Roads to Olefins -Sinopec [兼容模式] - Platts · Technical Solutions Major Solutions to Olefin...
Transcript of Roads to Olefins -Sinopec [兼容模式] - Platts · Technical Solutions Major Solutions to Olefin...
Petroleum, Gas, or CoalRoads to OlefinsRoads to OlefinsWANGChaosheng,RegionalRepresentative,Technology&Marketing
AsianRefiningSummit,Singapore,March,2016
Outline
Ⅰ Olefin/Polyolefin Demand and Capacity in China
Ⅱ Technical Solutions to Olefin Production
Ⅰ Olefin/Polyolefin Demand and Capacity in China
Ⅱ Technical Solutions to Olefin Production
Ⅲ Review of ProjectsⅢ Review of Projects
Ⅳ Sinopec Olefin TechnologiesⅣ Sinopec Olefin Technologies
Ⅴ SINOPEC T h l C LtdⅤ SINOPEC Technology Co., Ltd.
Outline
Ⅰ Olefin/Polyolefin Demand and Capacity in China
Ⅱ Technical Solutions to Olefin Supply
Ⅰ Olefin/Polyolefin Demand and Capacity in China
Ⅱ Technical Solutions to Olefin Supply
Ⅲ Review of ProjectsⅢ Review of Projects
Ⅳ Sinopec Olefin TechnologiesⅣ Sinopec Olefin Technologies
Ⅴ Si T h l C LtdⅤ Sinopec Technology Co., Ltd.
Olefin/Polyolefin Demand in China
Ethylene Demand and Capacity
Olefin/Polyolefin Demand in China
Propylene Demand and Capacity
Olefin/Polyolefin Demand in China
Propylene in 2015Ethylene in 2015
• Capacity growth 11% in 2015- No steam cracking
• Capacity growth 2% in 2015- No steam cracking g
- FCC: 130 K MTA- PDH: 1300 K MTA- CTO /MTO: 880 K MTA
gprofitability improved
- CTO + MTO new capacity: 300+450 K MTA
- Paraffin DH: 325 K MTA
• Demand continues to grow f
low operation ratedue to operation problem
and high cost - Balanced by 2.8 m MT of import
• Demand continues to grow - Driven by downstream.
B l d b 1 5 MT f i t- Balanced by1.5 m MT of import
Olefin/Polyolefin Demand in China
Butadiene Capacity and Growth
Olefin/Polyolefin Demand in China
Butadiene
• On-purpose capacity 14.3% of the total, low operation rate of oxidative dehydrogenation units due to low BD y gprice and high cost.
• Demand affected by the shrink auto industry rubber. Oversupply.
• Refinery / naphtha cracking C4 extraction will remain mainstream.
Olefin/Polyolefin Demand in China
Olefin Demand Continues Grow in the Future
• 2014 PE consumption per capita: China: 16 4 kg developed countries: 36~38 kgChina: 16.4 kg, developed countries: 36 38 kgPar by 2035 @4% growth
• 2014 PP consumption per capita: p p pChina: 14 kg, developed countries: 17~18 kgPar by 2022 @4% growth
Olefin capacity investment: moderate and rationalOlefin capacity investment: moderate and rational
Outline
Ⅰ Olefin and Polyolefin Demand in China
Ⅱ Technical Solutions to Olefin Production
Ⅰ Olefin and Polyolefin Demand in China
Ⅱ Technical Solutions to Olefin Production
Ⅲ Review of ProjectsⅢ Review of Projects
Ⅳ Sinopec Olefin TechnologiesⅣ Sinopec Olefin Technologies
Ⅴ Si T h l C LtdⅤ Sinopec Technology Co., Ltd.
