SAFETY DATA SHEET CARPLAN DEMON COOL
Transcript of SAFETY DATA SHEET CARPLAN DEMON COOL
Revision date: 14/10/2018 Revision: 1
SAFETY DATA SHEETCARPLAN DEMON COOL
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name CARPLAN DEMON COOL
Product number DCO101, DCO000
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Antifreeze liquid.
1.3. Details of the supplier of the safety data sheet
Supplier TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]
Manufacturer TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]
1.4. Emergency telephone number
Emergency telephone +44 (0)161 764 5981
SECTION 2: Hazards identification
2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified
Health hazards Acute Tox. 4 - H302
Environmental hazards Not Classified
2.2. Label elements
Pictogram
Signal word Warning
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Hazard statements H302 Harmful if swallowed.
Precautionary statements P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P501 Dispose of contents/ container in accordance with local regulations.
Contains ETHANEDIOL
Supplementary precautionarystatements
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.P330 Rinse mouth.P501 Dispose of contents/ container to …
2.3. Other hazards
This product contains substances classified as PBT.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
ETHANEDIOL 60-100%
CAS number: 107-21-1 EC number: 203-473-3 REACH registration number: 01-2119456816-28-0000
ClassificationAcute Tox. 4 - H302STOT RE 2 - H373
The full text for all hazard statements is displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information Effects may be delayed. Keep affected person under observation. For breathing difficulties,oxygen may be necessary. If breathing stops, provide artificial respiration. Get medicalattention. Remove affected person from source of contamination. Place unconscious personon the side in the recovery position and ensure breathing can take place. Never give anythingby mouth to an unconscious person.
Inhalation Remove affected person from source of contamination. Get medical attention if any discomfortcontinues. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration. If spray/mist has been inhaled, proceed as follows. Move affected personto fresh air and keep warm and at rest in a position comfortable for breathing. If throat irritationor coughing persists, proceed as follows. Get medical attention. Show this Safety Data Sheetto the medical personnel.
Ingestion Get medical attention immediately. Never give anything by mouth to an unconscious person.Try to induce vomiting. If vomiting occurs, the head should be kept low so that vomit does notenter the lungs. Rinse mouth thoroughly with water. Give plenty of water to drink. Get medicalattention if a large quantity has been ingested. Show this Safety Data Sheet to the medicalpersonnel.
Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention ifany discomfort continues.
Eye contact Do not rub eye. Rinse immediately with plenty of water. Remove any contact lenses and openeyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention if irritationpersists after washing. Show this Safety Data Sheet to the medical personnel.
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4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and thelength of exposure. Effects may be delayed. Keep affected person under observation.
Inhalation Irritation of nose, throat and airway.
Ingestion May cause discomfort if swallowed. May cause unconsciousness, blindness and possiblydeath. Central nervous system depression.
Skin contact Prolonged skin contact may cause redness and irritation.
Eye contact Irritation, burning, lachrymation, blurred vision after liquid splash.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Extinguish with the following media: Alcohol-resistant foam. Water spray, fog or mist. Carbondioxide (CO2). Dry chemicals.
Unsuitable extinguishingmedia
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards No unusual fire or explosion hazards noted.
Hazardous combustionproducts
Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides andother toxic gases or vapours.
5.3. Advice for firefighters
Protective actions duringfirefighting
No specific firefighting precautions known.
Special protective equipmentfor firefighters
Leave danger zone immediately. Use protective equipment appropriate for surroundingmaterials.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalationof spray mist and contact with skin and eyes. In case of spills, beware of slippery floors andsurfaces.
6.2. Environmental precautions
Environmental precautions Collect and dispose of spillage as indicated in Section 13. Avoid release to the environment.Avoid discharge into drains or watercourses or onto the ground.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Stop leak if possible without risk. Eliminate all sources of ignition. No smoking, sparks, flamesor other sources of ignition near spillage. Provide adequate ventilation. Provide adequateventilation. Contain spillage with sand, earth or other suitable non-combustible material. Avoidthe spillage or runoff entering drains, sewers or watercourses. Absorb spillage with non-combustible, absorbent material.
