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Scott Michael Grayson, Ph.D. (updated May 2015)

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Department of Chemistry Tulane University

2015 Percival Stern Hall New Orleans, LA 70118-5698

(504) 862-8135 (office) (504) 865-5596 (fax)

sgrayson@tulane.edu

Education & Training:

2002-2005 Post-doctoral research associate, University of Texas, Austin, Advisor: C. Grant Willson

2002 Ph.D., Polymer Chemistry, University of California, Berkeley, Advisor: Jean M.J. Fréchet

1998 M.Phil., Archaeological Chemistry, University of Bradford, UK, Advisor: Carl. P. Heron

1996 B.S., Chemistry and Mathematics, Tulane University

1996 B.A., History Tulane University

Professional Positions:

2012-present Associate Professor of Chemistry, Tulane University, New Orleans, LA

2005-2012 Assistant Professor of Chemistry, Tulane University, New Orleans, LA

Aug-Dec 2005 Visiting Professor of Chemistry, Washington University, St. Louis, MO

● Temporary position during evacuation on account of Hurricane Katrina

Awards and Recognition (since 1996)

2015 Front Cover, Journal of Polymer Science A: Polymer Chemistry 2015 Visiting Scholar, Tokyo Institute of Technology, Tokyo, JAPAN 2014 March Front Cover, Journal of the American Society for Mass

Spectrometry 2014 Weiss Presidential Fellow for Undergraduate Teaching (1 of 2 awarded across all schools at Tulane University) 2013 Spotlighted Article, Journal of Polymer Science Part A: Polymer Chemistry 2012 The Mortar Board Award for Excellence in Teaching (Non-tenured) 2011 Duren Professorship (for innovation in undergraduate teaching) 2011 Tulane Graduate Student Association Outstanding Teaching

Award (School of Science and Engineering) 2011 RSC Polymer Chemistry “Author of the Week” (February 25),

Royal Society of Chemistry 2011 Emerging Faculty Travel Award (visit to NSF), LA BOR 2011 Emerging Investigator, Royal Soc.Chem. Polymer Chemistry 2010 April Front Cover, Journal of Mass Spectrometry 2010 Top 10 Most Cited Article (from 2008), Macromolecules

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2010 Emerging Faculty Travel Award, (invited IUPAC lecture) LA Board of Regents 2009 Top 10 Most Downloaded Article (Oct 2009), Macromolecules 2009 NSF CAREER Award Recipient, NSF-Division of Materials Research 2008 Presidential Early Career Development Award, Tulane University 2007 Top 20 Most Cited Article (from 2006), Journal of the American

Chemical Society 2006 Ralph E. Powe Junior Faculty Enhancement Award, Oak Ridge

Assoc. Univ. 1996-2000 National Science Foundation Predoctoral Fellowship, NSF 1998 Outstanding Graduate Instructor Award, UC Berkeley 1996 Merck Index Award for Excellence in Chemistry, Tulane

Professional Positions, Service, and Memberships:

Professional Positions:

● Editorial Advisory Board, Journal of Macromolecular Science, Pure and Applied Chemistry (2008-present) ● Editorial Advisory Board, Reactive and Functional Polymers (2011-present)

Professional Service:

● Pacifichem 2015 symposium co-organizer: “Cyclic and topological polymers” (Honolulu, HI, 2015) ● ACS National Meeting symposium co-organizer: “Cyclic and multicyclic polymers” (joint PMSE and Polymer Division; New, Orleans, LA, April 2013) ● ACS National Meeting symposium co-organizer: “Polyoxazolines” (Polymer Division; San Diego, CA, March 2012) ● International Dendrimer Symposium 7, Co-organizer (Washington, DC, June 2011) ● ACS Southeastern/Southwestern Conference symposium organizer “Dendrimers and Cyclic Polymers” (New Orleans, LA; December 2010) ● ACS National Meeting symposium organizer: “Drug Delivery Systems” (Polymeric Materials Science and Engineering Division (New Orleans, LA; April 2008) ● Gordon Conference: Polymers, Discussion Leader “Polymers for Biomedical Applications” (Mount Holyoke, MA, June 2007)

Memberships: American Chemical Society, Polymer Division (1998-present); American

Chemical Society, Polymeric Materials: Science and Engineering Division (2003-present); American Society for Mass Spectrometry (2009-present).

Journal Referee (~# of manuscripts reviewed per journal) since 2006: Over 100 reviews for the following journals: Accounts of Chemical Research (1), ACS MacroLetters (3), Analytical Chemistry (1), Bioconjugate Chemistry (1), Biomacromolecules (3), Chemical Communications (4), Chemistry: A European Journal (1), The European Journal of Pharmaceutics and Biopharmaceuticals (1), High Performance Polymers (1), Journal of the American Chemical Society (27), Journal of the American Society of Mass Spectrometry (1), Journal of Organic Chemistry (3), Journal of Macromolecular Science: Pure and Applied Chemistry (9), Journal of Molecular Recognition (1), Journal of Polymer Science Part A: Polymer Chemistry (12), Journal of Polymer Science Part B: Polymer Physics (1); Langmuir (2), Macromolecular Chemistry and Physics (1), Macromolecular Rapid Communications (4),

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Macromolecules (21), Molecular Pharmaceutics (1), Nature Chemistry (2), Organic and Biomolecular Chemistry (1), Organic Letters (4), Pharmaceuticals (2), Polymer (3), Polymer Bulletin (1), Polymer Chemistry (2), Progress in Polymer Science (2), Rapid Communications in Mass Spectrometry (2), Reactive and Functional Polymers (3), Tetrahedron (2)

Grant Reviewer (# of grants reviewed per organization) since 2006 Total of 22 grants reviewed for the following organizations: National Science Foundation (11), Hong Kong Research Grants Council (4) American Chemical Society, Petroleum Research Fund (4), Cottrell Scholar, Research Corporation (2), Israel Science Foundation (1)

Consulting:

Legal Expert Witness:

Manufacturing Defect Case: Alan Shear and Carol Shear vs. Wellborn Cabinet, Inc. and Huey Brown’s Kitchen and Flooring Inc. Phelps & Dunbar, New Orleans, LA Sept 2010 - Jan 2011: Expert report and deposition on stains within polymeric paint/varnish. Case settled, May 2011. Patent Litigation Case: Kaneka Corporation vs. JBS Hair, Inc., UNO Company, Ltd. And Jinny Beauty Supply Company, Inc. Fenwick & West, San Francisco, CA Jan 2012 – Jun 2013: Expert witness in patent litigation case. (ongoing)

Corporate Consulting:

Sigma-Aldrich, Polymer Division, St. Louis, MO 2012-present: MALDI-TOF MS analysis/quality control of polymers prepared for commercial sale. July 2012-present

Service:

University/School: ● Member, SSE Alumni relations committee (2007-2012) ● Member, Newcomb Fellows grant review committee (2009-present) ● Member, Goldwater Fellowship nomination committee (2009-2010) ● Member, Graduate affairs committee (2013-present) ● Study abroad advisor, Chemistry department (2010-present) ● Member Honorary degrees committee (2014-present) ● Member, Selection Committee for the President’s Awards for Excellent Teaching (2015-present)

Department: ● Member, Chemistry faculty search committee (2006-2007) ● Member, Chemistry graduate student recruiting committee (2006-present) ● Faculty Co-organizer, Chemistry web page redesign (2005-2006) ● Member, Chemistry faculty search committee (2010-2011) ● Faculty Co-organizer, Chemistry web page redesign (2010-2011) Community:

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● Service Learning “Chemistry in the Community” Course (Spr 2007, Spr 2008, Spr 2009, Spr 2010, Spr 2011, Spr 2012, Spr 2013, Spr 2014, Spr 2015) ● Judge, Iberville Parish Science Fair (2008) ● Judge, St. James Parish Science Fair (2009)

Publications:

Submitted: Riggs, Brian C.; Elupula, Ravinder; Shipman, Joshua T.; Grayson, Scott M.; Chrisey, Douglas B. “The effects of aromatics in thiol-ene click polymer networks on energy storage properties.” J. Mater. Sci. submitted.

Ejaz, Muhammad; Alb, Alina M.; Kosakowska, Karolina, A.; Grayson, Scott M. “Silica nanoparticles with amphiphilic polymer grafts: stable ‘nanoparticle micelles’ for encapsulation of hydrophobic guests.” submitted. Accepted: 108) Riggs, Brian C.; Elupula, Ravinder; Rehm, Carolyn; Adireddy, Shiva; Grayson, Scott M.; Chrisey, Douglas B. “Click in ferroelectronic nanoparticles for dielectric storage.” ACS Applied Materials & Interfaces, 2015, in press

Published: 107) Foley, Casey D.; Zhang, Boyu; Alb, Alina M.; Trimpin, Sarah; Grayson, Scott M. “The use of ion mobility spectrometry-mass spectrometry to elucidate architectural dispersity within star polymers.” ACS Macro Letters 2015, 4, in press http://dx.doi.org/10.1021/acsmacrolett.5b00299

106) Cortez, M. A.; Godbey, W T.; Fang, Y.; Payne, M. E.; Cafferty, B. J.; Kosakowska, K. A.; Grayson, S. M. “The synthesis of cyclic poly(ethylene imine) and exact linear analogs: an evaluation of gene delivery comparing polymer architectures.” J. Am. Chem. Soc. 2015, 137, 6541-6549. http://dx.doi.org/10.1021/jacs.5b00980

105) Boertz, J.; Grayson, S. M. Malkoch, M. “SpheriCal® - Monodisperse polyester dendrimers as universal mass calibrants in MALDI-mass spectrometry.” Analytix 2015, 2, 16-17.

