Refining Petrochemicals Integration

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    Raza Jawad

    Regional Director, Business DevelopmentUOP Middle East Company, Dubai

    Refining & Petrochemicals

    IntegrationBusiness Drivers & Enabling Technologies

    2006 UOP LLC. All rights reserved.UOP 4698-01

    SAS-AIChE MeetingFebruary 27, 2007Al-Khobar, KSA

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    Refining & Petrochemicals IntegrationBusiness Drivers & Enabling Technologies

    Refining & petrochemicals markets

    Investment strategies

    Enabling technologies

    Concluding remarks

    UOP 4698-02

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    70%

    75%

    80%

    85%

    90%

    1980

    1985

    1990

    1995

    2000

    2005

    Average

    GlobalUtilisation,%

    Source: BP Statistical Review 2006

    Refining Situation

    Refining investments potentially attractive

    Refining utilisation significantly higher in 2004 - 06Margins currently above re-investment threshold

    0

    2

    4

    6

    8

    1990

    1994

    1998

    2002

    2006

    AverageCr

    ackingMargin,$/bbl

    Sources: BP Statistical Review 2006IEA 2005 / 6

    Investment

    threshold

    UOP 4698-03

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    Refining Investment Imperative

    ~ 1.5 Mb / d incrementalrefined fuels annually

    - ~ 45% in M. East + China

    - Clean transport fuel growth

    Refining investmentsessential

    - Capacity

    - Conversion

    - Upgrading

    Global Demand Growth

    0

    0.5

    1

    1.5

    2

    1996

    -200

    1

    2001

    -06

    2006

    -11

    Mb/day,a

    verage

    0

    0.5

    1

    1.5

    2

    2.5

    %p

    eryear,

    average

    Source: IEA, J uly, 2006

    $30 40billion

    per year

    Substantial investments essential UOP 4698-04

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    Investment Remuneration

    Escalating fabrication and constructioncosts affecting investment returns

    Investment Risk Remains Challenging

    10% Internal Rate

    of Return

    New 200 kb/dCracking refinery

    $4bn investment~ $6+/bbl average margin

    for 20+ years required

    UOP 4698-05

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    Risk Mitigation

    Feedstock and product flexibility

    - Opportunity feedstocks

    - Optimal upgrading & conversion

    - Maximize value addition

    - Prosper from cyclical markets

    Operational efficiency

    - Economies of scale

    - Energy- Control & optimization

    Flexibility, Efficiency, Integration

    Leading-EdgeTechnology

    UOP 4698-06

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    Advantages Of Integration

    UOP 4698-07

    Integrated refinery and petrochemical operationsminimize costs and optimize product distribution

    Optimized integration of hydrocarbon processes,

    energy, hydrogen, and water

    Feedstock flexibility to capitalize on available low

    cost crude oils and intermediates

    Supply chain optimization provides faster delivery

    of products

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    Adding Value to Crude

    $perTo

    n

    0100200300400500600700800

    Crude

    90010001200

    Fuels

    Gasoline

    J / K

    Diesel

    Fuel Oil

    Petrochemicals

    Benzene

    PropylenePP

    Styrene

    Petrochemicals Can Add Significant Value

    p-X

    UOP 4698-08

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    0

    5

    10

    15

    20

    25

    30

    2000 2001 2002 2003 2004 2005 2006 2007 2008 2009

    Demand

    Increase

    over1999

    -MMM

    T

    Other BZ BZ to CyclohexaneBZ to Phenolics BZ to Styrenics

    p-Xylene6.8%

    3.6%

    Sources: CMAI & UOP

    Aromatics Markets

    AnnualGrowth

    Strong Aromatics & Derivatives Growth UOP 4698-09

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    Refineries are main

    source of xylenes supply

    Future p-X demand

    growth expected to

    average 1.8M MTA/Yr

    3 To 4 World Scale p-X Complexes Annually

    p-Xylene Capacity & Demand(Committed Projects Only)

    0

    5

    10

    15

    20

    25

    30

    35

    40

    45

    50

    1992

    1996

    2000

    2004

    2008

    2012

    2016

    p-Xylene,

    MMTA

    Global Demand

    ProductionCapacity

    Futuresupplydeficit

    Sources: PCI & UOP

    UOP 4698-10

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    Propylene Market

    MT Propylene / MT Ethylene

    0.59

    2004 2006 2008 2010 2012 2014

    Supply fromsteam crackers

    ~18MM

    T

    A

    0.40

    0.35

    0.45

    S

    team

    Cracker

    Production

    0.54

    0.64

    Demand

    Source: CMAI 2005

    Demand

    0.62

    0.36

    Propylenedemand

    increasing

    faster thansupply fromconventional

    sources

    Growing Demand For On-Purpose PropyleneUOP 4698-11

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    BTX & Olefins: Integration Potential

