Support Information Green Chem - Royal Society of Chemistry · 2007-11-26 · S1 Supporting...
Transcript of Support Information Green Chem - Royal Society of Chemistry · 2007-11-26 · S1 Supporting...
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S1
Supporting Information
An alternative method for the regio- and stereoselective bromination of
alkenes, alkynes, toluene derivatives and ketones using a
bromide/bromate couple
Subbarayappa Adimurthy,*a Sudip Ghosh,b Paresh U. Patoliya,a Gadde
Ramachandraiah,*a Manoj Agrawal, Mahesh R. Gandhi, Sumesh C. Upadhyay, Pushpito
K. Ghosh,*a Brindaban C. Ranu*b aCentral Salt and Marine Chemicals Research Institute, Gijubhai Badheka Marg, Bhavnagar – 364 002, Gujarat, India. Fax : +91-278-2567562 bDepartment of Organic Chemistry, Indian Association for the Cultivation of Science,
Jadavpur, Kolkata – 700 032, India.
E-mail : [email protected]; [email protected]; [email protected],
Table of Contents Page no. 1H NMR and 13 C NMR Spectra of All Products S2-S79
in Tables 1-4 and 6
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S2
Br
Br
Entry-1, table-1
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S3
Br
Br
Entry-1, table-1
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S4
PhBr
Br
Entry-2, table-1
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S5
PhBr
Br
Entry-2, table-1
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S6
Br
Br
Entry-3, table-1
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S7
Br
Br
Entry-3, table-1
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S8
Br
Br
Entry-4, table-1
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S9
Br
Br
Entry-4, table-1
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S10
Br
Ph Br
Ph
Entry-5,table-1
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S11
Br
Ph Br
Ph
Entry-5,table-1
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S12
Br
Ph Br
Ph
Entry-6,table-1
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S13
Br
Ph Br
Ph
Entry-6,table-1
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S14
Ph
O
COOEt
Br
Br
Entry-7, table-1
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S15
Ph
O
COOEt
Br
Br
Entry-7, table-1
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S16
Br
COOEt
EtOOC
Br
Entry-8, table-1
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S17
Br
COOEt
EtOOC
Br
Entry-8, table-1
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S18
Ph
O
Ph
Br
Br
Entry-9, table-1
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S19
Ph
O
Ph
Br
Br
Entry-9, table-1
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S20
Ph
O
Br
Br
p-OMe ( C6H4)
Entry-10, table-1
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S21
Ph
O
Br
Br
p-OMe ( C6H4)
Entry-10, table-1
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S22
p-Cl (C6H4)Ph
O
Br
Br
Entry-11, table-1
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S23
p-Cl (C6H4)Ph
O
Br
Br
Entry-11, table-1
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S24
COPh
Br
Br
PhOC
Entry-12, table-1
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S25
COPh
Br
Br
PhOC
Entry-12, table-1
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S26
Ph
O
NO2
Br
Br
Entry-13, table-1
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S27
Ph
O
NO2
Br
Br
Entry-13, table-1
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S28
Br
Br
Entry-1, table-2
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S29
Br
Br
Entry-1, table-2
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S30
Br
Br
Entry-2, table-2
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S31
Br
Br
Entry-2, table-2
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S32
Ph
Br
H
Br
Entry-3, table-2
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S33
Ph
Br
H
Br
Entry-3, table-2
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S34
Br
Br
Entry-4, table-2
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S35
Br
Br
Entry-4, table-2
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S36
Br
Br
Entry-5, table-2
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S37
Br
Br
Entry-5, table-2
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S38
Ph
Br
Ph
Entry-6, table-2
Br
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S39
Ph
Br
Ph
Entry-6, table-2
Br
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S40
MeOOC
Br
Br
COOMe
Entry-7, table-2
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S41
MeOOC
Br
Br
COOMe
Entry-7, table-2
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S42
Cl
BrBr
H
Entry-8, table-2
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S43
Cl
BrBr
H
Entry-8, table-2
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S44
BrBr
H
Entry-9, table-2
OMe
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S45
BrBr
H
Entry-9, table-2
OMe
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S46
BrBr
Br
Entry-10, table-2
H
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S47
BrBr
Br
Entry-10, table-2
H
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S48
CH3
BrBr
H
Entry-11, table-2
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S49
CH3
BrBr
H
Entry-11, table-2
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S50
O
Br
Br
Entry-12, table-2
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S51
O
Br
Br
Entry-12, table-2
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S52
O
Br
Br
Entry-13, table-2
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S53
O
Br
Br
Entry-13, table-2
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S54
1H-NMR (entry 1, Table 3)
13C-NMR (entry 1, Table 3)
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S55
1H-NMR (entry 2, Table 3)
13C-NMR (entry 2, Table 3)
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S56
Gas Chromatogram (entry 2, Table 3)
Differential Scanning Calorimeter (DSC) Thermo gram (entry 2, Table 3)
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S57
1H-NMR (entry 3, Table 3)
13C-NMR (entry 3, Table 3)
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S58
1H-NMR (entry 4, Table 3)
13C-NMR (entry 4, Table 3)
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S59
1H-NMR (entry 5, Table 3)
13C-NMR (entry 5, Table 3)
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S60
1H-NMR (entry 6, Table 3)
13C-NMR (entry 6, Table 3)
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S61
1H-NMR (entry 7, Table 3)
13C-NMR (entry 7, Table 3)
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S62
1H-NMR (entry 8, Table 3)
13C-NMR (entry 8, Table 3).
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S63
1H-NMR (entry 9, Table 3)
13C-NMR (entry 9, Table 3)
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S64
1H-NMR (entry 10, Table 3)
13C-NMR (entry 10, Table 3)
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S65
1H-NMR (entry 1, Table 4)
13C-NMR (entry 1, Table 4)
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1H-NMR (entry 2, Table 4)
13C-NMR (entry 2, Table 4)
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1H-NMR (entry 3, Table 4)
13C-NMR (entry 3, Table 4)
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O
Br
Entry-1,table-5
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S69
O
Br
Entry-1,table-5
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S70
Br
O
Entry-2, table-5
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S71
Br
O
Entry-2, table-5
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S72
O
Br
Entry-3 ,table-5
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S73
O
Br
Entry-3 ,table-5
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S74
Br
O
Entry-4,table-5
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S75
Br
O
Entry-4,table-5
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S76
O
Br
Entry-5 ,table-5
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S77
O
Br
Entry-5 ,table-5
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S78
O
Br
Entry-6, table-5
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S79
O
Br
Entry-6, table-5
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S80