SAFETY DATA SHEET JMS STYLET-OIL - Amazon S3€¦ · SAFETY DATA SHEET JMS STYLET-OIL SECTION 15:...
12
SAFETY DATA SHEET JMS STYLET-OIL SECTION 2: HAZARD IDENTIFICATION Signal Word: Danger Skin Irritation: Causes mild skin irritation Eye Irritation: Causes eye irritation Acute Toxicity Oral: LD50 > 5,000 mg/kg Acute Toxicity Dermal: LD50 > 2,000 mg/kg Hazard Categories: Oral/Dermal/Inhalation Toxicity-5/5/5; Eye/Skin Irritation-2B/3; Aspiration Hazard-1 Hazard Statement: May be harmful if swallowed May be harmful in contact with skin Causes eye irritation Causes mile skin irritation May be harmful if inhaled May be fatal if swallowed and enters airways Aggravated Medical Condition: None known JMS Stylet-Oil is registered with the EPA FIFRA as a pesticide. Classifications on this SDS are not the same as the EPA label (#65564-1). Some Sections of the SDS are superseded by Federal law for a registered pesticide. Section 15 REGULATORY INFORMATION provides more detailed information. SECTION 3: INFORMATION ON INGREDIENTS: COMPONENT CAS NUMBERS % by Weight WHITE MINERAL OIL 64742-54-7; 64742-55-8; 98.00 8042-47-5 Inert Ingredients: Nonhazardous 2.9
Transcript of SAFETY DATA SHEET JMS STYLET-OIL - Amazon S3€¦ · SAFETY DATA SHEET JMS STYLET-OIL SECTION 15:...
SAFETYDATASHEETJMSSTYLET-OIL
SECTION2:HAZARDIDENTIFICATIONSignalWord: DangerSkinIrritation: CausesmildskinirritationEyeIrritation: CauseseyeirritationAcuteToxicityOral: LD50>5,000mg/kgAcuteToxicityDermal: LD50>2,000mg/kgHazardCategories: Oral/Dermal/InhalationToxicity-5/5/5;Eye/SkinIrritation-2B/3;AspirationHazard-1HazardStatement: Maybeharmfulifswallowed Maybeharmfulincontactwithskin Causeseyeirritation Causesmileskinirritation Maybeharmfulifinhaled MaybefatalifswallowedandentersairwaysAggravatedMedicalCondition:NoneknownJMSStylet-OilisregisteredwiththeEPAFIFRAasapesticide.ClassificationsonthisSDSarenotthesameastheEPAlabel(#65564-1).SomeSectionsoftheSDSaresupersededbyFederallawforaregisteredpesticide.Section15REGULATORYINFORMATIONprovidesmoredetailedinformation.
SECTION3:INFORMATIONONINGREDIENTS:COMPONENT CASNUMBERS %byWeightWHITEMINERALOIL 64742-54-7;64742-55-8; 98.00
8042-47-5InertIngredients: Nonhazardous 2.9
SAFETYDATASHEETJMSSTYLET-OIL
SECTION4:FIRSTAIDMEASURESEye:Checkforandremovecontactlenses.DONOTuseaneyeointment.Flushthoroughlywithwater,keepingeyelidsopenforatleast15minutes.Ifirritationoccurs,seekmedicalassistance.Inhalation:Removefromfurtherexposure.Useadequaterespiratoryprotectionifassistingsomeoneaffected.Ifrespiratoryirritation,nausea,dizzinessorunconsciousnessoccurs,seekimmediatemedicalassistance.Ifbreathinghasstopped,assistventilationwithamedicaldeviceorusemouth-to-mouthresuscitation.Ingestion:DONOTinducevomitingbecauseofdangerofaspiratingliquidintolungsunlessdirectedbyaphysicianorpoisoncontrolcenter.Lowtoxicityoningestion,haslaxativeeffectandrapidlyeliminated.Physicalassessmentadvised.Skin:Removecontaminatedclothing.Removeandlaundercontaminatedclothingbeforereuse.Washcontaminatedskinwithnon-abrasivesoapandwaterforatleast15minutes.Seekmedicalattentionifrednessorirritationoccurs.
