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    Refinery

    Overview

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    We will seeCrude and its characteristics

    Typical Refinery Configuration

    Major refinery Process1.Distillation (CDU/VDU)

    2.Alkylation3.Merox4.FCC ( For gas oils)5.Catalytic Cracking (Naphtha)

    6.Hydro treating and Cracking7.Delayed Coking8.Sulphur Block unit (Sulphur, Sour water stripper, Amineregeneration units)

    Questions ???

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    3

    ELEMENTAL COMPOSITION(%)RANGESELEMENTAL COMPOSITION(%)RANGES

    FOR CRUDEFOR CRUDE

    Carbon 83.9-86.8Carbon 83.9-86.8

    Hydrogen 11.0-14.0Hydrogen 11.0-14.0

    Sulphur 0.06-8.0Sulphur 0.06-8.0Nitrogen 0.02-1.7Nitrogen 0.02-1.7

    Oxygen 0.08-1.8Oxygen 0.08-1.8

    Metals 00-0.14Metals 00-0.14 Mainly vanadium and Nickel (Iron,Mainly vanadium and Nickel (Iron,magnesium ,Aluminum , Copper, Silver inmagnesium ,Aluminum , Copper, Silver in

    traces)traces)

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    PRINCIPAL TYPES OFPRINCIPAL TYPES OFHYDROCARBON PRESENTHYDROCARBON PRESENT

    Composition of Crude oil

    Paraffins:Straight chain compounds. Lighter ones are gas,heavier molecules are liquid (oil) and solid (wax).

    Naphthenes:consist of carbon rings, with or without sidechains; saturated with hydrogen; Naphthenes are chemicallystable. Lighter Naphthenes are liquids but heavier ones couldbe solid.

    Aromatics:compounds having a ring of 6 carbon atoms-Bzstructure they are relatively unstable.

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    Paraffins

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    Naphthenes

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    Aromatics

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    Classification of Crude oil Gravity as basis

    API Gravity = 141.5 - 131.5

    Sp. Gravity API Gravity is higher for lighter crude and lower for heavier crude.

    Lighter Crude API>350

    e.g, Mumbai High crude 400API

    Medium Crude API between 250&340

    e,g, Arabian crude: 340API

    Heavy Crude API

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    DIFFERENCE BETWEEN

    PARAFFINC & NAPTHENIC BASE

    9

    Paraffinic NapthenicSP.gravity of crude Low High

    Yield of gasoline High Low

    Octane no.(St. run) Low HighSulphur content Low High

    Smoke pt. Kerosene High Low

    Cetane value HSD High LowPour point of HSD High Low

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    Processing Schemes vs. type ofCrude oil

    Refinery processing scheme and product

    yields depend on type of crude in terms ofchemicals natureand gravity. Typically:

    Paraffinic crudesare good for straight run fuel

    production e.g diesel.

    Light crudeyields more gasoline.

    Medium crudegood for diesel production.

    Heavy crudesgive better bitumen

    Naphthenic crudegood for Lubricating oil.10

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    Flow scheme of a modern refinery

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    Reactions Resulting in CorrosionReactions Resulting in Corrosion

    MgClMgCl22+ H+ H22O Mg(OH)O Mg(OH)22 +2HCL+2HCL

    MgClMgCl22+ H+ H22S MgS +2HClS MgS +2HCl

    Fe + 2HCl FeClFe + 2HCl FeCl22 +H+H22

    FeClFeCl22 + H + H22S FeS + 2HClS FeS + 2HCl

    Fe + HFe + H22S FeS + HS FeS + H22

    HCl attacks heater tubes, trays, lining, OVHDHCl attacks heater tubes, trays, lining, OVHD

    condensercondenser Corrosion controlled by neutralizing amineCorrosion controlled by neutralizing amine

    injection and filming amines as inhibitorsinjection and filming amines as inhibitors

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    DESALTER

    CRUDE AT 120 - 140 DEG C

    PROCESS WATER

    LDT

    LDCV

    TRANSFORMER

    100-120 DEG C

    PDI

    DESALTED CRUD

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    WaterWaterCrude EmulsionCrude Emulsion

