SELECTIVE CATALYTIC REDUCTION “Nuking the NOx” Ed Saxman Arkansas Trucking Association November...
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Transcript of SELECTIVE CATALYTIC REDUCTION “Nuking the NOx” Ed Saxman Arkansas Trucking Association November...
![Page 1: SELECTIVE CATALYTIC REDUCTION “Nuking the NOx” Ed Saxman Arkansas Trucking Association November 11, 2008.](https://reader035.fdocuments.net/reader035/viewer/2022062421/56649d205503460f949f442c/html5/thumbnails/1.jpg)
SELECTIVE CATALYTIC SELECTIVE CATALYTIC REDUCTIONREDUCTION
“Nuking the NOx”
Ed SaxmanArkansas Trucking AssociationNovember 11, 2008
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0
10
20
30
40
50
60
70
80
90
100
1974 1988 1991 1994 1998 10'02 2007 2010E
mis
sio
n R
ed
uc
tio
n, %
(1
97
4 =
0)
NOx
Particulates
Series3
Emission DevelopmentEmission Development
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Particulate Reduction
60
65
70
75
80
85
90
95
100
1974 1988 1991 1994 1998 10'02 2007 2010
Em
iss
ion
Re
du
cti
on
, % (
19
74
= 0
)
.25 g / hp-hr
.1 g / hp-hr
.01 g / hp-hr
Emission DevelopmentEmission Development
regeneration
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NOx Reduction
60
65
70
75
80
85
90
95
100
1974 1988 1991 1994 1998 10'02 2007 2010
Em
iss
ion
Re
du
cti
on
, %
(1
97
4 =
0)
Massive EGR
SCR+EGR
Emission DevelopmentEmission Development
6
5
2.5
4
1.2
0.5
0.2
regeneration
“The technology does not exist to achieve 0.2 without regeneration”
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Regulated EmissionsRegulated Emissions
COCarbon Monoxide
HCHydrocarbons
PMParticulate Matter
Carbon (Soot)
NOxOxides of Nitrogen
NEAR ZERO
NEAR ZERONEAR ZERO
NEAR ZERO
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NEAR-ZERO EMISSIONS
With EPA’10, using Selective Catalytic Reduction (SCR), we will have achieved a 99% reduction
in all regulated pollutants from untreated levels.
99% Fewer Pollutants99% Fewer Pollutants
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• Why use SCR?– SUPERIOR fuel economy, compared to other solutions for EPA’10.
Total fuel costs will be significantly reduced, even allowing for the DEF.– Improved engine performance. Less EGR needed, less heat rejection
into cooling system results, greater power density, and higher efficiency.– Very little maintenance required– Reliable, proven approach (High volume production in other markets)
• What additions to the truck will be included?– DEF tank, on the driver’s side. Heated. Various sizes depending on fuel
capacity. Includes pump and filter.– Heated lines, pump to injector– DEF injector, mounted to today’s frame-mounted Diesel Particulate
Filter– SCR catalyst, behind DPF or vertically mounted
All About All About Selective Catalytic ReductionSelective Catalytic Reduction
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EPA’10 HardwareEPA’10 Hardware
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EPA’10 HardwareEPA’10 Hardware
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EPA’10 HardwareEPA’10 Hardware
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PLAIN AND SIMPLEPLAIN AND SIMPLE
WITH UREA YOU SIMPLY “NUKE THE NOx”WITH UREA YOU SIMPLY “NUKE THE NOx”
YOU CAN MAKE ALL THE ENGINE-OUT NOx YOU WANTYOU CAN MAKE ALL THE ENGINE-OUT NOx YOU WANT
AND NUKE IT IN THE AFTERTREATMENTAND NUKE IT IN THE AFTERTREATMENT
YOU CAN TUNE THE ENGINE TIMING AND PRESSURE RATIOS YOU CAN TUNE THE ENGINE TIMING AND PRESSURE RATIOS THE WAY THEY USED TO BE AND STILL HAVE A GENUINE THE WAY THEY USED TO BE AND STILL HAVE A GENUINE
NEAR-ZERO EMISSION COMPLIANT ENGINENEAR-ZERO EMISSION COMPLIANT ENGINE
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• The after-treatment system utilizes an injection of a solution of urea.
• Urea is a compound of nitrogen that turns to ammonia (NH3) when heated. When a urea solution is injected into the exhaust stream and passed over a catalyst, the urea reacts with the NOx to form just nitrogen and water vapor – both clean components of ‘air’.
In essence, NH3 + NOx = N2 + H20
Diesel Exhaust Fluid (Urea)Diesel Exhaust Fluid (Urea)
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• The main component of DEF is an organic nitrogen-rich compound called urea.
• Urea is synthesized from natural gas and carbon dioxide.• Urea is very widely used in agriculture as a fertilizer, most often distributed
in wax-coated pellets. (Not a water solution)• Urea is a compound of nitrogen that turns to ammonia (NH3) when heated.• Why call it DEF?
– Automotive industry wanted a generic name
• What is Diesel Exhaust Fluid made from?– 32.5% urea, 67.5% demineralized water– Must be kept extremely pure
• Why 32.5%?– Water solution with lowest freezing point, 12oF.– AUS32. Will also be an API standard.
Diesel Exhaust Fluid (Urea)Diesel Exhaust Fluid (Urea)
• The main component of DEF is an organic nitrogen-rich compound called urea.
