Syllabus Physical & Organic Chem. - Pre-Med (Sem.2)

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Transcript of Syllabus Physical & Organic Chem. - Pre-Med (Sem.2)

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    Prepared by: Mrs. Shyamala Devi.A.

    PRE-MEDICAL STUDIES

    PHYSICAL & ORGANIC

    CHEMISTRY

    (Semester 2)

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    SYLLABUS

    Electrochemistry

    Reaction kinetics

    Introduction to organic chemistry

    HydrocarbonsHaloalkanes

    Hydroxy compounds

    Aromatic compounds

    Carbonyl compoundsCarboxylic acids and derivatives

    Amines and derivatives

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    CHAPTER 1 - ELECTROCHEMISTRY

    Introduction

    Voltaic cell

    Cell voltage

    Standard electrode potential

    Standard hydrogen electrode (SHE)

    Electrolysis - introduction

    Electrolysis of molten salt andaqueous solution

    Uses of electrolysis

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    CHAPTER 2 REACTION KINETICS

    Introduction

    Rate law

    Integrated rate equationsCollision theory

    Arrhenius equation

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    CHAPTER 3 INTRODUCTION TO

    ORGANIC CHEMISTRY

    Introduction to organic compounds

    Bonding of carbon atom

    Classification of carbon atomsIsomerism

    Hybridization

    Types of reactions

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    CHAPTER 4 - HYDROCARBONS

    ALKANES

    Introduction to alkanes

    Naming of alkanes and cycloalkanes

    Physical properties of alkanes

    Reactions of alkanes

    - combustion- halogenation (mechanism of free

    radical substitution)

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    Continued

    - Cracking of alkanes

    Sources of alkanes

    ALKENES

    Introduction to alkenes

    Naming of alkenesPhysical properties of alkenes

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    Reactions of alkenes

    - Halogenation

    - Reaction with hydrogen halides

    (Markownikoffs rule)- Reaction with sulphuric acid

    - Hydrogenation

    - Hydration

    - Oxidation

    Sources of alkene

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    CHAPTER 5 - HALOALKANES

    Introduction to haloalkanes

    Classification of haloalkanes

    Physical properties

    Reactions of haloalkanes

    - reaction with cyanide ion

    - reaction with ammonia

    - reaction with silver nitrate

    - alkaline hydrolysis

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    Continued

    - Esterification

    - Ether formation

    - Elimination- Grignard reagent

    Sources of haloalkanes

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    CHAPTER 6 HYDROXY COMPOUNDS

    ALCOHOL

    Introduction

    Naming of alcoholsClassification of alcohols

    Physical properties of alcohol

    Making alcohols

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    Continued

    Reactions of alcohol- reaction with hydrogen halides

    - reaction with phosphorus halides

    - reaction with sulphur dichlorideoxide

    - oxidation

    - esterification- reaction with triiodomethane

    - dehydrogenation

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    Continued

    PHENOLIntroduction

    Physical & chemical properties of

    phenolReactions of phenol

    - reaction with bromine water

    - reaction with nitric acid- reduction

    Manufacturing phenol

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    CHAPTER 7 AROMATIC

    COMPOUNDS

    Introduction to benzene &

    methylbenzene

    Physical properties of benzene &

    methylbenzene

    Preparation of benzene &

    methylbenzene

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    Reactions of benzene &methylbenzene

    - nitration

    - halogenation- Friedel-Crafts acylation

    - Friedel-Crafts alkylation

    - combustion- sulphonation

    - oxidation

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    CHAPTER 8 CARBONYL

    COMPOUNDS

    IntroductionPhysical properties

    Making aldehydes and ketones

    Reactions of aldehydes and ketones

    - addition of hydrogen cyanide

    - addition of aqueous sodium

    hydrogen sulphate (IV)

    - reduction- oxidation

    - with triiodomethane

    - with 2,4-dinitrophenylhydrazine

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    CHAPTER 9 CARBOXYLIC ACID &

    ITS DERIVATIVES

    CARBOXYLIC ACID

    Introduction

    Making carboxylic acids

    Reactions:

    - esterifications

    - reduction

    - halogenation

    - oxidation

    - dehydration

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    Continued

    Acyl chloride

    - Introduction

    - Making acyl chlorides- Reactions:

    - with ammonia and amines

    - with alcohol and phenol- hydrolysis

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    Continued

    Esters

    - Introduction

    - Reactions- hydrolysis

    - saponification

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    Amides

    - Introduction

    - Reaction- hydrolysis

    - dehydration

    - Hoffmann degradation- reduction

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    CHAPTER 10 - AMINES

    Introduction

    Classification of amines

    Making aminesReaction with nitrous acid

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    THANK YOU!