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    Distillation of Crude OilDistillation of Crude OilDistillation of Crude OilDistillation of Crude Oil

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    Atmospheric Distillation

    Column Typical 40 to 50 actual trays No. of trays from bottom

    4 to 6 bottom stripping4 to 6 flash zone/heavy gas oil

    4 to 6 heavy gas oil/light gas oil

    4 to 6 light gasoil/kerosene4 to 8 kerosene/heavy naphtha

    4 to 8 heavy naphtha/light naphtha

    2 to 3 pump arounds each Top temperature: 80 to 100 above water dew point (1200to

    1300C typical)

    Flash zone below cracking temperature: 3850

    C typical

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    Crude Distillation

    Pump around Typically at product draw tray

    return 2 to 3 trays above

    60 to 800c temperature drop Stripping steam

    Bottom: 18 to 24 kg /std m3 of RCO

    Side strippers: 12 to 18 kg /std m3 ofstripped product

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    Typical Op. Condns. of Crude Column

    Crude Type 30 deg. API 40 deg. API

    Op. Parameters

    REF. DRUM

    Pr., Kg/cm2(a) 3.0 3.1

    temp., deg. C 45 45

    COL. TOP

    Pr., Kg/cm2(a) 3.5 3.6temp., deg. C 103 114

    FL. ZONE Pr., Kg/cm2(a) 3.9 4.0

    temp., deg. C 384 362O/F % 4 to 6 4 to 6

    COT temp., deg. C 387 364.5

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    Vacuum DistillationVacuum DistillationVacuum DistillationVacuum Distillation DRY DAMP WET

    Top pressure mmHg a 8 25 75

    Flash zone pressure mmHg a 24 42 95

    Heater outlet temp.0C 395 405 420

    Column dia Highest Int Least

    Steam Nil Int Highest

    Economics normally in favor of damp vacuum

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    COLUMN INTERNALS

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    Crude Distillation Column

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    Vacuum Distillation Column

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    Alkylation Alkylation combines low-molecular-weight olefins (primarily a mixture of

    propylene and butylene) with isobutene in the presence of a catalyst, eithersulfuric acid or hydrofluoric acid.

    The product is called alkylate and is composed of a mixture of high-octane,branched-chain paraffinic hydrocarbons.

    Alkylate is a premium blending stock because it has exceptional antiknock

    properties and is clean burning. The octane number of the alkylate dependsmainly upon the kind of olefins used and upon operating conditions.

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    ChemistryRSH + NaOH NaSR + H2O (1)

    4NaSR + O2+ 2 H2O 4NaOH + 2RSSR (2)

    4RSH + O2 2RSSR + 2 H2O (3)

    Reaction (1) is reverssible and favourable in forwarddirections, For

    Low molecular weight mercaptans. Low temperature.

    High Caustic concentration.

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    operating conditions

    EquipmentsEquipments TemperatureTemperature

    ( (00C)C)

    PressurePressure

    (Kg/cm(Kg/cm22g)g)

    Caustic prewashCaustic prewashcolumncolumn

    4545 19.519.5

    11stststage CFC causticstage CFC caustic

    wash contactorwash contactor4545 1818

    22ndndstage CFC causticstage CFC causticwash contactorwash contactor

    4848 17.517.5

    Oxidizer TowerOxidizer Tower 5252 3.5-5.53.5-5.5

    CFC solvent washCFC solvent wash

    contactorcontactor5252 33

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    CATALYTIC REFORMING

    CATALYTIC REFORMING IS AN IMPORTANT PROCESS INPETROLEUM REFINING AND PETROCHEMICALS INDUSTRIES.

    VALUE ADDITION TO STRAIGHT RUN NAPHTHA AND HASSIGNIFICANT INFLUENCE ON OVERALL ECONOMICS OF THEINDUSTRY

    CATALYTIC REFORMING PROCESS BASICALLY CONVERTSPARAFFINS AND NAPHTHENES TO HIGH OCTANE AROMATICCOMPONENTS AND THEREBY PRODUCES

    HIGH OCTANE MOTOR GASOLINE BLENDING STOCK RICH CONCENTRATES OF AROMATICS VIZ. BENZENE, TOLUENE

    AND XYLENES (BTX) H2 REQUIRED IN REFINERY FOR HYDROTREATING /

    HYDROCRACKING, THUS MAKING MORE ECONOMIC VIABLEPROCESS LPG AN ANOTHER VALUE ADDED PRODUCT.

