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    Rigid and Specialty Containers

    Bhupendra Singh

    Bloom Packaging Pvt. Ltd.

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    Topics for Discussion

    Rigid Containers Innovations in Rigid Containers

    Specialty Packaging

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    Some Examples

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    Materials Used in Rigid Packaging

    Polypropylene

    Polyethylene HDPE

    LDPE

    LLDPE

    EVA Polystyrene

    GPPS

    HIPS

    ABS

    SAN

    PVC

    PET

    PC

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    Materials Used

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    Injection Moulding

    eg. containers, pails, closures

    Blow Moulding

    eg. bottles, jars

    Thermoforming

    eg. cups, glasses, tubs, potion packs

    Rigid Plastic Packaging

    Injection Mouldingeg. containers, pails, closures

    Blow Mouldingeg. bottles, jars

    Thermoformingeg. cups, glasses, tubs, potion packs

    Rigid Plastic Packaging

    Processes

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    Extrusion Blow Molding

    Extrusion Pinch Off Blowing Cooling

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    Pinch Off

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    Injection Blow Molding

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    Blow Molds

    Material of Construction :

    Mild Steel Aluminum

    Beryllium Copper

    Essential requirements on the mould :

    Adequate cooling, preferably along the contours of the cavity

    Cooling of thicker areas of the article like neck, top and bottom

    pinch-offs.

    Surface Mating.

    Proper alignment of the two halves

    Sandblast finish for moulds of 5 litres and above of 40 / 50 mesh

    grit.

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    Modifications In Die Design

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    Testing can be divided in to two parts :

    Quality Control : Testing of incoming

    raw materials

    Quality Assurance : Testing of finished products

    Plastics testing can be divided into testing of plastic raw

    materials ( generally granules ) & testing of finished products

    after moulding.

    Testing of Rigid Packages

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    Processes

    High Density Polyethylene (HDPE) and Polypropylene (PP) are the

    most widely used resin for blow moulding applications.

    Types of Blow Moulding :

    Extrusion blow moulding - Continuous type and Intermittent type

    Injection blow moulding

    Extrusion stretch blow moulding

    Injection stretch blow moulding

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    Processing Temperatures

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    Additives for Rigid Containers What are Additives?

    Why are they used?

    Where are they used?

    What are their functions?

    Plastics are being used in every possible application.

    Thermoplastic materials are processed in the molten state at hightemperatures and under high shear. During their service life they have tosurvive severe exposure to conditions such as heat, light humidity,without changes in appearance or premature mechanical failure in somecases for several decades.

    WITHOUT SUITABLE ADDITIVES NONE OF THESEDEVELOPMENTS WOULD BE POSSIBLE

    ADDITIVES ARE THE MIRACLE WORKERS OF PLASTICS

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    Types of Additives

    1. Antioxidants

    2. UV Stabilizers

    3. PVC Stabilizers

    4. Plasticizers

    5. Flame Retardants6. SIip and Antiblock Agents

    7. Antistatic Agents

    8. Nucleating Agents

    9. Clarifying agents10. Chemical Foaming Agents

    11. Antimicrobial

    12. Lubricants

    (Internal and External)

    13. Fillers and Reinforcements

    14. Coupling agents15. Antifogging additives

    16. Acid Scavengers

    17. Polymer Processing aids

    18. Colourants19. Flourescent Whitening agents

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    Selection Criteria for Additives

    1. Property desired by the customer.

    2. Duration of Property desired.3. Polymer to be added to.

    4. Compatibility to the polymer.

    5. Temperature of processing and mode of processing.6. Mode of addition.

    7. Reaction with other additives in the system.

    8. Shelf life of the additive.9. Regulations and norms to be followed.

    10. Testing details.

    11. End use of the product.

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    Masterbatches

    What are they?

    - Highly concentrated colour or additive carriers which have to

    be let down at a low percentage to improve the properties of

    the moulding / extrudate.

    Types of masterbatches

    - Colour masterbatches and additive masterbatches

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    Colour Masterbatches

    Highly loaded with inorganic and

    organic pigments

    2 types of colour masterbatches

    1. Universal masterbatches. (Usually

    LLDPE based in India)

    2. Resin Specific masterbatches. (eg.

    PET based for PET, PC for PC etc.,)

    Shades are checked visually in

    a light booth and digitally

    using a colour

    spectrophotometer

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    Decoration

    UV Printing

    High Outputs 80 UPM 3colours

    Labeling

    High Speed accurate labelinglines working at 120 upm

    Hot foil Stamping

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    Design & Development

    2D Software AUTOCAD

    3D Software

    - Pro Engineering

    - Uni Graphics

    Imaging - 3D Studio

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    The IBC conceptExtremely light and space saving containersystem.

    Specially made for multi trip capabilities.

    Large packaging unit size, reduces number ofunits to be handled. Lower cost of filling, storage, handling

    and transportation.