6.4. Reference to other sections
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Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. For wastedisposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and openflame. Wear suitable protective equipment for prolonged exposure and/or high concentrationsof vapours, spray or mist. Good personal hygiene procedures should be implemented. Washhands and any other contaminated areas of the body with soap and water before leaving thework site. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours/spray and contact with skin and eyes. Avoid the formation of mists. Observe anyoccupational exposure limits for the product or ingredients. Avoid inhalation of vapours andspray/mists. Pregnant or breastfeeding women should not work with this product if there isany risk of exposure. Pregnant or breastfeeding women should not work with this product ifthere is any risk of exposure.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep away from heat, sparks and open flame. Keep container tightly closed. Keep containersupright. Keep only in the original container. Avoid contact with oxidising agents.
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parametersOccupational exposure limitsNo exposure limits known for ingredient(s).
ETHANEDIOL
Long-term exposure limit (8-hour TWA): WEL 20 ppm 52 mg/m³ vapourShort-term exposure limit (15-minute): WEL 40 ppm 104 mg/m³ vapourSkLong-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulateSkWEL = Workplace Exposure LimitSk = Can be absorbed through the skin.
8.2. Exposure controls
Protective equipment
Appropriate engineeringcontrols
Avoid inhalation of vapours. Observe any occupational exposure limits for the product oringredients. Provide adequate ventilation.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. Unless the assessment indicates a higher degree of protection isrequired, the following protection should be worn: Tight-fitting safety glasses.
Hand protection It is recommended that gloves are made of the following material: Nitrile rubber. Chemical-resistant, impervious gloves complying with an approved standard should be worn if a riskassessment indicates skin contact is possible.
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Other skin and bodyprotection
Wear suitable protective clothing as protection against splashing or contamination.
Hygiene measures Provide eyewash station. Wash contaminated clothing before reuse. Wash at the end of eachwork shift and before eating, smoking and using the toilet. Wash promptly if skin becomescontaminated. Promptly remove any clothing that becomes contaminated. When using do noteat, drink or smoke.
Respiratory protection No specific recommendations. Respiratory protection must be used if the airbornecontamination exceeds the recommended occupational exposure limit.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Coloured liquid.
Colour Colourless.
Odour Odourless.
pH pH (diluted solution): 6-7.5 100 g/l
Melting point Not determined.
Initial boiling point and range 100-195°C @ 760 mm Hg
Flash point Not applicable.
Evaporation rate Not determined.
Upper/lower flammability orexplosive limits
Not determined.
Vapour pressure Not determined.
Vapour density Not determined.
Relative density 1.05 @ 15°C
Solubility(ies) Miscible with water. Miscible with the following materials: acetone Alcohols.
Partition coefficient : -1.36
Auto-ignition temperature Not determined.
Decomposition Temperature Not determined.
9.2. Other information
Other information None.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity The following materials may react with the product: Oxidising materials.
10.2. Chemical stability
Stability Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions
Possibility of hazardousreactions
Not determined.
10.4. Conditions to avoid
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Conditions to avoid Avoid contact with the following materials: Oxidising materials.
10.5. Incompatible materials
Materials to avoid Strong oxidising agents.
10.6. Hazardous decomposition products
Hazardous decompositionproducts
Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides andother toxic gases or vapours.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological effects No information available.
Acute toxicity - oralATE oral (mg/kg) 833.33
Specific target organ toxicity - single exposureTarget organs Central nervous system Heart and cardiovascular system Kidneys
Inhalation May cause respiratory system irritation.
Ingestion Harmful if swallowed. May cause irritation. Symptoms following overexposure may include thefollowing: Stomach pain. Nausea, vomiting. Diarrhoea. May cause nausea, headache,dizziness and intoxication.
Skin contact Slightly irritating.
Eye contact Irritating to eyes.
Acute and chronic healthhazards
This chemical can be hazardous when inhaled and/or touched. A single exposure may causethe following adverse effects: Central nervous system depression.
Route of exposure Ingestion.
Target organs Kidneys Liver
Medical symptoms Allergic rash. Delayed, often serious, breathing problems. Tachycardia (excessively rapidheart beat, including rapid and weak pulse). Unconsciousness, possibly death.
SECTION 12: Ecological information
Ecotoxicity The product components are not classified as environmentally hazardous. However, large orfrequent spills may have hazardous effects on the environment.
