SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the...
Transcript of SAFETY DATA SHEET Araldite GY 6010 GY 250 · Araldite_GY 6010_GY 250 2.1. Classification of the...
Revision date: 06/07/2020 Revision: 02 Supersedes date: 01/11/2018
SAFETY DATA SHEETAraldite_GY 6010_GY 250
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name Araldite_GY 6010_GY 250
Chemical name 100% 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane
REACH registration number 01-2119456619-26-0012
CAS number 1675-54-3
EU index number 603-073-00-2
EC number 216-823-5
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Manufacturing of the substance.Formulation Industrial in closed systems.Industrial use as intermediate.Industrial use as monomer.Use on industrial site.Use by professional workers.DIY Consumer Applications.
Sector of Use Refer to Annexes (after Section 16)
Process category Refer to Annexes (after Section 16)
Environmental releasecategory
Refer to Annexes (after Section 16)
Application of the substance /the mixture
Epoxy Resin liquid
1.3. Details of the supplier of the safety data sheet
Manufacturer Jubail Chemical Industries Company (JANA)Tareeq 263, Jubail 1, Jubail Industrial City, 31961Kingdom of Saudi Arabia, (PO Box 10661)Tel. +966 13 3585002Fax. +966 13 [email protected]
Only Representative REACH1907/2006/EC Article 8
NAMA GermanyTeichstrasse 38D-79539 LörrachTel. + 49 762 1940 5410Fax. + 49 762 1940 5420
1.4. Emergency telephone number
Emergency telephone Emergency CONTACT (24-Hour-Number):GBK GmbH +49 (0)6132-84463
SECTION 2: Hazards identification
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2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified
Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317
Environmental hazards Aquatic Chronic 2 - H411
2.2. Label elements
EC number 216-823-5
Hazard pictograms
Signal word Warning
Hazard-determiningcomponents of labelling
2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane
Hazard statements H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.
Precautionary statements P261 Avoid breathing vapour/ spray.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P501 Dispose of contents/ container in accordance with national regulations.P273 Avoid release to the environment.P264 Wash … thoroughly after handling.
2.3. Other hazards
Results of PBT and vPvBassessment:
Not applicable.
SECTION 3: Composition/information on ingredients
3.1. Substances
Product name Araldite_GY 6010_GY 250
Chemical name 100% 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane
REACH registration number 01-2119456619-26-0012
EU index number 603-073-00-2
CAS number 1675-54-3
EC number 216-823-5
Chemical formula C21H24O4
SECTION 4: First aid measures
4.1. Description of first aid measures
General information Promptly remove any clothing that becomes wet or contaminated.
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Inhalation IF INHALED: Move affected person to fresh air at once. Place unconscious person on theirside in the recovery position and ensure breathing can take place. Get medical attention.
Ingestion IF SWALLOWED: Administer medicinal carbon. Get medical attention immediately.
Skin contact IF ON SKIN: Wash skin thoroughly with soap and water or use an approved skin cleanser. Donot use organic solvents. Get medical attention immediately.
Eye contact IF IN EYES: Rinse with water. Remove any contact lenses and open eyelids wide apart. Getmedical attention immediately.
4.2. Most important symptoms and effects, both acute and delayed4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No information available.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishingmedia
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards Vapours may form explosive mixtures with air. Oxides of carbon. In case of fire and/orexplosion do not breathe fumes.
Hazardous combustionproducts
Thermal decomposition or combustion products may include the following substances: Oxidesof carbon. Toxic gases or vapours.
5.3. Advice for firefighters
Special protective equipmentfor firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing. Wear chemical protective suit.
Additional information Dispose of fire debris and contaminated fire fighting water in accordance with officialregulations.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing, gloves, eye and face protection.
6.2. Environmental precautions
Environmental precautions Dispose of waste to licensed waste disposal site in accordance with the requirements of thelocal Waste Disposal Authority. Do not discharge into drains or watercourses or onto theground. Avoid the spillage or runoff entering drains, sewers or watercourses. Inform therelevant authorities if environmental pollution occurs (sewers, waterways, soil or air).
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Contain and absorb spillage with sand, earth or other non-combustible material. This can beeased by using warm soapy water. Alternatively, or if it is not water-soluble, absorb thespillage with an inert, dry material and place it in a suitable waste disposal container.
6.4. Reference to other sections
Reference to other sections Follow precautions for safe handling described in this safety data sheet. For personalprotection, see Section 8. For waste disposal, see Section 13.
