Report Title Air Emissions Compliance Monitoring Emissions ... · Report Title Air Emissions...

Document No: WAPRTL11281119 Licence Number: P0040-02 Visit No: 4 Licence Holder: Waterford Proteins Year: 2019 Facility Location: Ferrybank, Waterford Office: Limerick Version No: 1

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Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Anglo Beef Processors Ireland

Facility Name Waterford Proteins

Contact Person Colm Hayes

EPA Licence Number P0040-02

Licence Holder Anglo Beef Processors Ireland Unlimited Company

Stack Reference Number Thermal Oxidiser & Amine Bed

Dates of the Monitoring Campaign 28-11-2019

Job Reference Number WAPRTL11281119

Report Written By Mr. Michael Flood

Report Approved by Claire Boylan

Stack Testing Team Mr. Michael Flood and Mr. Shane McMahon

Report Date 13-01-2020

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver

Senior Quality Technician


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Contents

1.0 Executive Summary ................................................................................................................................................................................ 3 1.1 Overall aim of the monitoring campaign ................................................................................................................................................ 3 1.2 Summary of substances to be monitored at each emission point .......................................................................................................... 3 1.3 Special Requirements ............................................................................................................................................................................. 3 1.4 Summary of Results ................................................................................................................................................................................ 4 Emission Point Number: Thermal Oxidiser ........................................................................................................................................................ 4 Emission Point Number: Amine Bed Inlet ......................................................................................................................................................... 5 Emission Point Number: Amine Bed Outlet....................................................................................................................................................... 6 1.5 Operating Information ........................................................................................................................................................................... 7 1.6 Monitoring Deviations ............................................................................................................................................................................ 7 1.7 Reference Documents ............................................................................................................................................................................ 7 1.8 Revision History ...................................................................................................................................................................................... 7 Part 2: Supporting Information ........................................................................................................................................................................ 8 Appendix I ......................................................................................................................................................................................................... 9 1.1 Monitoring Personnel ............................................................................................................................................................................. 9 1.2 Equipment Inventory ............................................................................................................................................................................ 10 Appendix II ...................................................................................................................................................................................................... 11 2.1 Stack Emission Point Reference: Thermal Oxidiser .............................................................................................................................. 11 2.1.1 Suitability of Sample Location: ........................................................................................................................................................ 11 2.1.2 Stack Diagram ................................................................................................................................................................................. 12 2.1.3 Stack Raw Data ............................................................................................................................................................................... 13 2.2 Stack Emission Point Reference: ........................................................................................................................................................... 35 2.2.1 Suitability of Sample Location: ........................................................................................................................................................ 35 2.2.2 Stack Diagram ................................................................................................................................................................................. 36 2.2.3 Stack Raw Data ............................................................................................................................................................................... 37 Appendix III: Certificates and Process Detail Form ........................................................................................................................................ 44

Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.

All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.


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1.0 Executive Summary

1.1 Overall aim of the monitoring campaign

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified

in the site licence.

1.2 Summary of substances to be monitored at each emission point

Stack Name: TO

Total Particulate Matter

Total Gaseous Organic Compounds

Carbon Monoxide

Nitrogen Oxides (as NO2)

Oxygen

Carbon Dioxide

Sulphur Dioxide

Ammonia

Combustion Efficiency

Volumetric Flow Rate (Ref)

Stack Name: Amines Bed

Amines

1.3 Special Requirements

There were no special requirements


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1.4 Summary of Results

Emission Point Number: Thermal Oxidiser

Parameter Method Units Result MU +/- Limit O2 Ref.

(%)

Moisture

Ref. (%) Compliant Blanks Date Time on Time off

Accreditation

Sampling Analysis

Total Organic Compounds EN 12619 mg.m-3 1.0 0.45 - 17 0 N/a N/a 28-11-2019 10:34 11:04 Yes N/a

Carbon Monoxide EN 15058 mg.m-3 <1.7 0.5 - 17 0 N/a N/a 28-11-2019 10:35 11:05 Yes N/a

Nitrogen Oxides EN 14792 mg.m-3 180.8 10.7 - 17 0 N/a N/a 28-11-2019 10:35 11:05 Yes N/a

Oxygen EN 14789 vol% 4.6 0.3 - 17 0 N/a N/a 28-11-2019 10:35 11:05 Yes N/a

Carbon Dioxide ISO 12039 vol% 7.1 0.2 - 17 0 N/a N/a 28-11-2019 10:35 11:05 Yes N/a

Particulate Matter EN 13284-1 mg.m-3 <0.98 0.123 - 17 0 N/a <0.25 28-11-2019 12:11 12:41 No Yes

Volumetric Flow Rate (Ref) EN 16911 m3.h-1 63,333 4,166 - 17 0 N/a N/a 28-11-2019 12:11 12:41 Yes N/a

Boiler efficiency Calc % 89.12 - - - - - - 28-11-2019 10:35 11:05 - -

Sulphur Dioxide EN14791 mg.m-3 14.47 4.57 - 17 0 N/a 0.0266 28-11-2019 10:05 10:35 Yes Yes

Ammonia EN 14791 mg.m-3 <0.07 0.023 - 17 0 N/a <0.0526 28-11-2019 10:46 11:16 Yes Yes

Note 1: All results are normalised to standard temperature and pressure (0OC and 101.3kPa)

Note 2: All results are reported in the format as defined by the EPA in guidance note AG2:2018.


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Emission Point Number: Amine Bed Inlet


(%)

Moisture


Accreditation

Sampling Analysis

Amines (Total) EN 13649 mg.m-3 <0.35 <0.01 N/a N/a N/a N/a <0.07 28-11-2019 12:13 12:43 Yes Yes

Amines EN 13649 ppm <0.25 - N/a N/a N/a N/a <0.05 28-11-2019 12:13 12:43 Yes Yes



Note 3: Amines are referenced as Methylamine


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Emission Point Number: Amine Bed Outlet


(%)

Moisture


Accreditation

Sampling Analysis

Amines (Total) EN 13649 mg.m-3 <0.35 <0.01 N/a N/a N/a N/a <0.07 28-11-2019 13:05 13:35 Yes Yes

Amines EN 13649 ppm <0.25 - N/a N/a N/a N/a <0.05 28-11-2019 13:05 13:35 Yes Yes



Note 3: Amines are referenced as Methylamine


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1.5 Operating Information

Please reference Process Details as per Appendix III attached.

1.6 Monitoring Deviations

Stack Name:

Parameter Deviation

Total Particulate Matter

Port position not in full agreement with EN 15259 – straight length

not available after sample port but didn’t interfere with sampling.

Isokinetic Sampling outside ranges -5 to 15%

Total Gaseous Organic Compounds None

Carbon Monoxide None

Nitrogen Oxides (as NO2) None

Oxygen None

Carbon Dioxide None

Sulphur Dioxide None

Ammonia None

Volumetric Flow Rate (Ref)

Port position not in full agreement with EN 15259 – straight length

not available after sample port but didn’t interfere with sampling

EN 16911 - in accordance with MID 16911-1

Stack Name: Amines Bed

Parameter Deviation

Amines None

1.7 Reference Documents

Risk Assessment (RA) SOP 1011

Site Review (SR) SOP 1015

Site Specific Protocol (SSP) SOP 1015

1.8 Revision History

Revision Number Changes to the report

1 Original version of the report


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Part 2: Supporting Information

Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Anglo Beef Processors Ireland

