SECTION 1: Identification of the substance/mixture and of...

Acota™ Certonal™ FC-742 Electronic Grade Coating

Safety Data Sheet

Copyright, 2012, Acota Limited. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Acota products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Acota, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document group:Revision date:Transportation version number: 1.00 (22/12/2010)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifierAcota™ Certonal™ FC-742 Electronic Grade Coating

Product identification numbersFC-742

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified usesProtective Barrier Coating. For Industrial Use Only. Not Intended for Use as a Medical Device or Drug.

1.3. Details of the supplier of the substance or mixtureAddress: Acota Limited, Centrepoint, Knights Way, Battlefield, Shrewsbury, SY1 3BF.

E Mail : admin@acota .co.ukWebsite: www.acota.co.uk

1.4. Emergency telephone number+44 (0)1743 466200

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Symbols None.

Contains:

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16-0006-3 27/06/2012

Version number:Supersedes date:

9.0313/02/2012


No ingredients are assigned to the label.

Risk phrases None.Safety phrases None.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

IngredientMethyl nonafluorobutyl ether (REACH Reg. No.:01-0000016878-53)Methyl nonafluoroisobutyl ether (REACH Reg. No.:01-0000016878-53)Please see section 16 for the full text of any R phrases and H statements referred to in this sectionPlease refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Eye contactFlush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.

Skin contactWash with soap and water. If signs/symptoms develop, get medical attention.

InhalationNo need for first aid is anticipated.

If swallowedNo need for first aid is anticipated.

4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing mediaMaterial will not burn.

5.2. Special hazards arising from the substance or mixtureExposure to extreme heat can give rise to thermal decomposition.

5.3. Advice for fire-fighters

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CAS Nbr EU Inventory % by Wt Classification163702-07-6 ELINCS 422-

270-2163702-08-7 ELINCS 422-

270-2

20 - 80

20 - 80


No unusual fire or explosion hazards are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresVentilate the area with fresh air. Observe precautions from other sections.

6.2. Environmental precautionsAvoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.

6.3. Methods and material for containment and cleaning upContain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Place in a closed container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sectionsRefer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handlingAvoid skin contact with hot material. For industrial or professional use only. Store work clothes separately from other clothing, food and tobacco products. No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to the formation of hazardous decomposition products.

7.2. Conditions for safe storage including any incompatibilitiesStore away from strong bases.

7.3. Specific end use(s)See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limitsNo occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.

8.2. Exposure controls

8.2.1. Engineering controlsUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guidelines.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

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The following eye protection(s) are recommended: Safety glasses with side shields.

Skin/hand protection

Gloves made from the following material(s) are recommended: Nitrile rubber.

Respiratory protection

Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. If thermal degradation products are expected, use a full facepiece supplied-air respirator.

Thermal hazardsWear heat insulating gloves when handling this material to prevent thermal burns.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical propertiesPhysical stateSpecific Physical Form: Appearance/OdourpHBoiling point/boiling rangeMelting pointFlammability (solid, gas)Explosive propertiesOxidising propertiesFlash pointAutoignition temperatureFlammable Limits(LEL)Flammable Limits(UEL)Vapour pressureRelative densityWater solubility

Partition coefficient: n-octanol/waterEvaporation rateVapour density

ViscosityDensity

9.2. Other informationPercent volatileVOC less H2O & exempt solvents

SECTION 10: Stability and reactivity

10.1 ReactivityThis material is considered to be non reactive under normal use conditions

10.2 Chemical stabilityStable.

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Liquid. Liquid.Clear, colourless, with slight ethereal odour.Not applicable.61 ºC [@ 101,324.72 Pa ]-135 ºCNot classifiedNot classifiedNot classifiedNo flash point405 ºC [Details:ASTM E659-84][Details:None (ASTM E681-94, @100 °C)][Details:None (ASTM E681-94, @100 °C)]26,931 Pa [@ 25 ºC ]1.5 [Ref Std:WATER=1]< 12 ppm

No data available.49 [Ref Std:BUOAC=1]8.6 [Ref Std:AIR=1]

0.001 Pa-s [@ 23 ºC ]1.5 g/ml

98 % [Details:Exempt]


10.3 Possibility of hazardous reactionsHazardous polymerisation will not occur.

10.4 Conditions to avoidNot determined

10.5 Incompatible materialsStrong bases.

10.6 Hazardous decomposition productsSubstanceCarbon dioxide.

Carbon monoxide.