12.1. ToxicityAcute aquatic toxicityAcute toxicity - fish
LC₅₀, 96 hours: 72860mg/l mg/l, Fish
Acute toxicity - aquaticinvertebrates
EC₅₀, 48 hours: 46300 mg/l, Daphnia magna
Acute toxicity - aquatic plants IC₅₀, 72 hours: >6500mg/l mg/l, Algae
12.2. Persistence and degradability
Persistence and degradability The product is biodegradable.
12.3. Bioaccumulative potential
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Bioaccumulative potential The product is not bioaccumulating.
Partition coefficient : -1.36
12.4. Mobility in soil
Adsorption/desorptioncoefficient
Not available.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvBassessment
This substance is not classified as PBT or vPvB according to current EU criteria.
12.6. Other adverse effects
Other adverse effects Not applicable.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site inaccordance with the requirements of the local Waste Disposal Authority.
Disposal methods Confirm disposal procedures with environmental engineer and local regulations.
SECTION 14: Transport information
General The product is not covered by international regulations on the transport of dangerous goods(IMDG, IATA, ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Transport labelsNo transport warning sign required.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutantNo.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
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National regulations EH40/2005 Workplace exposure limits.
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Issued by Health & Safety Department
Revision date 14/10/2018
Revision 1
SDS number 32808
SDS status Approved.
Hazard statements in full H302 Harmful if swallowed.H373 May cause damage to organs (Kidneys) through prolonged or repeated exposure.
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SAFETY DATA SHEETDEMON SHOT
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name DEMON SHOT
Product number DSW050, DSW051
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Glass cleaner.
1.3. Details of the supplier of the safety data sheet
Supplier TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]
Manufacturer TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]
1.4. Emergency telephone number
Emergency telephone +44 (0)161 764 5981
SECTION 2: Hazards identification
2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Flam. Liq. 2 - H225
Health hazards Eye Irrit. 2 - H319
Environmental hazards Not Classified
2.2. Label elements
Pictogram
Signal word Danger
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DEMON SHOT
Hazard statements H225 Highly flammable liquid and vapour.H319 Causes serious eye irritation.EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P233 Keep container tightly closed.P243 Take action to prevent static discharges.P264 Wash contaminated skin thoroughly after handling.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water or shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P337+P313 If eye irritation persists: Get medical advice/ attention.P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.P403+P235 Store in a well-ventilated place. Keep cool.P501 Dispose of contents/ container in accordance with national regulations.P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.
Detergent labelling < 5% anionic surfactants, < 5% perfumes, Contains BENZISOTHIAZOLINONE,METHYLISOTHIAZOLINONE
Supplementary precautionarystatements
P240 Ground and bond container and receiving equipment.P241 Use explosion-proof electrical equipment.P242 Use non-sparking tools.
2.3. Other hazards
Not applicable.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
ETHANOL 60-100%
CAS number: 64-17-5 EC number: 200-578-6 REACH registration number: 01-2119457610-43-0000
ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319
IPA 2.5-<5.0%
CAS number: 67-63-0 EC number: 200-661-7 REACH registration number: 01-2119457558-25-0000
ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319STOT SE 3 - H336
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1,2-BENZISOTHIAZOL-3(2H)-ONE 0.001 - <0.1%
CAS number: 2634-33-5 EC number: 220-120-9
M factor (Acute) = 1
ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Dam. 1 - H318Skin Sens. 1 - H317Aquatic Acute 1 - H400
ETHANOL 0.001 - <0.1%
CAS number: 64-17-5 EC number: 200-578-6 REACH registration number: 01-2119457610-43-0000
ClassificationFlam. Liq. 2 - H225
ETHYL ACETATE 0.001 - <0.1%
CAS number: 141-78-6 EC number: 205-500-4 REACH registration number: 01-2119475103-46-0000
ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319STOT SE 3 - H336
The full text for all hazard statements is displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information Get medical attention if any discomfort continues. Remove affected person from source ofcontamination. Effects may be delayed. Keep affected person under observation.
Inhalation Remove affected person from source of contamination. Get medical attention if any discomfortcontinues. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration.
Ingestion Get medical attention if any discomfort continues. Rinse mouth thoroughly with water. Giveplenty of water to drink. Get medical attention if a large quantity has been ingested. Show thisSafety Data Sheet to the medical personnel.
Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention ifany discomfort continues.
