Rt Solutions-04!09!2011 XIII VXY Paper I Code B

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    13th VXY (Date: 04-09-2011) Review Test-2

    PAPER-1

    Code-B

    ANSWER KEY

    MATHS

    SECTION-2

    PART-A

    Q.1 D

    Q.2 C

    Q.3 C

    Q.4 B

    Q.5 B

    Q.6 B

    Q.7 D

    Q.8 C

    Q.9 D

    Q.10 A

    Q.11 A,B,C,D

    Q.12 A,C,D

    Q.13 A,C,D

    Q.14 A,B,D

    PART-C

    Q.1 0004

    Q.2 0002

    Q.3 0039

    Q.4 0005

    Q.5 0012

    Q.6 0003

    PHYSICS

    SECTION-1

    PART-A

    Q.1 B

    Q.2 C

    Q.3 C

    Q.4 A

    Q.5 B

    Q.6 A

    Q.7 D

    Q.8 A

    Q.9 D

    Q.10 D

    Q.11 D

    Q.12 A,B,D

    Q.13 A,C,D

    Q.14 B,D

    PART-C

    Q.1 0003

    Q.2 0010

    Q.3 0005

    Q.4 0010

    Q.5 0010

    Q.6 0002

    CHEMISTRY

    SECTION-3

    PART-A

    Q.1 B

    Q.2 B

    Q.3 B

    NOTE :Only for XY-Batch students

    Q.4 C

    NOTE : Only for V-Batch students

    Q.4 A

    Q.5 D

    Q.6 B

    Q.7 D

    Q.8 D

    Q.9 B

    Q.10 A

    Q.11 B,C,D

    Q.12 B,C

    Q.13 A,B

    Q.14 A,B

    PART-C

    Q.1 0500

    Q.2 0004

    Q.3 0012

    Q.4 0163

    Q.5 1566

    Q.6 2121

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    PHYSICS

    Code-B Page # 1

    PART-A

    Q.1

    [Sol. > c

    sin > sin c

    cos >n

    1..... (i)

    sin= n sin

    n

    sin = sin ..... (ii)

    sin< 1n2

    < sin1 1n2 ]

    Q.2

    [Sol. Kinetic energy is conserved

    22

    2

    VM

    2

    1MV

    2

    1

    +

    2

    1MV'2

    V22

    2

    'V4

    V

    'V2

    3 ]

    Q.3

    [Sol. WBBW vvv

    ; vBW

    = 3 (3) = 6 m/s

    Before collision : vBW

    = 6 m/s

    After collision, v'BW

    = vBW

    vw

    v'Bw

    vB' = v'

    Bw+ v

    w= 6 + 3 = 9 m/s ]

    Q.4

    [Sol. f = mBa B

    f

    a

    = 10 2 = 20 N ]

    Q.5

    [Sol. CBCB VVV

    VB

    VC

    VBC

    ]

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    PHYSICS

    Code-B Page # 2

    Q.6

    [Sol. WG

    + Wf= 0

    v=0Rough

    Smooth

    1

    2

    x

    2x

    u=0

    mg sin 3x mg cos 2x = 03 sin = 2 cos

    =2

    3tan ]

    Q.7

    [Sol. tan =r

    t

    a

    a= 2

    R

    R

    = tan1

    2

    r

    at

    an

    ]

    Q.8

    [Sol. In absence of air resistance

    Ei= E

    f

    Ki+ U

    i= K

    f+U

    f

    Kf

    = KiU

    U = 0Kf= KiV

    f= V

    i(independent of mass) ]

    Q.9

    [Sol. (Ksystem

    )total

    = KCM

    + (Ksystem

    )about CM

    =2

    1(m

    1+ m

    2) v

    c2 +

    2

    1v

    rel2

    =2

    1(4) (0.5)2 +

    2

    1

    4

    3(2)2 = 2J

    (Ksystem

    )total

    = 2 =

    2

    1 4 v

    c

    2 +

    2

    1

    4

    3 (3)2

    vc2 =

    16

    11]

    Q.10

    [Sol.if

    pppdtFJ

    KE = Kf Ki = m2

    p

    m2

    p2

    i

    2

    f

    W = KKKsd.Fif

    ]