104) Wang, Jing; Li, Zhaolei; Perez, Ricardo A.; Muller, Alejandro J.; Zhang, Boyu; Grayson,

Scott M.; Hu, Wenbing “Comparing crystallization rates between linear and cyclic poly(-caprolactones) via fast-scan chip calorimeter measurements.” Polymer 2015 63, 34-40. http://dx.doi.org/10.1016/j.polymer.2015.02.039

103) Ejaz, Muhammad; Puli, Venkata S.; Elupula, Ravinder; Adireddy, Shive; Riggs, Brian C.; Chrisey, Douglas B.; Grayson, Scott M. “Core-shell structured poly(glycidyl methacrylates)/BaTiO3 nanocomposites prepared by surface-initiated atom transfer radical polymerization: A novel material for high energy density dielectric storage.” J. Polym. Sci. A.; Polym. Chem. 2015, 53, 719-728. (featured front cover for March 15th 2015 issue.) http://dx.doi.org/10.1002/pola.27485

102) Xu, Zejing,; Li, Yejia; Zhang, Boyu; Purkait, Tapas; Alb, Alina; Mitchell, Brian S.; Grayson, Scott M.; Fink, Mark “Water-soluble PEGylated silicon nanoparticles and their assembly into

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swellable nanoparticle arrays” Journal of Nanoparticle Research, 2015, 11, 56. http://dx.doi.org/10.1007/s11051-015-2869-9

101) Adireddy, Shiva; Puli, Venkata S.; Sklare, Samuel C.; Lou, Tiffany J.; Riggs, Brian C.; Elupula, Ravinder; Grayson, Scott M.; Chrisey, Douglas B. “PVDF-BaSrTiO3 nanocomposites for flexible electrical energy storage devices.” Emerging Mater. Res. 2014 e-published. http://dx.doi.org/10.1680/emr.14.00013

100) Riggs, Brian C.; Elupula, Ravinder; Grayson, Scott M.; Chrisey, Douglas B. “Photonic curing of aromatic thiol-ene click dielectric capacitors via inkjet printing.” J. Mater. Chem A, 2014, 2, 17380-17386. http://dx.doi.org/10.1039/C4TA04030A

99) Perez, Ricardo A.; Lopez, Juan V.; Hoskins, Jessica N.; Zhang, B.; Grayson, Scott M.; Casas, Maria T.; Puiggali, J.; Muller, Alejandro J. “Nucleation and antinucleation effects of

functionalized carbon nanotubes on cyclic and linear poly(-caprolactones)” Macromolecules, 2014, 47, 3553-3566. http://dx.doi.org/10.1021/ma5005869

98) Puli, Venkata S.; Elupula, Ravinder, Riggs, Brian C.; Grayson, Scott M.; Katiyar, Ram S.; Chrisey, Doug B. “Surface modified BaTiO3-polystyrene nanocomposites for energy storage.” Int. J. Nanotechnol. 2014, 11, 910-920. http://dx.doi.org/10.1039/C4CC01372G

97) Liu, L.; Parameswaran, S.; Grayson, S. M.; Ashbaugh, H. S.; Rick, S. W. “Molecular dynamics simulations of linear and cyclic amphiphilic polymers in aqueous and organic environments” J. Phys Chem B. 2014, 118, 6491-6497. http://dx.doi.org/10.1021/jp412184h

96) Sreerama, Subramanya, G.; Elupula, R.; Laurent, Boyd A.; Grayson, Scott M. “Use of MALDI-ToF MS to elucidate the structure of oligomeric impurities formed during ‘click’ cyclization of polystyrene” React. Func. Polym. 2014, 80, 83-94 (special issue on cyclic polymers) http://dx.doi.org/10.1016/j.reactfunctpolym.2014.01.013

95) Pérez, Richardo A.; Córdova, Miguel E.; López, J.; Hoskins, Jessica N.; Zhang, Boyu; Grayson, Scott M.; Müller, Alejandro J. “Nucleation, crystallization, self-nucleation and thermal

fractionation of cyclic and linear poly(-caprolactone)s” React. Func. Polym. 2014, 80, 71-82. (special issue on cyclic polymers) http://dx.doi.org/10.1016/j.reactfunctpolym.2013.10.013

94) Ejaz, Muhammad.; Rai, Satish C.; Wang Kai; Zhang, Karen; Zhou, Weilie; Grayson, Scott M. “Surface initiated atom transfer radical polymerization of glycidyl methacrylate and styrene from boron nitride nanotubes.” J. Mater. Chem. C. 2014, 2, 4073-4079. http://dx.doi.org/10.1039/C3TC32511C

93) Zhang, Boyu; Zhang, Hong; Myers, Brittany M.; Elupula, Ravinder; Jayawickramarajah, Janarthanan; Grayson, Scott M. “Determination of polyethylene glycol end group functionalities by combination of selective reactions and characterization by matrix assisted laser desorption/ionization time of flight mass spectrometry.” Anal. Chim. Acta. 2014, 816, 28-40. http://dx.doi.org/10.1016/j.aca.2014.01.039

92) Zhang, Hong; Zhang, Boyu; Zhu, Mengyuan; Grayson, Scott M.; Schmehl, R. H.; Jayawickramarajah, Janarthanan. “Water-soluble porphyrin nanospheres: enhanced photo-physical properties via cyclodextrin driven double self-inclusion.” Chem. Commun. 2014, 50, 4853-4855. http://dx.doi.org/10.1039/C4CC01372G.

91) Zhang, Boyu; Zhang, Hong; Elupula, Ravinder, Alb, Alina M.; Grayson, Scott M. “Efficient Synthesis of High Purity Homo-arm and Mikto-arm Poly(ethylene Glycol) Stars Using Epoxide and Azide-Alkyne Coupling Chemistry” Macromol. Rapid Commun. 2014, 35, 146-151.

http://dx.doi.org/10.1002/marc.201300623

90) Grayson, Scott M.; Myers, Brittany K.; Bengtsson, Jonas; Malkoch, Michael “Advantages of Monodisperse and Chemically Robust “SpheriCal” Polyester Dendrimers as a “Universal” MS

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Calibrant. J. Am. Soc. Mass Spectrom. 2014, 25, 303-309: http://dx.doi.org/10.1007/s13361-

013-0777-8

- Featured front cover for March 2014 issue.

89) Myers, Brittany K.; Zhang, Boyu; Lapucha, Joanna E.; Grayson, Scott M. “The Characterization of Dendronized Poly(ethylene Glycol)s and Poly(ethylene Glycol) Multiarm Stars Using Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry.” Anal. Chim. Acta, 2014, 808, 175-189. http://dx.doi.org/10.1016/j.aca.2013.09.038

88) Wang, Yi; Alb, Alina M.; He, Jibao; Grayson, Scott M.”Neutral Amphiphilic Linear Homopolymers Prepared by Atom Transfer Radical Polymerization” Polym. Chem., 2014, 5, 622-629. http://dx.doi.org/10.1039/C3PY00916E

87) Myers, Brittany K.; Lapucha, Joanna E.; Grayson, Scott M. “Synthesis and MALDI ToF MS Characterization of Dendronized Poly(ethylene Glycols)” Brazil. J. Pharm. Sci. 2013, 49, 45-55.

86) Zhang, Boyu; Zhang, Hong; Li, Yejia; Hoskins, Jessica N.; Grayson, Scott M. ”Exploring the Effect of Amphiphlic Polymer Architecture: Synthesis, Characterization and Self-assembly of Both Cyclic and Linear Poly(ethylene glycol)-b-Polycaprolactone” ACS MacroLetters, 2013, 2,

845-848. http://dx.doi.org/10.1021/mz4003936

85) Zhang, Boyu, Grayson Scott M. “The ring-closure approach for synthesizing cyclic polymers” in Topological Polymer Chemistry: Progress of Cyclic Polymers in Synthesis, Properties and Functions, Tezuka, Y., Ed.; World Scientific Publishing, 2013, 157-197.

http://dx.doi.org/10.1142/9789814401289_0010

84) Ejaz, Muhammad.; Sunkara, Bhanukiran; Kamboj, Lakhinder; He, Jibao; John, Vijay T.; Pesika, Noshir S.; Grayson, Scott M. “A Facile One-Pot Method of Initiator Fixation for Surface-Initiated Atom Transfer Radical Polymerization on Carbon Hard Spheres.” J. Polym. Sci. Part

A, Polym. Chem. 2013, 51, 3314-3322. http://dx.doi.org/10.1002/pola.26728

83) Trimpin, S.; Li, J.; Grayson, S. M. Separation and characterization of cyclic and linear polymers by matrix assisted ionization vacuum (MAIV)-ion mobility spectrometry (IMS)-mass spectrometry (MS). Polym. Mater. Sci. Eng., 2013.

82) Grayson, S. M.; Zhang, B.; Elupula, R.; Cortez, M. A.; Laurent, B. A. Exploring the versatility of click chemistry in making cyclic polymers. Polym. Mater. Sci. Eng., 2013.

81) Elupula, R.; Laurent, B.; Grayson, S. M. Multi-arm globes via “click” coupling. Polym. Mater. Sci. Eng., 2013.

80) Zhang, B.; Zhang, H.; Hoskins, J.; Grayson, S. M. Exploring the effect of amphiphilic architecture: Synthesis, Characterization and Assembly of both Cyclic and Linear Poly(ethylene glycol)-b-polycaprolactone. Polym. Mater. Sci. Eng., 2013.

79) Ejaz, M.; Rai, S. Wang, K.; Zhou, W.; Grayson, S. M. Surface-initiated Atom Transfer Radical Polymerization onto Boron Nitride Nanotubes. Polym. Mater. Sci. Eng., 2013.

78) Wang, Y.; Grayson, S. M. Amphiphilic homopolymers prepared by ATRP. Polym. Mater. Sci. Eng., 2013.

77) Zhang, B.; Zhang, H.; Grayson, S. M. Tadpole-shaped amphiphilic poly(ethylene glycol)-b-polycaprolactone copolymer polymer prepared by ring-opening polymerization and click chemistry. Polym. Mater. Sci. Eng., 2013.

76) Zhang, B.; Zhang, H.; Hoskins, J. N.; Grayson, S. M. Synthesis of well-defined cyclic brush polymers by combination of atom transfer radical polymerization and click chemistry. Polym. Mater. Sci. Eng., 2013.

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75) Ejaz, M.; Sunkara, B.; Kamboj, L; John. V. T.; Pesika, N. S.; Grayson, S. M. One-pot method of immobilization of initiator on carbon hard spheres for surface-initiated atom transfer radical polymerization. Polym. Mater. Sci. Eng., 2013.

74) Muller, A. J.; Sun, H.; Chen, H.; Diaz, A.; Casas, M.; Puiggali, J.; Hoskins, J.; Grayson, S.; Perez, R. Crystallization kinetics and morphology of cyclic PCL: The determinating role of supercooling. Polym. Mater. Sci. Eng., 2013.