SECTION5:FIREFIGHTINGPROCEDURESEXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use streams of water. FIRE FIGHTING INSTRUCTIONS: Evacuate area. Prevent run-off from fire, control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes, Carbon Monoxide, and irritating vapors. FLAMMABILITY PROPERTIES: FLASH POINT ASTM D92 (open cup typical) ° F = COC > 360 ° F
SAFETYDATASHEETJMSSTYLET-OIL
SECTION6:SPILLORLEAKHANDLINGPROCEDURESSPILLMANAGEMENT:LandSpill:Stopleakifyoucandosowithoutrisk.Recoverbypumpingorwithsuitableabsorbent. WaterSpill:Stopleakifyoucandosowithoutrisk.Confinethespillimmediatelywithbooms.Warnothershipping.Removefromthesurfacebyskimmingorwithsuitableabsorbents.Seektheadviceofaspecialistbeforeusingdispersants.ENVIRONMENTALPRECAUTIONS:Largespills:Dikefaraheadofliquidspillforlaterrecoveryanddisposal.Prevententryintowaterways,sewers,basementsorconfinedareas.Contactlocalauthoritiesregardingspills/leaks.
SAFETYDATASHEETJMSSTYLET-OIL
SECTION8:EXPOSURECONTROLS/PERSONALPROTECTIONComponentswithworkplacecontrolparameters:Containsnosubstanceswithoccupationalexposurelimitvalues.Localexhaustshouldbesufficient.ENGINEERINGMEASURES:Nospecialventilationrequirements.Goodgeneralventilationshouldbesufficienttocontrolworkerexposuretoairbornecontaminates.PERSONALPROTECTIVEEQUIPMENTRespiratoryProtection:Userespiratoryprotectionwhenadequatelocalexhaustventilationisnotprovided,orexposureassessmentdemonstratesthatexposuresarewithinrecommendedexposureguidelines.Respiratorselectionmustbebasedonknownoranticipatedexposurelevels,thehazardsoftheproductandthesafeworkinglimitsoftheselectedrespirator.Filtertype: Organicvaporfilter HandprotectionMaterial: Neoprene,nitrile,polyvinylalcohol(PVA),Viton(R)Remarks: Chemical-resistant,imperviousglovescomplyingwithanapproved
standardshouldbewornatalltimeswhenhandlingchemicalproductsifariskassessmentindicatesthisisnecessary.
EyeProtection: Ifcontactislikely,safetyglasseswithsideshieldsare recommendedSkinandbodyprotection: Anyspecificclothinginformationprovidedisbasedon publishedliteratureormanufacturerdata.Thetypesof clothingtobeconsideredforthismaterialinclude: Noskinprotectionisordinarilyrequiredundernormal conditionsofuse.Inaccordancewithgoodhygiene practices,precautionsshouldbetakentoavoidskin contactHygienemeasures: Alwaysobservegoodpersonalhygienemeasures,suchaswashing
afterhandlingthematerialandbeforeeating,drinkingand/orsmoking.Routinelywashworkclothingandprotectiveequipmenttoremovecontaminants.Discardcontaminatedclothingandfootwearthatcannotbecleaned.Practicegoodhousekeeping.
ENVIRONMENTALCONTROLS: SEESECTIONS6,7,12,13
SECTION7:HANDLINGANDSTORAGEHANDLING: Smoking,eatinganddrinkingshouldbeprohibitedintheapplicationarea. Incaseofinsufficientventilation,wearsuitablerespiratoryequipment. Avoidcontactwitheyes,skinandclothing. Donotingest. Keepawayfromsourcesofheatandignition. Keepcontainerclosedwhennotinuse.STORAGE: Storeinoriginalcontainer.Openedcontainersshouldberesealedandkeptuprighttopreventleakage. Storeindry,cool,well-ventilatedarea. Storeislabelledcontainers. Donotstoreinheatordirectsunlight. Protectfromfreezing.