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    SCHEMATIC OF THE CCR PLATFORMING PROCESS

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    DEHYDROCYCLISATION OF PARAFFINS

    CH3 CH2 CH2 CH3 CH2 CH2 CH2 CH3

    CH2 CH2 CH2CH2 CH2 CH2

    H2C

    H2C

    H2C CH2

    CH2

    CH2

    3H2 +

    TOLUENEMETHYL CYCLEOHEXANE

    (O.N. = 120)

    C7H16(O.N. = 0)C7H14

    CYCLI-

    SATION

    DEHYDRO-

    GENATION

    3

    2

    1

    + H2

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    Fluid Catalytic Cracking Oil is cracked in the presence of a finely divided catalyst, which is maintained in an

    aerated or fluidized state by the oil vapours.

    The fluid cracker consists of a catalyst section and a fractionating section that operatetogether as an integrated processing unit.

    The catalyst section contains the reactor and regenerator, which, with the standpipe andriser, form the catalyst circulation unit. The fluid catalyst is continuously circulatedbetween the reactor and the regenerator using air, oil vapors, and steam as theconveying media.

    Preheated feed is mixed with hot, regenerated catalyst in the riser and combined with a

    recycle stream, vapourized, and raised to reactor temperature (485-540C) by the hotcatalyst.

    As the mixture travels up the riser, the charge is cracked at 0.7-2 bar.

    In modern FCC units, all cracking takes place in the riser and the "reactor" merelyserves as a holding vessel for the cyclones. Cracked product is then charged to afractionating column where it is separated into fractions, and some of the heavy oil is

    recycled to the riser.

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    The basic process of catalytic crackingThe basic process of catalytic crackingThe basic process of catalytic crackingThe basic process of catalytic crackingThe basic process of catalytic crackingThe basic process of catalytic crackingThe basic process of catalytic crackingThe basic process of catalytic cracking

    Hydrocarbon feed is brought into intimate contact with hot

    catalyst The feed is vaporized and cracked and leaves behind

    coke The vapors and catalyst are separated

    The vapors flow into a separation section The coke-laden catalyst is brought into contact with air The coke burns and leaves behind hot regenerated

    catalyst The hot catalyst is brought into intimate contact with

    hydrocarbon feed and the cycle continues..

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    Fluid Catalytic Cracking

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    Process flow diagram - HCU

    VV-2VV-1

    VV-4

    VV-3

    VV-6

    VV-5

    CC-01

    VV10

    CC-05

    VGO/CGO

    M/U H2

    RB-01

    RB-02

    FF-01

    FF-02

    RECYCLE H2

    RB-03

    RGCHHPS.

    CLPS off gas

    To H2 UNIT

    HY. [email protected]/H

    SKO

    71.131T/H

    HSD

    48.894T/H

    LPG

    3.874T/H

    LT. NAPH.

    @14.57T/H

    KA002A

    154

    M3/Hr

    3600C/170 Kg/Cm2

    3870C/170Kg/cm2R.H2

    2nd STAGE

    141 m3/Hr

    KA003A/B/C CC-06

    FF-3

    157 kg/cm21.1kg/cm2

    GN001

    35 kg/cm2

    2200C

    PRT

    568KW

    VV13

    Gas 1.482 T/H

    CHPS

    HHPS

    HLPS

    CLPS

    380

    4130C

    4100C

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    Desulfurization

    R

    R CH SH + H2 R CH2 R + H2S

    Denitrification

    RCH2CH2CH2NH2+ H2 RCH2CH2CH3+ NH3

    In the reactors, sulfur and nitrogen are removed from the

    feedstock. In general, the carbon skeleton of the feed molecule isnot altered by heteroatom removal; however, the boiling point ofthe molecule decreases by 27-54 C for sulfur compounds and upto 104C for nitrogen compounds.