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    Innovations in Design

    Easy to carry & Innovative Closure device

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    Innovations in Design

    Innovative Closure with

    Moisture absorber

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    Innovations in Design

    Innovative Vented

    Induction Sealing Wads

    Normal Wad Vented Wad

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    Innovations in Barrier Packaging

    Barrier Solutions Fluorination

    Co-extrusion

    Sulphonation

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    Direct Fluorination

    F

    FCFF

    F

    CH

    H

    HH

    F2

    The fluorination process is based on the

    formation of a fluorocarbon barrier layer

    on the polymer surface.

    The basic reaction which occurs with

    HDPE is a substitution of fluorine in

    place of hydrogen atoms on the polymerbackbone as shown in figure.

    The bulk properties of fluorine treatedplastic container remains unchanged.

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    Fluorination Techniques

    1 2 3 4 5

    F

    Offline Direct Fluorination Inline/ Online Fluorination

    1000ml.

    1 2 3

    F-C-HF-C-H

    F-C-H

    F-C-H

    H-C-FH-C-F

    H-C-F

    H-C-F

    F-C-HF-C-HF-C-H

    CF F

    CF F

    CF F

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    Testing of Fluorination

    Fluorination treatment is

    quantified using Fourier

    Transformation Infra

    Red Spectroscopy(FTIR). C-H bond

    shows peak absorption

    at 1440 1480 cm-1,

    while C-F bond givespeak absorbance at 930

    1320 cm-1.

    C-H Peak

    C-F Peak

    Before Fluorination

    After Fluorination

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    Applications for Fluorination Technology

    Chemical,petrochemical,

    automotive,

    Plugs for Solvent containers

    HDPE automotive fuel tanks

    Oil Packaging

    Flavor Packaging

    Direct PrintingApplications

    solvents,inks,

    hardener etc

    Pesticide

    Packaging

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    Applications for Fluorination Technology

    Surface Treatment for

    Chemical Resistance

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    Co-extrusion Technology

    Comprises of eitherthree, four or six layers,

    including HDPE and an

    inner EVOH or Nylon

    layer

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    Co-extrusion Technology

    Below is a typical cross section of a 6 layerco-ex container:1. PP / HDPE2. Adhesive3. EVOH / Nylon

    4. Adhesive5. Regrind / PCR6. PP / HDPEThese process steps are the same as for

    Extrusion Blow Moulding.

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    Sulphonation Technology

    The containers are treated with SO3

    gas on

    the Plastic Surface.

    Sulphonation of Plastic results in improved

    barrier Properties.

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    New Resins in Market

    N-MXD6 made from

    Meta xylene Diamide Due to its unique

    chemical composition

    and crystallinestructure, N-MXD6has excellent gasbarrier properties,

    especially in highhumidity conditionsas compared to N-6.

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    Nanocomposites

    Nano-composites

    are of Recent

    origin but they

    promise to rule thefuture of the Rigid

    containers.

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    Whats - Nanocomposites

    Nanocomposites particle size smaller than 1 X 10-9m

    Platy / layered structures that need to be separated byhigh shear to attain the advantage of the nanoclay.

    Very good overall physical properties at low additionlevels (3-4 %)

    Can behave as non halogenated flame retardants Low part weight

    Better Barrier properties

    Disadvantage: Expensive filler at present

    Application at the moment only automotive

    Technology is in Nascent Stage

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    Biodegradable Packaging

    PLA (Polylactic Acid)

    PHAs , {PHBV

    (Polyhydroxy Butyrate Velarate)}

    Starch Blends

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    Active Packaging

    Antimicrobial Packaging

    Scavenger Packaging

    Intelligent Packaging etc.

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    Innovations in Supply Chain

    Bar Code and RFID Systems

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    Bar codes on Retail items EAN or UPC

    890 1 0 0 0 0 1 0 0 1 0

    EAN prefix Prod no. CD EAN Prefix indicates

    - the country of EAN membership- EAN members identity

    Prod. No. : Item identity allocated by manufacturer/importer

    Check digit: Calculated from all preceding digits

    Real time locating system for Rigid Containers

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    Tagged

    Asset

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    ReaderTo System

    500 - 1000 m

    TaggedAsset

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    Real time locating system for Rigid Containers

    Reader

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    Retail supply chain

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    pp y

    Supplier Retailer Consumer

    RFID

    Data Recorded on the System

    Serial numberProduction date

    Filling dates and sites

    Tare weight etc.

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    Bhupendra Singh

    Bloom Packaging Pvt. Ltd.167- Ready Money Terrace, Dr. A.B. Road, Worli Naka, Worli, Mumbai 400 018

    Tel No. : 022-24970561, 32501137, 32501128

    Email: [email protected] , [email protected]

    www.bloompackaging.com,

    Thank You

    Questions ??