Technical Solutions
Major Solutions to Olefin Production
Steam CrackingFeedstock flexibility, product spectrum ,
downstream integration
Naphtha, LPG, ethane, propane
Maximize
FCC (DCC, CPP)
Maximizepropylene/ethylene gain, Competing with gasoline,
production cost
Access to Resid, VGO
production cost
PDHLow investment, on
purpose product Access to propane
MTO/MTP
Alternative resources, High investment,
environment, competing Methanol from Coal, Natural Gas,
Biomass, p guses
Others
Light hydrocarbon cracking,
Maximum utilization of materialOthersdehydrogenation, disproportionation
Maximum utilization of material
Technical Solutions
Economic Comparison
Scale (KTA)
FeedstockInvestment
(billionYuan)
Pre-tax Return
Rate(%)Mat OP
) ( )
S.CR 1000 Naphtha 4 13.8 94
CPP 1500*Paraffinic
3 17 8 91 +CPP 1500AR
3 17.8 91 +
DCC 1700* VGO 1.2 15.8 95 -
PDH 450 Propane 1.9 15.3 88
MTO 1800* Methanol 2.5 17.9 89 -
MTP 1660* Methanol 2 15.2 91 -
* Feedstock** Price prediction based on historical data,
*** Brent oil $80 / bbl
Technical Solutions
Watershed: 2010, Oil price 70 – 90 USD/bbl
• Before 2010, olefin/polyolefin expansion based crude feedstock
• 2010, first coal polyolefin plant in operation2010, first coal polyolefin plant in operation• After 2010, almost all olefin/polyolefin projects are coal
based, or MTO, PDH
• 2015~2019: New PP 12.23 m MTA, 73% of world total. Mainly coal or PDH basedMainly coal or PDH based.- Coal PP share: 10% in 2014, 30% in 2019
• 2015~2019: New PE 7.72 m MTA, 35% of world total.2015 2019: New PE 7.72 m MTA, 35% of world total. Mainly coal based.- Coal PE share: 4% in 2014, 26% in 2019
Technical Solutions
Ethylene + Propylene Capacity in 2015
• 48~50 m MTA• About 25% from CTO/MTOAbout 25% from CTO/MTO
C2 about 15% from none-crude
• PDH PP: 4.4 m MTA• CTP/MTO PP: 4.2 m MTA• PP Total: 28 m MTA
30%+ from none-crude
Technical Solutions
Cost Comparison
Outline
Ⅰ Olefin and Polyolefin Demand in China
Ⅱ Technical Solutions to Olefin Production
Ⅰ Olefin and Polyolefin Demand in China
Ⅱ Technical Solutions to Olefin Production
Ⅲ Review of ProjectsⅢ Review of Projects
Ⅳ Sinopec Olefin TechnologiesⅣ Sinopec Olefin Technologies
Ⅴ Si T h l C LtdⅤ Sinopec Technology Co., Ltd.
Review of Projects
PDH Built:
Project Scale (KMTA) Process Start Site
1 天津渤化 600 Oleflex 2013 天津
2 绍兴三圆 450 Oleflex 2014 绍兴绍兴 圆 绍兴
3 卫星石化 450 Oleflex 2014 嘉兴
4 海越股份 600 Catofin 2014 宁波
5 烟台万华 750 Oleflex 2015 烟台烟台万华 烟台
6 扬子江石化 600 Oleflex 2015 张家港
7 宁波福基 660 Oleflex 2015 宁波
8 山东京博(混合烷烃) 125 Oleflex 2015 山东8 山东京博(混合烷烃) 125 Oleflex 2015 山东
9 山东神驰(混合烷烃) 200 Oleflex 2015 东营
小计 4435
Review of Projects
PDH Planned:
10 扬子江石化(二期) 600 Oleflex 2017 张家港
11 宁波福基(二期) 660 Oleflex 2017 宁波
12 山东海力 600 C t fi 东营12 山东海力 600 Catofin 东营
13 长江天然气化工 650 Oleflex 南通
14 中国软包装 800 Oleflex 福清
15 石大胜华 200 Oleflex 东营