• Urea is synthesized from natural gas and carbon dioxide.• Urea is very widely used in agriculture as a fertilizer, most often distributed
in wax-coated pellets. (Not a water solution)• Urea is a compound of nitrogen that turns to ammonia (NH3) when heated.• Why call it DEF?
– Automotive industry wanted a generic name
• What is Diesel Exhaust Fluid made from?– 32.5% urea, 67.5% demineralized water– Must be kept extremely pure
• Why 32.5%?– Water solution with lowest freezing point, 12oF.– AUS32. Will also be an API standard.
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Freezing Point of Urea/Water Solutions
010
20304050
607080
90100
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
Percent Urea
Tem
per
atu
re,
oF
Diesel Exhaust FluidDiesel Exhaust Fluid
Wat
er
Die
sel
Exh
aust
Flu
id
Cry
stal
lin
e S
oli
d
Slu
rry
12oF
Ice
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• DEF Freezes at 12oF.
• You can walk up to a truck that has been standing over a frigid weekend and drive it away with no additional warm-up time.
• A few cc’s will melt immediately due to the heat from the exhaust.
• The tank heater will eventually melt the rest as you drive.
• Oh, by the way – one of the other uses for urea is as a de-icer. Google it.
So This Stuff Freezes?So This Stuff Freezes?
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• For every $1.00 of Diesel Exhaust Fluid you put in your truck with SCR technology, your diesel fuel costs will be reduced by nearly $2.00.
• "The total COST of fuel PLUS Diesel Exhaust Fluid for EPA'10 will be 5% LESS than our EPA’04 engine, under similar conditions."
How Much Extra How Much Extra Does That Stuff Cost?Does That Stuff Cost?
Quick,Quick,Gimme a BuckGimme a Buck
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How much Diesel Exhaust Fluid is required?
• Volvo is optimizing the amount of Diesel Exhaust Fluid (DEF) to be injected for US’10 standards, but the rate will probably fall in the 2-4% range.
• The more DEF, the lower the diesel fuel consumption. The less DEF, the more diesel fuel consumption. We will optimize for the lowest total cost.
What will be the price of Diesel Exhaust Fluid?
• According to Volvo’s information, it is estimated at about 3/4 the price per gallon of diesel fuel. The exact price will, as always, be set by the market.
Can the UREA infrastructure meet the additional demand?
• Easily. Globally over 100 million tons of urea were produced last year, primarily for agriculture, and also for cosmetics.
DEF Q&ADEF Q&A
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What about the base engine?• Base engine will only experience minor changes.
– Same proven injection system– Same camshaft– Same cylinder head– Same block
Changes for EPA’10Changes for EPA’10
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NOx: At Odds withNOx: At Odds with Fuel Economy Fuel Economy
EFFICIENCY vs. NOx
0
20
40
60
80
100
20 40 60 80
NOx Reduction, %
Effic
iency
, %
In general, the more efficient the combustion, the higher the NOx output.
The lower the NOx output, the lower the efficiency
Eff
icie
ncy
, %
more
more
less
less
EFFICIENCY vs. NOx
NOx Reduction, %
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Major improvements in NOx came with ultra high pressure fuel injection.
• Higher fuel injection pressure gives finer atomization for better combustion
• Shaped fuel injection delivery allows pressure rise to be controlled for best possible release of power.
• Proven Delphi Dual Solenoid fuel injector used since EPA’02 now delivers 35,000 psi for EPA’07
How Have We Been AbleHow Have We Been Ableto Reduce NOx andto Reduce NOx and
Still Maintain Fuel Economy? Still Maintain Fuel Economy?
Dual SolenoidDual SolenoidFuel InjectorFuel Injector
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Exhaust Gas RecirculationExhaust Gas Recirculation
• The big step in the evolution of the low-emission diesel was Exhaust Gas Recirculation. Some of the exhaust gas is recycled back through the engine under certain circumstances.
• The purpose of the EGR is not to ‘re-burn the exhaust’ • EGR dilutes the amount of oxygen in the intake charge. This
reduces the temperature of combustion and lowers formation of NOx.
EGR CoolerEGR Cooler
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Hydraulic Actuator
Pressure balanced poppet design
Solenoid hydraulic control valve
G. W. Lisk Co., Inc.
D11, D13, D16 EGR Valve
Near zero force to open, combined with powerful actuator => the valve will never stick
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October 2, 2007 -- FIRST FIVE EPA’10
TEST TRUCKS DELIVERED
EPA’10 Testing EPA’10 Testing ExperienceExperience
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• About Twenty EPA’10 Customer Function Trucks ~ Well Over a Million Miles • 23 SCR Evaluation Trucks since 2002
~ 9 Million Miles• ~150,000 SCR Euro IV and Euro V trucks globally
• We know what we’re doing
EPA’10EPA’10Testing ExperienceTesting Experience
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Engine
EGR Fuel
Fuel Mixing zone
DPF
Diesel Exhaust FluidReservoir
Sensors:3 Temperature sensors 1 Differential Pressure sensor2 NOx-sensors
OBD
DEF Mixing zone
SCR
Exhaust Outlet
On Board Diagnostics (OBD)On Board Diagnostics (OBD)
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Selective Catalytic ReductionSelective Catalytic Reduction
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Ready For COReady For CO22
In March, we exhibited seven CO2-Neutral trucks, each powered by a totally fossil carbon-free fuel (plus a diesel electric hybrid) at the Washington International Renewable Energy Conference (google WIREC).
The message was to policymakers was, “pick the RIGHT alternative fuel for the future, and we will develop an engine for it.”
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Ready For COReady For CO22
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• Thank you. Questions?