    Q.12

    [Sol. aB

    =r

    v2B =

    250

    225=10

    9= 0.9 m/s2

    ABBAvvv

    60vB

    vA

    vBA

    vBA

    = 60cosvv2vv BABA 22

    vBA

    = 2/1900225900 = 26 ]

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    PHYSICS

    Code-B Page # 3

    Q.13

    [Sol. j8i6a i6a t

    j8ac

    8r

    v2

    v = 4 i4v

    2r

    v ,

    ra t k3 ]

    Q.14

    [Sol. mv1Mv = 0

    mv1

    = Mv

    Wtotal

    = K =2

    1mv

    12 +

    2

    1Mv2

    Wtotal

    =2

    1m

    2

    m

    Mv

    +

    2

    1Mv2 =

    2v

    2

    1

    M

    m

    M2

    work done by man on himself = 2

    1

    mv12

    =

    2

    m

    Mvm

    2

    1

    =

    22

    vm

    M

    2

    1

    ]

    PART-C

    Q.1

    [Sol. As shown in figure, the forces acting on the block are the gravitational

    force mg, the normal reaction N, the static friction f, and the cenrifugal

    force with f = sN, P = m2r. Thus the conditions for equilibrium are 0

    mg x

    y

    N

    Pmg sin = P cos + sN,

    N = mg cos + P sin

    Hence mg sin = P cos + s mg cos + s P sin ,

    giving P =

    sincos

    cossin

    s

    smg = m2r,,

    or 2 =

    sincos

    cossin

    s

    s=

    r

    g=

    5

    3

    4

    1

    5

    45

    4

    4

    1

    5

    3

    4.0

    8.9= 10.3

    = 3.2 rad/s ]

    Q.2

    [Sol.2

    105k

    mg2

    u

    1

    f

    1

    v

    1

    20

    12

    20

    1

    10

    1

    v

    1

    v = 20 cm

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    PHYSICS

    Code-B Page # 4

    d1

    = 20 cm (initial distance of image from mirror)

    30

    23

    15

    1

    10

    1

    v

    1

    v = 30 cm

    d2

    = 30 cm (final distance of image from mirror)

    d2d

    1= 10 cm (distance in which the image oscillates) ]

    Q.3

    [Sol. sin 30 = 1.3 sin 1

    2

    1= 1.3 sin

    1

    sin 1

    = sin 1

    =6.2

    1

    tan 1

    =h

    d= 0.42 h =

    42.0

    d= 4.8 = 5 ]

    Q.4

    [Sol. After the mishap, the spaceship moves with an initial velocity v0 and a deceleration of 1 m/s2, while thesatellite moves with a constant speed v

    0. After the mishap, the two vessels will collide at a time t given by

    v0t = 50 + v

    0t

    2

    at2,

    or t =1

    100= 10s ]

    Q.5

    [Sol. When the maximum speed is achieved, the propulsive force is equal to the resistant force. Let F be this

    propulsive force, then

    F = aV and FV = 600 W

    Eliminating F, we obtain

    V2 =a

    400= 100 m2/s2

    and the maximum speed on level ground with no wind

    v = = 10 m/s ]

    Q.6

    [Sol. The "Scotchlite" sphere is a ball of index of refraction n, whose rear semi-spherical interface is a reflecting

    surface. The focal length in the image space, f, for a single refractive interface is given by

    f =

    1n

    nr

    where r is the radius of the sphere. The index of refraction of air is unity. The index of refraction of theglass is chosen so that the back focal point of the front semi-spherical interface coincides with the apex

    of the rear semi-spherical interface i.e.,

    f = 2r

    Hence n = 2. ]

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    MATHEMATICS

    Code-B Page # 1

    PART-A

    Q.1

    [Sol. Given, L =

    0

    0

    xtan

    xsin)1a(ax2Lim

    30x=

    xtan

    x

    x

    xsin)1a(ax2Lim

    3

    3

    30x

    As, L is finite so

    3

    53

    0x x

    ........!5

    x

    !3

    x

    x)1a(ax2Lim

    =3

    3

    0x x

    xofpowershighercontainingterms!3

    x)1a(x)1a3(

    Lim

    must exists.

