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![Page 1: Single Molecule Electronics And Nano-Fabrication of Molecular Electronic Systems S.Rajagopal, J.M.Yarrison-Rice Physics Department, Miami University Center.](https://reader030.fdocuments.net/reader030/viewer/2022032517/56649c7f5503460f94936717/html5/thumbnails/1.jpg)
Single Molecule Electronics And
Nano-Fabrication of Molecular Electronic Systems
S.Rajagopal, J.M.Yarrison-Rice
Physics Department, Miami University Center For Nanotechnology, Oxford, OH.
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Highlights
¤ Organometallic paddlewheel complex
¤ Fabrication of two electrode and gated devices using EBL
¤ Closing of gap using electrodeposition
¤ Breaking a nanowire by electromigration
¤ Characterization of the fabricated nanogap
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Process Steps
Fabricate nano-gap electrodes with EBL
Close gap to nano-gap using electrodeposition
Characterize the nano-gap
Deposit molecule and study the gap
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The Molecule
¤ Paddlewheel bridging ligands
¤ Re-Re Quadruple bond
¤ Anchoring thiol group
¤ Ir-Ir Double bond
¤ Os-Os Triple bond
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Fabrication of Nanogap Electrodes
¤ Raith 150 EBL system ¤ Different gold thickness (100/150/250 nm) on top of 30nm Cr
A B C
D
300nm
300nm
E
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Fabrication Results¤ Two electrode devices
¤ GDS2 design¤ Design gap 75nm
¤ Gap=74nm
¤ After metal evaporation of Cr/Au¤ Gap=53nm
1
2
3
¤ After EBL & development
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Fabrication Results¤ Gated electrode devices ¤ GDS2 gated
design¤ Design gap 60nm
¤ After metal evaporation of Cr/Au¤ Gap=10nm
¤ Gated device with 3 contact pads
1
2
3
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Closing the Gap Using Electrodeposition
¤ Packaging = Wire bonding + Epoxy cavity
¤ Package: Kovar material¤ Wire bonding of contact pads to external leads ; Substrate temp ~150° C¤ Epoxy cavity for forming the electrochemical cell
21
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Factors To Consider
¤ Method Setup ( 2 methods tried )¤ Electrolyte composition ( 2 compositions )¤ Deposition current ¤ Electrolyte concentration ( 4 concentrations)
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Closing the Gap Using Electrodeposition
¤ Method: Constant current ; Monitor the voltage across WE and RE¤ Electrolyte composition: 0.42 M Na2SO3 + 0.42 M Na2S2O3 + 0.05 M NaAuCl4
¤ Non-toxic and without strongly adsorbed ions¤ At room temperature
¤ Electrodeposition Setup 1 (Non Cyanide)
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Results of Electrodeposition (Method 1)
¤ Time evolution curve of Vgap at a constant current of 25 µA on a chart recorder
¤ SEM image of fused electrodes after electrodeposition
Stop
¤ I-V curve showing hysteresis
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Difficulties with Method 1
¤ Method requires precise switching on desired gap voltage Manual ( less precise)
¤ Open loop system (no feedback)
¤ Lacks control on deposition rate
¤ Solution stability problem
¤ No two fabricated pairs showed the same growth pattern with similar initial/final gap voltages
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Modified Setup – Self-terminating
¤ Method: Constant current ; More directional growth ¤ Preset current for desired gap : 5/10/20/50nA¤ Mix C & D : 0.4 M Na2SO3 + 0.4 M Na2S2O3 + 0.01 M Na2Au(S2O3)2 + 0.3 M Sodium citrate¤ Solution more stable (for more than 2 weeks)
Galvanostat
DMM
Faraday Cage
WE RE/CE
200μ
J. Xiang, B.Liu, B.Liu, B. Ren, Z.Q. Tian, Electrochemical Communications vol. 8, pp. 577-580, 2006
I total
I total = I dep + I tunnel
I dep I tunnel
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Electrodeposition ResultsMag=2.2 Kx I=-10nA Mag=36 Kx I=-
10nA
Left electrode
Right electrode
Abnormal growthBut, fine grain
size
Mag= 15 Kx I=-10nA
Left electrode
Right electrode
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Results & Difficulties
I (A)
V (V)
¤ Growth moderately fine, but not predictable in all pairs¤ Abnormal growth due to surface contamination¤ Small structural shapes of electrode not retained¤ Initial/Final V of nanogap showed no trend¤ All final I/V curves showed huge gaps
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Design and Setup Changed¤ New design tried to retain shape and avoid folding patterns¤ New electrolyte delivery to localize to single pair¤ Solution modification to minimize deposits on other electrode¤ Minimize surface contamination
700nm
Revamped
Previous
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