    Olefin saturation

    RCH2CH=CH2+ H2 RCH2CH2CH3

    Hydrocracking

    RCH2CH2CH2CH3 + H2 RCH3 + CH3CH2CH3

    Process Chemistry

    H d d t lli ti (HDM)

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    Fig. 5 Reaction mechanism for

    Hydrodemetallization (HDM)

    H d d lf i ti (HDS)

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    Fig. 6 Postulated mechanism for Hydrodesulfurization

    Hydrodesulfurization (HDS)

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    Fig. 7 Typical Desulfurization reactions

    Hydrodenitrification (HDN)

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    Hydrodenitrification (HDN)

    Fig. 8 Postulated mechanism for Hydrodenitrification

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    T i l H t t

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    Types of sulphur compounds

    Mercaptans R-SH

    Aliphatic Sulfide R-S-R

    Disulphide R-S-S-R

    Thiophenes

    Benzo-thiophene

    Typical Heteroatoms

    S

    C C

    CC

    S

    C

    C

    S

    C

    C

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    Nitrogen compounds

    PyrroleHN

    Indoles

    NH

    Carbazoles

    NH

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    Pyridine, quinolines

    & acridines

    Oxygen compounds Furan,

    Carboxylic acids & phenols

    Aromatics Benzene,

    Tetralin & biphenyl

    Naphthalenes and

    anthracenes

    N NN

    OH

    H2 Consumption & Heat Release

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    Reaction Hydrogen Consumption BTU/SCF

    Desulphurization 3 mol H2per mol of Sulfur 60

    Denitrification 5 mol H2per mol of Nitrogen 65-75

    Olefin Saturation 1 mol H2per mol of C=C 130-160Aromatic Saturation 3 mol H2per mol of ring Saturated. 70-85

    Heat Release Thumb Rule : 130 BTU/SCF for Olefin Saturation.

    60 BTU/SCF for every thing else.

    Typical Classes Of Molecule in HydroprocessingParaffins Poor Pour,Cloud, Octane ; Good Cetane

    Iso-paraffins Good Octane

    Olefins (mono) Good Octane (comes from FCC & Coker).

    Olefins (di) Foul Hydroprocessing equipment and catalyst.

    Naphthenes Poor Octane, Acceptable CetaneAromatic (mono) Good Octane (Large amount in FCC Product)

    Aromatic (di) Good Octane, Poor Cetane.

    Aromatic (poly) Foul Hydroprocessing Catalyst

    H2Consumption & Heat Release

    Order Of Reaction

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    Demetalization

    (Metals Removal From Feed) EASY

    Olefin Saturation

    (Destroy Double Bond With H2)

    Desulfurization

    (Sulfur Removal From Feed)

    S + H2H2S

    Denitrification

    (Nitrogen Removal From Feed)

    N + H2NH3

    Aromatics Saturation

    Cracking

    (Lower Boiling Point

    C12 C8 + C4 H2 HARD

    Order Of Reaction

    DCU FLOW DIAGRAM

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    VV-01

    RFO

    # 35

    # 27

    KERO-I

    -KERO-II

    183oC

    251oC

    CC-03

    CC-04

    GO

    HGO

    293oC

    341oC

    #25

    # 20

    GO CR

    HGO CR

    CC-01

    FF-01

    RB-01 RB-02

    CC-02

    445oC, 2.5 kg/cm2

    EA-06

    SOUR WATER

    OFF GAS

    425oC

    P-1.75Kg/cm2

    T-115oC

    320oC

    Cold VR

    Hot VR

    Slop

    PREHEAT

    502 oC

    BFW

    VV-02

    DCU FLOW DIAGRAM

    # 37

    # 43

    #29

    STEAM GEN

    SS

    SWITCHVALVE

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    OPERATING CONDITIONS

    HEATER OUTLET TEMPERATURE, oC 480 510

    COKE DRUM TEMPERATURE, oC 440 465

    COKE DRUM PRESSURE, Kg/cm2 1 5

    RECYCLE RATIO, VOL/VOL%OF FEED10 100

    CYCLE TIME 24 hrs

    INTRODUCTION T VISBREAKING

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    INTRODUCTION To VISBREAKING

    The atmospheric or vacuum residual oils are veryviscous and have high pour points. It is difficult topump them as fuel oil. Therefore, they must beblended with relatively high value distillates to meet

    the finished product viscosity specification.