Facility Name Waterford Proteins

Contact Person Colm Hayes

EPA Licence Number P0040-02

Licence Holder Anglo Beef Processors Ireland Unlimited Company

Stack Reference Number Thermal Oxidiser & Amine Bed

Dates of the Monitoring Campaign 28-11-2019

Job Reference Number WAPRTL11281119

Report Written By Mr. Michael Flood

Report Approved by Claire Boylan

Stack Testing Team Mr. Michael Flood and Mr. Shane McMahon

Report Date 13-01-2020

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver

Senior Quality Technician


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Appendix I

1.1 Monitoring Personnel

Team Leader Name Mike Flood

System approval ASL Team Leader Approved

Technician Name Shane McMahon

System approval ASL Technician Approved


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1.2 Equipment Inventory

ID Item of Equipment Used ID Item of Equipment Used ID Item of Equipment Used

ASLLK12EQ500 Pump X ASLLK12EQ525 Horiba (PG-250) X ASLLK13EQ501 Vernier Calipers

ASLLK12EQ532 Pump ASLLK14EQ501 Horiba-PG 350 ASLLK14EQ503 Vernier Calipers

ASLLK12EQ533 Pump ASLLK14EQ512 Horiba PG250Y ASLLK14EQ507 Vernier Calipers

ASLLK12EQ534 Pump ASLLK16EQ508 Horiba- PG250z ASLLK17EQ533 Vernier Calipers x

ASLLK12EQ535 Pump ASLLK17EQ515 Horiba 350 ASLLK18EQ506 Vernier Calipers

ASLLK12EQ536 Pump

ASLLK12EQ537 Pump

ASLLK12EQ538 Pump ASLLK12EQ526 Chiller ASLLK13EQ503 1kg weight

ASLLK12EQ540 Pump ASLLK14EQ513 Chiller ASLLK13EQ508 500g Hafner weight

ASLLK12EQ541 Pump ASLLK16EQ509 Chiller X ASLLK13EQ509 500g Hafner weight

ASLLK12EQ542 Pump ASLLK18EQ505 Chiller ASLLK14EQ515 500g Weight

ASLLK12EQ543 Pump ASLLK15EQ511 1kg Weight

ASLLK13EQ513 Pump ASLLK15EQ512 1kg weight

ASLLK13EQ514 Pump ASLLK16EQ501 Velocity Meter ASLLK16EQ511 1kg weight

ASLLK16EQ518 Pump ASLLK17EQ508 Velocity Meter ASLLK16EQ512 500g weight

ASLLK16EQ519 Pump ASLLK17EQ514 Velocity Meter ASLLK17EQ529 500g weight

ASLLK17EQ509 Pump ASLLK18EQ504 Velocity Meter ASLLK17EQ530 1kg weight

ASLLK17EQ510 Pump ASLLK19EQ502 Velocity Meter ASLLK19EQ513 500g weight x

ASLLK19EQ514 1kg weight x

ASLLK17EQ522 Pump ASLLK13EQ504 G4

ASLLK17EQ523 Pump ASLLK13EQ515 G4

ASLLK17EQ524 Pump ASLLK14EQ500 FID ASLLK15EQ501 G4

ASLLK17EQ525 Pump X ASLLK16EQ502 FID X ASLLK17EQ534 ST5

ASLLK17EQ526 Pump ASLLK17EQ517 FID ASLLK18EQ503 ST5 x

ASLLK18EQ517 Pump ASLLK19EQ508 FID ASLLK18EQ513 ST5

ASLLK18EQ518 Pump ASLLK17EQ535 Signal Cutter ASLLK19EQ509 ST5

ASLLK13EQ512 PCDD thermometer ASLLK14EQ510 Digital Protractor

ASLLK15EQ506 MF Meter X ASLLK14EQ511 Digital Protractor

ASLLK17EQ501 MF Meter ASLLK16EQ510 Measuring Tape ASLLK15EQ505 Digital Protractor

ASLLK17EQ542 MF Meter ASLLK16EQ513 Measuring Tape ASLLK16EQ507 Digital Protractor

ASLLK18EQ511 MF Meter ASLLK16EQ514 Measuring Tape ASLLK17EQ528 Digital Protractor x

ASLLK18EQ512 MF Meter ASLLK17EQ527 Measuring Tape x ASLLK18EQ507 Digital Protractor

ASLLK19EQ500 MF Meter ASLLK18EQ508 Measuring Tape

ASLLK19EQ501 MF Meter

ASLLK12EQ522 Balance

ASLLK12EQ527 Heated Line ASLLK16EQ515 Thermocouple K type ASLLK12EQ544 Balance

ASLLK14EQ509 Heated Line ASLLK16EQ516 Thermocouple K type ASLLK15EQ509 Balance

ASLLK14EQ514 Heated Line ASLLK18EQ510 K type Thermocouple ASLLK15EQ510 Balance

ASLLK17EQ502 Heated Line ASLLK19EQ503 K type Thermocouple ASLLK17EQ537 Balance x

ASLLK17EQ503 Heated Line ASLLK19EQ504 K type Thermocouple ASLLK17EQ538 Balance

ASLLK17EQ539 Heated Line ASLLK19EQ505 K type Thermocouple

ASLLK18EQ516 Heated Line ASLLK19EQ512 K type Thermocouple x

ASLLK19EQ523 Heated Line x

ASLLK17EQ519 Stopwatch

ASLLK12EQ518 S type Pitot Tube ASLLK17EQ520 Stopwatch

ASLLK12EQ520 L Type Pitot tube ASLLK17EQ521 Stopwatch

ASLLK13EQ506 S type Pitot Tube ASLLK18EQ509 Stopwatch

ASLLK14EQ506 Pitot + thermocouple ASLLK19EQ518 Stopwatch x

ASLLK16EQ506 S type Pitot Tube x

ASLLK16EQ517 S type Pitot Tube Long

ASLLK17EQ507 1 m S type & K type

ASLLK17EQ536 S type Pitot Tube




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Appendix II

2.1 Stack Emission Point Reference: Thermal Oxidiser

2.1.1 Suitability of Sample Location:

General Information Thermal Oxidiser

Permanent/Temporary Permanent

Inside/ Outside Outside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259

Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring

instruments Yes -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes

-

Platform has vertical base boards (approx. 0.25 m high) Yes

-

Platform has chains / self-closing gates at top of ladders Yes

-

There are no obstructions present which hamper insertion of

sampling equipment Yes -

Safe Access Available Yes

-

Easy Access Available Yes

-

Sampling Location / Platform Improvement Recommendations

None

EN 15259 Homogeneity Test Requirements

1.

Select Option:

1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack

2: Test results were obtained from previous Homogeneity test carried out by ASL

3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor

4: Homogeneity Test is required on this stack and the client has been informed of this requirement


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2.1.2 Stack Diagram

Figure 1: Thermal Oxidiser


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2.1.3 Stack Raw Data


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Title: Determination of Total Particulates

Method: EN 13284-1

Client Waterford Proteins

Test Date: 28/11/2019 Temperature at Pump 14.5 Deg C

Test Time: 12:11 Pressure at Pump 76.93 kPa

Laboratory Used: RPS Air Volume at Pump 0.8981 m3

Stack Name TO Humidity at Pumps 0 %

Run I.D. 1 Filter Weight 1.51 mg

Filter I.D. 193314 Front End Weight 1.13 mg

Moisture Content 39 % Reference Moisture - %

Reference Oxygen 17 % Flow Uncertainty 4166 m3/hr

Measured Oxygen 4.6 % Flow Uncertainty 6.6 %

Stack Flow Rate 24923 Nm3/hr

Adjusted Stack Flow Rate 63333 Nm3/hr, dry @ % Oxygen

Volume of Air Sampled 0.6476 Nm3

Leak Check Results Result % Leak

Before Sample 0 l/min 0.0

Average Flow Rate 21.63 l/min 0.0

Standard Maximum 0.4326 l/min 2%

Back Pressure 68 kPa

Standard Criteria to be Met Result Std. Requirement

Angle of Flow Yes <15 Degrees Probe material Stainless Steel

Negative Flow in the Stack Yes None Filter housing Stainless Steel

Pitot Pressure Difference Yes >5Pa Positioning of filter In Stack

Ratio of Flow Measurement Yes <3:1 Filter Size & Material 47mm Quartz

Stagnation Test Yes <10Pa

Pitot Tube Leak Check Result

Positive Pressure Pass -

Negative Pressure Pass -

Number of Ports 2 2

Straight length before sample point No > 5 Hydraulic Diameters

Straight length after sample point No > 5 Hydraulic Diameters to Stack Outlet or 2HD to Fan/ Bend

Sample Calculations

Blank (Filter and Front Wash Combined) 0.69 mg

Sample 1 (Filter and Front Combined) 2.64 mg

Volume of Air Sampled 0.6476 Nm3

Blank Result 1.07 mg/Nm3,

dry 0.25 mg/Nm3, dry @ Ref O2

Sample Result 4.08 mg/Nm3,

dry 0.98 mg/Nm3, dry @ Ref O2

Uncertainty of Measurement 0.12 mg/Nm3 Requirement <20% ELV

Emission Limit Value - mg/Nm3, dry @ Ref O2

Blank as Percentage of ELV - % Requirement <10% ELV or <0.5 mg/m3

Isokinetic Criterion Compliance Isokinetic Variation -5.6 % Allowable Isokinetic Range .- 5 to + 15 % Isokinetic Acceptable No -