73) Myers, B.; Grayson, S. M. Star-dendritic-linear polymers as a modular platform to probe unimolecular micelles. Polym. Prepr., 2013.

72) Eugene, Dawanne M.; Grayson, Scott M. “Unimolecular Micelles for Drug Delivery” in Encyclopedia of Supramolecular Chemistry, Atwood, J. L; Steed, J. W.; Wallace, K. J., Eds.; Taylor and Francis; New York. 2012.

71) Yol, Aleer M.; Dabney, David E.; Wang, Shin-Fan; Laurent, Boyd A.; Foster, Mark. D.; Quirk, Roderick P.; Grayson, Scott M.; Wesdemiotis, C. “Differentiation of Linear and Cyclic Polymer Architectures by MALDI Tandem Mass Spectrometry (MALDI-MS2)” J. Am. Soc. Mass

Spectrom. 2013, 24, 74-82. http://dx.doi.org/10.1007/s13361-012-0497-5

70) Su, Hsuan-Han; Chen, Hsin-Lung; Diaz, Angelica, Casas, Maria T.; Puiggali, Jordi; Hoskins, Jessica, N.; Grayson, Scott M.; Pérez, Ricardo A.; Müller, Alejandro, J. “New insights on the crystallization and melting of cyclic PCL chains on the basis of a modified Thomson-Gibbs

equation.” Polymer 2013, 54, 846-859. http://dx.doi.org/10.1016/j.polymer.2012.11.066

69) Elupula, Ravinder; Laurent, Boyd A. Grayson Scott M. “Advances in the Synthesis of Cyclic Polymers” in Synthesis of Polymers, Schlüter, A. D.; Hawker, C. J.; Sawamoto, J., Eds.; Wiley

VCH, 2012, 351-372. http://dx.doi.org/10.1002/9783527603978.mst0422

68) Li, Yejia; Zhang, Boyu; Hoskins, Jessica N.; Grayson, Scott M. Synthesis, Purification and Characterization of “Perfect” Star Polymers via “Click” Coupling. J. Polym. Sci. A: Polym.

Chem. 2012, 50(6), 1086-1101. http://dx.doi.org/10.1016/j.addr.2012.03.011

67) Wang, Yi; Grayson, Scott M. Approaches for the Preparation of Non-linear Amphiphilic Polymers and their Applications to Drug Delivery. Adv. Drug Deliv. Rev. 2012, 64(9), 852-865.

66) Grayson, Scott M. A Simple Visualization of Double Bond Properties: Chemical Reactivity and UV Fluorescence. J. Chem. Ed. 2012, 89, 925-927.

http://dx.doi.org/10.1021/ed200627c

65) Laurent, Boyd A.; Grayson, Scott M. Synthesis of Cyclic Amphiphilic Homopolymers and Their Potential Applications as Polymeric Micelles. Polymer Chemistry 2012, 3, 1846-1855;

http://dx.doi.org/10.1039/c1py00378j

64) Ejaz, Muhammad; Yu, Haini; Yan, Yong; Blake, Diane A.; Ayyala, Ramesh S.; Grayson, Scott M. Evaluation of Redox-Responsive Disulfide Cross-linked Poly(hydroxyethyl methacrylate) Hydrogels. Polymer 2011, 52, 5262-5270.

http://dx.doi.org/10.1016/j.polymer.2011.09.018

63) Hoskins, Jessica N.; Trimpin, Sarah; Grayson, Scott M. Architectural Differentiation of Linear and Cyclic Polymeric Isomers by Ion Mobility Spectrometry-Mass Spectrometry.

Macromolecules, 2011, 44, 6915-6918. http://dx.doi.org/10.1021/ma2012046

62) Laurent, Boyd A.; Grayson, Scott M. Synthesis of Cyclic Dendronized Polymers via Divergent "Graft-from" and Convergent Click "Graft-to" Routes: the Preparation of Modular Toroidal Macromolecules. J. Am. Chem. Soc., 2011, 133, 13421-13429.

http://dx.doi.org/10.1021/ja2024355

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61) Li, Yejia; Giles, Marco D.; Liu, Simin; Laurent, Boyd A.; Hoskins, Jessica N.; Cortez, Mallory A.; Sreerama, Subramanya G.; Gibb, Bruce, C.; Grayson, Scott M. A Versatile and Modular Approach to Functionalisation of Deep-cavity Cavitands via “Click” Chemistry. Chem.

Commun., 2011, 9036-9038. http://dx.doi.org/10.1039/c1cc11259g

60) Córdova, Miguel E.; Lorenzo, Arnaldo T.; Müller, Alejandro J.; Hoskins, Jessica N.;

Grayson, Scott M. Caracterización Térmica de Policaprolatonas Cíclicas y Lineales. Rev. Latin Am. Metal. Mat., 2011, S3, 46-47. 59) Poree, Dawanne E.; Giles, Marco D.; Lawson, Louise B.; He, Jibao; Grayson, Scott M. Synthesis of Amphiphilic Star Block Copolymers and their Evaluation as Transdermal

Carriers. Biomacromolecules, 2011, 12, 898-906. http://dx.doi.org/10.1021/bm101185t 58) Córdova, Miguel E.; Lorenzo, Arnaldo T.; Müller, Alejandro J.; Hoskins, Jessica N.; Grayson, Scott M. A Comparative Study on the Crystallization Behavior of Analogous

Linear and Cyclic Poly-Caprolactones). Macromolecules, 2011, 44, 1742-1746.

http://dx.doi.org/10.1021/ma200394h

57) Hoskins, Jessica N. Grayson, Scott M. Cyclic Polyesters: Synthetic Approaches and Potential Applications. Polym. Chem., 2011, 2, 289-299.

http://dx.doi.org/10.1039/c0py00102c

56) Cortez, Mallory A.; Grayson Scott M. Application of Time Dependent MALDI-TOF Mass Spectral Analysis to Elucidate Chain Transfer Mechanism during Cationic Polymerization of Oxazoline Monomers Containing Thioethers. Macromolecules, 2010, 43, 10152-10156.

http://dx.doi.org/10.1021/ma1019736

55) Li, Y.; Hoskins, J. N.; Sreerama, S. G.; Grayson S. M. MALDI-TOF MS Characterization of Polymers Containing an Azide Group: Evidence for Metastable Ions. Macromolecules, 2010,

41, 6225-6228. http://dx.doi.org/10.1021/ma100599n

54) Li, Y.; Hoskins, J. N.; Sreerama, S. G.; Grayson, M. A.; Grayson, S. M. The Identification of Synthetic Homopolymer End Groups and Verification of their Transformations Using MALDI-TOF Mass Spectrometry. J. Mass Spectrom., 2010, 45, 587-611.

http://dx.doi.org/10.1002/jms.1743

- Featured front cover for June 2010 issue.

53) Cortez, M. A.; Grayson S. M. The Thiolene Click Functionalization and Subsequent Polymerization of 2-Oxazoline Monomers. Macromolecules, 2010, 43, 4081-4090.

http://dx.doi.org/10.1021/ma9028294

52) Eugene, D. M.; Grayson, S. M.; Giles, Marco D. Characterization and Evaluation of Dendritic Star Block Copolymer via ATRP for Use as Transdermal Drug Delivery Agents. Polym. Prepr., 2010, 51, 99-100.

51) Cortez, M. A.; Grayson, S. M. Functional Group Modification and Subsequent Polymerization of 2-Oxazoline Monomers via Thiol-ene Click Chemistry. Polym. Prepr., 2010, 51, 103-104.

50) Cortez, M. A.; Grayson, S. M.; Cafferty, B. J. Synthesis and Characterization of Cyclic 2-Substituted Oxazoline Polymers. Polym. Prepr., 2010, 51, 466-467.

49) Eugene, D. M.; Grayson, S. M. Synthesis and Characterization of Cyclic Amphiphilic Block Copolymers via ATRP and Click Chemistry. Polym. Prepr., 2010, 51, 460-461.

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48) Li, Y.; Grayson, S. M.; Giles, M. D. Preparation of Well-defined and High Purity Star Polymers. Polym. Prepr., 2010, 51, 555-556.

47) Li, Y.; Giles, M. D.; Liu, S.; Gibb, B. C.; Grayson, S. M. Functionalization of Deep-Cavity Cavitand with Polymer Side Chains. Polym. Prepr., 2010, 51, 526-527.

46) Grayson, S. M.; Laurent, B. A.; Hoskins, J. N.; Eugene, D. M.; Sreerama, S. G.; Cortez, Mallory A. Using Click Chemistry to Diversity the Functionally and Architecture of Cyclic Polymers. Polym. Mater. Sci. Eng., 2010, 102, 660-670.

45) Grayson, S. M.; Gibb, B. C. Dendronized Cavitands: A Step towards a Synthetic Viral

Capsid? Soft Matter, 2010, 6, 1377-1382. http://dx.doi.org/10.1039/b921935h

44) Hoskins, J. N.; Grayson, S. M. Synthesis and Degradation Behavior of Cyclic Poly(-

Caprolactone) Macromolecules, 2009, 42, 6406-6413.http://dx.doi.org/10.1021/ma9011076

- 10th most read Macromolecules paper of the month (of ~150) - Oct 2009. - 40th most cite Macromolecules paper from 2009 (of 1290) - Jan 2012.