    Visbreaking, a thermal conversion process has beenfound to be a good process which reduces the

    viscosity and pour point of processed residues. Tomeet the fuel oil specifications, a small quantity ofdiluents or cutter stock (Light Gas Oil) may berequired.

    Visbreaking also produces a small amount of lightgases and gasoline.

    VISBREAKING

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    A mild liquid phase thermal conversion process to reduceviscosity and pour point of residues (coke formation avoided) forproducing lower viscosity product suitable to use as stable fuel oil.

    Products include:

    VISBROKEN GASES (UP TO C4-)

    VISBROKEN NAPHTHA (UP TO 150oC)

    VISBROKEN FUEL OIL (150oC+)

    OPTIONS FOR REFINERS

    Production of visbroken gas oil to be used as diesel

    Production of visbroken vacuum gas oil to be used as feed stock

    for FCC operation

    Production of visbroken vacuum residues to be used as refineryfuel oil

    TYPICAL COMBINATION CRACKING UNIT

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    Feed

    Visbreaker Heater

    Recycle Heater

    Main Fractionator

    Gas

    Gasoline

    Gas Oil

    Vacuum

    Vac.Fractionator

    Residue

    Operating conditions:

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    Operating conditions:

    Visbreaking temp. - at the heating coil outletrange from 450 - 500 C, depending on thedesign of the unit and the nature of the feed

    stock.

    Pressure - may vary between 4 and 20 bars,but higher pressure is often preferred, sincethis gives greater control over residence timeby minimizing vaporization.

    Residence Time Temperature andresidence are interchangeable within certainlimits

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    AN OVERVIEW OF SRB

    ATU

    ARU SWSSRU

    SRB

    H2S RICH GAS

    NH3 RICH GAS

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    SWS

    GSU ARU

    SRU

    inciS.W.EXDCU

    S.W.ex HCU

    SOUR FUEL

    GAS Ex DCU

    SOUR

    FUEL GAS

    Ex HCU

    SWEET FUEL GAS

    (

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    1/18/2013 55

    Claus ProcessClaus Process

    H2S O2

    Catalytic ConverterCatalytic Converter

    Sulphur Condenser

    Further Treatment

    LP Steam

    Sliquid

    200 - 3500

    C(340 - 6600F)

    130 - 2000C

    (270 - 3900F)

    S Yields in the range of 80 90%

    3 H2S + 3/2 O2 3/x Sx + 3H2O

    Modified-Claus ProcessModified-Claus Process

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    1/18/2013 56

    Modified-Claus ProcessModified-Claus Process

    Reaction Furnace

    Wasteheat exchanger

    Catalytic converter

    Sulphur condenser

    Further treatment

    H2S

    HP steam

    LP steam

    S liquid

    925-12500C

    (1700-23000F)

    170-3500C

    (340-6600F)

    130-2000C

    (270-3900F)

    O2

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    CLAUS PROCESSCLAUS PROCESSCLAUS PROCESSCLAUS PROCESS THE CONVENTIONAL CLAUS PROCESS WAS

    DELOVEPED C. F. CLAUS. THE PROCESS WAS LATER

    MODIFIED BY I. E. FRABENTHE PRESENT PROCESS CONSISTS OF A THERMAL

    STAGE FOLLOWED BY TWO OR THREE CATALYTIC

    RECTOR STAGES. THE THERMAL STAGE CONSISTS OF

    REACTION FURNACE, WASTE HEAT BOILER AND

    CONDENSER. IN THIS STAGE, H2S IS OXIDISED BY

    COMBUSTION AIR TO SO2 ACCORDING TO THE

    REACTION.3H2S +3/2O2 2H2S + SO2+H2O

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    EACH CATALYTIC STAGE CONSISTS OF FEED HEATER, CATALYIST BEDEACH CATALYTIC STAGE CONSISTS OF FEED HEATER, CATALYIST BEDEACH CATALYTIC STAGE CONSISTS OF FEED HEATER, CATALYIST BEDEACH CATALYTIC STAGE CONSISTS OF FEED HEATER, CATALYIST BED

