Rossing - Production Process

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    Uranium Oxide Production at

    Rssing UraniumA process overview

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    Summary of the Rssing Process

    Single product - U3O

    8

    Low grade deposit - 0.340kg/t U3O

    8

    Conventional shovel truck open pit.

    Sulphuric acid leach process

    Product is sold forward on long termcontracts

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    Key Metallurgical Parameters

    U3O

    8grade

    Acid consumption rate (Calc Index)

    Settling characteristics

    Geological make-up (Ore Type)

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    Hauling

    Haulpak 730E Truck Capacity = 180 tonnes

    Employ Trolley Assist

    1200 - 1400 volts DC 4 km of trolley line

    Save N$ 0.35/tonne

    Fuel Consumption365 l/hr -> 20 l/hr

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    Processing Plant

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    QUARTERNARY

    CRUSHERS

    RUN OF MINE ORE

    PRIMARY CRUSHER S

    SECONDARY CRUSHERS

    TERTIARY CRUSHERS

    RODMILLS

    ACID +

    Conarc Dust

    FERRIC

    REACTORS

    LEACH

    TANKS

    CYCLONES

    THICKENERS

    ROTOSCOOPS

    ACID

    OXIDANTS

    COMBINED TAILINGS

    TO DAM BARREN SOLUTION

    PREGNANT SOLUTION

    BARREN SOLUTION

    AMMONIUM HYDROXIDESOLVENT

    EXTRACTION

    AMMONIA GAS

    FILTRATION

    PRECIPITATIONCALCINING

    DRUMMED

    URANIUM OXIDE

    TWO - STAGE

    SCREENING

    FINE CRUSHINGLEACHING

    TAILINGSSANDS/SLIMES

    SEPARATION

    RECOVERY

    Reduction

    Extraction

    Recovery

    QUARTERNARY

    CRUSHERS

    RUN OF MINE ORE

    PRIMARY CRUSHER S

    SECONDARY CRUSHERS

    TERTIARY CRUSHERS

    RODMILLS

    ACID +

    Conarc Dust

    FERRIC

    REACTORS

    LEACH

    TANKS

    CYCLONES

    THICKENERS

    ROTOSCOOPS

    ACID

    OXIDANTS

    COMBINED TAILINGS

    TO DAM BARREN SOLUTION

    PREGNANT SOLUTION

    BARREN SOLUTION

    AMMONIUM HYDROXIDESOLVENT

    EXTRACTION

    AMMONIA GAS

    FILTRATION

    PRECIPITATIONCALCINING

    DRUMMED

    URANIUM OXIDE

    TWO - STAGE

    SCREENING

    FINE CRUSHINGLEACHING

    TAILINGSSANDS/SLIMES

    SEPARATION

    RECOVERY

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    Primary Crushers

    Operating Parameters:

    Two Primary Crushers fed withrun off mine material toproduce product size of less

    than 155mm Crushing Rate 2500-2600tph

    Crusher make is the OsbornGyratory (54/74)

    Crusher product is fed onto aCoarse Ore stock pile withcapacity of 250 000 tonnes

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    Pre-Screening Plant

    Removes the already fine material that is

    less than 15 mm

    Removes approximately 30% of materialto Fine Ore Stockpile

    Consists out of 1 set of scalping grizzly

    screens and 1 set of banana screens. Commissioned - 1999

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    Fine Crushing Plant

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    Fine Crushing Plant

    Plant capacity of 2300 tph

    Closed circuit plant

    Two secondary crushers

    Four tertiary screens

    Four tertiary crushers

    Six quaternary screens

    Two quaternary crushers

    Product size = -17 mm

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    Rodmills

    Four rod-mills in parallel Feed rate = 560 tph / mill

    Open circuit grinding

    Wet grinding (using

    recycled solution)

    Product size 30% +850

    microns/20 mesh

    Product size D80 is 1.1mm

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    Leach Process

    Sulphuric acid leaching 2 Modules

    Six leach tanks per module

    Tank capacity 1 Small mixing tank = 290 m3

    5 Large tanks = 1450 m3

    Retention time 8 - 9 hours

    Leach temperature 35 C

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    Mineral Composition Leach Feed

    Uranium bearing minerals:uranium at Rssing occurs in the form of

    uraninite, uranophane and betafite and is

    found in alaskite Gangue minerals:

    calcite (marble) makes up a very small

    proportion of the ore and is the majorconsumer of acid in Rssing ore

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    Factors That Influence the Rate of

    Dissolving Uranium From Rssing Ore

    Controllable leach parameters.