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DUCT AND GAS SPECIFICATION

Name to

Section Circular

Diameter [m] 1.47

Area [m2] 1.697

Ports B [#] 1

Points P [#] 12

Density ρn [kg/Nm3] 1.308

Carbon Dioxide CO2 [%] 7.1

Oxygen O2 [%] 4.6

Water Vapor Ratio rw [0;1] 0.392

Nozzle nz [mm] 14

Turbolence factor ft [sec] 1

Wall Adjustment Factor waf 1

PITOT DATA SPECIFICATION

Name p0.850

Velocity [m/sec] 5 0.85





NORMALIZATION FACTOR

Tnorm [K] 273

Pnorm [kPa] 101.3

DUCT FLOW RATE

Dry actual QVa [m3/h] 30705

Moist actual Q'Va [m3/h] 50503

Moist norm. [Tnorm Pnorm] Q'Vn [Nm3/h] 24923

Dry norm. [Tnorm Pnorm] QVn [Nm3/h] 15153

AVERAGE VALUES

Total Points [#] 1

Velocity v'a [m/sec] 8.27

Stack temperature tstack [°C] 270.44

Stack Pressure Pa [kPa] 99.51

Isokinetic Rate DI [%] -5.6

Velocity at nozzle v'N [m/sec] 7.799

Probe temperature tprobe [°C] 80.9

Filter temperature tfilter [°C] 30.1

Outlet temperature toutlet [°C] 5.8

Aux temperature taux [°C] 24.5

Ambient Pressure Pamb [kPa] 99.64

GAS METER SAMPLED VOLUMES

Elapsed time et [hh:mm:ss] 00:30:00

Norm. Volume [Tnorm Pnorm] Vgn [Nm3] 0.6476

Moist Volume at stack conditions V'ga [m3] 2.1587

Volume at dgm conditions Vdgm [m3] 0.8981

Gas meter temperature tdgm [°C] 14.5

Gas Meter Pressure Pdgm [kPa] 76.93


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start ts port point Probe pos Elapsed

Time tstack avg Pa avg

dP pitot avg

velocity avg

[timestamp] [###] [###] [cm] [hh:mm:ss] [°C] [kPa] [Pa] [m/sec]

28/11/2019

1 1 3.2 00:01:00 275.78 99.46 30.73 9.05 11:56:19

00:01:00 275.68 99.46 30.8 9.06

28/11/2019

1 2 9.9 00:01:00 280.45 99.46 31.01 9.13 11:57:21

00:01:00 280.38 99.46 31 9.13

28/11/2019

1 3 17.4 00:01:00 283.85 99.47 31.35 9.21 11:58:24

00:01:00 283.81 99.47 31.34 9.2

28/11/2019

1 4 26.1 00:01:00 284.33 99.47 30.72 9.12 11:59:30

00:01:00 284.35 99.47 30.82 9.13

28/11/2019

1 5 36.8 00:01:00 283.38 99.48 29.45 8.92 12:00:31

00:01:00 283.38 99.48 29.36 8.91

28/11/2019

1 6 52.3 00:01:00 283.06 99.48 29.06 8.86 12:01:33

00:01:00 283.08 99.48 29 8.85

28/11/2019

1 7 94.8 00:01:00 282.4 99.48 28.77 8.81 12:02:37

00:01:00 282.41 99.48 28.76 8.81

28/11/2019

1 8 110.3 00:01:00 281.88 99.48 30.51 9.07 12:03:40

00:01:00 281.88 99.48 30.46 9.06

28/11/2019

1 9 121 00:01:00 281.22 99.48 31.37 9.19 12:04:41

00:01:00 281.24 99.48 31.34 9.18

28/11/2019

1 10 129.7 00:01:00 280.74 99.49 30.06 8.99 12:05:50

00:01:00 280.74 99.49 29.98 8.98

28/11/2019

1 11 137.2 00:01:00 281.35 99.49 28.78 8.8 12:07:17

00:01:00 281.35 99.49 28.77 8.8

28/11/2019

1 12 143.9 00:01:00 281.94 99.48 30.42 9.05 12:08:21

00:01:00 281.92 99.48 30.35 9.04


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Uncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Method Version 14

Stack Name: TO

Measurement Equation

Limit value (ELV) 0 mg.m -3Reference oxygen 17 % by volume

Measured concentration 0.98 mg.m -3 (at reference conditions)

Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as percentage Uncertainty at lv Requirement of std

Sampled Volume Vm 0.8981 uVm 0.001 m 3 0.11 <=5%

Sampled gas Temperature Tm 287.5 uTm 2 k 0.70 <=2%

Sampled gas Pressure ρm 76.93 uρm 1 kPa 1.30 <=2%

Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%

Oxygen content O2,m 4.6 uO2,m 0.1 % by volume 2.17 <=5%

Mass particulate m 2.64 um 0.16 mg 6.00 #DIV/0! <5% of limit value

Note - Sampled gas humidity, temperature and pressure are values at the gas meter

Leak L 0.000 % 0.00 <=2%

Uncollected Mass UCM 0 mg 0 <=10%

(Instack f ilter - no rinse)

Intermediate calculations

Factor for std conds fs 0.72

uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009

Hm 0.007 0.007

Tm 0.003 0.005

ufs 0.013 1.78

Corrected volume V 0.65 uV 0.012 m 31.79

Factor for O2 correction fc 0.24

uncertainty components symbol sensitivity coeff u

O2,m 0.01 0.001

Factor for O2 Correction ufc 0.24 0.001 0.61

Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %

Corrected Volume (standard conditions)V 0.65 m3 1.51 0.02 mg.m-3 1.79 %

Mass m 2.64 mg 0.37 0.06 mg.m-3 6.00 %

Factor for O2 Correction fc 0.24 4.00 0.01 mg.m-3 0.61 %

Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %

Uncollected mass UCM 0.00 mg 0.37 0.00 mg.m-30.00 %

Combined measurement uncertainty 0.06 mg.m-3

Expanded uncertainty as percentage of measured value 12.58 % measured of value expressed with a level of confidence of 95%

(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.12 mg.m -3

sm fVV =

m

ref

cO

Of

,2

,2

21

21

−

−=

cfV

mc =

3.101

273

100

)100( m

m

m

sT

Hf

−=


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Title: Determination of Inorganic Compounds

Method: EN 14791 EN14791

Test Date: 28/11/2019

Test Time Started: 10:05 10:46

Test Time Finished: 10:35 11:16

Laboratory Used: RPS

Stack Reference: TO

Leak Check Results SO2 Ammonia

Prior to test: 0 0 l/min

Post Test: 0 0 l/min

Sample Volume Flow Rate: 2 2 l/min

Standard Requirement: <2 <2 %

Test Result: 0.0 0.0 %

Test Status Pass Pass

Reference Details

Reference Oxygen 17 %

Measured Oxygen 4.6 %

Reference Moisture 0 %

Calibration Details SO2 Ammonia

Pump Number: ASLLK12EQ500 ASLLK12EQ500

Calibration Unit: ASLLK15EQ506 ASLLK15EQ506

Calibration Rate Before Test: 2.2 2.2 Nl/min

Calibration Rate After Test: 2.2 2.2 Nl/min

Average sample Volume: 2.2 2.2 Nl/min

Sample Test Time: 30 30 minutes

Pump Gas Temperature: 9 9 OC

Pump Sample Pressure: 101.3 101.3 kPa

Normalised Gas Volume: 0.06600 0.06600 Nm3

Sample Details SO2 Ammonia

Impinger Solution 0.1M H2O2 0.1NH2SO4

Solution ID Number: Run 1 Run 1

Blank Identification Number: Run 1 Run 1

Impinger Material PTFE PTFE

Breakthrough Occurred No No

Transport Temp meets Standard Yes Yes

Analysed Within Specified Timeframe Yes Yes

Transport Container Airtight Yes Yes

Exposed to Sunlight No No

Calculations SO2 Ammonia

Laboratory Result Imp 1 59.8 0.1 ug/ml

Laboratory Result Imp 2 0.1 0.1 ug/ml

Impinger Final Volume Imp 1 100 145 ml

Impinger Final Volume Imp 2 62 52 ml

Combined Concentration 5.9862 0.0197 mg

Factor 0.667 1

Concentration 3.993 0.020 mg

Air Sample Volume 0.066 0.066 Nm3

Emissions Concentration 60.5 0.3 mg.m-3

Referenced Results SO2 Ammonia

Emissions Concentration 14.5 0.1 mg.m-3 Ref O2

Uncertainty 4.6 0.0 mg.m-3

Licence Limits - - mg.m-3

Blank Calculation SO2 Ammonia

Laboratory Impinger / Rinse Result 0.11 0.1 ug/ml

Factor 0.667 1 -

Blank Concentration 0.0 0.1 mg.m-3

% of Licence Limit - - %

Field Blank <10% ELV - -


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QGU-009-2013 Uncertainty calculation