Eye contact Do not rub eye. Rinse immediately with plenty of water. Remove any contact lenses and openeyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention if irritationpersists after washing. Show this Safety Data Sheet to the medical personnel.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and thelength of exposure. Effects may be delayed. Keep affected person under observation.
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Inhalation Vapours in high concentrations are anaesthetic. Symptoms following overexposure mayinclude the following: Headache. Fatigue. Dizziness. Central nervous system depression.Irritation of nose, throat and airway.
Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Ingestion of largeamounts may cause unconsciousness. May cause nausea, headache, dizziness andintoxication. Burning sensation in mouth.
Skin contact Prolonged skin contact may cause redness and irritation. Mild dermatitis, allergic skin rash.
Eye contact Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Extinguish with the following media: Foam, carbon dioxide or dry powder. Water. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishingmedia
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards Vapours may form explosive mixtures with air. May form explosive mixture with air at veryhigh concentration.
Hazardous combustionproducts
Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides andother toxic gases or vapours.
5.3. Advice for firefighters
Protective actions duringfirefighting
No specific firefighting precautions known.
Special protective equipmentfor firefighters
Leave danger zone immediately. Wear positive-pressure self-contained breathing apparatus(SCBA) and appropriate protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No smoking,sparks, flames or other sources of ignition near spillage. Avoid inhalation of spray mist andcontact with skin and eyes. In case of spills, beware of slippery floors and surfaces.
6.2. Environmental precautions
Environmental precautions Do not discharge into drains or watercourses or onto the ground. Collect and dispose ofspillage as indicated in Section 13.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Stop leak if possible without risk. Eliminate all sources of ignition. No smoking, sparks, flamesor other sources of ignition near spillage. Provide adequate ventilation. Provide adequateventilation. Contain spillage with sand, earth or other suitable non-combustible material. Avoidthe spillage or runoff entering drains, sewers or watercourses. Absorb spillage with non-combustible, absorbent material.
6.4. Reference to other sections
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Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. For wastedisposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and openflame. Wear suitable protective equipment for prolonged exposure and/or high concentrationsof vapours, spray or mist. Good personal hygiene procedures should be implemented. Washhands and any other contaminated areas of the body with soap and water before leaving thework site. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours/spray and contact with skin and eyes. Avoid the formation of mists. Observe anyoccupational exposure limits for the product or ingredients. Avoid inhalation of vapours andspray/mists.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep away from heat, sparks and open flame. Keep container tightly closed. Keep containersupright. Keep only in the original container. Store away from the following materials: Acids.Oxidising materials.
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parametersOccupational exposure limitsNo exposure limits known for ingredient(s).
IPA
Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³
ETHANOL
Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³Short-term exposure limit (15-minute): WEL
ETHYL ACETATE
Long-term exposure limit (8-hour TWA): WEL 200 ppmShort-term exposure limit (15-minute): WEL 400 ppmWEL = Workplace Exposure Limit
8.2. Exposure controls
Protective equipment
Appropriate engineeringcontrols
Avoid inhalation of vapours. Observe any occupational exposure limits for the product oringredients. Provide adequate ventilation.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. Unless the assessment indicates a higher degree of protection isrequired, the following protection should be worn: Tight-fitting safety glasses.
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Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. It should be noted that liquid maypenetrate the gloves. Frequent changes are recommended. It is recommended that glovesare made of the following material: Nitrile rubber. It is recommended that gloves are made ofthe following material: Polyvinyl chloride (PVC). Rubber (natural, latex).
Other skin and bodyprotection
Provide eyewash station.
Hygiene measures Wash contaminated clothing before reuse. Wash at the end of each work shift and beforeeating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptlyremove any clothing that becomes contaminated. When using do not eat, drink or smoke.
Respiratory protection No specific recommendations. Respiratory protection must be used if the airbornecontamination exceeds the recommended occupational exposure limit.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Clear liquid.
Colour Red.
Odour Slight alcoholic.
pH pH (concentrated solution): 9.00
Melting point Not determined.
Initial boiling point and range 82°C @ 1.013 hPa
Flash point 12°C
Evaporation rate Not determined.
Upper/lower flammability orexplosive limits
Not determined.
Vapour pressure Not determined.
Vapour density Not determined.
Relative density 0.830g/cm³ @ 20°C
Solubility(ies) Miscible with water.
Partition coefficient Not determined.
Auto-ignition temperature Not determined.