SECTION 7: Handling and storage
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7.1. Precautions for safe handling
Usage precautions No specific requirements are anticipated under normal conditions of use.
7.2. Conditions for safe storage, including any incompatibilities
Requirements to be met bystorerooms and receptacles
None.
Storage precautions Keep away from food, drink and animal feeding stuffs. Keep container tightly closed and dry.Store at temperatures between 2°C and 43°C.
Storage class 10 (TRGS 510) The product is non-combustible.
7.3. Specific end use(s)
Specific end use(s) No information available.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Ingredient comments No exposure limits known for ingredient(s).
DNEL Workers - Dermal; Long term : 8.33 mg/kg bw/TagWorkers - Dermal; Short term Acute: 8,33 mg/kg bw/TagWorkers - Inhalation; Short term Acute: 12.25 mg/m³Workers - Inhalation; Long term : 12.25 mg/m³
PNEC - STP; 10 mg/l- Fresh water; 0.006 mg/l- Sediment (Freshwater); 0.341 mg/kg/dwt- marine water; 0.001 mg/l- Sediment (Marinewater); 0.034 mg/kg/dwt- Soil; 0.065 mg/kg/dwt
Additional information: The lists valid during the making were used as basis
8.2. Exposure controls
Protective equipment
Appropriate engineeringcontrols
Provide adequate general and local exhaust ventilation.
Personal protection Keep away from food, drink and animal feeding stuffs. Remove contaminated clothing andwash the skin thoroughly with soap and water after work. Avoid contact with skin, eyes andclothing. Use appropriate skin cream to prevent drying of skin.
Eye/face protection Wear tight-fitting, chemical splash goggles or face shield. Personal protective equipment foreye and face protection should comply with European Standard EN166.
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Hand protection It is recommended that chemical-resistant, impervious gloves are worn. (EN 374). For userswith sensitive skin, it is recommended that suitable protective gloves are worn. It isrecommended that gloves are made of the following material: Rubber (natural, latex).Chloroprene rubber. Nitrile rubber. Viton rubber (fluoro rubber). Butyl rubber. Polyvinylchloride (PVC). Considering the data specified by the glove manufacturer, check during usethat the gloves are retaining their protective properties and change them as soon as anydeterioration is detected. The most suitable glove should be chosen in consultation with theglove supplier/manufacturer, who can provide information about the breakthrough time of theglove material.
Other skin and bodyprotection
Wear protective clothing.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Clear liquid.
Colour Colourless to pale yellow.
Odour Characteristic.
Odour threshold Not determined.
pH Not determined.
Melting point -16°C
Initial boiling point and range Not determined.
Flash point 264 - 268°C
Flammability (solid, gas) Not applicable.
Upper/lower flammability orexplosive limits
Not determined.
Vapour pressure Not determined.
Vapour density Not determined.
Density 1.15 - 1.17 g/cm3 @ 25°C
Solubility(ies) Slightly soluble in water.
Auto-ignition temperature Not determined.
Decomposition Temperature 320°C
Viscosity 8000 - 24000 mPa s @ 25°C
Explosive properties None.
Organic solvents 0.0%
VOC (EC) 0.00%
VOC (CH) 0,00%
Volatile by Wt:
9.2. Other information
Other information No information available.
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SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under the prescribed storage conditions.
Thermal decomposition /conditions to be avoided
Take precautionary measures against static discharge. Stable under the prescribed storageconditions.
10.3. Possibility of hazardous reactions
Possibility of hazardousreactions
Polymerization will not occur by itself. Masses of more than one pound (0.5 kg) of productplus an aliphatic amine will cause irreversible polymerization with considerable heat build-up.
10.4. Conditions to avoid
Conditions to avoid Keep at temperature not exceeding 300°C.
10.5. Incompatible materials
Materials to avoid Avoid contact with oxidising agents. Avoid contact with acids. Amines.
10.6. Hazardous decomposition products
Hazardous decompositionproducts
Thermal decomposition or combustion products may include the following substances:Aldehydes. Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of carbon. Toxic gases orvapours.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological effects Based on available data the classification criteria are not met.
Acute toxicity - oralAcute toxicity oral (LD₅₀mg/kg)
15,000.0
Species Rat
Acute toxicity - dermalAcute toxicity dermal (LD₅₀mg/kg)
23,000.0
Species Rabbit
ATE dermal (mg/kg) 23,000.0
Skin corrosion/irritationSkin corrosion/irritation Causes skin irritation.