SAFETYDATASHEETJMSSTYLET-OIL
SECTION9:PHYSICALANDCHEMICALPROPERTIESAppearance Clearandbrightneutral
BoilingPoint >200 °CPhysicalState LiquidOdor NoneVaporDensity(Air=1) N/APourPoint °C(F) -27(-5)FreezingPoint NDDensityat20 °C 0.85-0.862FlashPointphysical °C(F) >160(345)SeeSection5FlammableLimits LEL:NDUEL:NDViscositycStat40 °C 13AutoignitionTemperature NDVaporPressure <0.013kPa(0.1mmHg)at20 °CEvaporationRate(N-ButylAcetate=1) ND
SolubilityinWater Miscible
OxidizingProperties SeeSections3,15,16
SECTION10:STABILITYANDREACTIVITYSTABILITY: StableundernormalconditionsCONDITIONSTOAVOID: Excessiveheat.HighenergysourcesofignitionMATERIALSTOAVOID: StrongoxidizersHAZARDOUSDECOMPOSITIONPRODUCTS: DoesnotdecomposeatambienttemperaturesHAZARDOUSPOLYMERIZATION: Willnotoccur
SAFETYDATASHEETJMSSTYLET-OIL
SECTION11:TOXICOLOGICALINFORMATIONACUTETOXICITYPotentialacutehealtheffects: Inhalation: Noknownsignificanteffectsorcriticalhazards Ingestion: Noknownsignificanteffectsorcriticalhazards Skincontact:Noknownsignificanteffectsorcriticalhazards Eyecontact: NoknownsignificanteffectsorcriticalhazardsINHALATION CONCLUSION/REMARKSToxicity:LC50>5,000mg/m3 Minimallytoxic.Basedontestdataforother
structurallysimilarmaterials.Negligiblehazardatambient/normalhandlingtemperatures.Basedonassessmentofthecomponents
INGESTIONToxicity:LD50>5,000mg/kg
Minimallytoxic.Basedontestdataforstructurallysimilardata
SKIN:LD50>5,000mg/kg
Minimallytoxic.Basedontestdataforotherstructurallysimilarmaterials.Negligibleirritationatambienttemperatures.Basedontestdataforstructurallysimilarmaterials
EYE:Irritation Maycausemild,shortlastingdiscomforttoeyes.Basedontestdataforstructurallysimilarmaterials
SAFETYDATASHEETJMSSTYLET-OIL
SECTION11:TOXICOLOGICALINFORMATIONCHRONIC/OTHEREFFECTSFortheproductitself: Repeatedand/orprolongedexposuremaycauseirritationtotheskin,eyesorrespiratorytract.Baseoilseverelyrefined.Notcarcinogenicinanimalstudies.RepresentativematerialpassesIP-346,ModifiedAmestestand/orotherscreeningtests.Dermalandinhalationstudiesshowedminimaleffects;lungnon-specificinfiltrationofimmunecells,oildepositionandminimalgranulomaformation.Dermalandinhalationstudiesshowedminimaleffects.Notsensitizingintestanimals.CARCINOGENICEFFECTS:Containsnocarcinogens.Similarcompoundsessentiallynon-toxic.Nocomponentofthisproductatlevelsgreaterthan0.1%isidentifiedasacarcinogenbyACGIHortheInternationalAgencyforResearchonCancer(IARC).Nocomponentofthisproductatlevelsgreaterthat0.1%isidentifiedasacarcinogenbytheU.S.NationalToxicologyProgram(NTP)ortheU.S.OccupationalSafetyandHealthAct(OSHA),NTPofIARC.Althoughisnospecifictestdataonallthebaseoilcomponents,themineralbaseoilwouldnotbeexpectedtoexhibitcarcinogenicpotentialbasedonwhatisknownofthetoxicityofmineralbaseoilsingeneral.TheDMSOextractbyIP-346oftheoilislessthan3%(Typical0.2%withMaximum0.5%0.Consequently,itisnotclassifiedasacarcinogen.Thebaseoilinthisproductisseverelyhydro-treatedbyallhydro-processingroute.Bythisrefininghistorywouldbeshowednoevidenceofcarcinogenicpotential.MUTAGENICEFFECTS:Nocomponentofthisproductatlevelsgreaterthan0.1%isclassifiedbyestablishedregulatorycriteriaasamutagen.TERATOGENICEFFECTS/DEVELOPMENTALTOXICITY:Nocomponentofthisproductatlevelsgreaterthat0.1%isclassifiedbyestablishedregulatorycriteriaasteratogenicorembryonic.REPRODUCTIONTOXICITY:Nocomponentofthisproductatlevelsgreaterthan0.1%isclassifiedbyestablishedregulatorycriteriaasareproductivetoxin.OVER-EXPOSURESIGNS/SYMPTOMSSkin: NoknownsignificanteffectsofcriticalhazardsIngestion: NoknownsignificanteffectsofcriticalhazardsInhalation: Noknownsignificanteffectsofcriticalhazards
