuel.

    China is following suit and is building

    synfuel plants as well as developing

    coal-based petrochemicals.

    Korea is proceeding on major coal

    gasification projects for the production

    of electricity and synthetic natural

    gas (SNG).

    Figure 1: South Australia mines, including

    Arckaringa coal asset

    Energy decided to investigate the feasibility

    of exploiting these currently undeveloped

    reserves.

    In November 2005, Altona acquired the

    mineral exploration licence in the coal-

    bearing areas in the Arckaringa basin,

    covering 2,500 km2and including three

    coal deposits Westfield, Wintinna and

    Murloocoppie containing over 7.8b t of coal.

    These coal deposits are effectively one of the

    worlds largest undeveloped energy banks,

    capable of conversion into clean liquid fuels,

    low-cost power and high value industrial

    feedstocks. We carried out process feasibility

    studies (PFSs) for the mine development and

    the proposed coal to liquids plant. Sufficient

    technical and economic data was developed

    to select suitable technology licences. In2010 we formed a joint venture with Chinas

    CNOOC as a strategic partner. In return for

    financial investment, CNOOC owns 51% of

    the mineral exploration licences.

    coal-to-liquids for Australia?South Australia can also develop its energy

    economy based on indigenous coal reserves.

    The coal is ideally suited for gasification

    and for the coproduction of synfuels and

    electricity. Firstly the coal is gasified to

    produce raw syngas from which carbon

    dioxide is captured before the treated syngas

    is converted into synthetic liquid fuels asfollows:

    syngas can be converted into long chain

    liquid hydrocarbons (wax) (by the Fischer

    Tropsch process) which are then refined to

    produce primarily diesel, aviation fuel and

    naptha; or

    syngas can be converted into methanol,

    which is then polymerised into gasoline orolefins.

    multiple benefits at

    ArckaringaIn 2006 we carried out drilling programmes

    to confirm the coal quality and quantity and

    subsequently develop the design of the mine

    and synfuel plant (CTL). Due to the enormous

    size of the coal reserves, the coal extraction

    rate can be increased, so that there is ability to

    also co-produce gasoline and petrochemicals.

    The technologies required to produce

    synthetic fuels are well proven and the coal

    gasification process allows for the efficient

    and economic capture of carbon dioxide for

    sequestration, thus minimising greenhouse

    gas emissions.

    Also, the plant produces sufficient electricity

    to meet the operational needs as well as to

    export electricity into the transmission grid.

    The water from the mine development and

    the coal processing plant are treated to allow

    use in the plant and export of the water to the

    local farming communities and the mining

    enterprises.

    Our work to date using technical

    engineering companies in Australia, Europeand the US indicate that we could produce

    liquid fuels at a sale price of A$0.33/l,

    which is extremely competitive at todays

    international pricing, thus even providing

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    the future opportunity for export once theneeds of the South Australian market have

    been met. These costs will only be subjected

    to inflationary costs and are not exposed to

    international oil market volatility. The general

    public and industry at large would benefit

    from implementing the Arckaringa mine and

    CTL plant.

    Synfuel quality is superior to that

    produced from conventional crude oil.

    These properties include:

    lower specific gravity which results in lower

    payload, especially important for the aviation

    industry;no aromatics orcarcinogenic compounds;

    reduced sulphur and nitrogen emissions.

    There are minimal carbon dioxide emissions

    in the overall process with emission levels

    similar to natural gas power plant due to the

    carbon capture scheme.

    Were considering building a plant to

    convert some of the carbon dioxide into

    methanol, which can be directly added to the

    gasoline pool; there are favourable economics

    Combined cycle

    power plant

    Fischer-Tropsch

    synthesisCleanup

    Tail gas

    LPsteam

    Refining

    Diesel

    Naptha

    Other fuels

    By

    products

    Sulphur

    Inert slag

    Coal

    O2

    Syngas

    CO+2H2

    Gasification

    CO2

    Figure 2: Synfuel process schematic

    for conversion of methanol into gasoline.The Arckaringa Project is ideally placed to:

    supply fuel and chemicals to new resources

    and industrial projects;

    enhance power supply to the state grid and

    the national electricity market;

    distribute water to the region from mine

    dewatering and plant processes; and

    be a catalyst for regional development and

    employment.

    can it be done?The Arckaringa Project design was developed

    from prefeasibility technical studies, coveringCTL plant design and costing, open cut mine

    design and costing, a field drilling programme

    and follow up hydrogeological modelling,

    geotechnical evaluation and coal quality

    testing and analysis. From these studies and

    the large body of work from past evaluations

    of the Wintinna coal resource, we derived a

    project base case.

    A field drilling programme commenced in

    2006 and was completed in 2008, with the

    associated geotechnical, hydrogeological,

    coal testing and analysis and resources

    statements. During 2007, we commissioned

    CTL and power plant options optimisation

    work on mine costs and constructed a

    project economic model. Studies on fuel and

    electricity markets were also undertaken.