Hydrogen Fluoride

Perfluoroisobutylene (PFIB).

Toxic vapour, gas, particulate.

If the product is exposed to extreme conditions of heat from misuse or equipment failure, toxic decomposition products that include hydrogen fluoride and perfluoroisobutylene can occur.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Eye contactContact with the eyes during product use is not expected to result in significant irritation.

Skin contactContact with the skin during product use is not expected to result in significant irritation.

InhalationNo health effects are expected.

IngestionNo health effects are expected.

Toxicological Data

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ConditionAt elevated temperatures. - extreme conditions of

heatAt elevated temperatures. - extreme conditions of




heat

Acute ToxicityNameOverall product

Methyl nonafluoroisobutyl ether

Methyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Methyl nonafluorobutyl etherATE = acute toxicity estimate

Skin Corrosion/IrritationNameMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Serious Eye Damage/IrritationNameMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Skin SensitisationNameMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Respiratory SensitisationNameMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Germ Cell MutagenicityNameMethyl nonafluoroisobutyl etherMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl etherMethyl nonafluorobutyl ether

CarcinogenicityNameMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Reproductive Toxicity

RouteMethyl nonafluoroisobutyl etherMethyl nonafluoroisobutyl etherMethyl nonafluoroisobutyl ether

RouteIngestion

Inhalation-Vapor (4 hours)IngestionInhalation-Vapor (4 hours)Ingestion

SpeciesRabbitRabbit

SpeciesRabbitRabbit

SpeciesGuinea pigGuinea pig

Species

RouteIn VitroIn vivoIn VitroIn vivo

Route

ValueNot toxic to female reproduction

Not toxic to female reproduction

Not toxic to male reproduction

Species

SpeciesRat

Rat

Rat

ValueNo test data available; calculated ATE >5,000 mg/kgLC50 > 1,000 mg/l

LD50 > 5,000 mg/kgLC50 > 1,000 mg/l

LD50 > 5,000 mg/kg

ValueNo significant irritationNo significant irritation

ValueNo significant irritationNo significant irritation

ValueNot sensitizingNot sensitizing

ValueNo data availableNo data available

ValueNot mutagenicNot mutagenicNot mutagenicNot mutagenic

ValueNo data availableNo data available

Test result Exposure DurationNOAEL 1,000 mg/kg/dayNOAEL 129 mg/l

NOAEL 1,000 mg/kg/day

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Reproductive and/or Developmental EffectsName

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Ingestion

Inhalation

Ingestion

Species

Rat

RatRat

Rat

28 days

1 generation

28 days

Methyl nonafluoroisobutyl etherMethyl nonafluoroisobutyl ether

Methyl nonafluorobutyl ether

Methyl nonafluorobutyl etherMethyl nonafluorobutyl ether

Methyl nonafluorobutyl etherMethyl nonafluorobutyl ether

Target Organ(s)


Methyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether




Methyl

Inhalation

Inhalation

Ingestion

Inhalation

Ingestion

Inhalation

Inhalation

Not toxic to male reproduction

Some positive developmental data exist, but the data are not sufficient for classificationNot toxic to female reproduction

Not toxic to female reproductionNot toxic to male reproduction

Not toxic to male reproductionSome positive developmental data exist, but the data are not sufficient for classification

Target Organ(s)nervous system Some positive

data exist, but the data are not sufficient for classification

cardiac sensitization

nervous system Some positive data exist, but the data are not sufficient for classification

cardiac sensitization

Target Organ(s)liver

bone, teeth, nails, and/or hair

heart | skin |

Dog

Dog

Dog

Dog

Rat

Rat

Rat

NOAEL 129 mg/l

NOAEL 307 mg/l

NOAEL 1,000 mg/kg/dayNOAEL 129 mg/lNOAEL 1,000 mg/kg/dayNOAEL 129 mg/lNOAEL 307 mg/l

LOAEL 913 mg/l

NOAEL 913 mg/l

LOAEL 913 mg/l

NOAEL 913 mg/l

NOAEL 155 mg/l

NOAEL 129 mg/l

NOAEL 155

1 generation

during gestation

28 days

1 generation

28 days

1 generation

during gestation

10 minutes

10 minutes

10 minutes

10 minutes

13 weeks

11 weeks

13 weeks

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Specific Target Organ Toxicity - single exposureName Route