43) Laurent, Boyd A.; Grayson, Scott M. Synthetic Approaches for the Preparation of Cyclic

Polymers. Chem. Soc. Rev. 2009, 38, 2202-2213. http://dx.doi.org/10.1039/b809916m

42) Grayson, Scott M. Polymers Kept in the Loop. (News and Views) Nature Chemistry, 2009,

1, 178-179. http://dx.doi.org/10.1038/nchem.226

41) Giles, Marco D.; Liu, Simin; Emanuel, Roy L.; Gibb, Bruce, C.; Grayson, Scott M. Divergent Dendronization of Deep-Cavity Cavitands to Tune Host Solubility. Israel J. Chem., 2009, 49,

31-40. http://dx.doi.org/10.1560/IJC.49.1.31

- Invited, “Dendrimers and Related Compounds” special issue

40) Giles, Marco D.; Liu, Simin; Emanuel, Roy L.; Gibb, Bruce C.; Grayson, Scott M. Dendronized Supramolecular Nano-capsules: pH Independent, Water-Soluble Deep Cavity Cavitands Assemble via the Hydrophobic Effect. J. Am. Chem. Soc. 2008, 130, 14430-14431.

http://dx.doi.org/10.1021/ja806457x

39) Eugene, Dawanne M.; Grayson, Scott M. Efficient Preparation of Cyclic Poly(methylacrylate)-block-Poly(styrene) by Combination of Atom Transfer Radical Polymerization and Click Cyclization. Macromolecules, 2008, 41, 5082-5084.

http://dx.doi.org/10.1021/ma800962z

- 10th most cited Macromolecules paper from 2008 (of 1382) - Mar 2010. - Featured article in special “Virtual Issue” of Macromolecules, 2009, vi: http://pubs.acs.org/page/mamobx/vi/1

38) Grayson, Scott M.; Godbey, W T. The Role of Macromolecular Architecture in Passively Targeted Polymer Carriers for Drug and Gene Delivery. J. Drug Targeting, 2008, 15, 529-553.

37) Cortez, Mallory A.; Grayson, Scott M. Synthesis and Characterization of Star Oxazoline Polymer Structures. Polym. Mater. Sci. Eng., 2008, 98, 436-437.

36) Cortez, Mallory A.; Grayson, Scott M. Synthesis of 2-Hydroxyethyl Acrylate-2-Oxazoline Block Copolymers Utilizing Click Chemistry. Polym. Mater. Sci. Eng., 2008, 98, 438-439.

35) Eugene, Dawanne, M.; Grayson, Scott M. Cyclization of Amphiphilic Block Copolymers. Polym. Mater. Sci. Eng., 2008, 98, 456-457.

34) Eugene, Dawanne, M.; Giles, Marco D.; Grayson, Scott M. Encapsulation of Polar Dye within Dendritic Star Block Copolymers. Polym. Mater. Sci. Eng., 2008, 98, 458-459.

10

33) Giles, Marco D.; Grayson, Scott M. Divergent Polyester Dendronization of Cavitands to Tune Host Solubility. Polym. Mater. Sci. Eng., 2008, 98, 466.

32) Giles, Marco D.; Eugene, Dawanne M.; Grayson, Scott M. Synthesis of Polyester Based Dendrimers as Precursors for Amphiphilic Star Block Copolymers. Polym. Mater. Sci. Eng., 2008, 98, 467-468.

31) Hoskins, Jessica N.; Grayson, Scott M. End Group Analysis of Poly(ε-caprolactone) by MALDI-TOF MS. Polym. Mater. Sci. Eng., 2008, 98, 478-479.

30) Hoskins, Jessica N.; Grayson, Scott M. Synthesis of Cyclic Poly(ε-caprolactone). Polym. Mater. Sci. Eng., 2008, 98, 480-481.

29) Laurent, Boyd A.; Grayson, Scott M. Synthesis of Linear and Cyclic Amphiphilic Homopolymers as Unimolecular Invertible Micelles. Polym. Mater. Sci. Eng., 2008, 98, 502-503.

28) Li, Yejia; Giles, Marco D.; Grayson, Scott M. Assembly of Star Polymers by Clicking Linear Polymers to Poly(alkynated) Dendrimers. Polym. Mater. Sci. Eng., 2008, 98, 509-510.

27) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne, M.; Hoskins, Jessica N.; Eberle, Jeremy; Willham, Kaitlin A. Exploration of Cyclic Polymer Architectures using Click Chemistry. Polym. Prepr., 2008, 51, 174.

26) Laurent, Boyd A.; Grayson, Scott M. Water-soluble Cyclic Dendronized Polymers Via a Divergent “Graft From” Approach for Guest Encapsulation. Polym. Prepr., 2008, 51, 287-288.

25) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne M. “Cyclic Styrenes as Substrates for Unimolecular Micelles” in Polymers for Biomedical Applications, Kulshrestha, A. S. and Mahapatro, A., Eds.; ACS Symposium Series; American Chemical Society: Washington DC. 2008, 977, 37-50.

24) Willham, Kaitlin A.; Laurent Boyd A.; Grayson, Scott M. The Synthesis of a pH-Independent Bifurcated Amphiphile. Tetrahedron Lett., 2008, 49, 2091-2094.

http://dx.doi.org/10.1016/j.tetlet.2008.01.132

23) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne M. The Use of Click Chemistry to Prepare Functional Cyclic Polymers for Transdermal Drug Delivery. Polym. Prepr., 2006, 49 (2), 459-460.

22) Laurent, Boyd A.; Grayson, Scott M. Synthesis and Functionalization of Cyclic Poly(hydroxyl)styrene Derivatives. Polym. Prepr., 2006, 49 (2), 247-248.

21) Eugene, Dawanne M.; Grayson, Scott M. Synthesis of Dendritic Star Block Copolymers via ATRP for Use as Transdermal Drug Delivery Agents. Polym. Prepr., 2006, 49 (2), 246.

20) Laurent, Boyd A.; Grayson, Scott M. An Efficient Route to Well-Defined Macrocyclic Polymers via “Click” Cyclization. J. Am. Chem. Soc., 2006, 128, 4238-4239.

http://dx.doi.org/10.1021/ja0585836 - Featured in “Research Highlights” of Nature Materials, 2006, 5, 341. - 15th most cited J. Am. Chem. Soc. paper from 2006 (of 3310) - Aug 2010.

Worked carried out as post-doctoral fellow at University of Texas:

11

19) Meiring, J. E.; Lee, S.; Costner, E. A.; Schmid, M. J.; Michaelson, T. B.; Willson, C. G.; Grayson, S. M. Pattern Recognition of Shape-Encoded Hydrogel Biosensor Arrays. Opt. Eng., 2009, 48, 37201.1-37201.14.

18) Schmid, Matthew J.; Manthiram, Kalpana; Grayson, Scott M.; Willson, James C.; Meiring, Jason E.; Bell, Kathryn M.; Ellington, Andrew D.; Willson, C. Grant. Feature-Multiplexing – A Novel Probe Placement Methodology for Microarray Devices. Angew. Chemie, 2006, 45, 3338-3341.

17) Grayson, Scott M.; Long, Brian K.; Kusomoto, Shiro; Osborn, Brian P.; Callahan, Ryan P.; Chambers, Charles C.; Willson, C. Grant. Synthesis and Characterization of Norbornane-diol Isomers and Their Fluorinated Analogues. J. Org. Chem., 2006, 71, 341-344.

16) Meiring, Jason E.; Schmid, Matthew J.; Grayson, Scott M.; Rathsack, Benjamin M.; Johnson,

David M.; Kirby, Romy; Kannappan, Ramakrishnan; Manthiram, Kalpana; Stotts, Jennifer; Hogan, Zachary L.; Ellington, Andrew D.; Willson, C. Grant. Hydrogel Biosensor Array Platform Indexed by Shape. Chem. Mater., 2004, 16, 5574-5580.

15) Grayson, Scott M.; Schmid, Matthew J.; Meiring, Jason E.; Desai, Vijay; U, Daniel S.; Manthiram, Kalpana; Ellington, Andrew D.; Willson, C. Grant. The Self-assembly of Hydrogel Sensors into a Functional Array. Polym. Prepr., 2004, 45 (2), 432-433.

14) Leeson, Michael J.; Yueh, Wang; Tattersall, Peter I.; Pawloski, Adam; Grayson, Scott M.; Willson, C. Grant. The Synthesis and Reactivity of 3-Diazo-4-oxocoumarins for Photolithographic Applications. Chem. Mater., 2004, 16 (9), 1763-1769.

13) Tattersall, Peter I.; Breslin, David; Grayson, Scott M.; Heath, William; Lou, Kathleen; McAdams, Christopher L.; McKean, Dennis; Rathsack, Benjamin, M.; Wilson, C. Grant. Synthesis and Properties of Diazopiperidiones for Use in Non-Chemically Amplified Deep UV Photoresists. Chem. Mater., 2004, 16 (9), 1770-1774.

12) Schmid, Matthew J.; Meiring, Jason E.; Kirby, Romy; Manthiram, Kalpana; Grayson, Scott M.; Ellington, Andrew D.; Willson, C. Grant. Functionalizing Hydrogel Based Biosensors with DNA Oligomers for Single Nucleotide Polymorphism Detection. Polym. Mater. Sci. Eng., 2003, 89, 215-216.

11) Meiring, Jason E.; Schmid, Matthew J.; Grayson, Scott M.; Rathsack, Benjamen M.; Johnson, David M.; Kirby, Romy; Kannappan, Ramakrishnan; Manthiram, Kalpana; Stotts, Jennifer; Hogan, Zachary L.; Russel, Ryan J.; Pishko, Michael V.; Ellington, Andrew D.; Willson, C. Grant. Hydrogel Biosensor Arrays Indexed through Shape Recognition. Polym. Mater. Sci. Eng., 2003, 89, 217-218.

10) Grayson, Scott M.; Willson, C. Grant. Self-orienting and Self-assembling Mesoscale Amphiphilic Hydrogels. Polym. Mater. Sci. Eng., 2003, 89, 219-220.

Worked carried out as graduate student at University of California, Berkeley:

9) Lee, Cameron C.; Grayson, Scott M.; Fréchet, Jean M. J. Synthesis of Narrow-Polydispersity Degradable Dendronized Aliphatic Polyesters. J. Poly. Sci., Part A: Polym. Chem., 2004, 42 (14), 3563-3578.

8) Grayson, Scott M.; Fréchet, Jean M. J. Synthesis and Chemical Modification of Novel Triallyl Chloride Dendrimer Core. Org. Lett., 2002, 4, 3171-3174.

7) Grayson, Scott M.; Fréchet, Jean M. J. Convergent Dendrons and Dendrimers: from Synthesis to Applications. Chem. Rev., 2001, 101, 3819-3868.

12

6) Grayson, Scott M.; Fréchet, Jean M. J. Divergent Synthesis of Dendronized Poly(p-hydroxystyrene). Macromolecules, 2001, 34, 6542-6544.