16 卫星石化(二期) 600 Oleflex 嘉兴
17 鹏尊能源 300 Oleflex 湛江17 鹏尊能源 300 Oleflex 湛江
18 盘锦和运 600 盘锦
19 上海华谊 600 上海
M f th l d PDH MTO j t ill b t d l d
小计 5610
• Many of the planned PDH, MTO projects will be postponed or canceled
Review of Projects
CTO/MTO Built + 4 more:
Startup ProjectMathanol Cpty
(KMTA)M OP Rate
Olefin Cpty (KMTA)
O OP Rate
2010年8月 神华包头一期 1800 95% 600 100%
2010年9月 神华宁煤一期 1680 95% 500 100%
2011年6月 大唐多伦 1680 0% 460 35%2011年11月 中原石化 600 -- 200 100%2013年1月 宁波富德 -- -- 600 65%2013年9月 南京惠生 -- -- 300 100%2014年7月 寿光鲁清 -- -- 200 0%
2014年7月 延长中煤榆林 1800 80% 600 110%
2014年8月 神华宁煤二期 -- -- 500 100%
2014年8月 中煤榆林一期 1800 95% 600 106%2014年8月 中煤榆林 期 1800 95% 600 106%
2014年9月 山东玉皇 -- -- 100 80%2014年11月 宁夏宝丰 1800 95% 600 100%2014年11月 神达化工 -- -- 340 80%2014年12月 陕西蒲城 1800 92% 680 84%2014年12月 陕西蒲城 1800 92% 680 84%
2014年12月 东营瑞昌一期 -- -- 100 0%
2014年12月 沈阳蜡化 -- -- 100 95%2015年3月 齐成华滨 -- -- 200 30%2014年4月 浙江兴兴 -- -- 690 100%2014年4月 浙江兴兴 690 100%2015年4月 鲁深发 -- -- 200 30%
7570
Review of Projects
CTO/MTO Planned:
• By 2017, 14 MMTA new MTO capacity approved, with 5 MMTA PE and 5 8 MMTA PP5 MMTA PE and 5. 8 MMTA PP
• Another 10 MMTA CTO are proposed
Many of these projects will be postponed or canceledMany of these projects will be postponed or canceled though, the impact on market will be huge.
to die or to change the game?to die or to change the game?
Review of Projects
Future investment in coal chemical
• Utilization of Coal• Feedstock availability for fuels and chemicals• Government policy change on coal chemical
- Local GDP- Environment concern, public awareness- Water problem- Carbon emission international commitment - Taxation
• Crude / propane / ethane price• Downstream market: location, demand and price
• Economics: Pre-tax return rate btw. 5%~10% at 50~60 USD/bbl Brent - UBS
Review of Projects
Future investment in olefins
Steam CrackingFeedstock flexibility: naphtha, LPG,
ethane, propaneDownstream integration
FCC (DCC CPP)Maximum utilization
FCC (DCC, CPP)Upstream integration
PDH etcOpportunity feedstock
PDH etcIndependent players
CTO/MTO …
Outline
Ⅰ Olefin/Polyolefin Demand and Capacity in China
Ⅱ Technical Solutions to Olefin Production
Ⅰ Olefin/Polyolefin Demand and Capacity in China
Ⅱ Technical Solutions to Olefin Production
Ⅲ Review of ProjectsⅢ Review of Projects
Ⅳ Sinopec Olefin TechnologiesⅣ Sinopec Olefin Technologies
Ⅴ Si T h l C LtdⅤ Sinopec Technology Co., Ltd.
Sinopec Olefin Technologies
Related Technologies
CBLSteam Cracking, Flexible to feedstock, unique tube technologyunique tube technology
DCC Deep Catalytic CrackingCPP Catalytic Pyrolysis Process
OCC Olefin Catalytic CrackingOCC Olefin Catalytic Cracking
SMTO Methanol to Olefin
….
Sinopec Olefin Technologies
SINOPEC has a complete system for technology R&D, engineering and operation, from oil E&P, refining, to petrochemicals.