Serious eye damage/irritationSerious eye damage/irritation Causes eye irritation.
Respiratory sensitisationRespiratory sensitisation Not available.
Skin sensitisationSkin sensitisation Sensitising.
Germ cell mutagenicityGenotoxicity - in vitro Based on available data the classification criteria are not met.
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CarcinogenicityCarcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicityReproductive toxicity - fertility Fertility - NOAEL 750 mg/Kg bw/day, Subcutaneous, Rat
Reproductive toxicity -development
Developmental toxicity: - NOAEL: 180 mg/Kg bw/day, Dermal, Rabbit
Specific target organ toxicity - single exposureSTOT - single exposure Based on available data the classification criteria are not met.
Specific target organ toxicity - repeated exposureSTOT - repeated exposure Based on available data the classification criteria are not met.
Aspiration hazardAspiration hazard Based on available data the classification criteria are not met.
Toxicological information of the main substances found in the product:
SECTION 12: Ecological information
General Notes The product contains a substance which is toxic to aquatic organisms. Water hazard class 2(German Regulation) (Self-assessment): hazardous for water Do not allow product to reachground water, water course or sewage system. Danger to drinking water if even smallquantities leak into the ground.
Ecotoxicity Toxic for fish.
12.1. Toxicity
Toxicity Adopt good working practices, so that the product is not released into the environment.
Acute aquatic toxicityAcute toxicity - fish LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss
Acute toxicity - aquaticinvertebrates
EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna
Acute toxicity - aquatic plants EC₅₀, 72 hours: 11 mg/l, Freshwater algae
Acute toxicity -microorganisms
EC₅₀, 3 hours: 100 mg/l, Notes: micro-organism
12.2. Persistence and degradability
Biodegradation Not readily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential Bioaccumulation is unlikely.
12.4. Mobility in soil
Mobility No information available.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvBassessment
Not applicable.
12.6. Other adverse effects
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Other adverse effects No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
General information External recovery, treatment, recycling and disposal of waste should comply with allapplicable local and/or national regulations.
European waste catalogue: 08 04 09: waste adhesives and sealants containing organic solvents or other hazardoussubstances
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 3082
UN No. (IMDG) 3082
UN No. (ICAO) 3082
14.2. UN proper shipping name
Proper shipping name(ADR/RID)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin)
Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin), MARINEPOLLUTANT
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy Resin)
14.3. Transport hazard class(es)
ADR/RID class 9
ADR/RID classification code M6
ADR/RID label 9
IMDG class 9
ICAO class/division 9
Transport labels
14.4. Packing group
ADR/RID packing group III
IMDG packing group III
ICAO packing group III
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
14.6. Special precautions for user
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EmS F-A, S-F
ADR transport category 3
Emergency Action Code •3Z
Hazard Identification Number(ADR/RID)
90
Tunnel restriction code (-)
Transportation AdditionalInformation: ADR/IMDG
Excepted Quantities (EQ): Code:E1
Limited Quantities (LQ): 5 L
Maximum Net Quantity perInner Packaging:
30 ml
Maximum Net Quantity perOuter Packaging:
1000 ml
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16December 2008 on classification, labelling and packaging of substances and mixtures (asamended).
Qualifying quantity forapplication of lower-tierrequirements (2012/18/EU):
200MT
Qualifying quantity forapplication of upper-tierrequirements(2012/18/EU):
500MT
15.2. Chemical safety assessment
A chemical safety assessment has been carried out.
SECTION 16: Other information
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Abbreviations and acronymsused in the safety data sheet
RID: European Agreement concerning the International Carriage of Dangerous Goods byRail.ICAO: International Civil Aviation OrganisationADR: European Agreement concerning the International Carriage of Dangerous Goods byRoad.IMDG: International Maritime Dangerous Goods.IATA: International Air Transport Association.GHS: Globally Harmonized System.EINECSCAS: Chemical Abstracts Service.VOCV: Lengkungsabgabe auf fluchtingen organischen Verbindungen, Schweiz (SwissOrdinance on volatile organic compounds)VOC: Volatile Organic Compounds (USA,EU)OECD: Organization for Economic Cooperation and DevelopmentDNEL: Derived No Effect Level.PNEC: Predicted No Effect Concentration.LC₅₀: Lethal Concentration to 50 % of a test population.LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).PBT: Persistent, Bioaccumulative and Toxic substance.vPvB: Very Persistent and Very Bioaccumulative.Skin Irrit. 2 - H315Skin Irrit. = Skin irritationSkin Sens. = Skin sensitisationSkin Sens. 1 - H317Eye Irrit. = Eye irritationEye Irrit. 2 - H319Aquatic Chronic 2 - H411
Revision comments SECTION 01: Identification of the substance/mixture and of the company/undertakingSECTION 03: Composition/information on ingredients SECTION 02: Hazards IdentifcationSECTION 03: Composition/information on ingredients SECTION 07: Handling and StorageSECTION 08: Exposure Controls/Personal Protection SECTION 09: Physical and ChemicalProperties SECTION 10: Stability and Reactivity SECTION 11: Toxicological InformationSECTION 12: Ecological Information SECTION 14: Transportation Information SECTION 16:Other Information
Revision date 06/07/2020
Revision 02
Supersedes date 01/11/2018
SDS number 4640
Hazard statements in full H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.