Specific Target Organ Toxicity - repeated exposureName Route

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Inhalation

Inhalation

Inhalation

Inhalation

Inhalation

Inhalation

Inhalation

Value

All data are negative

All data are negative

Value

Some positive data exist, but the data are not sufficient for classificationSome positive data exist, but the data are not sufficient for classificationAll data are

Rat

Rat

Rat

Rat

Rat

Rat

Rat

Species Test result Exposure Duration

Species Test result Exposure Duration

nonafluoroisobutyl ether








Ingestion

Ingestion

Inhalation

Inhalation

Inhalation

Ingestion

Ingestion

endocrine system | hematopoietic system | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory systemendocrine system | liver

heart | hematopoietic system | immune system | nervous system | eyes | kidney and/or bladder | respiratory systemliver

bone, teeth, nails, and/or hair

heart | skin | endocrine system | hematopoietic system | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory systemendocrine system | liver

heart | hematopoietic system | immune system | nervous system | eyes | kidney and/or bladder | respiratory system

negative

Some positive data exist, but the data are not sufficient for classificationAll data are negative

Some positive data exist, but the data are not sufficient for classificationSome positive data exist, but the data are not sufficient for classificationAll data are negative

Some positive data exist, but the data are not sufficient for classificationAll data are negative

Rat

Rat

Rat

Rat

Rat

Rat

Rat

mg/l



NOAEL 155 mg/l

NOAEL 129 mg/l

NOAEL 155 mg/l



28 days

28 days

13 weeks

11 weeks

13 weeks

28 days

28 days

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Aspiration HazardNameMethyl nonafluoroisobutyl etherMethyl nonafluorobutyl ether

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labeling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.

12.1. Toxicity

Acute aquatic hazard:Not acutely toxic to aquatic life by GHS criteria.

Chronic aquatic hazard:Not chronically toxic to aquatic life by GHS criteria.

No component test data available.

Material Organism TypeAcota™ Certonal™FC-742 Electronic Grade CoatingAcota™ Certonal™FC-742 Electronic Grade CoatingAcota™ Certonal™FC-742 Electronic Grade Coating

12.2. Persistence and degradabilityNo test data available.

12.3 : Bioaccumulative potentialNo test data available.

12.4. Mobility in soilPlease contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effectsNo information available.

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Fathead minnow Laboratory

Green algae

Water flea

Laboratory

Laboratory

Exposure Test endpoint Test result96 hours

96 hours

48 hours

ValueNot an aspiration hazardNot an aspiration hazard

LC50

IC50

EC50

>7.9 mg/l

>8.9 mg/l

>10 mg/l


SECTION 13: Disposal considerations

13.1 Waste treatment methodsDispose of contents/ container in accordance with the local/regional/national/international regulations

This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of Acota, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/EC and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor.

EU waste code (product as sold)070103*14 06 02*

SECTION 14: Transportation information

FC-742

Not hazardous for transportation

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory statusContact Acota for more information.

15.2. Chemical Safety AssessmentNot applicable

SECTION 16: Other information

Revision information:Revision Changes:Aspiration Hazard Table was modified.Section 11: Acute Toxicity table was modified.Carcinogenicity Table was modified.Serious Eye Damage/Irritation Table was modified.Germ Cell Mutagenicity Table was modified.Skin Sensitisation Table was modified.Respiratory Sensitisation Table was modified.Reproductive Toxicity Table was modified.Skin Corrosion/Irritation Table was modified.Target Organs - Repeated Table was modified.Target Organs - Single Table was modified.Section 11: Lactation table heading was deleted.Lactation Table was deleted.Section 11: Lactation table - Name heading was deleted.Section 11: Lactation table - Route heading was deleted.

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Organic halogenated solvents, washing liquids and mother liquorsOther halogenated solvents and solvent mixtures


Section 11: Lactation table - Species heading was deleted.Section 11: UN GHS Classification table heading was deleted.Section 11: Lactation table - UN GHS Classification heading was deleted.Section 11: Lactation table - Value heading was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.

Acota United Kingdom MSDSs are available at www.acota.co.uk

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