    (3a1) = 0 a = 31

    and L = !3

    )1a(

    = 6

    13

    1

    = 9

    1

    .

    Hence, (a + L) =9

    1

    3

    1 =

    9

    13 =

    9

    4. Ans.]

    Q.2

    [Sol. Given, x2 + px + p + 2 = 02k

    k

    Now, sum of roots = 3k =p .........(1)

    and product of roots = 2k2 = p + 2 .........(2)

    From (1) and (2), we get

    2p3

    p2

    2

    2p29p18 = 0 (2p + 3) (p 6) = 0

    p =2

    3, 6.

    Hence, integral value of p = 6. Ans.]

    Q.3

    [Sol. Given,

    f() =

    cos111

    1sin11111

    Applying C1 C

    1C

    3and C

    2 C

    2C

    3, we get

    f() =

    cos1coscos

    1sin0

    100

    Now, expanding along R1, we get

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    MATHEMATICS

    Code-B Page # 2

    f() = sin cos

    So, f() = 0 =2

    n, n I.

    Clearly, =2

    , ,

    2

    3are possible solutions in interval (0, 2). Ans.]

    Q.4

    [Sol. As, f(x) is continuous at x = 5, so f (5+

    ) = f(5) = f(5

    ) ........(1)

    Now, f (5 ) = ]x[x2

    sinLim5x

    = 45

    2sin

    = 1.

    Also, f (5+) = 3x

    8x3xabLim

    2

    5x

    = 3ab2

    From equation (1), we get

    3ab2 = 5(b1) = 1 b =5

    6and a =

    108

    25. Ans.]

    Q.5

    [Sol. Given,

    P(n) =

    n

    2n2

    )1n2(

    41

    So, P(n) =

    n

    2n2

    2

    )1n2(

    41n2=

    n

    2n2

    )1n2(

    1n23n2

    Now,

    n

    2n 1n2

    1n2)n(P

    n

    2n 1n2

    3n2=

    )1n2........(753

    )1n2()1n2.....(975

    )1n2........(753

    )3n2.....(531

    1n2

    1

    3

    )1n2()n(P

    Hence,3

    1)n(PLim

    n

    Ans.]

    Q.6

    [Sol.MB

    Given, I =

    2

    2

    3

    23 dx)3x(cos)x(

    Put, x + = t dx = dt, so

    I =

    2

    2

    23 dt)tcost( =

    2

    2functioneven

    22

    2functionodd

    3 dttcosdtt

    = 2

    0

    2 dttcos2 =24

    2

    .

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    MATHEMATICS

    Code-B Page # 3

    2

    0

    2

    0

    2t

    0t

    2

    42

    t2sint

    2

    1dtt2cos1

    2

    1dttcos,As

    Hence, I10

    =

    2

    10

    = 5 Ans.]

    Q.7

    [Sol. We must have, 1x3

    4x1

    2

    1x34x1

    2

    x34x

    2

    + 1 0 and x34x

    2

    1 0

    0x3

    )1x)(4x(

    and 0

    x3

    )1x)(4x(

    x =4,3,2,1, 1, 2, 3, 4. Hence, number of integral values is 8. Ans.]

    Q.8

    [Sol.MB

    Given, f(x) = x | x | and g(x) = sin x

    Let G(x) =

    0x,xsin

    0x,xsinxxsin)x(fg

    2

    2

    Clearly,G'(0+) =G'(0) = 0G (x) = gof (x) is differentiable at x = 0 .

    Also, G ' (x) =

    0x,xcosx2

    0x,xcosx22

    2

    G ' (x) is continuous at x = 0.

    Now, G " (x) =

    0x,xsinx4xcos2

    0x,xsinx4xcos2222

    222

    G "(0) =2 and G"(0+) = 2 Hence G '' (0+) G ''(0)

    G (x) = gof (x) is not twice differentiable at x = 0.Hence, S-1 is true, but S-2 is false. Ans.]

    Q.9

    [Sol.am

    S-1 : Clearly, domain of f = R{2, 1} Domain of f(x) is not symmetric about origin.So, f(x) is not an even function.

    Obviously S-2 is true.