Disclaimer This information relates only to the specific material designated and may not be valid for suchmaterial used in combination with any other materials or in any process. Such information is,to the best of the company's knowledge and belief, accurate and reliable as of the dateindicated. However, no warranty, guarantee or representation is made to its accuracy,reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability ofsuch information for his own particular use.
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Annex: Exposure scenario 1
Short title of the exposure scenario M-1 Manufacture
· Process category
PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure
or processes with equivalent containment conditions
PROC15 Use as laboratory reagent
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
· Environmental release category ERC1 Manufacture of the substance
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency 5 workdays/week.
· Worker Regular use with exposure up to 8 hrs. per workday.
· Environment The product must not be released into the environment.
· Physical parameters
The data on the physical - chemical properties in the Exposure Scenario is based on the properties of the
preparation.
· Physical state Fluid
· Concentration of the substance in the mixture The substance is main component.
· Used amount per time or activity
12000 tons per year
40 tons per day
· Other operational conditions Observe the general safety regulations when handling chemicals.
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
· Other operational conditions affecting worker exposure
Avoid contact with eyes
Avoid contact with the skin.
Avoid long-term or repeated skin contact.
· Other operational conditions affecting consumer exposure Keep out of the reach of children.
· Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
· Worker protection
· Organizational protective measures
Handling procedures must be well documented.
Ensure that activities are executed by specialists or authorised personnel only.
· Technical protective measures
Use product only in enclosed systems.
Ensure that suitable extractors are available on processing machines
· Personal protective measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Tightly sealed goggles
Chemical resistant gloves (EN 374)
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Avoid contact with the skin.
· Measures for consumer protection
Ensure adequate labelling.
Keep locked up and out of the reach of children.
Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Air Exhaust air is introduced into the gas scrubber.
· Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures
Disposal must be made according to official regulations.
Ensure that waste is collected and contained.
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· Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available
Annex: Exposure scenario 2
. Short title of the exposure scenario F-2 Formulation Industrial in closed systems
· Process category
PROC9 Transfer of substance or mixture into small containers (dedicated filling line, including weighing)
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC4 Chemical production where opportunity for exposure arises
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled
exposure or processes with equivalent containment condition
· Environmental release category ERC2 Formulation into mixture
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency 5 workdays/week.
· Worker Regular use with exposure up to 8 hrs. per workday.
· Environment The product must not be released into the environment.
· Physical parameters
· Concentration of the substance in the mixture Raw material.
· Used amount per time or activity 14000 tons per year
· Other operational conditions
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Avoid long-term or repeated skin contact.
Other operational conditions affecting consumer exposure Keep out of the reach of children.
Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
· Worker protection
· Organisational protective measures
Ensure that activities are executed by specialists or authorised personnel only.
Handling procedures must be well documented.
· Technical protective measures
The work process has to be performed under closed conditions.
Ensure that suitable extractors are available on processing machines
Use product only in enclosed systems.
· Personal protective measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin. Avoid contact with the eyes. Tightly sealed goggles Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Measures for consumer protection
Keep locked up and out of the reach of children.
Ensure adequate labelling.
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
Disposal measures
Disposal must be made according to official regulations.
Ensure that waste is collected and contained.
· Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system
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Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (oral) The calculated value is smaller than the DNEL.
· Worker (dermal) The calculated value is smaller than the DNEL.
· Worker (inhalation) The calculated value is smaller than the DNEL.
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available.