SAFETYDATASHEETJMSSTYLET-OIL
SECTION12:ECOLOGICALINFORMATIONTheinformationgivenisbasedondataavailableforthematerial,thecomponentsofthematerialandsimilarmaterials.ECOTOXICITY
Materialnotexpectedtobeharmfultoaquaticorganisms.MOBILITY
Miscibleinwater.Withoutagitationseparationfromwaterwilloccurwiththeoilfloatingtothewatersurface
PERSISTENCEANDDEGRADABILITYBiodegradationisinherentlyexpected
BIOACCUMULATIONPOTENTIAL Hasthepotentialtobioaccumulate,howevermetabolismorphysicalpropertiesmayreducethebioconcentrationorlimitbioavailability?ECOLOGICALDATADataforHighlyRefinedSeverelyHydrotreatedoilforsimilarmaterialsTEST Duration OrganismType TestResultsAquatic–ChronicToxicity
21days Waterflea NOELR1.05mg/l:dataforsimilar
7days Fish NOEC:>5,000mg/l(IUCLIDDataset)
7days AquaticInvertebrates NOEC:>5,000mg/l(IUCLIDDataset)
Careshouldbetakentominimizereleaseofthisproductintotheenvironment
EnvironmentalFate&DistributionPersistence&DegradationToxicityEffectonEffluentTreatment
NoDataAvailableNoDataAvailableProductmaybepartiallyremovedinbiologicaltreatmentprocesses
OtherTypical(notaspecification) AcuteToxicitytoFishEffectConcentrationonAlgaeReadyBiodegradabilityRespirationInhibitionAbsorption/DesorptionAbioticDegradability-Hydrolysis
NoDataAvailableNoDataAvailableNoDataAvailableNoDataAvailableNoDataAvailableNotmeasurable
SAFETYDATASHEETJMSSTYLET-OIL
SECTION13:DISPOSALCONSIDERATIONSDisposalmethods:ThismaterialmustbedisposedofaccordingtoFederal,Stateorlocalprocedures
undertheResourceConservationandRecoveryAct:"Empty"containersretainresidue(liquidand/orvapor)andcanbedangerous.DONOTPRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRINDOREXPOSESUCHCONTAINERSTOHEAT,FLAME,SPARKS,STATICELECTRICITY,OROTHERSOURCESOFIGNITION:THEYMAYEXPLODEANDCAUSEINJURYORDEATH.Donotattempttocleansinceresidueisdifficulttoremove."Empty"drumsshouldbecompletelydrained,properlybungedandpromptlyreturnedtoadrumreconditioner.Allothercontainersshouldbedisposedofinanenvironmentallysafemannerandinaccordancewithgovernmentalregulations.
SECTION14:TRANSPORTINFORMATIONUNProperShippingName: NotregulatedbyDOT,IATAorIMDGMarinePollutant: NotaPollutantSpecialProvisionsfortransport: NoneidentifiedThis product in non-hazardous. The product contains no known carcinogens. No special warning labels are required under OSHA 29CFR 1910.1200. OSHA hazard warnings are not applicable for this product. Therefore, no OSHA Warnings would appear on the label. No EPA hazard classification code. HS TARIFF CLASSIFICATION:2710.19.4540
SAFETYDATASHEETJMSSTYLET-OIL
SECTION15:REGULATORYINFORMATIONEurope MaterialisnotdangerousasdefinedbytheEUDangerousSubstances/PreparationsDirectives.
EULABELING:NotregulatedaccordingtoEUdirectives.MaterialisnotdangerousasdefinedbytheEUDangerousSubstances/PreparationsDirectivesClassificationandlabelinghavebeenperformedaccordingtoEUDirectives67/548/EEC,1999/45/ECand2001/58/EC(includingamendments)andtheintendeduse
UnitedStates EPASARATitleIIIChemicalListings Section302ExtremelyHazardousSubstances:None Section304CERCLAHazardousSubstances:None SARA311/312CATEGORIES
1. Immediate(Acute)HealthEffects:YES2. Delayed(Chronic)HealthEffects:NO3. FireHazard:NO4. SuddenReleaseofPressureHazard:NO5. ReactivityHazard:NO
OSHAHAZARDCOMMUNICATIONHAZARD:Whenusedforitsintendedpurposes,thismaterialisnot classifiedashazardousinaccordancewithOSHA29CFR1910.1200Canada
WHMIS(CanadianWorkplaceHazardousMaterialsInformationSystems)ThisproductwhentestedasawholeisnotacontrolledsubstancewithinthemeaningoftheHazardousProductsAct.