    Hence, S-1 is false, but S-2 is true. Ans.]

    [Note :Here f(x) =

    8x8x

    x1x

    1xx

    3

    32

    3

    32

    22 f(x) =22 xx

    22 f(x) = f(x) (not possible)

    As, domain of f = R{2, 1} f(x) is not an even function. ]Q.10

    [Sol.mb

    S-1: As, roots of equation 2x2 + 7x + 10 = 0 are non-real, so both roots must be common.

    )say(10

    c

    7

    b

    2

    a

    So, a = 2, b = 7, c = 10

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    MATHEMATICS

    Code-B Page # 4

    Hence,b

    ca2 =

    7

    104= 2.

    Obviously, S-2 is true and explaining S-1 also. Ans.]

    Q.11

    [Sol.vkb

    Obviously, f(x) = sin1x and f '(x) =2

    x1

    1

    f '

    2

    3= 2.

    Note : sin1x > x x (0, 1) f

    3

    2>

    3

    2.

    Also,x

    xsinLim

    1

    0x

    = 1.

    Again, f (x) +

    2x1f = sin1x + sin1

    2x1 = sin1x + cos1x =

    2

    Ans.]

    Q.12

    [Sol. Given, f(x) =n2

    2n22

    n x1

    )x(sinx)x2(nLim

    l

    Now,

    1xfor),xsin(

    1xfor,2

    1sin3n

    1x0for),x2(n

    )x(f

    22

    2

    22

    l

    l

    =

    x1),xsin(

    1x,

    2

    1sin3n

    1x1),x2(n

    1x,2

    1sin3n

    1x),xsin(

    2

    2

    2

    l

    l

    l

    Now, verify alternatives.

    [Note : f(x) is an even function also.]

    Q.13

    [Solys

    Given, xcotcosectancossin 111 =6

    211

    x1tancossin = 6

    62x

    1sin

    2

    1

    2x2 = 2 x2 = 2 x = 2 .

    So, x1

    = 2 and x2 = 2Now, verify alternatives. Ans.]

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    MATHEMATICS

    Code-B Page # 5

    Q.14

    [Sol.

    (A) As, f(x) and g(x) are continuous for every xR and fog (x) is defined,

    then obviously )x(gf is also continuous for every xR.

    (B) As, f(x) is continuous on R such that 0)x(fLimx

    and 0)x(fLimx

    , so clearly

    f(x) must be bounded .

    (C) Let f(x) = cos (x)3x + 1clearly, f(x) is a continuous function in [0, 1].Also f(0) = 10 + 1 = 2 and f(1) =13 + 1 =3 f(0) f(1) < 0So, by intermediate value theorem, the equation f(x) = 0 has atleast one root in (0, 1).

    Note that f '(x) = sin (x)3 < 0 x [0, 1] f(x) is strictly decreasing function on [0, 1].Hence, the equation f(x) = 0 will have exactly one root in (0, 1).

    (D) We know that every continuous function in [a, b] is always bounded.

    So, there exists some c [a, b] where f(x) attains its maximum value .So, by extreme value theorem, f(c) f(x) x [a, b]

    PART-CQ.1

    [Sol.mkj

    Clearly, f(0+) =x

    ]xtan[aLim

    0x

    = a +x

    0= a.

    and f (0) =

    30x x

    xtanxbLim =

    3

    3

    0x x

    .......3

    xxx

    bLim = b1.

    As, f (x) is continuous at x = 0, so f(0+) = f(0) = f (0).

    So, a = 3 and b1 = 3 b = 4

    Hence,

    0r

    r

    b

    a=

    0r

    r

    4

    3= terms..........

    4

    3

    4

    31

    2

    =

    4

    31

    1

    = 4. Ans.]

    Q.2

    Sol. Given, f(x) = (2a + b) cos1 x + (a + 2b) sin1x

    = (2a + b) cos1 x + (a + 2b)

    xcos2

    1

    = (a

    b) cos1 x + (a + 2b) 2

    .

    Clearly, domain of f(x) = [1, 1] and f(x) is a continuous decreasing function on [1, 1].