    AND SULPHUR CONDENSER. CHEMICAL THERMODYNAMICAND SULPHUR CONDENSER. CHEMICAL THERMODYNAMICAND SULPHUR CONDENSER. CHEMICAL THERMODYNAMICAND SULPHUR CONDENSER. CHEMICAL THERMODYNAMIC

    EQUILIBRIUM IS ESTABLISHED IN EACH BED ACCORDING TO THEEQUILIBRIUM IS ESTABLISHED IN EACH BED ACCORDING TO THEEQUILIBRIUM IS ESTABLISHED IN EACH BED ACCORDING TO THEEQUILIBRIUM IS ESTABLISHED IN EACH BED ACCORDING TO THE

    CLAUS REACTIONCLAUS REACTIONCLAUS REACTIONCLAUS REACTION

    2H2H2H2H2222S + SOS + SOS + SOS + SO2222 3/n Sn + 2H 3/n Sn + 2H 3/n Sn + 2H 3/n Sn + 2H2222OOOO

    FOR MAXIMUM SULPHUR RECOVERY, IT IS IMPORTANT TO MAINTAINFOR MAXIMUM SULPHUR RECOVERY, IT IS IMPORTANT TO MAINTAINFOR MAXIMUM SULPHUR RECOVERY, IT IS IMPORTANT TO MAINTAINFOR MAXIMUM SULPHUR RECOVERY, IT IS IMPORTANT TO MAINTAINHHHH2222S : SOS : SOS : SOS : SO2222 MOLE RATIO OF 2:1. DEPENDING UPON THE HMOLE RATIO OF 2:1. DEPENDING UPON THE HMOLE RATIO OF 2:1. DEPENDING UPON THE HMOLE RATIO OF 2:1. DEPENDING UPON THE H2222SSSS

    CONCENTRATION IN THE FEED.CONCENTRATION IN THE FEED.CONCENTRATION IN THE FEED.CONCENTRATION IN THE FEED.

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    REACTION FURNACEREACTION FURNACEREACTION FURNACEREACTION FURNACE

    MAIN REACTIONS

    H2S + SO2 S + H2O

    2H2S + SO2 2H20 + 3S

    2NH3+ O2 3H2O + N2

    SIDE REACTIONS

    CH4+ 2O2 CO2+ 2H2O

    CO2+ H2S COS + H2OCOS + H2S CS2 + H2O

    2H2S + HEAT 2H2 + S2

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    SOUR WATER STRIPPER

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    S

    T

    R

    I

    P

    P

    E

    R

    I

    S

    T

    R

    I

    P

    P

    E

    R

    II

    S.W.

    TANK

    S / D

    CBD

    WPC

    1001

    WLC

    1004

    SDV

    1007

    SDV

    1004

    WPC1101

    WPC

    1102

    WTC

    1107 WFC

    1105

    WFF

    C

    1102

    WTC

    1103

    WLC

    1106

    WPC1201

    WTC

    1205WFC

    1202

    WFFC

    1201

    WLC

    1201

    S.W.ex DCU SW

    S.W. ex HCU SW

    S.W, ex GSU

    F M

    COOLER

    EE-

    001

    N2

    EE

    03A/B

    WFC

    1101

    EE

    002PA

    001

    STD.W.

    COOLER

    EA-02

    EA-01

    EE-04

    EE-05

    SL

    SM

    WLC

    1102

    WF

    C

    1002

    PA

    003

    PA

    02

    PA-04

    WFC1203

    TO

    EE01

    PA

    005

    FLAR

    E

    INCI

    .

