Safe/Secure Transport of Chemicals
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Transcript of Safe/Secure Transport of Chemicals
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SAND No. 2012-5234CSandia is a multi-program laboratory operated by Sandia Corporation, a Lockheed Martin Company,
for the United States Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.
Safe/Secure Transport
of Chemicals
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Transportation
Hazardous Shipments
Modes of Transport
Regulations
Packaging
Labels
Documentation
Emergencies and Security
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Transportation: Hazardous Shipments
Laboratory samples
Equipment
Domestic shipments
International shipments
Quantity of material
Take what, where, and how much into account when making hazardous shipments
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Transportation: Hazardous Shipments
Chemical◦ Toxic◦ Oxidizers◦ Corrosive◦ Flammable◦ Explosive
Physical◦ Cryogens◦ Compressed gases◦ Magnetic
Biological◦ Infectious pathogens◦ Genetically modified organisms
Radioactive substances
Take types of hazards into account when making hazardous shipments
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Transportation: Hazardous Shipments
External events◦ Collisions, crashes, accidents
Internal Events◦ Release or spill due to
equipment or containment failure
Consequences◦ Injuries or fatalities◦ Property damage◦ Environmental damage◦ Institution impacts
Fines Negative press
Consider all that could go wrong and the consequences when making hazardous shipments
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Transportation: Modes of Transport
Air
Waterway
Rail
Road◦ Vehicle◦ Cart or bicycle
Hand carry
Transport vehicle may carry both people and your shipment
Take mode of transport into account when making hazardous shipments
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Transportation: Regulations
Thousands of regulated hazardous materials
Differences in regulations by country
Penalties can be severe◦ Willfully violation of US
hazardous material transportation regulations Fines up to $250,000 Prison for up to 5 years Both fine and prison
International regulations◦ UN Model Regulations◦ International Maritime Dangerous
Goods (IMDG) Code◦ International Air Transport
Association (IATA)
Special requirements, restrictions, or limitations
Training requirements, certifications
Take regulations into account when making hazardous shipments
Title 18 U.S.C.HMR; 49 CFR Parts 171-180
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Transportation: Regulations
Assistance from trained person
◦ CSSO, other
◦ Knows regulations
◦ Has required certifications
◦ Can ensure use of licensed, approved shipping companies
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Transportation: Packaging
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Container within a container Specific requirements depend on material and other factors
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Transportation: Documentation
Safety Data Sheets Shipping order Bill of lading Manifest Full shipper, receiver
addresses Packing and labeling
certification Verification of receipt
Follow up documentation◦ Incident/accident reports
http://worldamazingpictures.files.wordpress.com/2010/09/worlds-biggest-ship-accidents-6.jpg?w=400
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Transportation: Emergencies and Security
Emergency contacts◦ Regulation requirements
local, national, international
Public relations◦ Designate spokesperson
beforehand◦ Be responsive to public
concerns
Higher risk shipments require higher security◦ Special regulations
Photos: TSA User’s Guide on Security Seals for Domestic Cargo
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Labels
Hazard Labels◦ GHS
Transportation Labels◦ Transportation pictograms
Combination labels◦ Container label (inner and
outer)◦ Transportation
documentation Packing list
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Labels: Information
properly and fully identify material use proper, full chemical name
◦ no abbreviations ◦ ID codes, e.g., UN Numbers
Specify quantities, concentrations, number of containers
Indicate specific hazard class ◦ according to regulations
Include emergency information◦ contact names
24/7 phone numbers Language(s)
◦ proper universal symbols
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Corrosive Irritant Health Hazard Acute Toxicity
Flammable Explosion Oxidizer Compressed Gas
GHS Hazard Labels
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Example Layout: Bottle Label
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Transportation: Package Labels
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Transportation Pictograms
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Example: Outer Shipping Container
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Handling
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Where, how, who opens shipment?
Should package be opened in a hood?
Is material radioactive, flammable, reactive, explosive, etc.?
Is monitoring equipment needed?
Is special storage needed on receipt?
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Who requires training?
Managers Packers Handlers Loaders Drivers All shipping and
receiving personnel Mailroom personnel
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Internal Transportation
Secondary Containment◦ Hand carry
Carts◦ PPE◦ Spill kit
Documentation◦ Update Inventory◦ SDS
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Transport of Gas Cylinders
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Transport References
UNECE, “Globally Harmonized System Of Classification and Labeling of Chemicals (GHS),” 1st edition, 2003, online,
http://www.unece.org/trans/danger/publi/ghs/ghs_rev00/00files_e.htmlInternational Airlines Transportation Association, Dangerous Goods
Regulations(DGR), 2008, not online,http://www.iata.org/ps/publications/9065.htmUN International Maritime Organization (IMO),http://www.imo.org/European Union (EU) Transport Activitieshttp://europa.eu/US Department of Transportation (DOT) http://www.dot.gov
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Acknowledgement
International Labour Organization (ILO)
International Occupational Safety and Health Centre (CIS)
Programme on Safety and Health at Work and the Environment (SafeWork)
http://www.ilo.org/public/english/protection/safework/cis/index.htm
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Any Questions?
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