    So, range of f (x) = [ f min

    (x = 1), fmax

    (x =1) ]

    Now, f min

    (x = 1) = (a + 2b)2

    and f

    max(x =1) = (ab)+ (a + 2b)

    2

    = 3a

    2

    .

    Range of f(x) =

    2

    a3,2

    )b2a(

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    MATHEMATICS

    Code-B Page # 6

    As, Domain of f and range of f are the same set,

    So, (a + 2b)2

    =1 ... (1) and 3a

    2

    = 1 .... (2)

    On solving (1) and (2) we get

    3

    2a and

    3

    4b

    Hence, (a

    b) =

    34

    3

    2

    = 23

    6

    3

    4

    3

    2

    Ans.]

    Q.3

    [Sol.aj

    Given, area (O1O

    3O

    5) = 312

    4

    3(side)2 = 312

    [Note:O1O2O3 is equilateral with length of each side equal 4r]

    (O1

    O3) = 34 .

    B M

    A

    CN

    30

    O1

    O3 O5

    4r

    O6

    O4

    O2

    a

    Also, O1O

    3= 4r = 34 .

    r = 3 (radius of circle)

    In BMO3,

    BM

    MO3

    = tan 30

    3

    1

    BM

    3 BM = 3.

    Also, BC = BM + MN + CN

    a = 3 + 4 3 + 3 or a = 6 + 4 3

    So, area (ABC) = 43

    a2 = 2

    3464

    3

    = 2

    3233 = 312213 = 36 + 321 = q21p (Given) p = 36, q = 3.

    Hence, (p + q) = 39. Ans. ]

    Q.4

    [Sol.MB

    Given, | x |24 | x | + 3| k1| = 0 .........(1)

    As above equation (1) have four distinct real roots so both roots of equation (1)

    must be positive and distinct.

    Now,

    (i) D > 0 16

    12 + 4 | k

    1| > 0 1 + | k

    1| > 0, which is true k R.(ii) Sum of roots > 0 4 > 0, which is truekR.(iii) Product of roots > 0 3| k1| > 0 | k1| < 3 2 < k < 4.

    must be satisfied simultaneously.

    1 2 3 k (2, 4).Clearly, possible integral values of k are1, 0, 1, 2, 3. Ans.]

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    MATHEMATICS

    Code-B Page # 7

    Aliter : Graph for f(x) = x24 x + 3.

    O

    y

    x3 2 1 1 2 3

    (0, 3)

    (2,1)(2,1)

    Now, x24 x + 3 = 1k will have exactly four roots if 1k < 32 < k < 4.

    Clearly, possible integral values of k are1, 0, 1, 2, 3. Ans.]

    Q.5

    [Sol. Given, f(xy) = f(x) + f(y) + x2y2(x2 + y2) x, yR+ ............(1)

    As, f '(x) =h

    )x(f)hx(fLim0h

    =

    h

    xf

    x

    h1xf

    Lim0h

    =

    h

    xfx

    h1x

    x

    h1x

    x

    h1fxf

    Lim

    22

    22

    0h

    =h

    hx

    2x2

    Limh

    1x

    h1f

    Lim0h0h

    ........(2)

    Put, x = y = 1 in equation (1), we get

    f(1) = 2f(1) + 12 f(1) = 1.

    f ' (x) =x

    2x2

    x

    hx

    )1(fx

    h1f

    Lim0h

    (Using equation (1))

    f '(x) = x2x

    2

    x

    3 f '(x) = x2

    x

    1 f(x) = x2 + ln + C

    Also f(1) = 1 C = 0Hence, f(x) = x2 + ln x.

    Clearly, 0

    1

    dx)x(f18 = 0

    1

    2dxxlnx18 = 18

    0

    1

    0

    1

    P.B.I

    III

    2 dx1xndxx

    l

    01

    0

    1

    3

    xxnx3

    x18 l = 18

    13

    1=

    3

    218 = 12. Ans.]

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    MATHEMATICS

    Code-B Page # 8

    Q.6

    [Sol.AT

    Given, f(x) = 1cos2 x2 + 2 (cos1) x + 2 cos1Clearly, graph of f(x) is parabola opening upward.