Decomposition Temperature Not determined.
Viscosity <10 mm²/s @ 20°C
Explosive properties Not considered to be explosive.
Explosive under the influenceof a flame
Not considered to be explosive.
Oxidising properties Does not meet the criteria for classification as oxidising.
9.2. Other information
Other information None.
SECTION 10: Stability and reactivity
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10.1. Reactivity
Reactivity The following materials may react with the product: Acids. Aldehydes. Isocyanates. Strongoxidising agents.
10.2. Chemical stability
Stability Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions
Possibility of hazardousreactions
Not determined.
10.4. Conditions to avoid
Conditions to avoid Avoid contact with strong oxidising agents. Avoid heat, flames and other sources of ignition.Avoid contact with acids. Avoid contact with the following materials: Acids. Oxidising agents.The following materials may react violently with the product: Earth metals such as sodium,potassium and barium.
10.5. Incompatible materials
Materials to avoid Strong acids. Strong oxidising agents. Alkali metals. Metal oxides. Aldehydes. Isocyanates.
10.6. Hazardous decomposition products
Hazardous decompositionproducts
Does not decompose when used and stored as recommended.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Inhalation No specific health hazards known.
Ingestion May cause discomfort if swallowed.
Skin contact Prolonged and frequent contact may cause redness and irritation.
Eye contact Irritating to eyes.
SECTION 12: Ecological information
Ecotoxicity The product components are not classified as environmentally hazardous. However, large orfrequent spills may have hazardous effects on the environment.
12.1. ToxicityAcute aquatic toxicity12.2. Persistence and degradability
Persistence and degradability There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential No data available on bioaccumulation.
Partition coefficient Not determined.
12.4. Mobility in soil
Mobility The product is miscible with water and may spread in water systems.
Adsorption/desorptioncoefficient
Not available.
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12.5. Results of PBT and vPvB assessment
Results of PBT and vPvBassessment
This substance is not classified as PBT or vPvB according to current EU criteria.
12.6. Other adverse effects
Other adverse effects Not available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site inaccordance with the requirements of the local Waste Disposal Authority.
Disposal methods Confirm disposal procedures with environmental engineer and local regulations.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 1993
UN No. (IMDG) 1993
UN No. (ICAO) 1993
UN No. (ADN) 1993
14.2. UN proper shipping name
Proper shipping name(ADR/RID)
FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)
Proper shipping name (IMDG) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)
Proper shipping name (ICAO) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)
Proper shipping name (ADN) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, ISOPROPANOL)
14.3. Transport hazard class(es)
ADR/RID class 3
ADR/RID classification code F1
ADR/RID label 3
IMDG class 3
ICAO class/division 3
ADN class 3
Transport labels
14.4. Packing group
ADR/RID packing group II
IMDG packing group II
ICAO packing group II
ADN packing group II
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14.5. Environmental hazards
Environmentally hazardous substance/marine pollutantNo.
14.6. Special precautions for user
EmS F-E, S-E
ADR transport category 2
Emergency Action Code •3YE
Hazard Identification Number(ADR/RID)
33
Tunnel restriction code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations EH40/2005 Workplace exposure limits
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Issued by Health & Safety Department
Revision date 16/08/2018
Revision 1
Supersedes date 27/07/2018
SDS number 32775
SDS status Approved.
Hazard statements in full H225 Highly flammable liquid and vapour.H302 Harmful if swallowed.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H336 May cause drowsiness or dizziness.H400 Very toxic to aquatic life.EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
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SAFETY DATA SHEETDEMON ICE
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name DEMON ICE
Product number CDI001, CDI002, CDI096
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Antifreeze liquid.
1.3. Details of the supplier of the safety data sheet
Supplier TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]
Manufacturer TETROSYL LIMITEDBuryLancashireEnglandBL9 7NY0161 764 59810161 797 [email protected]
1.4. Emergency telephone number
Emergency telephone +44 (0)161 764 5981
SECTION 2: Hazards identification
2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Flam. Liq. 3 - H226
Health hazards STOT RE 2 - H373
Environmental hazards Not Classified
2.2. Label elements
Pictogram
Signal word Warning
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Hazard statements H226 Flammable liquid and vapour.H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P233 Keep container tightly closed.P243 Take precautionary measures against static discharge.P260 Do not breathe vapour/ spray.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water/ shower.P314 Get medical advice/ attention if you feel unwell.P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.P403+P235 Store in a well-ventilated place. Keep cool.P501 Dispose of contents/ container in accordance with national regulations.
