Synthesis of Optically Pure 1,2-Diaryl- and 1,2-Alkylaryl-1,2-amino Sulfides.
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2005 Thioethers Q 0580 Synthesis of Optically Pure 1,2-Diaryl- and 1,2-Alkylaryl-1,2-amino Sulfides. — Coupling of thioether (I) with the (S)-sulfinylaldimines (II) offers an efficient access to optically pure 1,2-amino sulfides. Derivatives of type (IV) and (V) are potential ligands. The reaction of (I) with (R)-sulfinylaldimines proceeds with low stereo- selectivity. — (ARROYO*, Y.; MEANA, A.; RODRIGUEZ, J. F.; SANTOS, M.; SANZ-TEJEDOR, M. A.; GARCIA RUANO, J. L.; J. Org. Chem. 70 (2005) 10, 3914-3920; Dep. Quim. Org., Univ. Valladolid, E-47071 Valladolid, Spain; Eng.) — Jannicke 40- 104
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Transcript of Synthesis of Optically Pure 1,2-Diaryl- and 1,2-Alkylaryl-1,2-amino Sulfides.
2005
ThioethersQ 0580 Synthesis of Optically Pure 1,2-Diaryl- and 1,2-Alkylaryl-1,2-amino Sulfides. —
Coupling of thioether (I) with the (S)-sulfinylaldimines (II) offers an efficient access to optically pure 1,2-amino sulfides. Derivatives of type (IV) and (V) are potential ligands. The reaction of (I) with (R)-sulfinylaldimines proceeds with low stereo-selectivity. — (ARROYO*, Y.; MEANA, A.; RODRIGUEZ, J. F.; SANTOS, M.; SANZ-TEJEDOR, M. A.; GARCIA RUANO, J. L.; J. Org. Chem. 70 (2005) 10, 3914-3920; Dep. Quim. Org., Univ. Valladolid, E-47071 Valladolid, Spain; Eng.) — Jannicke
40- 104