v2





Sampled Volume Gas Vm 0.066 uVm 0.001 m 31.52 <=2%

Sampled gas Temperature T m 282 uTm 2 k 2.00 <2.5 k




Concentration in impinger C 59.9 uC 1.797 mg/l 3.00 <5%

Impinger solution volume VS 162 uVS 0.001 l 0.00 <1%

Mass Analyte m 5.9862 um 0.18 mg 3.00 #DIV/0! <5% of limit value


Leak L 0 % 0.00 <=2%




ρm 0.010 0.010

Hm 0.010 0.010

T m 0.003 0.007

ufs 0.015 1.57




O2,m 0.01 0.001




Mass m 5.99 mg 10.11 1.81 mg.m-3 3.00 %


Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %

Combined uncertainty 2.29 mg.m-3




cfV

mc =

sm fVV =

m

ref

cO

Of

,2

,2

21

21

−

−=

cfV

mc =


20 of 44

QGU-009-2013 Uncertainty calculation

v2










Concentration in impinger C 0.2 uC 0.006 mg/l 3.00 <5%

Impinger solution volume VS 197 uVS 0.001 l 0.00 <1%

Mass Analyte m 0.0197 um 0.00 mg 3.00 #DIV/0! <5% of limit value


Leak L 0 % 0.00 <=2%




ρm 0.010 0.010

Hm 0.010 0.010

T m 0.003 0.007

ufs 0.015 1.57




O2,m 0.01 0.001




Mass m 0.02 mg 15.15 0.01 mg.m-3 3.00 %


Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %





cfV

mc = cf

V

mc =

cfV

mc =


21 of 44

Title: Determination of Combustion Flue Gases

Method: EN 14792 / EN 14789 / EN 15058/ ISO 12039

Test Date: 28/11/2019

Stack Name: TO Quality Assurance

Test Start Time: 10:35 Probe Material Stainless Steel

Reference Conditions Filtration Type/size Stainless Steel

Measured Oxygen 4.6 % Heated Filter used Yes

Reference Oxygen 17 % No. of sampling lines 1

Reference Moisture 0 % No. of Sampling points 1

Sampling point I.D.s 1

Parameter CO NO O2 CO2

Emission Limit Values mg.m-3 ref - - - -

Instrument Range ppm 200 500 25% 20%

Span Gas Value ppm 155 462 20.90% 16.04%

Acceptable Gas Range - Yes Yes Yes Yes

Calibration Gas Reference No. - ASLLK18ING445 ASLLK19ING520 - ASLLK19ING535

Calibration Gas Uncertainty % 0.4 0.9 0.5 0.9

Calibration Gas Start Bar Bar 55 45 - 47

Expiry Date - Jul-21 Feb-20 - Feb-22

Quality Assurance Units

Conditioning Unit Temperature C 2 2 2 2

Average Temperature < C 2 2 2 2

Allowable Temperature - 4 4 4 4

Temperature Acceptable - Pass Pass Pass Pass

Pump flow rate l/min. 0.5 0.5 0.5 0.5

Instrument Zero Drift Units

Instrument Zero (Ambient air or Nitrogen) Nitrogen Nitrogen Nitrogen Nitrogen

Instrument Zero (Pre) ppm 0 0 0.00% 0.00%

Instrument Zero (Check) ppm 0.9 0.8 0.24% 0.15%

Compliance Statement Pass / Fail Pass Pass Pass Pass

Instrument Zero (Post) ppm 1.2 1.4 0.28% 0.17%

Zero Drift ppm 1.2 1.4 0.28% 0.17%

Allowable Zero Drift (Less than 2%) ppm equiv. 3.1 9.2 0.418 -

Adjustable Zero Drift (2 - 5%) / 4% CO2 ppm equiv. 7.8 23.1 1.045 0.6416

Zero Drift Failure (<5% / >4% CO2) ppm equiv. 7.8 23.1 1.045 0.6416

Zero Drift Acceptable - Pass Pass Pass Pass

Adjust for Zero Drift - Yes Yes Yes Yes

Reject results - Yes Yes Yes Yes

Calculated Drift % 0.8% 0.3% 1.3% 1.1%

Instrument Span Drift Units

Instrument Span Down (Pre) ppm 155 462 20.90% 16.04%

Instrument Check Span (Post) ppm 153.7 461.1 20.82% 16.10%

Span Drift ppm -1.3 -0.9 -0.08% 0.06% Allowable Span Drift (less than 2%/ CO2 4%) ppm equiv. 3.1 9.24 0.418 0.6416

