SAFETY DATA SHEET · CA-14TM Mastic Not available. Liquid. Product identifier Other means of...

CA-14TM Mastic

Not available.

Liquid.

Product identifier

Other means of identification

Product type

Section 1. Identification:

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SAFETY DATA SHEETCA-14TM Mastic

Compliant SDS for GHS - Canada WHMIS 2015

Identified uses

Emergency telephone number (with hours of operation)

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Supplier/Manufacturer :

Polyguard CA-14TM Mastic is a general maintenance coating of excellent quality for use on buried steel.

Supplier's details : IN-LINE PIGGING SOLUTIONS LTD.220-40TH Avenue NE Calgary, AB T2E 2M7CanadaTel: 1-403-930-5150Fax: 1-403-250-3362Web site:www.inlingepigging.com

Polyguard Products Inc.4101 South Interstate 45Ennis, TX 75119Tel: 214-515-5000Email address: [email protected] site: www.polyguard.com

CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-388724/7

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Section 2. Hazard identificationFLAMMABLE LIQUIDS - Category 2ACUTE TOXICITY (oral) - Category 4SKIN IRRITATION - Category 2EYE IRRITATION - Category 2ASKIN SENSITIZATION - Category 1GERM CELL MUTAGENICITY - Category 1CARCINOGENICITY - Category 1TOXIC TO REPRODUCTION (Fertility) - Category 1TOXIC TO REPRODUCTION (Unborn child) - Category 1SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2AQUATIC HAZARD (ACUTE) - Category 2AQUATIC HAZARD (LONG-TERM) - Category 2

Classification of the substance or mixture

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GHS label elements

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com 1/13

CA-14TM Mastic

Section 2. Hazard identification

Signal word : Danger

Hazard statements : H225 - Highly flammable liquid and vapor.H302 - Harmful if swallowed.H319 - Causes serious eye irritation.H315 - Causes skin irritation.H317 - May cause an allergic skin reaction.H340 - May cause genetic defects.H350 - May cause cancer.H360 - May damage fertility or the unborn child.H371 - May cause damage to organs.H336 - May cause drowsiness or dizziness.H373 - May cause damage to organs through prolonged or repeated exposure.H411 - Toxic to aquatic life with long lasting effects.

Hazard pictograms :

Precautionary statements

Prevention : P201 - Obtain special instructions before use.P202 - Do not handle until all safety precautions have been read and understood.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P271 - Use only outdoors or in a well-ventilated area.P273 - Avoid release to the environment.P260 - Do not breathe vapor.P270 - Do not eat, drink or smoke when using this product.P264 - Wash hands thoroughly after handling.P272 - Contaminated work clothing should not be allowed out of the workplace.

Response : P391 - Collect spillage.P314 - Get medical attention if you feel unwell.P308 + P311 - IF exposed or concerned: Call a POISON CENTER or physician.P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.P302 + P352 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water.Take off contaminated clothing and wash it before reuse.P333 + P313 - If skin irritation or rash occurs: Get medical attention.P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing.P337 + P313 - If eye irritation persists: Get medical attention.

Storage : P405 - Store locked up.

Disposal : P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

Other hazards which do not result in classification/HHNOC/PHNOC

: None known.


CA-14TM Mastic

Section 3. Composition/information on ingredients

Toluene 10 - 30 108-88-3Pitch, petroleum, arom. 10 - 30 68187-58-6Methanol 5 - 10 67-56-1Distillates (petroleum), solvent-dewaxed heavy paraffinic 5 - 10 64742-65-05-Methylchrysene 0.1 - 1 3697-24-3Benzo[a]pyrene 0 - 0.1 50-32-8Benz[a]anthracene 0 - 0.1 56-55-3

Ingredient name CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Other means of identification

: Not available.

CAS number : Not applicable.

Substance/mixture

Product code : Not available.

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

% (w/w)

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs,the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. If necessary, call a poison center or physician.

Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes.Get medical attention. If necessary, call a poison center or physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse.Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing.If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician.If unconscious, place in recovery position and get medical attention immediately.Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First-aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

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Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Causes serious eye irritation.:Eye contact

Potential acute health effects


CA-14TM Mastic

Section 4. First-aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Harmful if swallowed. Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : Causes skin irritation. May cause an allergic skin reaction.

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousnessreduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessreduced fetal weightincrease in fetal deathsskeletal malformations

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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Use dry chemical, CO2, water spray (fog) or foam.

Extinguishing media

Do not use water jet or water-based fire extinguishers.

Suitable extinguishing media

:

Unsuitable extinguishing media

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CA-14TM Mastic

Section 5. Fire-fighting measures

Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

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Special protective actions for fire-fighters

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Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13).Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

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: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material.May be harmful to the environment if released in large quantities. Collect spillage.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble.Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".