8 Research Institutes Sinopec Engineering Group
FRIPP-Fushun Research Institute of Petrochemical ProcessingPEPRIS-Exploration &
SRIPE- Research Institute of Petroleum Engineering
Processing
BRICI-Beijing Research Institute of Chemical Industry
Production Research Institute
Institute of Chemical Industry
QDSEI-Qingdao Safety
RIPP-Research Institute of Petroleum Processing
SGRI G h i lSRIPT-Shanghai Research Institute of Petrochemical Tech
Q Q g yEngineering Institute SGRI- Geophysical
Research Institute
Sinopec Olefin Technologies: CBL
CBL Steam Cracking Technology
• Sinopec has rich experience in cracking furnace design
to realize value cracking and increase feedstock flexibility
and development (CBL technology). Single furnace max
capacity is 200 KTA.
300 KTA furnace under design.
• Spectrum of feedstock: from light feedstock, such as
fethane and light hydrocarbons, to heavy feedstock as
diesel and HVGO.
• Till now 113 furnaces have been built by using CBL• Till now, 113 furnaces have been built by using CBL
technology. The total capacity is 11.3 Mt.
Gas furnaces: 23. Total gas capacity is 2.7 Mt.g p y
Sinopec Olefin Technologies : CBL
Enhanced heat transfer technology
High temperature(780~900℃), short residence time and lower hydrocarbon partial pressure
H t i t d t th fl b d l Ch ll Heat resistance due to the flow boundary layer and coking, resulting in over temp. and shortened run length
Challenges
Quick heat transfer through tube wall into the fluid body
Reduce cokingTargets
g Extend run length
Solution: Swirling Element Radiant Tube technology (SERT)
Enhance heat transfer, reduce coking and extending run lengthEnhance heat transfer, reduce coking and extending run length
Sinopec Olefin Technologies: CBL
To change the flow pattern of the
SERT for Steam Cracking Furnace Tube
To change the flow pattern of the fluid body
Thinner boundary layerThinner boundary layer
Reduced coking rate
Reduce Tube Metal Temperature (TMT)
Extend run length
To change feedstock flow pattern: from plug flow to swirl flow- increase flow velocity along the tube perimeter, and reduce the laminar boundary layer. Turbulent flow to enhance heat transfer y y- the scouring force of the feedstock flow reduces the coke formation
Sinopec Olefin Technologies : CBL
SERT for Steam Cracking Furnace
The influence of SERT on the cracking furnaceitem Without SERT With SERT
P d t i ld BASE N t ti
The influence of SERT on the cracking furnace
Product yields BASE Not negative
TMT BASE Reduce at least 20℃
Run length BASE Increase at least 40%
Capacity BASE Increase about 7%
Operation BASE No additional workload
* Under the same operation conditions with insertion of the tube with twisted-tape Under the same operation conditions, with insertion of the tube with twisted-tape
• Lower cost! (comparing with other heat transfer enhancing technologies)• Can be installed on incumbent tubes
Tubes with SERT insertion can handle flexible feeds (naphtha propane etc )• Tubes with SERT insertion can handle flexible feeds (naphtha, propane, etc.)
Sinopec Olefin Technologies : SERT
Comparison between furnaces with and without SERT
SERT for Steam Cracking Furnace
• TMT • Pressure drop
1100
1120
1140
1100
1120
1140
TMT NO SERT280
290 no SERT with SERT
1040
1060
1080
1040
1060
1080
ubew
all t
emp
260
270
essu
re (K
pa)
with SERT
980
1000
1020
980
1000
1020
tu
With SERT240
250
inle
t pr
0 20 40 60 80 100980 980
runlength(day) 0 10 20 30 40 50 60 70230
run length (day)
Sinopec Olefin Technologies : SERT
ZHENHAI 1,000 KTA Ethylene complex (SERT used)
– Feed:HVGO, NAP, C2/C3, LPG, C5– Thermal Eff.: 93.8-94.5%– Run length g
• NAP: more than 119 days • C2: 133 days
HVGO: 121 days• HVGO: 121 days– Liquid furnace: CBL-Ⅲ– Gas furnace: CBL-R– Capacity:
• 120 kta gas feed• 100 kta liquid feed (9 furnaces)100 kta liquid feed (9 furnaces)• 150 kta liquid feed, double firebox
– Feed in on Apr. 20, 2010
Sinopec Olefin Technologies : SERT
SERT for any kind cracking furnace tube
B 2013 SERT h b i t ll d i
Commercial Experience Commercial Experience
By 2013, SERT has been installed in 113 ethylene cracking furnaces, including installations in Malaysia, Thailand and USA.