5) Grayson, Scott M.; Fréchet, Jean M. J. Divergent Synthesis of Aliphatic Polyester Dendrons Grafted to Poly(hydroxystyrene). Polym. Mater. Sci. Eng., 2001, 84, 861-862.

4) Grayson, Scott M.; Fréchet, Jean M. J. Synthesis and Surface Functionalization of Aliphatic Polyether Dendrons. J. Am. Chem. Soc., 2000, 122 (42), 10335-10344.

3) Grayson, Scott M.; Jayaraman, Manikandan; Fréchet, Jean M. J. Selective Surface Modification of Orthogonally Protected Aliphatic Polyether Dendrons. Polym. Prep., 2000, 41, 167-168.

2) Grayson, Scott M.; Jayaraman, Manikandan; Fréchet, Jean M. J. Convergent Synthesis and 'Surface' Functionalization of a Dendritic Analog of Poly(ethylene glycol). Chem. Commun., 1999, 1329-1330.

1) Grayson, Scott M.; Jayaraman, Manikandan; Fréchet, Jean M. J. A Novel Synthesis of Aliphatic Polyether Dendrimers. Polym. Mater. Sci. Eng.,1999, 80, 64-65.

Patents: Inventors: Grayson, Scott M.; Cortez, Mallory A.

Title: Polyplex Gene Delivery Vectors

US Patent Application 2013/011569 A1 PCT filed 21 March 2011 Inventor: Grayson, Scott M.

Title: Tuned Synthetic Dendrimer Calibrants for Mass Spectrometry

U.S. Patent Application 61/649920 filed 21 May 2012 Inventor: Grayson, Scott M.

Title: Synthetic Dendrimer MALDI Calibrants

U.S. Patent 8,846,848, issued 30 September 2014 Licensed by Tulane University to Polymer Factory, Stockholm, Sweden Commercialized under the name Spherical™ distributed by Sigma-Aldrich

13

Cumulative Citations:

JOURNAL NAME

IMPACT FACTOR

REFERENCE (Year, Vol, Pg#)

TIMES CITED thru

2005

TIMES CITED thru

2007

TIMES CITED thru

2009

TIMES CITED thru

2011

TIMES CITED thru

2013

TIMES CITED thru

2014

TIMES CITED thru

present

ACS Macro Letters 5.242 2013, 2, 845-848 - - - - - 8

Adv. Drug Delivery Reviews

12.88 2012, 64, 852-865 - - - - 22 47

Analytica Chimica Acta

4.517 2014, 808, 175-189 - - - - - -

Analytica Chimica Acta

4.517 2014, 816, 28-40 - - - - - -

Brazilian J. of Pharmaceutical Sci.

0.302 2013, 49, 45-55 - - - - 0 0

Angewandte Chemie 10.23 2006, 45, 3338-3341 - 0 2 2 3 3

Biomacromolecules 4.502 2011, 12, 898-906 - - - 1 16 20

Chemical Communications

4.031 1999, 1329-1330 19 23 28 29 31 32

Chem. Commun. 6.169 2011, 9036-9038 - - - - 4 8

Chem. Commun. 6.718 2014, 50, 4853-4855 - - - - - -

Chemical Reviews 21.04 2001, 101, 3819-3868 326 518 685 868 1017 1093

Chemical Society Reviews

13.08 2009, 38, 2202-2213 - - 1 41 93 128

Chemistry of Materials

4.103 2004, 16, 1763-1769 0 2 2 2 2 2

Chem. Mater. 4.103 2004, 16, 1770-1774 2 4 12 15 18 18

Chem. Mater. 4.103 2004, 16, 5574-5580 1 5 14 21 33 36

Israel Journal of Chemistry

0.372 2009, 49, 31-40 - - 0 1 2 2

Journal of the American Chemical Society (JACS)

6.516 2000, 122, 10335-10344

34 43 54 59 64 67

JACS 7.696 2006, 128, 4238-4239 - 51 153 258 328 379

JACS 7.885 2008, 130, 14430-14431

- - 7 25 31 35

JACS 9.019 2011, 133, 13421-13429

- - - - 20 32

Journal of the American Society for Mass Spectrometry (JASMS)

3.592 2013, 24, 74-82 - - - - 1 4

JASMS 3.592 2014, 25, 303-309 - - - - - 1

Journal of Chemical Education

0.817 2012, 7, 925-927 - - - - 0 1

Journal of Drug Targeting

2.030 2008, 156, 329-356 - - 5 20 32 39

Journal of Mass 3.289 2010, 45, 587-611 - - 1 4 10 16

14

Spectrometry

Journal of Materials Chemistry C

new 2014, 2, 4073-4079 - - - - - 1

Journal of Organic Chemistry

3.790 2006, 71, 341-344 - 3 5 6 6 6

Journal of Physical Chemistry B

3.377 2014, 118, 6491-6497 - - - - - -

Journal of Polymer Science, Part A: Polymer Chemistry

2.773 2004, 42, 3563-3578 12 22 31 36 39 41

JPSA Polym. Chem. 3.543 2012, 50, 1086-1101 - - - - 6 12

JPSA Polym. Chem. 3.245 2013, 51, 3314-3322 - - - - 1 2

Macromolecular Rapid Communications

4.608 2014, 35, 146-151 - - - - - 3

Macromolecules 3.621 2001, 34, 6542-6544 38 57 66 82 92 93

Macromolecules 4.411 2008, 41, 5082-5084 - - 20 66 88 100

Macromolecules 4.539 2009, 42, 6406-6413 - - 0 33 62 77

Macromolecules 4.838 2010, 43, 4081-4090 - - 0 7 15 20

Macromolecules 4.838 2010, 43, 6225-6228 - - - 5 11 17

Macromolecules 4.838 2010, 43, 10152-10156

- - - - 2 3

Macromolecules 5.167 2011, 44, 1742-1746 - - - 3 15 21

Macromolecules 5.167 2011, 44, 6915-6918 - - - - 7 7

Macromolecules 5.927 2014, 47, 3553-3566 - - - - - -

Nature Chemistry 17.93 2009, 1,178-179 - - 1 8 11 15

Optical Engineering 0.553 2009, 48, 037201 - - 0 1 1 1

Organic Letters 4.092 2002, 4, 3171-3174 5 8 13 18 21 21

Polymer 3.438 2011, 52, 5262-5270 - - - 0 1 4

Polymer 3.766 2013, 54, 846-859 - - - - 0 3

Polymer Chemistry 5.231 2011, 2, 289-299 - - - 6 20 35

Polymer Chemistry 5.231 2012, 3, 1846-1855 - - - - 8 16

Polymer Chemistry 5.368 2014, 5, 622-620 - - - - - 1

Reactive & Functional Polymers

2.822 2014, 80, 71-82 - - - - - 1

R&FP 2.822 2014, 80, 83-94 - - - - - 1

Soft Matter 4.457 2010, 6, 1377-1382 - - - 2 2 3

Tetrahedron Letters 2.615 2008, 49, 2091-2094 - - 2 3 4 4

Preprints:

Polym. Prep. 2000, 41, 1329-1330 0 1 1 1 1 1

Polym. Prep. 2006, 49, 459-460 - 1 1 1 1 1

Polym. Prep. 2008, 49, 287-288 - - 1 1 1 1

15

TOTAL CITATIONS 443 743 1093 1627 2179 2498 TULANE CITATIONS 52 175 491 832 1081

*Green shading denotes independent work from Tulane since 2005, bold SMG as corresponding author. Doctoral Students Mentored:

Name Graduation Present position (projected)

Dawanne E. Poree (BOR) Aug 2010 Program Manager, Polymers, US Army Research Office, Raleigh-Durham, NC

Boyd A. Laurent (BOR) July 2011 Research Scientist, Nalco, Sugarland, TX Yejia Li Aug 2011 Research Scientist, Ashland Inc., NJ Marco D. Giles Aug 2011 IRACDA p-doc fellow, J. Wang, Baylor Med. Sch. TX Mallory A. Cortez (BOR) Oct 2011 Asstistant Professor (tenure track),

Nicholls State U.Thibodaux, LA Jessica N. Hoskins (BOR) Oct 2011 Research Scientist, Stepan Company, Northfield, IL

Boyu Zhang Apr 2015 Research Scientist, Brewer Science, Rolla, MO Ravinder Elupula (2015) Brittany K. Myers (2015) Joseph Giesen (BOR) (2016)

Karolina Kosakowska (IGERT) (2017)

Jennifer Marple (2018)

Ca’ra Schexnayder (2018) Molly Payne (BOR) (2019)

Farihah Haque (2019)

Masters Students Mentored:

Name Graduation Present position (projected)

Yi Wang 2014 Intern Wellsprings Bioscience Undergraduate Students Mentored:

Name Graduation Present position (projected)

Kaitlin Willham (honors thesis) 2007 U. of Chicago Medical School, MD Jeremy Eberle 2008 applying to doctoral programs, Psychology Brian Cafferty (honors thesis) 2009 GATech, pursuing Ph.D. in Chemistry Swati Jain (honors thesis) 2009 UT Memphis, pursuing Pharmacy degree Gesine Veits (honors thesis) 2009 Ph.D. in Chemistry, UC, Santa Barbara, Lin Bai (honors thesis) 2010 M.S., Biomed. Eng. Washington U., L’Oreal Owen Williams 2010 UT, Austin, pursuing Ph.D. in Chemistry Alegra Grieb (honors thesis) 2012 Tulane Medical School Monica Schwarz (honors thesis) 2012 University of Utah, Medical School Beau Pritchett 2012 CalTech, pursuing Ph.D. in Chemistry

16

Kasey Hamilton 2013 applying to art conservation programs Alex Justen 2013 Johns Hopkins, pursuing Ph.D. in Bioeng. Matt Kiok 2014 LSU Medical School, pursuing M.D. Joanna Lapucha 2014 employee, Schlumberger Amy Milman (2015) Post-doctoral researchers mentored:

Name Appointment Present position

Dr. S. Gupta Sreerama 2008-2010 research scientist, US Pharmacopeia (Rockville, MD) Dr. Muhammed Ejaz 2009-present

Press and Commentary about Research from the Grayson Group: 16) Tulane researchers awarded grant to develop smart polymers. Tulane New Wave, 19