Adjustable Span Drift (2 - 5%) ppm equiv. 7.75 23.1 1.045 -

Span Drift Failure (Greater than 5%) ppm equiv. 7.75 23.1 1.045 0.6416

Span Drift Acceptable (Y/N) - Yes Yes Yes Yes

Adjust for Span Drift - No No No No

Reject results - No No No No

Calculated Drift % -0.8% -0.2% -0.4% 0.4%

Heated Line Check Including Leak Check

Span Gas Conc. ppm 155 462 20.90% 16.04%

Zero Check Acceptable Limit (+/-) ppm 3.1 9.24 0.42% 0.32%

Heated Line Check Zero Gas ppm 1.2 1.3 0.22% 0.06%


Heated Line Check Span Gas ppm or % 153.6 459.1 20.78% 15.94%

Span Gas Leak Detected ppm or % -1.4 -2.9 -0.12% -0.10%

Leak check acceptable (< 2%) ppm or % 3.1 9.24 0.418 0.3208


Response Time (<200 seconds) Yes Yes Yes Yes


22 of 44

Test Conditions Units

Run Ambient Temperature Range C 9

Raw Data

Date/Time CO NOx CO2 O2

ppm ppm vol% vol%

28/11/2019 10:35 1.500 389.167 7.221 3.780

28/11/2019 10:36 1.783 381.925 7.223 3.851

28/11/2019 10:37 1.592 388.467 7.228 3.435

28/11/2019 10:38 1.525 387.950 7.228 3.502

28/11/2019 10:39 1.358 379.367 7.219 3.790

28/11/2019 10:40 1.142 371.350 7.219 4.718

28/11/2019 10:41 1.317 368.075 7.191 4.980

28/11/2019 10:42 0.983 362.875 7.191 5.631

28/11/2019 10:43 0.967 364.217 7.193 4.874

28/11/2019 10:44 1.117 371.333 7.188 4.150

28/11/2019 10:45 1.250 367.367 7.184 4.552

28/11/2019 10:46 1.033 367.350 7.179 4.532

28/11/2019 10:47 0.967 364.192 7.174 4.293

28/11/2019 10:48 0.825 362.183 7.169 5.036

28/11/2019 10:49 0.967 354.350 7.164 5.048

28/11/2019 10:50 0.758 359.300 7.159 4.993

28/11/2019 10:51 0.808 348.083 7.164 4.104

28/11/2019 10:52 0.583 346.067 7.124 4.413

28/11/2019 10:53 0.558 354.908 7.109 4.392

28/11/2019 10:54 0.783 372.108 7.104 3.650

28/11/2019 10:55 0.542 374.375 7.030 4.807

28/11/2019 10:56 0.567 369.842 7.056 5.300

28/11/2019 10:57 0.808 368.325 7.067 3.931

28/11/2019 10:58 0.942 373.092 7.059 4.202

28/11/2019 10:59 0.842 372.517 7.037 4.344

28/11/2019 11:00 0.750 371.700 7.028 5.525

28/11/2019 11:01 0.500 365.308 7.018 5.465

28/11/2019 11:02 0.683 368.292 7.009 5.105

28/11/2019 11:03 0.758 369.825 6.999 4.852

28/11/2019 11:04 0.592 372.508 6.989 5.247

Average 1.0 368.9 7.1 4.6


23 of 44

Referenced Data

CO NOx CO2 O2

mg/Nm3 Reference O2 vol% vol%

28/11/2019 10:35 0.4 182.0 7.22 3.78

28/11/2019 10:36 0.5 179.4 7.22 3.85

28/11/2019 10:37 0.4 178.1 7.23 3.44

28/11/2019 10:38 0.4 178.5 7.23 3.50

28/11/2019 10:39 0.4 177.5 7.22 3.79

28/11/2019 10:40 0.3 183.7 7.22 4.72

28/11/2019 10:41 0.4 185.1 7.19 4.98

28/11/2019 10:42 0.3 190.3 7.19 5.63

28/11/2019 10:43 0.3 182.0 7.19 4.87

28/11/2019 10:44 0.3 177.5 7.19 4.15

28/11/2019 10:45 0.4 179.9 7.18 4.55

28/11/2019 10:46 0.3 179.7 7.18 4.53

28/11/2019 10:47 0.3 175.6 7.17 4.29

28/11/2019 10:48 0.3 182.8 7.17 5.04

28/11/2019 10:49 0.3 179.0 7.16 5.05

28/11/2019 10:50 0.2 180.8 7.16 4.99

28/11/2019 10:51 0.2 165.9 7.16 4.10

28/11/2019 10:52 0.2 168.1 7.12 4.41

28/11/2019 10:53 0.2 172.1 7.11 4.39

28/11/2019 10:54 0.2 172.7 7.10 3.65

28/11/2019 10:55 0.2 186.3 7.03 4.81

28/11/2019 10:56 0.2 189.8 7.06 5.30

28/11/2019 10:57 0.2 173.8 7.07 3.93

28/11/2019 10:58 0.3 178.9 7.06 4.20

28/11/2019 10:59 0.2 180.2 7.04 4.34

28/11/2019 11:00 0.2 193.6 7.03 5.52

28/11/2019 11:01 0.2 189.5 7.02 5.47

28/11/2019 11:02 0.2 186.7 7.01 5.10

28/11/2019 11:03 0.2 184.5 7.00 4.85

28/11/2019 11:04 0.2 190.5 6.99 5.25

Average 0.3 180.8 7.1 4.6

Uncertainty of Measurement 0.5 10.7 0.24 0.35

Uncertainty as % of ELV 0.00 0.00 - -

Standard Requirement <6% <10% <25% <6%

0.0

50.0

100.0

150.0

200.0

250.0

CO

NOx


24 of 44

Uncertainty calculation for Gaseous Measurement CO

Limit value 0 mg/m 3 (corrected) Cal gas conc 193.75 mg.m -3 Correction for reference conditions

O2, % Moisture, % Pressure, KPa Temperature, K

Measured concentration 1.20 mg/m3 Full Scale 250 mg/m 3ref 17.00 0.00 101.30 273.00

Measured concentration 0.28 mg/m 3 (Corrected) measured 4.55 0.00 101.30 273.00

Uncert 0.35 1.00 0.00 1.00

Factors 0.24 1.00 1.00 1.00

Uncertainty in factor 0.01 0.01 0.00 0.00

Correction Factor 0.24 uf 0.01

Performance characteristics Value specification Effect of drift

Response time 30 seconds 180.000 0.00 mg/m3

Logger sampling interval 60 seconds 0.00 % full scale

Measurement period 30 minutes

Number of readings in measurement 30

Repeatability at zero 0.25 % full scale <1 % range

Repeatability at span level 0.15 % full scale <2 % range

Deviation from linearity(lack of f it) 0.7 % of value <2 % range

Zero drift 1.5 mg/m3 <2% range / 24hr ranges

Span drift -1.625 mg/m3 <2% range/24hr min max value at calib

volume or pressure f low dependence 0.02 % of full scale/3 kPa <2 % / 3 kPa flow 95.00 105 100 kPa

atmospheric pressure dependence 0.8 % of full scale/2 kPa <3% / 2 kPa pressure 100.76 100.92 100.88 kPa

ambient temperature dependence 0.01 % full scale/10K <3% range / 10 K temp 287 288.5 287.5 K

N2O (mg/m3) 20 0.2 mg/m3 N2O range 0 40 0 mg/m3

CO2 (% vol) 15 0.2 mg/m3 CO2 range 0 15 0 %vol

CH4 (mg/m3) 40 0.7 mg/m3 CH4 range 0 57 0 mg/m3

H2O (% vol) 20 0.2 mg/m3 H2O range 0 1 0 %vol

dependence on voltage 0.1 % full scale/10V <2% range Voltage 93 121 110 V

losses in the line (leak) -0.90 % of value < 0.1%vol /10 volt

Uncertainty of calibration gas 0.4 % of value < 2% of value

Performance characteristic Uncertainty Value of uncertainty quantity mg/m3

Standard deviation of repeatability at zero ur0 for mean use rep at span

Standard deviation of repeatability at span level urs for mean 0.07

Lack of f it ufit 0.00

Drift u0dr 0.00

volume or pressure f low dependence uspres 0.05

atmopsheric pressure dependence uapres 0.06

ambient temperature dependence utemp 0.00

N2O (mg/m3) uinterf 0.23 Use largest of sum of all positive or all negative influences

CO2 (% vol) uinterf 0.12 0.93 all +ves Criteria

CH4 (mg/m3) uinterf 0.58 0 all -ves sum <4% range

H2O (% vol) uinterf 0.01 0.93 largest 0.024

Dependence on voltage uvolt 0.22 Value to use for intereference uncertainty

losses in the line (leak) uleak -0.01 uint 0.93

Uncertainty of calibration gas ucalib 0.00

Measurement uncertainty

Combined uncertainty 0.96 mg/m3

Expanded uncertainty k = 2 1.92 mg/m3

Uncertainty corrected to std conds 0.47 mg/m 3

Expanded uncertainty expressed with a level of confidence of 95%0.00 % ELV

Expanded uncertainty expressed with a level of confidence of 95%0.47 mg.m -3

Expanded uncertainty expressed with a level of confidence of 95%163.85 % value


25 of 44

QGU-007-2013 Uncertainty calculation for Gaseous Measurement Carbon Dioxide

V2.2 Jul-08

Limit value n/a %vol Calibration gas 0.1604 %vol

Measured concentration 7.13 %vol Full Scale 25 %vol

Performance characteristics Value specification

Response time 30 seconds < 200 s

Logger sampling interval 60 seconds 0.00 % vol

Measurement period 30 minutes 0.00 % value

Number of readings in measurement 30 Assuming 1 minute collected over 1 hour

Repeatability at zero 0.015 % by volume stdev <0.2 % range

Repeatability at span level 0.014 % by volume stdev <0.4 % range

Deviation from linearity 0.13 % vol +/- <0.3 % volume

Zero drift (during measurement period) 0 % vol at zero level +/- <2% of volume / 24hr

Span drift (during measurement period) 0 % vol at span level +/- <2% volume/24hr min max value at calib

volume or pressure f low dependence 0 % of fs / 10l/h +- 5 l/h <1% range flow 5 15 10 l/h

atmospheric pressure dependence 0.3 % of fs/kPa +- 2kPa < 1.5 % range pressure 99.00 101 100 kPa

ambient temperature dependence -0.07 % by volume /10K +- 15K <0.3% volume 10 K temp 280 285 285 K