The SERT in the online furnace
Applicable, when • Revamp: replace the radiant coils
• Revamp: modify the incumbent coils
• Build new cracking furnace
Sinopec Olefin Technologies: DCC
DCC (Deep Catalytic Cracking)
1. Maximum propylene and butylenes production2. Riser reactor plus fluid bed reactor with p
continuous reaction/regeneration circulation operation. Reaction temperature is much lower than that of steam cracking.
3. Recracking a portion of DCC part range or full k d hth li ith ith trange cracked naphtha coupling with or without
C4 cut in the DCC operation will increase the yield of propylene and BTX at a naphthayield of propylene and BTX at a naphtha expense.
4 Proprietary catalyst4. Proprietary catalyst
Sinopec Olefin Technologies: DCC
Block flow diagram of DCC/CPP plant & integration
To diesel blending
GasPurificate
EthyleneRecovery
Unit
Light
Ethylene to plant
Propylene to storageEnds Unit
C3 & C4Purification Split
C3Spliter
C
To storageC3 cut
Propylene to storage
LPG to storage
FractionatorGasolineSelective
Hydrogenation
Vacuum
H2 Otherfeeds
C4cut
H2
Gasoline
C cut to MTBE PlantVGOHTU
DCC/CPP reactor& Regenerator
gasoil C4 cut to MTBE Plant
Decanted oil to fuel
Sinopec Olefin Technologies: DCC
DCC Commercial Mode
Two DCC operation modes in commercial prunning:DCC-IDCC-I
Riser plus fluidized dense bed reactor Manxumum proplyene operation modep p y p
DCC-IIRiser reactorRiser reactorManxumum isoolefins operation mode
Sinopec Olefin Technologies: DCC
Light olefin yields from the representatives feedstock for DCC-I
Number 1 2 3 4
VGO VGO + Resid VGO + DAO VGO Feedstock VGO
Paraffinic baseVGO + Resid Paraffinic base
VGO + DAO interm base Naphthenic
base
Density, g/cm3 0.8449 0.8621 0.9085 0.9249
UOP K 12.7 12.6 12.0 11.4
Hydrogen, w% 14.23 13.62 12.52 12.24
Olefin yields, w%
Ethylene 5.8 3.6 3.5 3.6
Propylene 23.7 22.9 18.3 13.2
Butylenes 17.8 17.4 14.0 10.6
Sinopec Olefin Technologies: DCC
Light olefin yields from representative feedstock for DCC-II
Number 1 2 3 4
Feedstock VGO VGO + Resid VGO + DAO VGO NaphthenicFeedstock Paraffinic base Paraffinic base interm base Naphthenic
base
Density, g/cm3 0.8579 0.8939 0.8983 0.9249
UOP K 12.4 12.5 12.0 11.4
Hydrogen, w% 13.45 12.87 12.63 12.24
Olefin yields, w%
Propylene 14.3 11.8 12.5 7.9
Isobutylene 6.1 5.3 4.6 3.5
Isoamylenes 6.8 5.5 5.8 4.1
Sinopec Olefin Technologies: CPP
CPP (Catalytic Pyrolysis Process)
1. Maximum ethylene and propylene
2. Riser reactor with continuous reaction/ regeneration circulation operation. Reaction temperature is much lower than that of steam cracking.