GermanyWaterHazardousClass(WGK):1(lowhazardtowater)NATIONALLEGISLATION/REGULATIONS Ozonedepletingchemicals:NoozonedepletingchemicalsarepresentorusedinmanufactureREGULATORYSTATUSANDAPPLICABLELAWSANDREGULATIONS Complieswiththefollowingnational/regionalchemicalinventoryrequirements:DSL,ENCS,T SCA Special:
SAFETYDATASHEETJMSSTYLET-OIL
SECTION15:REGULATORYINFORMATIONREGULATORYSTATUSANDAPPLICABLELAWSANDREGULATIONS Complieswiththefollowingnational/regionalchemicalinventoryrequirements:DSL,ENCS,T SCA Special: Inventory StatusAICS AllcomponentsarelistedorexemptedELINCS RestrictionsApplyIECSC AllcomponentsarelistedorexemptedKECI AllcomponentsarelistedorexemptedPICCS Allcomponentsarelistedorexempted
DetailU.S.Regulations
USINVENTORY(TSCA8b):ListedoninventorySARATitleIIISection302ExtremelyHazardousSubstances(40CFRPart355):ThisproductisnotregulatedunderSection302ofSARAand40CFRPart355SARATitleIIISections311/312HazardousCategorization(40CFRPart370):DefinedasImmediate(Acute)HealthEffectsbyOSHAunder29CFR1910.1200(d)SARA313toxicchemicalnotificationandreleasereporting:NoproductswerefoundCERCLASections102a/103HazardousSubstances(40CFRPart302.4):ThismaterialisnotregulatedunderCERCLASections103and107
StateRegulations Noproductswerefound
CaliforniaProp65:Noproductswerefound
SAFETYDATASHEETJMSSTYLET-OIL
USAHazardousMaterialInformationSystemandNationalFireProtectionAssociation(U.S.A.)DegreeofHazard NFPA HMIS HAZARDRATINGS Health 1 1 Insignificant Fire 1 1 Slight Reactivity 0 0 Moderate PersonalProtection B High Theinformationandrecommendationscontainedhereinare,tothebestofourknowledgeandbelied,accurateandreliableasofthedateissued.Youcancontactustoensurethatthisdocumentisthemostcurrentavailable.Theinformationandrecommendationsareofferedfortheuser’sconsiderationandexamination.Itistheuser’sresponsibilitytosatisfyitselfthattheproductissuitablefortheintendeduse.Ifbuyerrepackagesthisproduct,itistheuser’sresponsibilitytosatisfyhealth,safetyandothernecessaryinformationisincludedwithand/oronthecontainer.Appropriatewarningsandsafe-handlingproceduresshouldbeprovidedorretransmissionofthisdocument,inwholeorinpartisnotpermitted.
SECTION16:OTHERINFORMATIONThisproductsafetydatasheetwaspreparedincomplianceandConformstoHazComm2012/UnitedStates.CertainelementsrefertoCommissionDirective2001/58/EC.,91/155/EEC,67/548/EECand1999/45/ECforreferenceaswellastheirrelevantamendments,ontheapproximationoflaws,regulationsandadministrativeprovisionsrelativetotheclassification,packagingandlabelingofdangeroussubstancesandpreparations.DateofIssue:6-February2018ATE=AcuteToxicityEstimateBCF=BioconcentrationFactorGHS=GloballyHarmonizedSystemofClassificationandLabelingofChemicalsIATA=InternationalAirTransportAssociationIBC=IntermediateBulkContainerIMDG=InternationalMaritimeDangerousGoodsLogPow=logarithmoftheoctanol/waterpartitioncoefficientMARPOL73/78=InternationalConventionforthePreventionofPollutionfromShips,1973asmodifiedbytheProtocolof1978.(“Marpol”)=marinepollutionUN=UnitedNationsN/D=Notdetermined;N/A=NotapplicableKEYTOTHERISKCODESINSECTION2AND3OFTHISDOCUMENT(forinformationonly)EURiskPhrases:R20:HarmfulbyinhalationR65:Harmful:maycauselungdamageifswallowedSafetyPhrases:S2:KeepoutofreachofchildrenS62:Isswalloweddonotinducevomiting:seekmedicaladviceimmediatelyandshowthiscontainerorlabel