September 2014 http://tulane.edu/news/releases/pr_091914.cfm

15) Tulane gets grant for polymers research. The New Orleans Advocate, 24 September 2014

14) Tulane scientist share grant for smart polymers research. The New Orleans City Business, 19 September 2014

13) Undergraduates call them brilliant inspirational teachers. Tulane New Wave, 14 May 2014 http://tulane.edu/news/newwave/051414_undergrad_teaching_awards.cfm

12) Tulane in New Orleans gets $1 million grant to develop dispersants for clean up of oil spill New Orleans Times Picayune 25 July 2013

11) Tulane researchers using BP grant to develop less toxic dispersant WWNO/NPR, 12 July 2013. http://wwno.org/post/tulane-researchers-using-bp-grant-develop-less-toxic-dispersant

10) Tulane team gets funding to develop better oil dispersant New Orleans City Business, 10 July 2013. http://neworleanscitybusiness.com/blog/tag/scott-grayson/

9) Researchers get more funding. Mississippi Business Journal, 30 September 2012

8) S.M. Grayson featured as “author of the week” in Polymer Chemistry, a journal from the Royal Society of Chemistry, UK, 27 February 2011

7) Eugene, D. M.; Grayson, S. M. Macromolecules 2008, 41, 5082-5084. Ranked as the 10th most cited Macromolecules manuscript as of 30 AUG 2010

6) Hoskins, J. N.; Grayson, S. M. Macromolecules, 2009, 42, 6406-6413. Ranked as a top 10th most downloaded manuscript from Macromolecules manuscript in Oct 2009

5) Eugene, D. M.; Grayson, S. M. Macromolecules 2008, 41, 5082-5084. Featured article in Macromolecules Virtual Issue Vol vi, Issue 1 “Click Chemistry in Macromolecular Science” 28 May 2009: American Chemical Society Publications online http://pubs.acs.org/page/mamobx/vi/1

4) Laurent, B. A.; Grayson, S. M. J. Am. Chem. Soc. 2006, 128, 4238. Most Cited Articles Published in 2006. American Chemical Society Publications online, ranked as the 18th most cited J. Am. Chem. Soc. manuscript as of 31 Dec 2007 http://pubs.acs.org/journals/jacsat/promo/most/most_cited/2006.html

3) A good shot in the Arm. Gambit Weekly, 10 July 2007 Commentary on PKFSI grant.

17

2) Laurent, B. A.; Grayson, S. M. J. Am. Chem. Soc. 2006, 128, 4238 subject of research highlight: Polymers Come Full Circle: Click Chemistry Ties up Loose Ends in Polymer Synthesis. Nature Materials, 2006, 5, 341.

1) Vaccine Grant is a Shot in the Arm. New Orleans Times Picayune, 15 April 2006 Commentary on NIH grant. Oral Conference Presentations: (Presenting Author Underlined) 59) Grayson, Scott M. Exploring the effect of PEI architecture on gene transfection Fusion Conference on Drug Delivery Phoenix, AZ 28th September 2015 (invited).

58) Grayson, Scott M. The Elucidation of Macromolecular Architecture Using Gel Permeation Chromatography and Mass Spectrometry TOSOH GPC Conference Washington, DC 1st September 2015 (invited).

57) Grayson, Scott M. The potential of ion mobility spectrometry-mass spectrometry (IMS-MS) for elucidating polymer architecture 250th ACS National Meeting Boston, MA 17th August 2015

56) Grayson, Scott M. Exploring the role of covalent architecture in the behavior of amphiphilic polymers 250th ACS National Meeting Boston, MA 17th August 2015 (invited). 55) Grayson, Scott M. Overcoming the critical micelle concentration: Exploring nanoparticles with amphiphilic grafts as concentration-independent “unimolecular micelle” nanodispersants for oil spill remediation 250th ACS National Meeting Boston, MA 17th August 2015

54) Grayson, Scott M. Tuning Amphiphilic Nanomaterials for Environmental and Biomedical Applications. Jackson State PREM Conference Jackson, MS 24th July 2015 (invited).

53) Grayson, Scott M. The Use of Ion Mobility Spectrometry-Mass Spectrometry to Elucidate Polymer Architecture. Omics Mass Spectrometry Conference New Orleans, LA 13th July 2015 (invited).

52) Grayson, Scott M. Overcoming the Critical Micelle Concentration: Exploring Nanoparticles with Amphiphilic Grafts as Concentration-Independent Unimolecular Micelles 2015 Gulf of Mexico Oil Spill and Ecosystem Science Conference Houston, TX 19th February 2015.

52) Grayson, Scott M. Investigations of Amphiphilic Macromolecules with Complex Architecture 4th Zing Polymer Chemistry Conference Cancun, Mexico 12th December 2014.

51) Grayson, Scott M. The Use of Mass Spectrometry for the Characterization of Functional Polymers ACS Southwest Regional Meeting Dallas, TX 21st November 2014 (invited).

50) Grayson, Scott M. Investigations of the Effect of Architecture on the Self-assembly and Guest Encapsulation in Cyclic and Branched Macromolecules 248th ACS National Meeting San Francisco, CA 12th August 2014 (invited).

49) Grayson, Scott M. Exploring the Effect of Dendritic Branching and Cyclic Topologies on Block Copolymer Self-Assembly 4th International Symposium on Biomedical Applications of Dendrimers Lugano, SWITZERLAND 19th June 2014.

48) Grayson, Scott M. Exploring the Effect of Polymer Architecture on Self-assembly 11th National Graduate Research Polymer Conference Baton Rouge, LA 2nd June 2014 (invited).

18

47) Grayson, Scott M. The Effect of Polymer Architecture on the Conformation and Self-assembly of Amphiphilic Macromolecules. LASiGMA Annual Conference, Baton Rouge, LA 5th May 2014 (invited).

46) Zhang, Boyu; Zhang, Hong; Li, Yejia; Hoskins, Jessica, N.; Elupula, R.; Grayson, S. M. Exploring Amphiphilic Copolymer Architectures with Cyclic Topology based on Poly(ethylene glycol) and Polycaprolactone: Synthesis, Characterization, and Self-assembly Behavior 247th ACS National Meeting, Excellence in Graduate Polymer Research Symposium, Dallas, TX, March 16, 2014 (invited).

45) Grayson, Scott M. Using Mass Spectrometry to Characterize Polymer Function and Architecture International Symposium of Polymer Analysis and Characterization New Orleans, LA 10-12th June 2013 (invited).

44) Grayson, Scott M. Exploring the Versatility of Click Chemistry in Making Cyclic Polymers 245th ACS National Meeting Cyclic and multicyclic polymers. PMSE/POLY; New Orleans, LA; 10th April 2013 (invited).

43) Grayson, Scott M. Efficient and Accelerated Approaches for Preparing Well-defined Macromolecular Structures Simpósio de Dendrímeros São Paulo, BRAZIL 1st October 2012 (invited).

42) Grayson, Scott M. Application of CuAAC Chemistry for Preparing Complex Cyclic and Multicyclic Polymers Macro 2012, 44rd IUPAC World Polymer Conference Blacksburg, VA; 26th June 2012 (invited).

41) Cortez, Mallory A., Cafferty Brian J.; Grayson, Scott M. Synthesis of Cyclic Poly(ethylene Imine)s and Exact Linear Analogs 243th ACS National Meeting, Poly(2-oxazoline)s and related pseudo-polypeptide structures. PMSE; San Diego, CA; 27th March 2012 (invited).

40) Grayson, Scott M.; Giles, Marco D.; Li, Yejia Using “Click” Polymer Conjugation to Modify the Properties of Deep Cavity Cavitands 67th Southwestern Regional Meeting of American Chemical Society, Austin, TX; 9th November 2011 (invited).

39) Grayson, Scott M.; Gibb, Bruce C. Exploring the Surface Modification of Macrocycles via Copper-Catalyzed Azide-Alkyne Cycloaddition “Click” Couplings 46th Midwest/39th Great Lakes Regional Meeting of American Chemical Society, St. Louis, MO; 18th October 2011 (invited).

38) Grayson, Scott M. Control of Branching in Amphiphilic Polymers to Tune Aggregation Behavior of Carriers Polymers in Medicine and Biology 2011, Santa Rosa, CA; 5th September 2011 (invited).

37) Grayson, Scott M.; Laurent, Boyd A.; Poree, Dawanne E.; Wang, Yi Amphiphilic Polymers: Effect of Branching and Architecture on Self-assembly 242th ACS National Meeting, Function through Macromolecular Assembly, PMSE; Denver, CO; 29th August 2011 (invited).

36) Grayson, Scott M. Using Click to Prepare Dendronized Macrocycles and other Dendronized Macromolecules Seventh International Dendrimer Symposium, Washington, DC; 28th June 2011 (invited).

35) Hoskins, Jessica, N.; Grayson S. M. Ion Mobility Spectrometry-Mass Spectrometry of Unique Polymer Architectures 62nd Southeastern Regional Meeting of American Chemical Society, New Orleans, LA; 3rd December 2010.

34) Li, Yejia; Giles, Marco D.; Liu, Simin; Laurent, Boyd, A.; Hoskins, Jessica N.; Cortez, Mallory A.; Sreerama, S. Gupta; Gibb, Bruce C.; Grayson, Scott M. A Versatile and Modular Approach

19

to Functionalization of Deep Cavity Cavitands 62nd Southeastern Regional Meeting of American Chemical Society, New Orleans, LA; 3rd December 2010.

33) Grayson, Scott M. Explorations of Polymer Modified Macrocycles and Macrocyclic Polymers 62nd Southeastern Regional Meeting of American Chemical Society, New Orleans, LA; 1st December 2010 (invited).

32) Grayson, Scott M. The Use of Click to Prepare Biocompatible Biodegradable Polymer Macrocycles Zing Polymer Chemistry Conference, Puerto Morelos, MEXICO 19-22nd November 2010 (invited).

31) Grayson, Scott M. The Use of Click Chemistry to Construct Functionalised Cyclic Polymers Macro 2010, 43rd IUPAC World Polymer Conference Glasgow, SCOTLAND; 11-16th July 2010 (invited).