Contains ETHANEDIOL
Detergent labelling < 5% perfumes
Supplementary precautionarystatements
P240 Ground/ bond container and receiving equipment.P241 Use explosion-proof electrical equipment.P242 Use only non-sparking tools.
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.2. Mixtures
ETHANEDIOL 10-<30%
CAS number: 107-21-1 EC number: 203-473-3 REACH registration number: 01-2119456816-28-0000
ClassificationAcute Tox. 4 - H302STOT RE 2 - H373
ETHANOL 10-<30%
CAS number: 64-17-5 EC number: 200-578-6 REACH registration number: 01-2119457610-43-0000
ClassificationFlam. Liq. 2 - H225
IPA 2.5-<5.0%
CAS number: 67-63-0 EC number: 200-661-7 REACH registration number: 01-2119457558-25-0000
ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319STOT SE 3 - H336
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METHANOL 0.5-<1%
CAS number: 67-56-1 EC number: 200-659-6 REACH registration number: 01-2119433307-44-0000
ClassificationFlam. Liq. 2 - H225Acute Tox. 3 - H301Acute Tox. 3 - H311Acute Tox. 3 - H331STOT SE 1 - H370
DIETHANOLAMINE 0.001 - <0.1%
CAS number: 111-42-2 EC number: 203-868-0
ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Dam. 1 - H318STOT RE 2 - H373
ETHYL ACETATE 0.001 - <0.1%
CAS number: 141-78-6 EC number: 205-500-4 REACH registration number: 01-2119475103-46-0000
ClassificationFlam. Liq. 2 - H225Eye Irrit. 2 - H319STOT SE 3 - H336
CYCLOHEXANE 0.001 - <0.1%
CAS number: 110-82-7 EC number: 203-806-2
M factor (Acute) = 1 M factor (Chronic) = 1
ClassificationFlam. Liq. 2 - H225Skin Irrit. 2 - H315STOT SE 3 - H336Asp. Tox. 1 - H304Aquatic Acute 1 - H400Aquatic Chronic 1 - H410
The full text for all hazard statements is displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
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General information Get medical attention if any discomfort continues. Remove affected person from source ofcontamination. Effects may be delayed. Keep affected person under observation. Whenbreathing is difficult, properly trained personnel may assist affected person by administeringoxygen. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration.
Inhalation Remove affected person from source of contamination. Get medical attention if any discomfortcontinues. For breathing difficulties, oxygen may be necessary. If breathing stops, provideartificial respiration.
Ingestion Get medical attention if any discomfort continues. Rinse mouth thoroughly with water. Giveplenty of water to drink. Get medical attention if a large quantity has been ingested. Show thisSafety Data Sheet to the medical personnel. Get medical attention immediately.
Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention ifany discomfort continues.
Eye contact Do not rub eye. Rinse immediately with plenty of water. Remove any contact lenses and openeyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention if irritationpersists after washing. Show this Safety Data Sheet to the medical personnel.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and thelength of exposure. Effects may be delayed. Keep affected person under observation.
Inhalation Vapours in high concentrations are anaesthetic. Symptoms following overexposure mayinclude the following: Headache. Fatigue. Dizziness. Central nervous system depression.Irritation of nose, throat and airway.
Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Ingestion of largeamounts may cause unconsciousness. May cause nausea, headache, dizziness andintoxication. Burning sensation in mouth. May cause unconsciousness, blindness and possiblydeath.
Skin contact Prolonged skin contact may cause redness and irritation. Mild dermatitis, allergic skin rash.
Eye contact Irritation of eyes and mucous membranes. Irritation, burning, lachrymation, blurred vision afterliquid splash.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Extinguish with the following media: Foam, carbon dioxide or dry powder. Water. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishingmedia
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards Vapours may form explosive mixtures with air. May form explosive mixture with air at veryhigh concentration.
Hazardous combustionproducts
Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides andother toxic gases or vapours.
5.3. Advice for firefighters
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Protective actions duringfirefighting
No specific firefighting precautions known.