    1. Grind (30% +20Mesh).

    2. Reagent Concentrations

    - Acid & Oxidants

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    Washing Circuit

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    Washing Circuit

    Solid liquid separation processCyclones

    Roto-scoops

    ThickenersProduct solution contains uranium ina sulphate form (Uranyl Sulphate)

    Concentration of pregnant solution is0.180 g/l (uranium)

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    Continuous Ion Exchange

    Concentration stageAdsorption process (contacting vessels)

    Ionic resin beads

    Elution process (eluting columns)

    Acidic solution (10% acid)

    Concentrated Eluate is Uranyl sulphate

    Product solution 4 - 5 g/l (uranium)

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    Solvent Extraction

    Concentration and Purification stage Mixer settler units

    Liquid-liquid ion exchange process

    Organic tertiary amine is used as Extractant

    Ammonium sulphate is used as stripping

    medium

    Product solution is uranyl sulphate

    Concentration of uranium in product:13-15 g/l

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    Final Product Recovery

    Optimum precipitation takes place at pH 7.3

    Ammonia is used to raise pH

    Ammonium di-uranate is precipitated

    De-watering process thickener drum filters

    Roasting process at 830CProduct quality is more than 98% U3O8

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    QUARTERNARY

    CRUSHERS

    RUN OF MINE ORE

    PRIMARY CRUSHER S

    SECONDARY CRUSHERS

    TERTIARY CRUSHERS

    RODMILLS

    ACID +

    Conarc Dust

    FERRIC

    REACTORS

    LEACH

    TANKS

    CYCLONESTHICKENERS

    ROTOSCOOPS

    ACID

    OXIDANTS

    COMBINED TAILINGS

    TO DAM

    BARREN SOLUTION

    PREGNANT SOLUTION

    BARREN SOLUTION

    AMMONIUM HYDROXIDESOLVENT

    EXTRACTION

    AMMONIA GAS

    FILTRATION

    PRECIPITATIONCALCINING

    DRUMMEDURANIUM OXIDE

    TWO - STAGE

    SCREENING

    FINE CRUSHINGLEACHING

    TAILINGSSANDS/SLIMES

    SEPARATION

    RECOVERY

    Reduction

    Extraction

    Recovery

    QUARTERNARY

    CRUSHERS

    RUN OF MINE ORE

    PRIMARY CRUSHER S

    SECONDARY CRUSHERS

    TERTIARY CRUSHERS

    RODMILLS

    ACID +

    Conarc Dust

    FERRIC

    REACTORS

    LEACH

    TANKS

    CYCLONESTHICKENERS

    ROTOSCOOPS

    ACID

    OXIDANTS

    COMBINED TAILINGS

    TO DAM

    BARREN SOLUTION

    PREGNANT SOLUTION

    BARREN SOLUTION

    AMMONIUM HYDROXIDESOLVENT

    EXTRACTION

    AMMONIA GAS

    FILTRATION

    PRECIPITATIONCALCINING

    DRUMMEDURANIUM OXIDE

    TWO - STAGE

    SCREENING

    FINE CRUSHINGLEACHING

    TAILINGSSANDS/SLIMES

    SEPARATION

    RECOVERY

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    Questions ?

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    Roto-scoopsOVERFLOW TO

    THICKENER CIRCUIT

    LEACH PLANT DISCHARGE

    CYCLONE

    UNDERFLOW TO

    1ST STAGE ROTOSCOOP SANDS TO 2ND

    STAGE ROTOSCOOP

    BARREN SOLUTIONFROM CIX

    2ND STAGE OVERFLOW =

    WASH SOLUTION TO 1ST

    STAGE ROTOSCOOP

    WASHED SANDS TO TAILINGSFIRST STAGE OVERFLOW

    RETURNS TO JOIN LEACH

    DISCHARGE AND CYCLONE

    FEED

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    ThickenersPATH OF SLIMES THROUGH THE THICKENERS

    CYCLONE OVERFLOW

    FROM ROTOSCOOP

    SECTION

    WASHED SLIMES TO TAILINGS

    PATH OF SOLUTION THROUGH THE SECTION

    BARREN SOLUTION FROM CIX

    PREGNANT

    SOLUTION

    TO CIX

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    Continuous Ion Exchange

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    Solvent Exchange

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    Final

    Product

    Recovery

    OK LIQUOR

    FROM SX

    NH3 GAS

    PRECIPITATION

    YELLOW CAKE THICKENER

    AMMONIUM

    SULPHATETO SX PLANT

    WATER WATER

    STORAGE STORAGEFIRST STAGE

    FILTER, WASH

    AND REPULP

    SECOND STAGE

    FILTER, WASH

    AND REPULP

    6 HEARTH

    CALCININGFURNACE

    THICKENER UNDERFLOW SG 1.3 - 1.5

    pH 7.2-7.3

    HAMMER MILL

    DRUMMED

    URANIUMCALCINED

    PRODUCT