3. Catalyst: Proprietary catalyst
4 Feedstock: VGO and heavier4. Feedstock: VGO and heavier
Sinopec Olefin Technologies: CPP
CPP Commercial Mode
Three test modes were carried out during gcommercial trial of CPP technology:
CPP-P is for max propylene production,
CPP-E is for max ethylene production.
CPP-P&E is for max ethylene & propylene production.p
Sinopec Olefin Technologies: CPP
CPP Demonstration unit- feedstock properties
Test mode CPP‐P CPP‐P&E CPP‐E
Density(20℃)/g cm‐3 0 9002 0 9015 0 9012Density(20℃)/g.cm 3 0.9002 0.9015 0.9012CCR, wt% 4.7 4.9 4.7H, wt% 12.82 12.86 12.84S, wt% 0.16 0.16 0.16N, wt% 0.29 0.26 0.25Ni ppm 5 8 6 2 6 3Ni, ppm 5.8 6.2 6.3Group composition, wt%
Saturates 56.3 54.8 55.5Aromatics 27.2 28.4 28.0Resin 15.7 16.0 15.7Asphaltene 0.8 0.8 0.8Asphaltene 0.8 0.8 0.8
Sinopec Olefin Technologies: CPP
CPP Demonstration unit- Products yield
Test Mode CPP‐P CPP‐P&E CPP‐E
Products yield, wt%
Dry gas 17.64 26.29 37.13
LPG 43.72 36.55 28.46
C5+Naphtha 17.84 17.61 14.825 p
LCO 11.75 8.98 7.93
Coke 8.41 9.67 10.66Coke 8.41 9.67 10.66
Losses 0.64 0.90 1.00
Sinopec Olefin Technologies: CPP
CPP Demonstration unit- olefins yield
Olefins yield,wt% CPP‐P CPP‐P&E CPP‐EOlefins yield,wt% CPP P CPP P&E CPP E
C2= 9.77 13.71 20.37
C3= 24.60 21.45 18.23
C4= 13.19 11.34 7.52
Total olefins yield, wt% 46.96 46.50 46.12y ,
Sinopec Olefin Technologies: CPP
CPP Demonstration unit- Naphtha
Test modes CPP‐P CPP‐P&E CPP‐E
D it / 3 0 8158 0 8261 0 8315Density,g/cm3 0.8158 0.8261 0.8315
RON 97.8 101.6 102.5
MON 82.1 87.6 87.8MON 82.1 87.6 87.8
Group(GC), wt %
n‐Paraffins 6.30 3.76 1.24
i‐Paraffins 3.77 2.96 2.63
Naphthenes 1.73 1.51 0.76
Olefins 9.28 12.79 16.25
Aromatics 78.92 78.98 79.12
Sinopec Olefin Technologies: DCC/CPP
Light olefin Yield Comparison among FCC,DCC &CPP
25 FCC DCC CPP
15
20
d, m
%
5
10
Ole
fin y
iel
0Ethylene Propylene Butylenes
O
Sinopec Olefin Technologies: DCC/CPP
CPP/DCC operation parameters
Technology F C C D C C C P P
Reaction Temp. oC Base +0‐50oC +80‐150 oC
/CTO, M/M Base 1.5‐2 times 2‐4 times
Reaction Time, s Base longer longerg g
Reaction Pressure Base Lower Lower
Steam Base More Much More
Sinopec Olefin Technologies: DCC/CPP
Jinan Company SINOPEC
SINOPEC DCC Technology Commercial Experience
Jinan Company, SINOPEC Start up November 1990 First DCC unit in the world
Jinan
TPI Thailand’s TPI Start up May1997 First DCC unit outside China
Petro Rabigh
Rabigh Refining & Petrochemical Co.
Start up February 2012 The largest capacity 92,000 bbl/d
There are 16 DCC units under designing, construction and
(460 MMT/a)
running in the world10 unitsChina
2 unitsThailand
1 unitsRussia
1 unitsSaudiArabic
2 unitsIndiaChina Thailand Russia ArabicIndia
Sinopec Olefin Technologies: COAT
Recover C2 from refinery off-gas
Refinery off-gas includes
• FCC dry gasFCC dry gas
• The content of ethylene and ethane, about 10~20%
• Coking dry gas & light hydrocarbon dry gas, etc.Coking dry gas & light hydrocarbon dry gas, etc.