    FLARE

    SRU-VV02

    SRU-VV02

    TO DCU/ETP

    H2S RICH GAS

    C

    W

    SOUR WATER STRIPPER

    SOUR WATERSOUR WATERSOUR WATERSOUR WATER

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    NITRGEN AND SULPHUR COMPOUNDSIN CRUDE OILS

    H2S + NH3

    NH3

    WATER CONTAININGNH3WITH SMALL AMOUNTS OF H2S

    SOUR WATERCOMPOSITION NH3 100 5000ppmw H2S 100 10000ppmw

    CH, PHENOL, HCS, CO2, COOH, S-, M+

    ADVERSELY AFFECTS BOILOGICAL LIFE.TREATED BEFORE DISCHARGING

    REFINING PROCESSES

    AMINE TREATING (-H2S)

    WATER WASH

    How much do we use?

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    63

    How much do we use?

    Imagine a lake 10 miles long, 9 miles wideand 60 feet deep. Fill that lake with oil. Thatwould be about as much oil as the entireworld uses in one year. The United Stateswould use about 1/4 of it.

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    1/18/2013 64

    THANK YOUTHANK YOU

    IOCL MATHURA REFINERY

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    C

    D

    U

    V

    D

    U

    VBU

    BBU

    FCCU

    OHCUDHDT

    DHDS

    N

    S

    L

    H2 Plant

    CRUMSQP

    LPG

    NAP

    HVY

    NAPH

    ATF

    KERO

    AGO

    NAPH

    DIESEL

    NAPH

    DIESEL

    LIQ

    FUEL

    VGO

    VR

    VR

    VB TAR

    VB NAPHTHA

    BITUMEN

    ST RUN NAPH

    REFORM

    F

    CC

    LTGASO

    MS

    FCC TCO

    AR

    LPG

    LHT NAPH

    HVY NAPH

    KERO

    DIESEL

    RELIANCE JAMNAGAR REFINERY COMPLEX

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    CDU

    VD

    U

    KeroMEROX

    Sat GasConcn

    Delayed

    Coker

    VGO

    HDT

    DHDT

    FCCU

    HEAVYNAPHHDT

    Gasoline

    MEROX

    CRUDE

    Light

    Kerosene

    ATMResidue

    Diesel

    HAGO

    Diesel

    Unstabilis

    ed

    Naphtha

    Naphtha

    Coke to PPVacuum

    Resid

    LIGHTNAPH

    HDT

    H2 PLANT

    H2

    C5 -C6

    Unsat gasconc.

    LPGMEROX

    PropyleneRecovery

    LPG

    Heavy kerosene

    C5

    -C10

    NC

    6/BN

    Sat LPG

    MEROXC3/C4

    LPG

    NormalButane

    Recovery

    N- Butane

    Ga

    soline

    toStorage

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    Source K J Pai, L &T

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    Source K J Pai, L &T

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    Source K J Pai, L &T

    3-D Model View

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    Fig.

    Construction status - RefineryConstruction status - RefineryConstruction status - RefineryConstruction status - Refinery

    Fi

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    HCU / DHT Overall Progress:92.8%

    71

    Fig.4

    Overview of Reliability Concerns for Hydroprocessing PlantsOverview of Reliability Concerns for Hydroprocessing PlantsOverview of Reliability Concerns for Hydroprocessing PlantsOverview of Reliability Concerns for Hydroprocessing Plants

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    Richmond Isomax Fire 1989Richmond Isomax Fire 1989Richmond Isomax Fire 1989Richmond Isomax Fire 1989

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    Brittle FractureBrittle FractureBrittle FractureBrittle Fracture

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    Brittle FractureBrittle FractureBrittle FractureBrittle Fracture

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    Richmond steam generator brittle fracture duringhydrotest

    TANKAGE AREA

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    Essar Oil Refinery, Vadinar

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    Reaction sectionReaction sectionReaction sectionReaction section

    Riser (reactor)

    Maintains the feed and the catalyst in close contact as

    a well-dispersed mixture while avoiding backmixing

    Designed to minimise catalyst sticking to the walls

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    Reaction sectionReaction sectionReaction sectionReaction section

    Riser Termination Device

    Designed to eliminate post-riser cracking thermal / secondary

    Stripping zone

    Designed to keep hydrocarbons out of the

    regenerator

    Reactor internalsReactor internalsReactor internalsReactor internals

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    Riser Termination device

    Catalyst to regen

    Vapors to fractionator

    Secondary cyclones

    Stripper baffles