CA-14TM Mastic

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene measures. Remove contaminated clothing and protective equipment before entering eating areas.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

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Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use.Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools.Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

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Precautions for safe handling

Toluene CA Alberta Provincial (Canada, 4/2009). Absorbed through skin. 8 hrs OEL: 50 ppm 8 hours. 8 hrs OEL: 188 mg/m³ 8 hours.CA British Columbia Provincial (Canada, 5/2015). TWA: 20 ppm 8 hours.CA Ontario Provincial (Canada, 7/2015). TWA: 20 ppm 8 hours.CA Quebec Provincial (Canada, 1/2014). Absorbed through skin. TWAEV: 50 ppm 8 hours. TWAEV: 188 mg/m³ 8 hours.CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin. STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours.

Methanol CA Alberta Provincial (Canada, 4/2009). Absorbed through skin. 8 hrs OEL: 262 mg/m³ 8 hours. 8 hrs OEL: 200 ppm 8 hours. 15 min OEL: 250 ppm 15 minutes. 15 min OEL: 328 mg/m³ 15 minutes.CA British Columbia Provincial (Canada, 5/2015). Absorbed through skin. TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes.CA Ontario Provincial (Canada, 7/2015). Absorbed through skin.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits


CA-14TM Mastic

Section 8. Exposure controls/personal protection TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes.CA Quebec Provincial (Canada, 1/2014). Absorbed through skin. TWAEV: 200 ppm 8 hours. TWAEV: 262 mg/m³ 8 hours. STEV: 250 ppm 15 minutes. STEV: 328 mg/m³ 15 minutes.CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin. STEL: 250 ppm 15 minutes. TWA: 200 ppm 8 hours.

Distillates (petroleum), solvent-dewaxed heavy paraffinic CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 5 mg/m³ 8 hours. Form: Mist 15 min OEL: 10 mg/m³ 15 minutes. Form: MistCA Quebec Provincial (Canada, 1/2014). TWAEV: 5 mg/m³ 8 hours. Form: Mist STEV: 10 mg/m³ 15 minutes. Form: Mist

5-Methylchrysene CA Saskatchewan Provincial (Canada, 7/2013). STEL: 0.6 mg/m³, (measured as benzene solubles) 15 minutes. TWA: 0.2 mg/m³, (measured as benzene solubles) 8 hours.

Benzo[a]pyrene CA Quebec Provincial (Canada, 1/2014). TWAEV: 0.005 mg/m³ 8 hours.CA Saskatchewan Provincial (Canada, 7/2013). STEL: 0.6 mg/m³, (measured as benzene solubles) 15 minutes. TWA: 0.2 mg/m³, (measured as benzene solubles) 8 hours.

Benz[a]anthracene CA Saskatchewan Provincial (Canada, 7/2013). STEL: 0.6 mg/m³, (measured as benzene solubles) 15 minutes. TWA: 0.2 mg/m³, (measured as benzene solubles) 8 hours.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer,check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn,unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

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Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection


CA-14TM Mastic

Section 8. Exposure controls/personal protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity,wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

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Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Viscous.]

Not available.

1.1

3.2 [Air = 1]

5.1 kPa (38 mm Hg) [room temperature]

Very slightly soluble in the following materials: cold water and hot water.

Aromatic.Odor

pH

Black.Color

Evaporation rate 2.7 (Butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: 7.2222°C (45°F) [Setaflash.]

Not available.

Not applicable.

Viscosity 19,000-30,000 cps

Not applicable.Odor threshold

Partition coefficient: n-octanol/water

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Appearance

Boiling point : 100 to 121°C (212 to 249.8°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Lower: 1%Upper: 8%

Decomposition temperature : Not available.

Volatility Not available.:

VOC (w/w) : 330 g/L

Section 10. Stability and reactivity

The product is stable.Chemical stability :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.


CA-14TM Mastic

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Strong oxidizers.

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Incompatible materials :

Section 11. Toxicological information

Acute toxicity

Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hoursMethanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours

LC50 Inhalation Gas. Rat 64000 ppm 4 hoursLD50 Dermal Rabbit 15800 mg/kg -LD50 Oral Rat 5600 mg/kg -

Distillates (petroleum), solvent-dewaxed heavy paraffinic

LD50 Dermal Rabbit >5000 mg/kg -

LD50 Oral Rat >5000 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Mutagenicity

Teratogenicity

Reproductive toxicity

Irritation/Corrosion

Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 mg

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Eyes - Mild irritant Rabbit - 870 µg -Eyes - Severe irritant Rabbit - 24 hours 2 mg -Skin - Mild irritant Pig - 24 hours 250 µl -Skin - Mild irritant Rabbit - 435 mg -Skin - Moderate irritant Rabbit - 24 hours 20 mg -Skin - Moderate irritant Rabbit - 500 mg -

Benzo[a]pyrene Skin - Mild irritant Mouse - 14 µg -

Product/ingredient name Result Score Exposure Observation

Sensitization

Species

Specific target organ toxicity (single exposure)

Information on toxicological effects

There is no data available.