Annex: Exposure scenario 3
Short title of the exposure scenario IW-4 Industrial use as intermediate
· Product category PC19 Intermediate
· Process category
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled
exposure or processes with equivalent containment condition
PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure or
processes with equivalent containment conditions
PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent
containment conditions.
· Environmental release category ERC6a Use of intermediate
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency 5 workdays/week.
· Worker Regular use with exposure up to 8 hrs. per workday.
· Environment The product must not be released into the environment.
· Physical parameters
· Concentration of the substance in the mixture Raw material.
· Used amount per time or activity 1200 tons per year
· Other operational conditions
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Avoid long-term or repeated skin contact.
· Other operational conditions affecting consumer exposure Keep out of the reach of children.
· Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
· Worker protection
· Organisational protective measures
Ensure that activities are executed by specialists or authorised personnel only.
Handling procedures must be well documented.
· Technical protective measures
The work process has to be performed under closed conditions.
Ensure that suitable extractors are available on processing machines
Use product only in enclosed systems.
· Personal protective measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin. Avoid contact with the eyes. Tightly sealed goggles Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Measures for consumer protection
Keep locked up and out of the reach of children.
Ensure adequate labelling.
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures
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Disposal must be made according to official regulations.
Ensure that waste is collected and contained.
Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (oral) The calculated value is smaller than the DNEL.
· Worker (dermal) The calculated value is smaller than the DNEL.
· Worker (inhalation) The calculated value is smaller than the DNEL.
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available.
Annex: Exposure scenario 4
Short title of the exposure scenario IW-3 Industrial use as monomer
· Process category
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC3 Manufacture or formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition
PROC2 Chemical production or refinery in closed continuous process with occasional controlled exposure or
processes with equivalent containment conditions
PROC1 Chemical production or refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions.
· Environmental release category
ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency 5 workdays/week.
· Worker Regular use with exposure up to 8 hrs. per workday.
· Environment The product must not be released into the environment.
· Physical parameters
· Concentration of the substance in the mixture Raw material.
· Used amount per time or activity 900 tons per year
· Other operational conditions
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Avoid long-term or repeated skin contact.
· Other operational conditions affecting consumer exposure Keep out of the reach of children.
· Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
· Worker protection
· Organisational protective measures
Ensure that activities are executed by specialists or authorised personnel only.
Handling procedures must be well documented.
· Technical protective measures
The work process has to be performed under closed conditions.
Ensure that suitable extractors are available on processing machines
Use product only in enclosed systems.
· Personal protective measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin. Avoid contact with the eyes. Tightly sealed goggles Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Measures for consumer protection
Keep locked up and out of the reach of children.
Ensure adequate labelling.
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
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. Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures
Disposal must be made according to official regulations.
Ensure that waste is collected and contained.
. Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system
. Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (oral) The calculated value is smaller than the DNEL.
· Worker (dermal) The calculated value is smaller than the DNEL.
· Worker (inhalation) The calculated value is smaller than the DNEL.
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available.
Annex: Exposure scenario 5
· Short title of the exposure scenario IW6 Use on industrial site
· Process category
PROC15 Use as laboratory reagent
PROC13 Treatment of articles by dipping and pouring
PROC10 Roller application or brushing
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC7 Industrial spraying
· Environmental release category ERC5 Use at industrial site leading to inclusion into/onto article
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency 5 workdays/week.
· Worker Regular use with exposure up to 8 hrs. per workday.
· Environment The product must not be released into the environment.
· Physical parameters
· Concentration of the substance in the mixture Raw material.
· Used amount per time or activity 600 tons per year
· Other operational conditions
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
· Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Avoid long-term or repeated skin contact.
· Other operational conditions affecting consumer exposure Keep out of the reach of children.
· Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
Worker protection
· Organisational protective measures
Ensure that activities are executed by specialists or authorised personnel only.
Handling procedures must be well documented.
· Technical protective measures
The work process has to be performed under closed conditions.
Ensure that suitable extractors are available on processing machines
Use product only in enclosed systems.
· Personal protective measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin. Avoid
contact with the eyes. Tightly
sealed goggles Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Measures for consumer protection
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Keep locked up and out of the reach of children.
Ensure adequate labelling.
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures
Disposal must be made according to official regulations.
Ensure that waste is collected and contained.
. Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
. Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (oral) The calculated value is smaller than the DNEL.
· Worker (dermal) The calculated value is smaller than the DNEL.
· Worker (inhalation) The calculated value is smaller than the DNEL.
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available.