    These studies, together with the historical

    database and the field drilling and associated

    technical programmes, constituted a

    prefeasibility body of work at a standard

    which permitted an informed decision on

    proceeding to the bankable feasibility stage

    (BFS).

    where were at

    Along with CNOOC we started the two-yearBFS programme for the mine and CTL plant

    development in October 2010.

    To date, major milestones achieved include:

    the Chinese authorities have confirmed the

    Left to right: Arckaringa Creek and hillsnear Wintinna, April 2010; Investigations

    underway

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    key findings

    Key findings from the pre-feasibility level studies are

    described below:

    geology and coal resourcesThe Wintinna Deposit contains up to 3,900m t of coal

    resources. The resources statement incorporating the results

    of the field drilling programme show a Joint Ore Reserves

    Committee (JORC) compliant resource estimate of 1,287m t

    which covers only about 25% of the area of the deposit.

    mine design and costsThe Wintinna deposit can be mined as a conventional open cut and back fill

    operation.

    The initial box cut will take approximately 2 years to uncover first coal, thereafter

    mining is virtually steady state through dewatered overburden and gently dipping,

    consistent coal seams.

    The mine footprint after 30 years at 1015m t/y of coal will be around 20 km

    2

    .Groundwater modelling shows that average dewatering volumes are significant,

    estimated at up to 600m l/d in early years reducing to 300m l/d.

    CTL and power plant design and costsThe base case CTL plant comprises gasification, FischerTropsch liquids and

    combined cycle power generation. It is a complex but integrated facility that

    combines to produce 30,000 bbl/d (10m bbl/y) of diesel products and naptha, and

    the export of 560 MWh

    (4m MWh/y) of electricity to the grid and/or third parties.

    infrastructure requirementsThe mine and CTL plant site is remote from large regional centres but has the prime

    advantage of proximity to the Adelaide Darwin railway and the Stuart Highway.

    The costs of normal mine site infrastructure, with the exception of the grid

    transmission link, have already been factored into project economic model.

    Connecting the power plant to the national electricity grid will benefit the grid

    system in terms of load balancing, especially if the plant operates in base load mode.

    fuels and electricity marketsThe fuel market in SA and NT can absorb all of 10m bbl/y of liquid fuels from the

    CTL plant:

    the SA and NT market relies totally on imports of diesel fuel and is estimated at

    9m bbl/y currently and forecast to rise steadily to around 12m bbl/y by 2014

    fuels can be exported via the nearby rail link to Darwin to supply markets in Asia,

    particularly China

    It is anticipated that the lower density specification for CTL diesel (0.77) compared

    to conventional refinery diesel (0.83) will be accommodated in future within the Diesel

    Fuel Standard.

    Electricity market studies show costs of generating power at Arckaringa are

    sufficiently low to enable the power plants export capacity to be dispatched into the

    national grid.

    environmental issues and approvalsThe key issues are the impact of mine dewatering on regional water sources,

    mound springs associated with the Great Artesian Basin (GAB) and aquifer systems,

    and CO2mitigation.

    The management plan for pumping, diversion and disposal of groundwater will

    require a water allocation licence (WAL) from state government authorities to ensure

    it protects local water supplies, GAB mound springs, flora and fauna species etc.

    CO2mitigation plans include plant capture, compression and storage at asequestration site already identified in the East Officer Basin, around 100 km from

    the proposed CTL plant site, for long-term sequestration under a gas storage

    licence.

    Arckaringa coal asset in terms of both qualityand quantity;

    South Australian government approval for

    the field programme commencing this year

    for the specification and location of coal and

    geotechnical boreholes and hydrological

    tests wells;

    reconfirmation of the suitability of the coal

    for gasification; and

    re-evaluation of the mine and CTL plant

    development options and project economics.

    The BFS will further optimise the

    configuration of the overall complex in

    respect of the project economic model,compliance with environmental legislation

    and overall logistics for products export.

    Were confident that South Australias coal

    reserves can allow it to become a regional

    leader in synfuels production and offset its

    reliance on imported fuels, thus achieving

    economic benefits and homeland security.

    tce

    Peter Fagiano(pfagiano@altonaenergy.

    com) is director at Altona Energy.

    Miracles can happen even

    to those who are small,

    flammable and dressed all

    in black.*The miracle isthat coal can be convertedinto synthetic fuels andpetrochemicals whileminimising any effluentsor emissions into theenvironment.

    * From Lemony Snickets book

    The Lump of Coal

    IChemE EVENTS

    Gasification 11

    Cagliari, Sardinia, Italy

    811 May

    Gasification technology provides an

    attractive conversion route to fuels

    and chemicals from a wide range of

    primary energy sources. Most of the

    undesirable by-products created by

    conventional combustion processes are

    either eliminated, converted into saleable

    products, or can be captured for safe

    storage. Gasification 11 will take a close

    look at the latest developments in the field.

    Register now: www.icheme.org/

    events/gasi11