• Less ethylene but more ethane
• At present, refinery off-gas are mainly used as fuel gas.At present, refinery off gas are mainly used as fuel gas.
• How to make good use of refinery off-gas and convert low
b h d b i t hi h l dd d d tcarbon hydrocarbons into high value-added products are an
important topic for refining enterprise to enhance their
competitiveness.
Sinopec Olefin Technologies: COAT
Extract the ethylene-rich gas from FCC dry gas
Recover C2 from refinery off-gas
Extract the ethylene rich gas from FCC dry gas
cryogenic separation pressure swing adsorption (PSA) oil absorption
Commercialized• High recovery of ethylene
• Large investment,hi h ti
Commercialized• More equipments,• complicated control,
Commercialized• High recovery of ethylene
• Less equipments,i l ti• high energy consumption,
• complicated operation
p• short operating cycle • simple operation,
• long operating cycle
Sinopec Olefin Technologies: COAT
Fuel gas CO O NOx
Technology Features of COAT
Fuel gas CO2 O2、NOx
t n
C2-rich gasre
ssio
n ni
t
ptio
n U
nit
gena
tion
nitoniz
atio
nU
nitFCC off-gas
53kt/a
Com
pr Un
Abs
orp
Deo
xyg un
Dec
arb U108 kt/a
H2,CH4,N2,O2,NOx,CO,etc. are removed by the process above 0℃. The obtained C2-rich gas is sent to caustic washing tower of ethylene unit. Surplus waste heat in refinery can be used to supply heat and cold sources Surplus waste heat in refinery can be used to supply heat and cold sources. Through lithium bromide water absorption refrigerating equipment, 5℃ cold water can
be obtained to supply cold sources. The propylene refrigeration compressor and dryerare NOT needed.
Refinery C4 fraction is used to absorb C2 fraction. The stable gasoline is used torecover the losing C4 fraction entrained by fuel gas.
Sinopec Olefin Technologies: COAT
Case StudyCase Study
Recover C2 from refinery off-gas
The first COAT unit successfully and safely began in 2011 and is producing high quality C2 gas to the ethylene plant. (oil-in: September 22th, 2011)
Ethylene recovery rate is 93%, with 80%+ ethylene and ethane in the products. Oxygen content is lower than 0.1PPM.
There are 4 new units either in construction or in detailedconstruction or in detailed engineering.
100 kt/a COAT Unit in Qilu, Sinopec
Sinopec Olefin Technologies: COAT
Technology advantagesTechnology advantages
High recovery of ethylene the performance data of Qilu unit is 93% C2 recovery (guaranteed value:
92%).
Simple process use conventional and less equipment no need of adsorbent (Ref use conventional and less equipment, no need of adsorbent (Ref.
technology: complicated process and more equipment)
Stable operation simple operation, stable running, long operation cycle. (Ref. technology:
complicated control, unstable running, short operation cycle)
Less floor area Less floor area Qilu unit covers about 2700m2, the floor area increases a little with scaling
up. (Ref. technology: one unit covers about 3800m2, the floor areai h ith li )increases much more with scaling up)
Sinopec Olefin Technologies: COAT
Technology advantagesTechnology advantagesL i t t Low investment Using less pieces of conventional equipment, and using the refinery’s
surplus waste heat
High quality product
Unique advantages in impurity removal
Less energy consumption: The low grade heat source of refinery is used: Qilu uses the surplus low
pressure steam as the heat source of absorption refrigeration and towerp p greboiler, with no need of high quality steam.
If the waste hot oil of refinery is used as the heat source, the energyconsumption of the unit will be further decreasedconsumption of the unit will be further decreased.