Annex: Exposure scenario 6
· Short title of the exposure scenario PW-5 Professional use
· Process category
PROC24 High (mechanical) energy work-up of substances bound in /on materials and/or articles
PROC11 Non industrial spraying
PROC13 Treatment of articles by dipping and pouring
PROC19 Manual activities involving hand contact
PROC8b Transfer of substance or mixture (charging and discharging) at dedicated facilities
PROC10 Roller application or brushing
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities
· Environmental release category
ERC8c Widespread use leading to inclusion into/onto article (indoor)
ERC8f Widespread use leading to inclusion into/onto article (outdoor)
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency 5 workdays/week.
· Worker Regular use with exposure up to 8 hrs. per workday.
· Environment The product must not be released into the environment.
· Physical parameters
· Concentration of the substance in the mixture Raw material.
· Used amount per time or activity 4000 tons per year
· Other operational conditions
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
. Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Avoid long-term or repeated skin contact. Indoor
application.
Outdoor application.
· Other operational conditions affecting consumer exposure Keep out of the reach of children.
· Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
· Worker protection
· Organisational protective measures
Ensure that activities are executed by specialists or authorised personnel only.
Handling procedures must be well documented.
· Technical protective measures
The work process has to be performed under closed conditions.
Ensure that suitable extractors are available on processing machines
Use product only in enclosed systems.
· Personal protective measures
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Do not inhale gases / fumes / aerosols.
Avoid contact with the skin. Avoid
contact with the eyes. Tightly
sealed goggles Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Measures for consumer protection
Keep locked up and out of the reach of children.
Ensure adequate labelling.
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures
Disposal must be made according to official regulations.
Ensure that waste is collected and contained.
· Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (oral) The calculated value is smaller than the DNEL.
· Worker (dermal) The calculated value is smaller than the DNEL.
· Worker (inhalation) The calculated value is smaller than the DNEL.
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available.
Annex: Exposure scenario 7
Short title of the exposure scenario
· Sector of Use C-7 DIY Consumer Applications
· Product category
PC9b Fillers, putties, plasters, modelling clay
PC9a Coatings and paints, thinners, paint removers
PC1 Adhesives, sealants
· Environmental release category
ERC8c Widespread use leading to inclusion into/onto article (indoor)
ERC8f Widespread use leading to inclusion into/onto article (outdoor)
· Description of the activities / processes covered in the Exposure Scenario
See section 1 of the annex to the Safety Data Sheet.
· Conditions of use
· Duration and frequency
Frequency of use:
1-3 applications per year: 1-3/year. Applikation pro Jahr : 1-3/year
· Environment The product must not be released into the environment.
· Physical parameters
· Concentration of the substance in the mixture Raw material.
· Used amount per time or activity 30 annual tons per plant
· Other operational conditions
· Other operational conditions affecting environmental exposure
Observe section 6 of the Safety Data Sheet (Accidental release measures).
Use only on hard ground.
· Other operational conditions affecting worker exposure
Avoid contact with eyes.
Avoid contact with the skin.
Avoid long-term or repeated skin contact. Indoor
application.
Outdoor application.
· Other operational conditions affecting consumer exposure Keep out of the reach of children.
· Other operational conditions affecting consumer exposure during the use of the product Not applicable.
· Risk management measures
· Worker protection
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· Organisational protective measures
Ensure that activities are executed by specialists or authorised personnel only.
Handling procedures must be well documented.
· Technical protective measures
The work process has to be performed under closed conditions.
Ensure that suitable extractors are available on processing machines
Use product only in enclosed systems.
· Personal protective measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin. Avoid
contact with the eyes. Tightly
sealed goggles Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Measures for consumer protection
Keep locked up and out of the reach of children.
Ensure adequate labelling.
· Environmental protection measures
Avoid release to the environment. Obtain special instructions / refer to Safety Data Sheet.
· Water Do not allow to reach sewage system.
· Soil Prevent contamination of soil.
· Notes In case of unintended release of the product: See section 6 of the Safety Data Sheet.
· Disposal measures
Disposal must be made according to official regulations.
Ensure that waste is collected and contained
. Disposal procedures
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Waste type Partially emptied and uncleaned packaging
· Exposure estimation
· Worker (oral) The calculated value is smaller than the DNEL.
· Worker (dermal) The calculated value is smaller than the DNEL.
· Worker (inhalation) The calculated value is smaller than the DNEL.
· Consumer Not relevant for this Exposure Scenario.
· Guidance for downstream users No further relevant information available.