CO2 (% vol) 15 0.07 % by volume per 15 CO2 range 8 15 0 % vol

NO (mg/m3) 300 0.02 % by volume per 300 NO range 100 150 0 mg/m3

NO2 (mg/m3) 30 0 % by volume per 30 NO2 range 5 7.5 0 mg/m3

Combined interference 0.56 % range <2% range Voltage 105 115 110 V

Dependence on voltage 0.1 % by volume /10V +- 5% < 0.1%vol /10 volt

Losses in the line (leak) 0.623441397 % of value < 2% of value

Uncertainty of calibration gas 0.9 % of value

Performance characteristic Uncertainty Value of uncertainty quantity % vol

Standard deviation of repeatability at zero ur0 for mean Only use rep at span



Drift u0dr 0.00


atmospheric pressure dependence uapres 0.04

ambient temperature dependence utemp -0.02

CO2 0.05 Use largest of sum of all positive or all negative influences

NO 0.01 0.06 all +ves Criteria

NO2 0.00 0 all -ves sum <2% value

Combined interference (from mcerts) 0.08 0.06 largest 0.142616063

dependence on voltage uvolt 0.03 Value to use for intereference uncertainty

losses in the line (leak) uleak 0.03 uint 0.06


Measurement uncertainty 7.13 %vol

Combined uncertainty 0.12 %vol

% of value 1.70 %

Coverage factor k = 2

Expanded uncertainty expressed with a level of confidence of 95% 3.41 % of value

Expanded uncertainty expressed with a level of confidence of 95% 0.24 % vol

Effect of drift

range of variation from conditions at calibration


26 of 44

QGU-010-2013 Uncertainty calculation for Gaseous Measurement EN 14792 Nox

v4

Limit value 0 mg.m -3 (corrected) NO2 Gas NO Correction for reference conditions

Full Scale 500 ppm O2, % Moisture, % Pressure, KPa Temperature, K

Measured concentration 368.88 ppm Cal gas conc 462 ppm ref 17.00 0.00 101.30 273.00

Measured concentration 757.31 mg.m -3 (273K, 101.3kPa) NO2 Conversion 2.053 measured 4.55 0.00 101.30 273.00

Ratio NO/NO2 100.00 Full Scale 1026.5 mg.m -3 (NO2) Factors 0.24 1.00 1.00 1.00

Cal gas conc 948.486 mg.m -3 (NO2) Correction Factor 0.24

Performance characteristics Value specification Effect of drift

Response time 30 seconds 180.000 1.51 mg/m3 0.136280303

Number of readings in measurement 30 0.20 % value

Repeatability at zero 0.03 % full scale 0.200

Repeatability at span level 0.06 % full scale 2.000

Deviation from linearity 0.2 % of value 2.000 ranges

Zero drift 0.28 % full scale 2.000 min max value at calib

Span drift -0.18 % full scale 2.000 flow 95 105 100

volume or pressure f low dependence 0 % of full scale/kPa 0.033 pressure 101.30 101.3 101.3

atmospheric pressure dependence 0 % of value/kPa 0.750 temp 289 289 283

ambient temperature dependence 0.3 % full scale/10K 0.300 NH3 range 0 0 0

NH3 (20 mg/m3) 0 mg/m3 CO2 range 0 15 0

CO2 (15%) 0.209 % by vol H2O range 0 0 0

H2O (30%) 0.0 % by vol 4.000 Instrument Voltage Rating 110

dependence on voltage 0.1 % full scale/10V 2%fs/10V Voltage 93 121 110

converter eff iciency 95 % 95%

losses in the line (leak) 0.627705628 % of value 2% of value


Measurement performance related to stationary conditions

Performance characteristic Uncertainty


Standard deviation of repeatability at span level urs for mean 0.01 Use largest negative or positive interferent effect

Lack of f it ufit 1.19 0 0.00

Drift u0dr 0.87 0 0.12

volume or pressure f low dependence uspres 0.00 0 0.00

atmopsheric pressure dependence uapres 0.00 0 0.12

ambient temperature dependence utemp 0.18 Interference uncertainty 0.12

NH3 (20 mg/m3) uinterf 0.00

CO2 (15%) 0.12

H2O (30%) 0.00

Dependence on voltage uvolt 0.09

Converter eff iciency uceff 21.86

losses in the line (leak) uleak 2.74


Measurement uncertainty Result 757.31 mg/m3



Uncertainty corrected to std conds 10.70 mg.m-3 (corrected)

Expanded uncertainty expressed with a level of confidence of 95% 0.00 % ELV

Expanded uncertainty expressed with a level of confidence of 95% 10.70 mg.m -3 at ELV

Value of uncertainty quantity


27 of 44

QGU-007-2013 Uncertainty calculation for Gaseous Measurement Oxygen EN14789

V2.2 Jul-08

Limit value n/a %vol Calibration gas 0.209 %vol

Measured concentration 4.55 %vol Full Scale 0.25 %vol


Response time 30 seconds < 200 s

Logger sampling interval 60 seconds 0.00 % vol

Measurement period 30 minutes 0.00 % value

Number of readings in measurement 30 Assuming 1 minute collected over 1 hour

Repeatability at zero 0.015 % by volume stdev <0.2 % range

Repeatability at span level 0.014 % by volume stdev <0.4 % range

Deviation from linearity 0 % vol +/- <0.3 % volume

Zero drift (during measurement period) 0.0028 % vol at zero level +/- <2% of volume / 24hr

Span drift (during measurement period) -0.0008 % vol at span level +/- <2% volume/24hr min max value at calib

volume or pressure f low dependence 0 % of fs / 10l/h +- 5 l/h <1% range flow 5 15 10 l/h

atmospheric pressure dependence 0.3 % of fs/kPa +- 2kPa < 1.5 % range pressure 99.00 101 100 kPa

ambient temperature dependence -0.07 % by volume /10K +- 15K <0.3% volume 10 K temp 280 285 285 K

CO2 (% vol) 15 0.07 % by volume per 15 CO2 range 8 15 0 % vol

NO (mg/m3) 300 0.02 % by volume per 300 NO range 100 150 0 mg/m3

NO2 (mg/m3) 30 0 % by volume per 30 NO2 range 5 7.5 0 mg/m3

Combined interference 0.56 % range <2% range Voltage 105 115 110 V

Dependence on voltage 0.1 % by volume /10V +- 5% < 0.1%vol /10 volt

Losses in the line (leak) 0.574162679 % of value < 2% of value


Performance characteristic Uncertainty Value of uncertainty quantity % vol

Standard deviation of repeatability at zero ur0 for mean Only use rep at span



Drift u0dr 0.00


atmospheric pressure dependence uapres 0.04

ambient temperature dependence utemp -0.02

CO2 0.05 Use largest of sum of all positive or all negative influences

NO 0.01 0.06 all +ves Criteria

NO2 0.00 0 all -ves sum <2% value

Combined interference (from mcerts) 0.08 0.06 largest 0.22

dependence on voltage uvolt 0.03 Value to use for intereference uncertainty

losses in the line (leak) uleak 0.13 uint 0.06


Measurement uncertainty 4.55 %vol

Combined uncertainty 0.17 %vol

% of value 3.80 %

Coverage factor k = 2

Expanded uncertainty expressed with a level of confidence of 95% 7.59 % of value

Expanded uncertainty expressed with a level of confidence of 95% 0.35 % vol

Effect of drift

range of variation from conditions at calibration


28 of 44

Title: Determination of Moisture Content

Method EN 14790

Stack Name TO

Test Time 10:05:00

Leak Check Results

Prior to test: 0

Post Test: 0

Sample Volume Flow Rate: 2

Standard Requirement: <2%

Test Result: 0

Test Status Pass

Calibration Details

Pump Number ASLLK17EQ525

Calibrator Number ASLLK15EQ506

Calibration Rate Before 2.2 N Litres per Minute

Calibration Rate After 2.2 N Litres per Minute

Air Volume at Pump 2.2 N Litres per Minute

Temperature at Pump 12 Deg C

Pressure at Pump 101.3 kPa

Sample Time 30 Minutes

Volume from Mass Flow Meter 0.066 Nm3

Impinger Weights Initial Final Difference

Total Impinger Weight 572.1 606.3 34.2

Volume of Air Sampled 0.066 Nm3 34.2

Moisture Content (EN 14790) 39.20 %

Uncertainty 1.97 %


29 of 44

QGU-009-2013 Uncertainty calculation for EN 14791

v2


Limit value (ELV) mg.m -3








Leak L 2 % 2.00 <=2%




ρm 0.009 0.009

Hm 0.010 0.010

T m 0.003 0.007

ufs 0.015 1.57


Factor for O2 correction fc #REF!


O2,m #REF! #REF!

Factor for O2 Correction ufc #REF! #REF! #REF!