30) Trimpin, Sarah; Hoskins, Jessica N.; Wijerathne, Kanchana; Inutan, Ellen; Grayson, Scott M. Library of Polymer Architectures Examined by Ion Mobility Spectrometry-Mass Spectrometry 58th Annual American Society for Mass Spectrometry Conference, Salt Lake City, UT; 24th May 2010.

29) Cortez, Mallory A.; Grayson, Scott M. Functional Group Modification and Subsequent Polymerization of 2-Oxazoline Monomers via Thiol-ene Click Chemistry. 236th ACS National Meeting, San Francisco, CA; POLY-18; 23rd March 2010.

28) Eugene, Dawanne. M.; Grayson, Scott M.; Giles, Marco D. Characterization and Evaluation of Dendritic Star Block Copolymer via ATRP for Use as Transdermal Drug Delivery Agents. 236th ACS National Meeting, San Francisco, CA; POLY-19; 23rd March 2010.

27) Grayson, Scott M.; Laurent, Boyd A.; Hoskins, Jessica N.; Sreerama, Subramanya G.; Eugene, Dawanne M.; Cortez, Mallory A. Using Click Chemistry to Diversify the Functionality and Architecture of Cyclic Polymers 236th ACS National Meeting, San Francisco, CA; PMSE-414; 23rd March 2010.

26) Grayson, Scott M. Building Complexity in Cyclic Polymers Pacific Polymer Conference Cairns, AUSTRALIA; 7th December 2009 (invited keynote speaker).

25) Grayson, Scott M.; Giles, Marco D.; Laurent, B. A.; Emanuel, R. L.; Liu, S.; Gibb, B. C. Dendronized Macrocycles for Supramolecular Guest Encapsulation 61th Southeastern Regional Meeting of American Chemical Society, San Juan, PR; 23rd October 2009 (invited).

24) Grayson, Scott M. Clicking Together Complex Macromolecules. Gordon Research Conference Mt. Holyoke College, S. Hadley, MA; 25th June 2009 (invited).

23) Grayson, Scott M. Exploration of Polymer Architecture: Dendronized Macrocycles for Supramolecular Guest Encapsulation Sixth International Dendrimer Symposium, Stockholm, Sweden;15th June 2009 (invited).

22) Grayson, Scott M. Characterizing Functionality and Architecture in Synthetic Polymers. Bruker Users Meeting, American Society of Mass Spectrometry Conference, Philadelphia, PA; 30th May 2009 (invited).

21) Giles, Marco D. Liu, Simin; Emanuel, Roy L., Jr.; Gibb, Bruce, C.; Grayson, Scott M. Preparation of Dendronized Cavitands for Supramolecular Drug Encapsulation and Delivery, 60th Southeastern Regional Meeting of the American Chemical Society, Nashville, TN; 15th November 2008.

20

20) Grayson, Scott M.; Laurent, Boyd A.; Hoskins, Jessica N.; Eugene, Dawanne M. Using Click Chemistry to Prepare a Diversity of Polymers, 60th Southeastern Regional Meeting of the American Chemical Society, Nashville, TN; 14th November 2008 (invited). 19) Eugene, Dawanne M.; Giles, Marco D.; Grayson, Scott M. Synthesis of Dendritic Star Block Copolymers for Use as Transdermal Drug Delivery Agents. 60th Southeastern Regional Meeting of the American Chemical Society, Nashville, TN; 14th November 2008.

18) Grayson, Scott M.; Eugene, Dawanne M.; Laurent, Boyd A.; Giles, Marco D. Supramolecular Encapsulation of Guest Molecules in Macromolecular Carriers 236th ACS National Meeting, Philadelphia, PA; POLY-053; 17th August 2008.

17) Laurent, Boyd A.; Grayson, Scott M. Water-soluble Cyclic Dendronized Polymers via a Divergent “Grafting from” Approach for Guest Encapsulation 235th ACS National Meeting, Excellence in Graduate Polymer Science Research, POLY-244; New Orleans, LA; 7th April 2008 (one of seven awarded students for graduate symposium). 16) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne M.; Hoskins, Jessica N., Eberle, Jeremy; Willham, Kaitlin, A. Exploration of Cyclic Polymer Architectures Using Click Chemistry 235th ACS National Meeting, Efficient Transformations in Polymer Chemistry, POLY-578; New Orleans, LA; 10th April 2008 (invited).

15) Grayson, Scott M. Designing Nanoscale Polymer Carriers for Transdermal Drug Delivery 235th ACS National Meeting, Chemistry in Medicine, SOCED-012; New Orleans, LA; 8th April 2008 (invited).

14) Grayson, Scott M. Characterizing Well-defined, Complex Macromolecular Architectures Using MALDI-TOF MS and NALDI-TOF MS: A Synthetic Macromolecular Chemist’s Perspective, Mass Spectrometry of Synthetic Polymers Workshop, National Institute of Standards and Technology, Gathersburg, MD; 6th March 2008 (invited).

13) Grayson, Scott M.; Laurent, Boyd A.; Eberle, Jeremy Nanoloops via Click Cyclization of Linear Polymers. Abstracts, 59th Southeastern Regional Meeting of American Chemical Society, Greenville, SC; 26th October 2007 (invited).

12) Grayson, Scott M.; Laurent, Boyd A. Preparation of Unprecidented “Toroidal” Polymers through Dendronization of Cyclic Polymers Fifth International Dendrimer Symposium, Toulouse, France; August 28 – September 1, 2007.

11) Grayson, Scott M.; Laurent, Boyd A.; Eberle, J. Cyclic and Toroidal Polymers Prepared Using Click Chemistry. Canadian Society for Chemistry, 90th Annual Conference, Winnipeg, MB, CANADA; 29th May 2007 (invited).

10) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne, M. Cyclic Polymers as Scaffolds for Drug Delivery Controlled Release Society Meeting, Long Beach, CA; 7-11th July 2007.

9) Grayson, Scott M.; Laurent, Boyd A. The Effect of Polymer Architecture on the Enhanced Permiability and Retention (EPR) Effect for Selective Delivery of Drugs to Tumor Masses International Polymer Therapeutics Symposium, Berlin, Germany; 19-21st February 2007.

8) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne M. The Use of Click Chemistry to Prepare Functional Cyclic Polymers for Transdermal Drug Delivery. 232th ACS National Meeting, PMSE-459, San Francisco, CA; 10-14th September 2006.

7) Grayson, Scott M.; Laurent, Boyd A.; Eugene, Dawanne, M.; Giles, Marco. The Synthesis of Amphiphilic Polymer Nanoparticles for Drug Delivery Applications. AIChE 2nd International

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Conference on Bioengineering and Nanotechnology, Santa Barbara, CA; 5-7th September 2006.

6) Grayson, Scott M.; Schmid, Matthew J.; Meiring, Jason E.; Desai, Vijay; U, Daniel S.; Manthiram, Kalpana; Ellington, Andrew D.; Willson, C. Grant The Self-assembly of Hydrogel Sensors into a Functional Array. 228th ACS National Meeting, POLY-453, Philadelphia, PA; 22-26th August 2004.

5) Grayson, Scott M.; Schmid, Matthew J.; Meiring, Jason, E.; Desai, Vijay; U, Daniel, S.; Manthiram, Kalpana; Ellington, Andrew D.; Willson, C. Grant. Self-assembled Shape-encoded Hydrogel Sensor Array. 17th Polymer Networks Conference, Bethesda, MD; 15-19th August 2004.

4) Grayson, Scott M.; Willson, C. Grant. Self-orienting and Self-assembling Amphiphilic Hydrogels. 226th ACS National Meeting, PMSE-150, New York, NY; 7-11th September, 2003.

3) Grayson, Scott M.; Lee, Cameron C.; Fréchet, Jean M. J. The Convergent and Divergent Dendronization of a Biodegradable Poly(caprolactone). 224th ACS National Meeting, POLY-425, Boston, MA; 18-22nd August, 2002.

2) Grayson, Scott M.; Fréchet, Jean M. J. Divergent Synthesis of Aliphatic Polyester Dendrons Grafted to Poly(hydroxystyrene). 221st ACS National Meeting, PMSE-477, San Diego, CA; 1-5th April 2001.

1) Grayson, Scott M.; Jayaraman, Manikandan; Fréchet, Jean M. J. A Novel Synthesis of Alphatic Polyether Dendrimers. 217th ACS National Meeting, PMSE-105, Anaheim, CA; 21-25th, March 1999.

Invited Seminars at Universities/Institutes: 53) 09 February 2015 Texas A&M, Biomedical Engineering Department 52) 15 January 2015 Tokyo Institute of Technology-O’okayama, Tokyo JAPAN 52) 14 January 2015 Tokyo Institute of Technology-Suzukake, Tokyo JAPAN 51) 08 January 2015 Waseda University, Tokyo, JAPAN 50) 03 October 2014 Virginia Tech, Chemistry Department 49) 24 September 2014 Notre Dame, Chemistry Department 48) 18 November 2013 Nichols State University, Chemistry Department 47) 18 October 2013 UMass Amherst, Polymer Science and Engineering 46) 08 October 2013 New York University, Chemistry Department 45) 05 October 2013 Columbia University, NY, Chemistry Department 44) 24 May 2013 Bogaziçi University, Istanbul, TURKEY 43) 01 March 2013 University of New Orleans, Chemistry Department 42) 03 October 2012 Universidade de São Paulo, São Paulo, BRAZIL 41) 20 September 2012 Instituto de Macomoleculas, UF Rio de Janiero, BRAZIL 40) 18 September 2012 Universidade Federal Ouro Preto, Ouro Preto, BRAZIL 39) 17 August 2012 Royal Institute of Technology (KTH) Stockholm, SWEDEN 38) 19 March 2012 Loyola University (New Orleans), Chemistry Department 37) 07 December 2011 University of S. Mississippi, Polymer Science Department 36) 02 December 2011 Case Western University, Macromolecular Science & Eng. 35) 30 September 2011 Southern Methodist University, Chemistry Department 34) 29 September 2011 Texas Christian University, Chemistry Department 33) 28 September 2011 University of Texas, Arlington, Chemistry Department