    Strong growth potential

    Attractive value addition

    Assured feedstock supply

    - Potential for low cost & distressed refinery

    intermediates High value return streams to refinery, e.g.,

    hydrogen, high octane gasoline

    Potential To Raise Returns & Mitigate Risk

    + PetrochemicalsRefining

    UOP 4698-12

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    Integration Strategies

    LightOlefins

    BTX

    Detergents

    Chemicals

    Hydrogen

    Power

    Technology Provides Link

    Crude

    Oil

    Naphtha

    Reformate

    FCC Intermediates LPG Cracked Naphtha

    Light Cycle Oil

    Residues

    Kerosene

    Refinery

    UOP 4698-13

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    Crude

    Oil

    Naphtha

    Reformate

    FCC Intermediates LPG Cracked Naphtha

    Light Cycle Oil

    Residues

    Kerosene

    Refinery

    Integration Strategies

    LightOlefins

    BTX

    Detergents

    Chemicals

    Hydrogen

    Power

    Technology Provides Link UOP 4698-14

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    AGO / VGO

    Refinery Light Olefins Integration

    Gasoline

    Fuel oil

    C3=

    FCC

    PropyleneRecovery

    OlefinCracking

    UOP 4698-15

    Olefin Cracking: Developed by Total Petrochemicals & UOPDoubles Propylene Production & Reduces C4/C5 Olefins

    LPG

    AGO / VGO

    Fuel oil

    Gasoline

    C3=

    Lt. OlefinRecovery

    FCC

    C2=Lt. Olefin

    Recovery

    FCC

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    Olefin Cracking EnhancesGas To Olefins

    Ethylene &Propylene

    Gas UOP / HydroMTO Process

    MethanolSynthesis

    OlefinCracking

    20% increase in light olefin yields

    Nearly 80% reduction in C4+ by-products

    2:1 propylene/ethylene productionratio

    UOP 4698-16

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    PetroFCCTM Process: BTX + Olefins

    Naphtha

    DistillateFuel OilCoke

    53.5

    14

    75

    28

    9.5

    5.55

    C4s

    11

    1914C4

    =

    Traditional FCC PetroFCC Process Light Olefins

    C3s6.5

    24

    22C3=

    C2-

    9

    6C2

    =

    3

    18

    Aromatics

    BTX

    The

    Petrochemicals Refinery

    Enabler UOP 4698-17

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    Tatorayprocess

    Aromatics Processing

    p-Xylene

    XyleneFractionation

    Parexprocess

    Benzene

    CCRPlatforming

    process

    Naphtha

    Conversion

    Ring Adjustment

    Separation

    UOP 4585C-11

    Proven performance track record

    State of the art technology continuous innovation

    Cost effective designs; high on-stream efficiency

    90% ofp-X capacity since 1970 uses Parex process

    BTFractionation

    Sulfolane

    process

    Isomarprocess

    UOP 4698-18

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    BTX Innovation: LCO-XTM Process

    FCC light cycle oil (LCO)

    - Distillate range intermediate product

    - High sulfur, high density, highly aromatic

    - Difficult to blend to clean transport fuel

    High content of multi-ring aromatics

    - Unlock benzene and xylenes

    Low value asfuel blendstock

    Low cost,high

    value BTXfeedstock

    $0.75/Bbl crude increase in operating margin

    LCO-X process for converting LCO to BTX recentlyannounced

    UOP 4698-19

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    Refining

    Gasification

    Syn Gas Production

    HydrogenCarbon monoxideFertilizerSNGOlefinsMethanol/Ethanol

    Acetic acid

    NaphthaDieselJet fuelWax

    Electricity

    Separation

    O2, N2, CO2, S, sulfuric acid

    TransportationFuels

    Resid

    Natural Gas Reforming

    Electricity

    Hydrogen

    A Future Scenario

    Chemicals

    GasConversion

    Power

    CrudeOil

    Resid

    Technology Developments Key To Deeper IntegrationUOP 4698-20

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    Innovation, Research, Development

    Broaden the knowledgebase

    Leverage academic andindustrial experts

    Keys to success: Collaboration / alliances

    Commercialize

    Technology ImperativeA Key Enabler

    UOP Awarded National Medal of Technology in 2005

    over 85 years of sustained technical leadership and innovationfor the worldwide petroleum refining and petrochemical

    industriesbenefited quality of life throughout the world.

    Universities

    GovernmentLabs

    Startups

    TechnologyLeaders

    Customers

    Suppliers

    uop

    A Honeywell Company

    UOP 4698-21

    Ref: National Medal of Technology Award to UOP, 2005

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    Summary

    Strong growth of refining and petrochemicalsmarkets, healthy margins

    - Investment in additional capacity essential

    Integrating petrochemicals with refining canmitigate investment risk

    Continuing technology innovation key enablerfor successful integration

    UOP 4698-22

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    Thank You

    UOP 4698-23