Supporting Information A flexible Pinner Preparation … Supporting Information A flexible Pinner...
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S1 Supporting Information A flexible Pinner Preparation of Orthoesters. The model case of Trimethylorthobenzoate. Marco Noè,* Alvise Perosa and Maurizio Selva* Table of Contents: S2 MS spectra for selected compounds S7 1 H NMR spectra of O-methyl-imidates 2a-c Electronic Supplementary Material (ESI) for Green Chemistry This journal is © The Royal Society of Chemistry 2013
Transcript of Supporting Information A flexible Pinner Preparation … Supporting Information A flexible Pinner...
S1
Supporting Information
A flexible Pinner Preparation of Orthoesters. The model case of Trimethylorthobenzoate.
Marco Noè,* Alvise Perosa and Maurizio Selva*
Table of Contents:
S2 MS spectra for selected compounds
S7 1H NMR spectra of O-methyl-imidates 2a-c
Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
S2
MS spectra for selected compounds
Figure S1. MS spectrum of O-methyl-propioimidate 2a.
Figure S2. MS spectrum of O-methyl-pentaneimidate 2b.
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AbundanceScan 482 (2.994 min): ORTOPR~1.D
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AbundanceScan 245 (6.232 min): ORTOVAL.D
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
S3
Figure S3. MS spectrum of O-methyl-benzoimidate 2c.
Figure S4. MS spectrum of trimethylorthopropionate 3a.
Figure S5. MS spectrum of trimethylorthopentanoate 3b.
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AbundanceScan 523 (9.401 min): MN460H2.D
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AbundanceScan 749 (4.607 min): MN574.D
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AbundanceScan 409 (8.396 min): ORTOVAL.D
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
S4
Figure S6. MS spectrum of trimethylorthobenzoate 3c.
Figure S7. MS spectrum of methyl-propionate 4a.
Figure S8. MS spectrum of methyl-pentanoate 4b.
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AbundanceScan 703 (12.227 min): ORTOBENZ.D
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AbundanceScan 205 (2.667 min): MN_ORTOP.D
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AbundanceScan 117 (4.558 min): ORTOVAL.D
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
S5
Figure S9. MS spectrum of methylbenzoate 4c.
Figure S10. MS spectrum of benzamide 5c.
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AbundanceScan 444 (8.449 min): MN460H2.D
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AbundanceScan 798 (12.713 min): MN460H2.D
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
1H NNMR spectrra of methy
Figur
Figur
ylimidates 2
e S11. 1H NM
e S12. 1H NM
2a-c
MR of O-methy
MR of O-meth
yl-propioimid
yl-valeroimid
date 2a.
date 2b.
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
Figurre S13. 1H NMMR of O-methhyl-benzoimiddate 2c.
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Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013
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