Special protective equipmentfor firefighters
Leave danger zone immediately. Wear positive-pressure self-contained breathing apparatus(SCBA) and appropriate protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No smoking,sparks, flames or other sources of ignition near spillage. Avoid inhalation of spray mist andcontact with skin and eyes. In case of spills, beware of slippery floors and surfaces.
6.2. Environmental precautions
Environmental precautions Do not discharge into drains or watercourses or onto the ground. Collect and dispose ofspillage as indicated in Section 13.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Stop leak if possible without risk. Eliminate all sources of ignition. No smoking, sparks, flamesor other sources of ignition near spillage. Provide adequate ventilation. Provide adequateventilation. Contain spillage with sand, earth or other suitable non-combustible material. Avoidthe spillage or runoff entering drains, sewers or watercourses. Absorb spillage with non-combustible, absorbent material.
6.4. Reference to other sections
Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. For wastedisposal, see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and openflame. Wear suitable protective equipment for prolonged exposure and/or high concentrationsof vapours, spray or mist. Good personal hygiene procedures should be implemented. Washhands and any other contaminated areas of the body with soap and water before leaving thework site. Do not eat, drink or smoke when using the product. Avoid inhalation ofvapours/spray and contact with skin and eyes. Avoid the formation of mists. Observe anyoccupational exposure limits for the product or ingredients. Avoid inhalation of vapours andspray/mists.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep away from heat, sparks and open flame. Keep container tightly closed. Keep containersupright. Keep only in the original container. Store away from the following materials: Acids.Oxidising materials.
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure Controls/personal protection
8.1. Control parametersOccupational exposure limitsNo exposure limits known for ingredient(s).
ETHANEDIOL
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Long-term exposure limit (8-hour TWA): WEL 20 ppm 52 mg/m³ vapourShort-term exposure limit (15-minute): WEL 40 ppm 104 mg/m³ vapourSkLong-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulateSk
ETHANOL
Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³Short-term exposure limit (15-minute): WEL
IPA
Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³
METHANOL
Long-term exposure limit (8-hour TWA): WEL 200 ppm 266 mg/m³Short-term exposure limit (15-minute): WEL 250 ppm 333 mg/m³Sk
DIETHANOLAMINE
Long-term exposure limit (8-hour TWA): OES 3 ppm 15 mg/m³Short-term exposure limit (15-minute): OES
ETHYL ACETATE
Long-term exposure limit (8-hour TWA): WEL 200 ppmShort-term exposure limit (15-minute): WEL 400 ppm
CYCLOHEXANE
Long-term exposure limit (8-hour TWA): WEL 100 ppm 350 mg/m³Short-term exposure limit (15-minute): WEL 300 ppm 1050 mg/m³WEL = Workplace Exposure Limit
Sk = Can be absorbed through the skin.
8.2. Exposure controls
Protective equipment
Appropriate engineeringcontrols
Avoid inhalation of vapours. Observe any occupational exposure limits for the product oringredients. Provide adequate ventilation.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. Unless the assessment indicates a higher degree of protection isrequired, the following protection should be worn: Tight-fitting safety glasses.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. It should be noted that liquid maypenetrate the gloves. Frequent changes are recommended. It is recommended that glovesare made of the following material: Nitrile rubber. It is recommended that gloves are made ofthe following material: Polyvinyl chloride (PVC). Rubber (natural, latex).
Other skin and bodyprotection
Provide eyewash station.
Hygiene measures Wash contaminated clothing before reuse. Wash at the end of each work shift and beforeeating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptlyremove any clothing that becomes contaminated. When using do not eat, drink or smoke.
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Respiratory protection No specific recommendations. Respiratory protection must be used if the airbornecontamination exceeds the recommended occupational exposure limit.
SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Appearance Clear liquid.
Colour Blue.
Odour Slight alcoholic.
pH pH (concentrated solution): 6.5 - 7.5
Melting point Not determined.
Initial boiling point and range ~100°C @ 1.013 hPa
Flash point 30.5°C
Evaporation rate Not determined.
Upper/lower flammability orexplosive limits
Not determined.
Vapour pressure Not determined.
Vapour density Not determined.
Relative density 1.02g/cm³ @ 20°C
Solubility(ies) Soluble in water.
Partition coefficient Not determined.
Auto-ignition temperature Not determined.
Decomposition Temperature Not determined.