    As, range of f(x) is [0,), so discriminant = 0

    b24ac = 0 4 (cos1)2 1cos24 1cos2 = 0 4 (cos1)24 (22(cos1)2) = 0 (cos1)2 + (cos1)2 = 22 f(x)

    x-axis

    cos

    1 = = cos

    1==1 (Think)Hence, 12 = 0 + 2 + 1 = 3. Ans.]

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    CHEMISTRY

    Code-B Page # 1

    PART-A

    Q.1

    [Sol. H2O (l, 1 atm, 373 K) H

    2O (g, 1 atm, 373 K)

    the reaction is at equilibrium at given condition, so

    G = 0 STotal

    = 0

    Ssys

    > 0 (Heat is added to the system and phase is changing)

    so Ssurr

    < 0

    q > 0 (Heat is added)

    U > 0 (Heat is added)H > 0 (U > 0 and P

    2V

    2P

    1V

    1> 0) ]

    Q.2

    [Sol. SiF4, XeF

    4, BH

    4

    All the hybrid orbitals having same percent of s-character so they have same

    bond length.

    SF4Non equivalnt hybridisation due to the presence of different percent of s-character in the hybrid

    orbitals, all the bond length of SF4are not equivalent.

    ]

    Q.3

    [Sol. Strongest acid and strongest base takes reaction maximum in forward direction. ]

    NOTE :Only for XY-Batch students

    Q.4

    [Sol. q = w

    U = q + w

    U = q + q = 2q

    nCvmT= 2 n CmT

    or Cm = 2

    CVm

    or Cm

    = R2)1(

    R

    ]

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    CHEMISTRY

    Code-B Page # 2

    NOTE : Only for V-Batch students

    Q.4

    [Sol. H = PR )BE()BE(= (2 350 + 500)(1500)

    =300 kJ mol1 ]

    Q.5

    [Sol.

    ]

    Q.6

    [Sol.

    O

    ||ClCCHCHCH

    223

    4C

    O

    ||ClC

    |

    CHCHCH33

    3C

    ]

    Q.7

    [Sol. ]

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    CHEMISTRY

    Code-B Page # 3

    Q.8

    [Sol. For an irreversible cyclic process, Ssurr

    0 as Ssys

    = 0 for any cyclic process because entropy is

    state function.

    Suniv.

    = Ssys

    + Ssurr

    > 0 (For Irreversible process)

    Ssurr

    > 0 ]

    Q.9

    [Sol. ST.-1 :

    ST-2 : dz2 (Electrodensity present in z-axis as well as x and y axis so nodel plane = 0)]

    Q.10

    [Sol. In polar aprotic solvent more the charge density more will be the nucleophilicity. ]

    Q.12

    [Sol. Planar the restricted system

    Two different groups should be present on that restricted atoms. ]

    Q.13

    [Sol. ]

    Q.14

    [Sol. (A)

    O

    OH

    (Aromatic)

    (B)

    O

    OH

    (Aromatic)

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    CHEMISTRY

    Code-B Page # 4

    (C)

    O

    OH

    (Anti Aromatic)

    (D)

    O

    OH

    (Non Aromatic) ]

    PART-C

    Q.1

    [Sol. H = U + HgRT

    H =43 kJ mol1

    )TT(CHH 12PoT

    oT 12

    T1

    = 500 K ]

    Q.2

    [Sol. In a electro rich compound if halogen is act as bridge it is a 3C4ebond

    ;

    ;

    BF3

    and BCl3

    do not dimerised due to the presence of pp backboning between B and Halogen

    atom.

    don't having 3C4ebonds ]

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    CHEMISTRY

    C d B P # 5

    Q.3

    [Sol.

    ]

    Q.4

    [Sol. 35 + 22 + 63 + 32 + 11 = 163 ]

    Q.5

    [Sol. In a 2D-sheet silicate

    Total number of oxygen atoms are shared in each tetrahedral unit = 3

    So, Effective number of oxygen atoms = 15

    Number of Si-atoms = 6

    Charge = 6 ]

    Q.6

    [Sol. (a) Compound which shows intermolecular H-bonding has higher solubility than compound has

    intramolecular H-bonding.

    (b) More the surface area more will be the boiling point.

    (c) More EDG on C, more the stability

    (d) More electronegativity more theI ]