SECA Poster 2014...SECA Poster 2014.pptx Author: Lara-Curzio, Edgar Created Date: 20140722153605Z...
Transcript of SECA Poster 2014...SECA Poster 2014.pptx Author: Lara-Curzio, Edgar Created Date: 20140722153605Z...
Composite seals can be designed to exhibit a range of viscosity values to perform over the large temperature gradients experienced by SOFCs and with necessary compliance to accommodate stack displacements, par>cularly for cells with large ac>ve surface area, which might not be flat or parallel. Characteriza+on of mul+component silicate glasses
The effect of >me of exposure (in air or in a gas mixture of H2+N2+H2O) on the microstructure and chemical composi>on of two mul>component silicate glasses (SCN and G6) is being inves>gated for >mes of exposure in excess of 25,000 hrs.
The kine>cs of precipita>on of crystalline phases (e.g., BaO, KAlSi3O8, MgCaSi2O6, CaSiO3) have been determined, along with the evolu>on of the distribu>on of pore sizes.
SCN: SEM-‐COM Co. Inc., Toledo, OH 43623. G6: Whatman, Piscataway, NJ 08855
Silicate Glass Composite Seals for SOFCs E. Lara-‐Curzio, V. Garcia-‐Negron, D. McClurg, S. Waters and A. Shyam.
Materials Science & Technology Division, Oak Ridge Na>onal Laboratory, Oak Ridge, TN 37831-‐6062
Y-‐S Chou and J. Stevenson Pacific Northwest Na>onal Laboratory, Richland, WA 99354
Acknowledgments. Research sponsored by the US Department of Energy, Office of Fossil Energy, SECA Core Technology Program at ORNL under Contract DEAC05-‐00OR22725 with UT-‐Bahelle, LLC. Contributors include Beth Armstrong and John Henry of ORNL.
Mixtures of SCN or G6 glasses, frangible zirconium oxide par>cles or fibers and an organic binder (polylac>de acid) have been blended to achieve homogeneous and uniform composi>ons, which can be subsequently extruded and deposited by fused deposi>on.
Background Crystalliza>on-‐resistant glasses are being considered for SOFC sealing applica>ons because of their self-‐healing characteris>cs and ability to relax thermal stresses via viscous flow. Furthermore, their chemical composi>on and physical and mechanical proper>es can be tailored to match SOFC designs requirements. Here we present results from the characteriza>on of Engineered Glass Seals, consis>ng of a crystalliza>on-‐resistant glass matrix and a ceramic frangible, compliant second phase.
Large in-‐plane and axial temperature gradients exist in SOFC stacks during opera>on.
Effect of >me of exposure on the viscosity of SCN glass (top) and microstructural evolu>on of SCN and G6 glasses sintered onto YSZ substrates (lek).
Engineered composite seals Engineered seals consis>ng of a mul>-‐component silicate glass matrix and zirconia-‐based frangible par>cles or ceramic fibers have been developed. Their welng behavior and thermophysical proper>es have been characterized as a func>on of temperature and concentra>on of second phase.
Viscosity of composite seals as a func>on of temperature and concentra>on of second phase (top) and scanning electron micrograph (bohom).
Summary Engineered composite seals, consis>ng of a mul>component silicate glass matrix and zirconia-‐based second phase (frangible par>cles or fibers) have been developed for SOFCs. Their physical proper>es (e.g., compliance, viscosity, thermal expansion) can be tailored to address the wide distribu>on of temperatures experienced by SOFCs and to seal cells with large ac>ve surface area, which might not be parallel or flat. The effect of >me of exposure (in air or in a gas mixture of H2+N2+H2O) on the microstructure and chemical composi>on of two mul>component silicate glasses has been studied for >mes of exposure in excess of 25,000 hrs. Low-‐cost manufacturing procedures are being developed, including fused deposi>on, which provides a means for prin>ng seals with a spa>al distribu>on of viscosity values and high material u>liza>on.
SCN G6
25,000 hrs
H2+H2O+N2 H2+H2O+N2
in progress in progress
Extruded filament consis>ng of polyac>de acid, SCN glass and frangible ceramic par>cles for fused deposi>on
Engineered glass seals have also been successfully manufactured by tape cas>ng and screen prin>ng. The figure on the right shows a screen-‐printed seal consis>ng of G6 glass and frangible YSZ par>cles between two 8YSZ tapes.