Viscosity 200 - 400 cP @ 20°C
Explosive properties Not considered to be explosive.
Explosive under the influenceof a flame
Not considered to be explosive.
Oxidising properties Does not meet the criteria for classification as oxidising.
9.2. Other information
Other information None.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity The following materials may react with the product: Acids. Aldehydes. Isocyanates. Strongoxidising agents.
10.2. Chemical stability
Stability Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions
Possibility of hazardousreactions
Not determined.
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10.4. Conditions to avoid
Conditions to avoid Avoid contact with strong oxidising agents. Avoid heat, flames and other sources of ignition.Avoid contact with the following materials: Acids. Oxidising agents. The following materialsmay react violently with the product: Earth metals such as sodium, potassium and barium.
10.5. Incompatible materials
Materials to avoid Strong acids. Strong oxidising agents. Alkali metals. Metal oxides. Aldehydes. Isocyanates.
10.6. Hazardous decomposition products
Hazardous decompositionproducts
Does not decompose when used and stored as recommended.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological effects No information available.
Acute toxicity - oralATE oral (mg/kg) 2,232.14
Acute toxicity - dermalATE dermal (mg/kg) 51,724.14
Acute toxicity - inhalationATE inhalation (vapours mg/l) 517.24
Inhalation May cause drowsiness or dizziness. High concentrations of vapours may irritate respiratorysystem and lead to headache, fatigue, nausea and vomiting.
Ingestion May cause stomach pain or vomiting.
Skin contact Prolonged and frequent contact may cause redness and irritation.
Eye contact May cause temporary eye irritation.
Acute and chronic healthhazards
May cause damage to organs through prolonged or repeated exposure.
SECTION 12: Ecological Information
Ecotoxicity The product components are not classified as environmentally hazardous. However, large orfrequent spills may have hazardous effects on the environment.
12.1. Toxicity
Acute toxicity - fish Not available.
Acute toxicity - aquaticinvertebrates
Not available.
12.2. Persistence and degradability
Persistence and degradability There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential No data available on bioaccumulation.
Partition coefficient Not determined.
12.4. Mobility in soil
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Mobility The product is soluble in water.
Adsorption/desorptioncoefficient
Not available.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvBassessment
This substance is not classified as PBT or vPvB according to current EU criteria.
12.6. Other adverse effects
Other adverse effects Not available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
General information Waste is classified as hazardous waste. Dispose of waste to licensed waste disposal site inaccordance with the requirements of the local Waste Disposal Authority.
Disposal methods Confirm disposal procedures with environmental engineer and local regulations.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 1993
UN No. (IMDG) 1993
UN No. (ICAO) 1993
UN No. (ADN) 1993
14.2. UN proper shipping name
Proper shipping name(ADR/RID)
FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)
Proper shipping name (IMDG) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)
Proper shipping name (ICAO) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)
Proper shipping name (ADN) FLAMMABLE LIQUID, N.O.S. (CONTAINS ETHANOL, Isopropanol)
14.3. Transport hazard class(es)
ADR/RID class 3
ADR/RID classification code F1
ADR/RID label 3
IMDG class 3
ICAO class/division 3
ADN class 3
Transport labels
14.4. Packing group
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ADR/RID packing group III
IMDG packing group III
ADN packing group III
ICAO packing group III
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutantNo.
14.6. Special precautions for user
EmS F-E, S-E
ADR transport category 3
Emergency Action Code •3Y
Hazard Identification Number(ADR/RID)
30
Tunnel restriction code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations EH40/2005 Workplace exposure limits
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18December 2006 concerning the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH) (as amended).
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
SECTION 16: Other information
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 07/08/2017
Revision 3
Supersedes date 19/07/2017
SDS number 32442
SDS status Approved.
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Hazard statements in full H225 Highly flammable liquid and vapour.H226 Flammable liquid and vapour.H301 Toxic if swallowed.H302 Harmful if swallowed.H304 May be fatal if swallowed and enters airways.H311 Toxic in contact with skin.H315 Causes skin irritation.H318 Causes serious eye damage.H319 Causes serious eye irritation.H331 Toxic if inhaled.H336 May cause drowsiness or dizziness.H370 Causes damage to organs .H373 May cause damage to organs through prolonged or repeated exposure.H373 May cause damage to organs (Kidneys) through prolonged or repeated exposure.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.
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