Leak L 0.45 mg.m-3 1.00 0.45 mg.m-3 1.15 %




Expanded uncertainty in units of measurement 1.97 %


30 of 44

Parameter Value

FT 277.52

Ambient Temp 9

A2 (Fuel Specific Factors) 0.66

Oxygen level in air 20.9

Measured oxygen 4.6

Formula = qA = (FT-AT) x (A2 / 21- O2) + B

FT - AT 268.52

A2 / 20.9- O2 0.0404908

plus B fuel specific factors 0.009

Calculation of efficiency qA 10.88

% 89.12

Formula = qA = fx FT-AT/Co2


31 of 44

Title: Determination of Total Organic Compounds

Method: EN 12619

Client: Waterford Proteins

Stack Reference: TO

Licence Limits

Emission Limit Value - mg.m-3

Flow Rate Limit - m3.Hr-1

Results

TOC Concentration 1.0 mg.m-3

Flow Rate 0 m3.Hr-1

Uncertainty of Measurement 0.45 mg.m-3

Reference Conditions

Temperature (K) 273.13 0K

Pressure (kPa) 101.3 kPa

Gas (Wet or Dry) 0

Oxygen 17 %

Stack Concentrations

Oxygen 4.6 %

Moisture 39.2 %

CO2 7.1 %

Quality Data Units

Sampling Time 10:34 -

Instrument Range 99.9 ppm

Span Gas Value 76 ppm

Acceptable Gas Range Yes 50 - 90% of Range

Oven Temperature 185.2 0C

Average Temperature 185.2 0C

Temperature Acceptable Yes Yes or No

Sample line temperature 181 C

Zero Drift Units

Zero Down Sampling Line (Pre) 0 ppm

Zero Down Sampling Line (Post) 0.3 ppm

Zero drift 0.3 ppm

Allowable Zero Drift (2%) 1.52 ppm

Zero Drift Acceptable (<2%) Yes Yes or No

Adjust for Zero Drift Limit (2 - 5%) No Yes or No

Reject results if > 5% 3.8 ppm

Span Drift Units

Span (Pre) 76 ppm

Span (Post) 75.6 ppm

Span Drift -0.4 ppm

Allowable Span Drift 1.52 ppm

Span Drift Acceptable (<2%) Yes Yes or No

Adjust for Zero Drift Limit (2 - 5%) No Yes or No

Reject results if > 5% 3.8 ppm

Leak Check

Span Gas Conc. 76 ppm

Recorded Conc. down Line 75.8 ppm

Leak Result -0.2 ppm

Leak check acceptable (< 2%) 1.52 (Y/N)

Response Time (<200 seconds) Yes Yes or No

Parameter

Standard EN 12619

Technical Procedure 2009

Probe material Stainless Steel

Filtration Type Ceramic Filter

Heated Head Filter Used Yes

Heated Line Temperature 181 Deg C

Span Gas Reference Number ASLLK19ING546

Span Gas Expiry Date Jul-22


32 of 44

Span Gas Start Pressure (bar) 46 bar

Gas Cylinder Concentration (ppm) 76 ppm

Span Gas Uncertainty (%) 0.9 %

Zero Gas Type Nitrogen

Number of Sampling Lines Used 1

Number of Sampling Points Used 1

Sample Point I.D's 1

Measured Quantities

Certified Range of Analyser 10000 ppm

Operational Range of Analyser 99.9 ppm

Measured Reading 1 ppm

Non linearity 0.4995 ppm

Temperature Dependent Zero drift 0.15 ppm Per Degree

Temperature Dependent Span drift 0.0999 % Per Degree

Cross-sensitivity 0.1 ppm

Leak -0.2 ppm

Calibration Gas uncertainty 0.9 ppm


33 of 44

Title: Determination of Total Organic Compounds

Method: EN 12619


Stack Reference: TO

Run 1 Time ppm mg.m-3

1 10:34:17 3.4 5.5

2 10:35:17 3.6 5.8

3 10:36:17 1.6 2.6

4 10:37:17 2.8 4.5

5 10:38:17 1.2 1.9

6 10:39:17 2.4 3.9

7 10:40:17 1.6 2.6

8 10:41:17 1.6 2.6

9 10:42:17 8.2 13.2

10 10:43:17 2.6 4.2

11 10:44:17 1.8 2.9

12 10:45:17 1.2 1.9

13 10:46:17 2.0 3.2

14 10:47:17 0.4 0.6

15 10:48:17 1.4 2.3

16 10:49:17 0.8 1.3

17 10:50:17 2.0 3.2

18 10:51:17 1.0 1.6

19 10:52:17 0.8 1.3

20 10:53:17 1.6 2.6

21 10:54:17 0.6 1.0

22 10:55:17 1.4 2.3

23 10:56:17 0.0 0.0

24 10:57:17 0.8 1.3

25 10:58:17 0.0 0.0

26 10:59:17 0.2 0.3

27 11:00:17 0.8 1.3

28 11:01:17 1.2 1.9

29 11:02:17 0.8 1.3

30 11:03:17 0.4 0.6

Average 1.6 2.6

Adjusted for O2 and Moisture 1.0

0.02.04.06.08.0

10.012.014.0

TOC

ppm

mg.m-3


34 of 44

Uncertainty calculation for Gaseous Measurement TOC

Stack Reference: TO

Limit value 0 mg/m 3 (corrected) Cal gas conc 122.36 mg.m -3 (Propane)

Measured concentration 1.606666667 ppm

Measured concentration 3 mg/m3 (101.3kPa, 273K)

Measured concentration 3 mg/m 3 (Corrected)


Response time 90 seconds 180.000

Logger sampling interval 60 seconds

Measurement period 30 minutes

Number of readings in measurement 30

Repeatability at zero 0.25 % full scale <1 % range

Repeatability at span level 0.15 % full scale <2 % range

Deviation from linearity(lack of f it) 0.65 % of value <2 % range

Zero drift 0.2 mg/m3 <2% range / 24hr

Span drift 1 mg/m3 <2% range/24hr

Volume or pressure f low dependence 0 %of full scale/kPa <2 % / kPa

Atmospheric pressure dependence 0 %of value /kPa <3% / kPa

Ambient temperature dependence 0 % full scale/10K <3% range / 10 K

Losses in the line (leak) 0 % of value < 0.1%vol /10 volt

Uncertainty of calibration gas 2 % of value < 2% of value

Performance characteristic Uncertainty Value of uncertainty quantity mg/m3




Drift u0dr 0.22


atmopsheric pressure dependence uapres 0.00

ambient temperature dependence utemp 0.00

losses in the line (leak) uleak 0.00


Measurement uncertainty



Expanded uncertainty expressed with a level of confidence of 95% #DIV/0! % ELV

Expanded uncertainty expressed with a level of confidence of 95% 0.45 mg.m -3

Expanded uncertainty expressed with a level of confidence of 95% 17.27 % value

Requirement in standard is for uncertainty to be < 10% at ELV at standard conditions


35 of 44

2.2 Stack Emission Point Reference:

2.2.1 Suitability of Sample Location:

General Information Amine Bed

Permanent/Temporary Permanent

Inside/ Outside Outside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259

Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring

instruments N/a -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) N/a

-

Platform has vertical base boards (approx. 0.25 m high) N/a

-

Platform has chains / self-closing gates at top of ladders N/a

-

There are no obstructions present which hamper insertion of

sampling equipment Yes -

Safe Access Available Yes

-

Easy Access Available Yes

-

Sampling Location / Platform Improvement Recommendations

None

EN 15259 Homogeneity Test Requirements

1.

Select Option:

1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack

2: Test results were obtained from previous Homogeneity test carried out by ASL

3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor

4: Homogeneity Test is required on this stack and the client has been informed of this requirement


36 of 44

2.2.2 Stack Diagram

Figure 2: Amine Bed


37 of 44

2.2.3 Stack Raw Data


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Title: Determination of Speciated Organic Compounds