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32) 25 March 2011 Louisiana State University, Polymer Chemistry Seminar 31) 24 January 2011 Georgia Tech, School of Polymer, Textile and Fiber Eng. 30) 17 December 2010 University of Texas, Austin, Chemistry Department 29) 15 December 2010 Duquesne University, School of Pharmacy 28) 10 December 2010 Royal Institute of Sweden (KTH) Stockholm, SWEDEN 27) 18 November 2010 Trinity University, San Antonio, Chemistry Department 26) 17 November 2010 University of the Incarnate Word, Chemistry Department 25) 23 September 2010 Oklahoma State University, Chemistry Department 24) 01 April 2010 Northwestern University, Chemistry Department 23) 10 November 2009 University of Tel Aviv, Tel Aviv, ISRAEL, Chemistry Dept. 22) 06 November 2009 Freie Universität, Berlin, GERMANY, Chemistry Dept. 21) 04 November 2009 von Humboldt Universität, Berlin, GERMANY, Chemistry 20) 08 October 2009 Xavier University (New Orleans), Chemistry Department 19) 24 September 2009 Southern University, Baton Rouge Chemistry Department 18) 28 August 2009 Mississippi State University, Chemistry Department 17) 20 October 2008 Loyola University (New Orleans), Chemistry Department 16) 13 October 2008 Delaware Valley Mass-Spectrometer Users Group Meeting 15) 19 September 2008 Davidson College, Chemistry Department 14) 18 September 2008 Johnson C. Smith College, Natural Science Department 13) 17 September 2008 Winthrop College, Chemistry Department 12) 05 August 2008 National Institute of Standards, Polymer Division 11) 02 November 2007 Williams College, Chemistry Department 10) 12 October 2007 Colorado State University, Chemistry Department 9) 11 October 2007 Metropolitan State College of Denver, Chemistry Dept. 8) 20 September 2007 Xavier University (New Orleans), Chemistry Department 7) 14 September 2007 University of S. Mississippi, Chemistry Department 6) 07 September 2007 University of New Orleans, Chemistry Department 5) 05 March 2007 University of S. Mississippi, Polymer Science Department 4) 26 February 2007 University of Akron, Polymer Science Department 3) 12 February 2007 Virginia Tech, Chemistry Department 2) 07 November 2006 Louisiana State University, Chemistry Department 1) 05 August 2006 Montana State University, Chemistry Department

Tutorials/Short Courses/Corporate Talks: 11) Grayson, Scott M. The Synthesis and Characterization of Block Copolymers with Exotic Architecture, Brewer Scientific Inc., Rolla MO; August 21th 2015.

10) Grayson, Scott M. The Application of MALDI-TOF MS towards the Characterization of

Synthetic Polymers, Cambridge Polymer Group, Cambridge, MA; August 14th 2015.

9) Grayson, Scott M. The Use of Mass Spectrometry for the Characterization of Polymer

Architecture and Functionality, Tokyo Institute of Technology-Ookayama, Tokyo, JAPAN;

January 9th 2015.

8) Grayson, Scott M. Application of Mass Spectrometry toward Elucidating the Structure of

Synthetic Polymers, I-PRIME Workshop; Minneapolis, MN, May 27th 2014.

7) Grayson, Scott M. Polymer Characterization using Mass Spectrometry, POLY-RMC Polymer Characterization Workshop Tulane University, New Orleans, LA; November 11th 2013.

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6) Grayson, Scott M. Application of MALDI-TOF MS and IM-MS for Elucidating

Macromolecular Architecture, ACS National Meeting, TOSOH User Meeting Tutorial,

Indianapolis, IN; September 9th 2013.

5) Grayson, Scott M. Crash Course in MALDI-TOF MS: The Basics for Optimizing Polymer Analysis: Bogaziçi University, Istanbul, TURKEY; May 24th 2013.

4) Grayson, Scott M. ACS Tutorial: Using Mass Spectrometry to Elucidate Polymer

Functionality and Architecture, ACS National Meeting, Polymer Division, New Orleans, LA;

April 7-11th 2013.

3) Grayson, Scott M. Characterization of Polymers and Biomacromolecules using MALDI-TOF MS. POLY-RMC Polymer Characterization Workshop Tulane University, New Orleans, LA; November 30th 2012.

2) Grayson, Scott M. MALDI Crash Course: The Optimization of MALDI-TOF Mass Spectra for Polymers and Bioconjugated Polymers Royal Institute of Sweden, Stockholm, SWEDEN; August 14th 2012.

1) Grayson, Scott M. How To Characterize Macromolecules Using MALDI-TOF MS. Tulane University, New Orleans, LA; January 29th 2009.

Present Research Support:

As Principle Investigator: Development of Cost-efficient and Concentration-independent Dispersants for Improved Oil Spill Remediation Funding Agency: Gulf of Mexico Research Initiative GOMRI-2012-II-798 PI: Scott Grayson Total Funds: $1,000,000 Award Duration: 09/12—12/15 Synthetic Investigations of Modular Hyperbranched Polyesters with a Tunable Degree of Branching

and Addressable Functionalities Funding Agency: LA Board of Regents - Pfund PI: Scott Grayson Total Funds: $10,000 Award Duration: 01/14—12/14 The Modular Synthesis and Fundamental Properties of Hyperbranched Polymers Based on bis-MPA Monomer: Comparisons with Dendrimer and Linear Analogs Funding Agency: American Chemical Society; Petroleum Research Fund: PRF 53980-ND7 PI: Scott Grayson Total Funds: $100,000 Award Duration: 09/14-08/16 Novel Amphiphlic Polymers to Elucidate the Effect of Architecture on Micellization Funding Agency: National Science Foundation, Chemistry, MSN: CHE 1412439 PI: Scott Grayson Total Funds: $540,000 Award Duration: 09/14—07/17

As Co-Principal Investigator: REU Site: Summer Materials Research @ Tulane (SMART) Funding Agency: National Science Foundation DMR 1460637 PI: Hank Ashbaugh Award Duration: 09/15-08/18 Total Amount: $349,581 SMG Funds: (all fund for summer student recruiting) Louisiana Alliance for Simulation Guided Materials Applications (LA-SiGMA) Funding Agency: National Science Foundation, EPSCoR 1003897 PI: Michael Khonsari Award Duration: 09/10-08/15

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Total Amount: $20,000,000 SMG Funds: $180,000 The Smart Material Design, Analysis and Processing Consortium (SMATDAP) Funding Agency: National Science Foundation, EPSCoR IIA-1430280 PI: Michael Khonsari Award Duration: 09/14-08/17 Total Amount: $5,950,000 SMG Funds: $296,000

Completed Research Support

As Single Investigator:

NSF CAREER: Synthesis, Characterization, and Applications of Cyclic Polymer “Nanoloops” Funding Agency: National Science Foundation, Division of Materials Research PI: Scott Grayson Total Funds: $475,000 Award Duration: 08/09—07/14

Tulane Bridge Research Fund Funding Agency: Office of the Research Tulane University PI: Scott Grayson Total Funds: $30,000 Award Duration: 06/12—10/12

Presidential Early Career Development Award Funding Agency: Office of the President, Tulane University PI: Scott Grayson Total Funds: $60,000 Award Duration: 09/08—09/11 Travel Grant to Visit NSF Program Officers Funding Agency: LA Board of Regents, Travel Grants for Emerging Faculty PI: Scott Grayson Amount: $1,200 Award Duration: 03/11

Travel Grant to Present an Invited Paper at the IUPAC World Conference Funding Agency: LA Board of Regents, Travel Grants for Emerging Faculty PI: Scott Grayson Amount: $1,200 Award Duration: 06/10

Modular Exploration of Polymer Architecture for Improving Plasmid Transfection for Gene Therapy Funding Agency: Tulane Research Enhancement Fund: Phase I PI: Scott Grayson Amount: $25,000 Award Duration: 12/07—11/09

Preparation of Unimolecular Reverse Micelles for Transdermal Delivery of Therapeutics Funding Agency: Lousiana Board of Regents, Research Competitiveness Subprogram, PI: Scott Grayson Amount: $135,000 Award Duration: 07/06—06/09

Novel Polymeric Amphiphiles for Hydrocarbon Solubilization and Spill Remediation Funding Agency: American Chemical Society: Petroleum Research Fund (Type G) PI: Scott Grayson Amount: $40,000 Award Duration: 07/07-06/09

Applications of "Click" Cyclized Macrocyclic Styrenic Polymers Funding Agency: Oak Ridge Associated Universities, Powe Junior Faculty Enhancement PI: Scott Grayson Amount: $10,000 Award Duration: 05/06—04/07

As Co-Principal Investigator:

Tulane/Xavier Vaccine Peptide Program Funding Agency: U. S. Army Medical Research PI: Vijay John Award Duration: 07/10-06/13 Total Amount: $254,000 SMG Funds: $60,000 MRI-R2: Acquisition of a High Resolution Field Emission Transmission Electron Microscope for Research in Self-Assembled, Synthetic and Biomolecular Materials

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Funding Agency: National Science Foundation PI: Vijay John Award Duration: 01/10-12/12 Total Amount: $1,300,000 SMG Funds: (shared equipment only)

Center for Excellence in Vaccine Development Funding Agency: Louisiana Board of Regents, Post-Katrina Support Fund Initiative PI: Alistair Ramsay Award Duration: 07/07-06/12 Total Amount: $5,500,000 SMG Funds: (shared resources only)

Design, Delivery and Development of Therapeutic Peptides Funding Agency: Louisiana Board of Regents, Research & Educational Enhancement Program PI: Robert Garry Award Duration: 09/07-08/11 Amount: $5,800,000 SMG Funds: $170,600

Nanoparticle Delivery of Vaccines Funding Agency: National Institute of Health PI: John Clements Award Duration: 02/06-02/11 Amount: $2,200,000 SMG Funds: $276,700

Upgrade of Mass Spectrometry Facilities for Chemical Analysis Funding Agency: Louisiana Board of Regents, Traditional Enhancement Program PI: Mark Fink Award Duration: 06/08-05/09 Amount: $115,000 SMG Funds: (shared resources only)

Acquisition of a Matrix Assisted Laser Desorption Ionization Time of Flight Mass Spectrometer Funding Agency: National Science Foundation, Major Research Instrumentation Program PI: Russ Schmehl Award Duration: 09/06-08/08 Amount: $395,000 SMG Funds: (shared resources only)