Classification

Product/ingredient name

Toluene - 3 - A4 - -Distillates (petroleum), solvent-dewaxed heavy paraffinic

- - - A4 - -

5-Methylchrysene - 2B Reasonably anticipated to be a human carcinogen. - - +

ACGIH EPA NIOSHNTPIARCOSHA


CA-14TM Mastic


Information on the likely routes of exposure

Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Harmful if swallowed. Can cause central nervous system (CNS) depression.:Ingestion

Skin contact : Causes skin irritation. May cause an allergic skin reaction.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousnessreduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessreduced fetal weightincrease in fetal deathsskeletal malformations

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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Delayed and immediate effects and also chronic effects from short and long term exposure

Specific target organ toxicity (repeated exposure)

Toluene Category 3 Not applicable. Narcotic effectsMethanol Category 1 Not determined Not determined

Name Category

Name Category

Toluene Category 2 Not determined Not determined

Aspiration hazard

Name Result

Toluene ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Route of exposure

Target organs

: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects

Short term exposure


CA-14TM Mastic


May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

General :

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :

May cause genetic defects.Mutagenicity :

May damage the unborn child.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : May damage fertility.

Potential chronic health effects

Numerical measures of toxicity

Oral 1416.4 mg/kgDermal 4249.3 mg/kgInhalation (vapors) 42.49 mg/L

Route ATE value

Acute toxicity estimates

Potential immediate effects

: No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards.

Potential immediate effects

: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.

Section 12. Ecological information

Bioaccumulative potential

Toxicity

Toluene Acute EC50 11600 µg/L Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult

48 hours

Acute EC50 6000 µg/L Fresh water Daphnia - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling)

48 hours

Chronic NOEC 2 mg/L Fresh water Daphnia - Daphnia magna 21 daysMethanol Acute LC50 2500000 µg/L Marine water Crustaceans - Crangon crangon - Adult 48 hours

Acute LC50 3289 mg/L Fresh water Daphnia - Daphnia magna - Neonate 48 hoursAcute LC50 290 mg/L Fresh water Fish - Danio rerio - Egg 96 hours

Benzo[a]pyrene Acute EC50 5 µg/L Fresh water Algae - Scenedesmus acutus 72 hoursAcute LC50 11 mg/L Marine water Crustaceans - Gammarus duebeni 48 hoursAcute LC50 0.25 mg/L Fresh water Daphnia - Daphnia magna - Neonate 48 hoursChronic NOEC 12 µg/L Fresh water Crustaceans - Eurytemora affinis -

Nauplii21 days

Benz[a]anthracene Acute LC50 97.5 µg/L Fresh water Daphnia - Daphnia magna - Neonate 48 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability



CA-14TM Mastic

Section 12. Ecological informationLogPow BCF Potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Toluene 2.73 90 lowPitch, petroleum, arom. 4.5 to 6 - highMethanol -0.77 <10 lowBenzo[a]pyrene 6.13 - highBenz[a]anthracene 5.76 257.04 low

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible.Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

COATING SOLUTION (Toluene,Methanol)

3

II


UN1139

3

II

UN1139

Emergency schedules (EmS)F-E, S-E

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IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No.

TDG Classification

UN1139


3

II

No.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).

AERG : 127


CA-14TM Mastic

Section 14. Transport informationSpecial precautions for user Transport within user’s premises: always transport in closed containers that are

upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

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Section 15. Regulatory information

Canada inventory : All components are listed or exempted.

Canadian lists

The following components are listed: Methanol; TolueneCanadian NPRI :

CEPA Toxic substances : The following components are listed: 5-Methylchrysene

Section 16. Other information

History

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United NationsHPR = Hazardous Products Regulations

Procedure used to derive the classification

Classification Justification

FLAMMABLE LIQUIDS - Category 2 On basis of test dataACUTE TOXICITY (oral) - Category 4 Calculation methodSKIN IRRITATION - Category 2 Calculation methodEYE IRRITATION - Category 2A Calculation methodSKIN SENSITIZATION - Category 1 Calculation methodGERM CELL MUTAGENICITY - Category 1 Calculation methodCARCINOGENICITY - Category 1 Calculation methodTOXIC TO REPRODUCTION (Fertility) - Category 1 Calculation methodTOXIC TO REPRODUCTION (Unborn child) - Category 1 Calculation methodSPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -Category 2

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) -Category 2

Calculation method

AQUATIC HAZARD (ACUTE) - Category 2 Calculation methodAQUATIC HAZARD (LONG-TERM) - Category 2 Calculation method

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Date of issue

Prepared by : KMK Regulatory Services Inc.

Version :

: 11/15/2016

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