Method: EN 13649


Test Date: 28/11/2019

Test Time: 12:13

Laboratory Used: RPS

Stack Reference: Inlet

Leak Check Results Amines

Prior to test: 0 l/min

Post Test: 0 l/min

Sample Volume Flow Rate: 0.48 l/min

Standard Requirement: <5 %

Test Result: 0 %

Test Status Pass

Calibration Details Amines

Pump Number: ASLLK12EQ500

Calibration Unit: ASLLK15EQ506

Calibration Unit Uncertainty: <2 %

Calibration Rate Before Test: 0.48 Nl/min

Calibration Rate After Test: 0.48 Nl/min

Maximum allowed flow 0.5 Nl/min

Average sample Volume: 0.48 Nl/min

Sample Test Time: 30 minutes

Pump Gas Temperature: 9 OC

Pump Sample Pressure: 101.3 kPa

Normalised Gas Volume: 0.01440 Nm3

Tube Details Amines

Tube Type: 226-10

Tube Identification Number: 8388201235

Blank Identification Number: 8388201238

Main Adsorbent Layer 400 mg

Backup Adsorbent Layer 200 mg

Containment Material Glass

Breakthrough Occurred No

Tubes in Lab in <7 days Yes

Tubes >7 days were stored <4 Deg C

Tubes >7 days were stored Dark -

Transport Container Airtight Yes

Exposed to Sunlight No

Transport Temp <20 Deg C Yes

Field Blank <10% Analyte Value Yes

Field Blank <10% ELV Yes

Test Details

Adsorption Tube Temperature: 9 OC


39 of 44

Amines

Class I ug/tube mg.Nm-3

Diethylamine 1 0.07

Dimethylamine 1 0.07

Ethanolamine 1 0.07

Methyamine 1 0.07

Triethylamine 1 0.07

Concentration Uncertainty

mg.Nm-3 mg.Nm-3

Total Class I 0.35 0.01


40 of 44


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Title: Determination of Speciated Organic Compounds Method: EN 13649 Client: Waterford Proteins

Test Date: 28/11/2019 Test Time: 13:05 Laboratory Used: RPS Stack Reference: Outlet

Leak Check Results Amines Prior to test: 0 l/min Post Test: 0 l/min

Sample Volume Flow Rate: 0.47 l/min Standard Requirement: <5 % Test Result: 0 %

Test Status Pass

Calibration Details Amines Pump Number: ASLLK17EQ525 Calibration Unit: ASLLK15EQ506

Calibration Unit Uncertainty: <2 % Calibration Rate Before Test: 0.47 Nl/min Calibration Rate After Test: 0.47 Nl/min Maximum allowed flow 0.5 Nl/min

Average sample Volume: 0.47 Nl/min Sample Test Time: 30 minutes Pump Gas Temperature: 9 OC Pump Sample Pressure: 101.3 kPa

Normalised Gas Volume: 0.01410 Nm3

Tube Details Amines Tube Type: 226-10

Tube Identification Number: 8388201234 Blank Identification Number: 8388201238 Main Adsorbent Layer 400 mg Backup Adsorbent Layer 200 mg

Containment Material Glass Breakthrough Occurred No Tubes in Lab in <7 days Yes Tubes >7 days were stored <4 Deg C

Tubes >7 days were stored Dark - Transport Container Airtight Yes Exposed to Sunlight No Transport Temp <20 Deg C Dark

Field Blank <10% Analyte Value Yes Field Blank <10% ELV Yes

Test Details

Adsorption Tube Temperature: 9 OC


42 of 44

Amines

Class I ug/tube mg.Nm-3

Diethylamine 1 0.07

Dimethylamine 1 0.07

Ethanolamine 1 0.07

Methyamine 1 0.07

Triethylamine 1 0.07

Concentration Uncertainty

mg.Nm-3 mg.Nm-3 Total Class I 0.35 0.01


43 of 44

Uncertainty calculation Outlet TA Luft Class 1


Limit value (ELV) 0 mg.m-3

Reference oxygen % by volume

Measured concentration 0.35 mg.m-3

(at reference conditions)


Sampled Volume Gas Vm 0.0141 uVm 0.0001 m3

0.71 <=2%

Sampled gas Temperature Tm 282 uTm 2 k 2.00 <2.5 k



Oxygen content O2,m uO2,m 0.1 % by volume #DIV/0! <=5%


Leak L 0.5 % 0.50 <=2%




ρm 0.010 0.010

Hm 0.010 0.010

Tm 0.003 0.007

ufs 0.015 1.57

Corrected volume V 0.01 uV 0.000 m3

1.74



O2,m 0.05 0.005



Corrected Volume (standard conditions) V 0.01 m3

25.98 0.01 mg.m-3

1.74 %

Factor for O2 Correction fc 1.00 0.35 0.00 mg.m-3

0.48 %

Leak L 0.00 mg.m-3

1.00 0.00 mg.m-3

0.29 %




Expanded uncertainty in units of measurement 0.0129 mg.m-3

sm fVV =

m

ref

cO

Of

,2

,2

21

21

−

−=

cfV

mc =

3.101

273

100

)100( m

m

m

sT

Hf

−=


44 of 44

Appendix III: Certificates and Process Detail Form

Attach Process Details.

Test Certificate Date 02/01/2020

AIR SCIENTIFIC (LK)**NEW**

Unit 5 Caherdavin Business Centre

Caherdavin

Ennis Road

Limerick

V94 NT63

Client Order No. WAPRTL111281119

WK19-13565Certificate No.

Issue No. 1

Contact 03/12/2019Date ReceivedMichael Flood

Description 2x filters and 2x washes for TPM Technique Gravimetric Stack

Sample No. 1097228 7. TO Filter Method

D9 (MCERTS)(U)1.51 mgTotal particulate matter

Sample No. 1097229 8. TO Wash Method

D9(MCERTS)(U)1.13 mgTotal particulate matter

Sample No. 1097230 9. Blank Filter Method

D9 (MCERTS)(U)0.19 mgTotal particulate matter

Sample No. 1097231 10. Blank Wash Method

D9(MCERTS)(U)<0.50 mgTotal particulate matter

RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen

Road. Salford. M5 3EZ

Page 1 of 2

Date 02/01/2020Test Certificate


1Issue No.

Client AIR SCIENTIFIC (LK)**NEW**

Approved By Date

Tony DruryTested By 24/12/2019Date

Joanne Dewhurst

Operational

For and on authority of RPS Laboratories Ltd.

Method Symbols (U) Analysis is UKAS Accredited

(N) Analysis is not UKAS Accredited

Concentration values (mg/m3 and ppm) are not covered by the scope of UKAS accreditation.

Results stated as ml are refering to the sample volume.

Analysis carried out on samples 'as received'

This document may not be reproduced other than in full, except with the written approval of the issuing laboratory.

RPS Laboratories terms and conditions apply - a copy is available on request.

02/01/2020



Page 2 of 2




Caherdavin

Ennis Road

Limerick

V94 NT63



Issue No. 1


Description 3x solutions for Ammonia Technique IC Stack

Sample No. 1097225 3. TO Ammonia IMP 1&2 Method

A6 (MCERTS)(U)<0.1 µg/ml 105 mlAmmonia

Sample No. 1097226 4. TO Ammonia IMP 3 Method


Sample No. 1097227 6. Blank Ammonia Method




Page 1 of 2



1Issue No.


Approved By Date

Lora McKerracherTested By 20/12/2019Date

Joanne Dewhurst

Operational









20/12/2019



Page 2 of 2




Caherdavin

Ennis Road

Limerick

V94 NT63



Issue No. 1


Description 3x solutions for Sulphate Technique IC Stack

Sample No. 1097222 1. TO SO2 IMP 1&2 Method

C27(U)59.8 µg/ml 95 mlSulphate

Sample No. 1097223 2. TO SO2 IMP3 Method


Sample No. 1097224 5. Blank SO2 Method




Page 1 of 2



1Issue No.


Approved By Date

Siddeka ChowdhuryTested By 13/12/2019Date

Joanne Dewhurst

Operational









Lora McKerracher 13/12/2019

16/12/2019



Page 2 of 2




Caherdavin

Ennis Road

Limerick

V94 NT63



Issue No. 1


Description 3x tubes for Amines Technique IC

Sample No. 1097232 11. Amines Inlet Method

Diethylamine

<1 µg

Dimethylamine

<1 µg

Ethanolamine

<1 µg

Methylamine

<1 µg

Trimethylamine

<1 µg

A1(U)Amine Suite

Sample No. 1097233 12. Amines Outlet Method

Diethylamine

<1 µg

Dimethylamine

<1 µg

Ethanolamine

<1 µg

Methylamine

<1 µg

Trimethylamine

<1 µg

A1(U)Amine Suite



Page 1 of 2



1Issue No.


Sample No. 1097234 13. Amines Blank Method

Diethylamine

<1 µg

Dimethylamine

<1 µg

Ethanolamine

<1 µg

Methylamine

<1 µg

Trimethylamine

<1 µg

A1(U)Amine Suite

Approved By Date

Siddeka ChowdhuryTested By 10/12/2019Date

Joanne Dewhurst

Operational









Tammy Illingworth 20/12/2019

20/12/2019



Page 2 of 2

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