The successful running of the off-gas recovery unit using Cold OilAbsorption Technology shows that it is reliable and can be widelyAbsorption Technology shows that it is reliable and can be widelyapplied.
Sinopec Olefin Technologies: LECT
Proprietary technology
Low Energy Ethylene Separation Technology
Proprietary technology minimum energy consumption easy operation high reliability.
Front-end Depropanization & Hydrogenation Quench Quench Compression, Front-end depropanization & hydrogenation, Cold separation, Hot separation and refrigeration systems.
Sinopec Olefin Technologies: LECT
Process Process Scheme Scheme Low Energy Ethylene Separation Technology
QO TowerQW TowerCGC1~4
HP DeC3 C2 Hydrogenation
C3 Washer
Propylene LP DeC3
Alkaline Tower
pyFractionatorDeC1 Tower
Pre-demethanizerEthylene Fractionator
Cold Box
DeethanizerFractionator
C3 Hydrogenation
C2 Washer
Sinopec Olefin Technologies: LECT
C1/C2/C3 Catalysts & Processes
C1 - Low Temperature Methanation
C2 - Selective Hydrogenation Technology
C2 - Selective Hydrogenation Technology
C3 - Selective Hydrogenation Technology Methanation
Catalyst• High activity in low
temperature 150 ~ 200℃
Technology• Front-end Selective
Hydrogenation Technology for Removal of Acetylene
Technology• Tail-end Selective
Hydrogenation Technology for Removal of Acetylene
Technology • Liquid-phase Selective
Hydrogenation Process and Catalyst for the Removal of Methyl200℃
• Adapting to various reactor and process
• Excellent operation flexibility & low cost
Removal of Acetylene in DepropanizerProcess
Removal of Acetylene in C2 Fraction
Removal of Methyl Acetylene and Propadiene in C3 Fractions
flexibility & low cost
Sinopec Olefin Technologies
• DCC/CPP
SummarySummary
- Leading technology for producing light olefins with heavy feedstock, which bridge refining with petrochemical industry.
CBL Steam Cracking ith SERT• CBL Steam Cracking with SERT- Leading technology for enhancing heat transfer and preventing coking.
COAT• COAT- Low investment to recover C2 from dry gas from FCC and other source.
LECT• LECT- A low energy ethylene separation technology, front-end depropanation
Sinopec Sinopec Technology Co. Ltd.Technology Co. Ltd.
Sinopec Technology Co. Ltd. is a subsidiary of SINOPEC Corp, in h f th li i d t f i f SINOPEC’ P i tcharge of the licensing and transferring of SINOPEC’s Proprietary
technologies and involved actively in global licensing market.
Process Design Package
Note: Providing the PDP is the main
Basic Engineering Design
ote o d g t e s t e abusiness of Sinopec Technology
Detailed Engineering Design Technical Service EPC Contractor Turn-key Project
Sinopec Sinopec Technology Co. Ltd.Technology Co. Ltd.
Operating Model of Business Activities
SinopecTechProject Management
Technical Resources
Technical Business Activities
Business Team
Cooperation
Support
Partners Research Inst.
Cooperation Licensing Clients
Engineering Support
Engineering Corp.
Sinopec Sinopec Technology Co. Ltd.Technology Co. Ltd.
SINOPEC Regional Representatives of Technology & MarketingSINOPEC Regional Representatives of Technology & Marketing
Offices in:• New York
Main Responsibilities
• Frankfurt• Hong Kong • Technology licensing
• Seeking cooperation opportunities with partnersopportunities with partners
• Quick response to alliances and clients
Contact Information Contact Information
For more information:For more information:For more information:For more information:http://www.sinopectech.com/english
Contact: Contact: WANG ChaoshengRegional Representative, Technology & Marketing SINOPEC Hong Kong Representative Office
Email: [email protected] Add.: 20/F., Office Tower, Convention Plaza
1 Harbour Road Wanchai Hong Kong1 Harbour Road, Wanchai, Hong Kong