Razyor Ranch Gas Unit in Denton, Texas

8/11/2019 Razyor Ranch Gas Unit in Denton, Texas

1/20

)

Denton Ra )Resources

Air Monitoring Results Denton City/Range Resources

Estimate of ESLExceedences

December and February Test Comparisons

)

Pollutant CAS MW Results Results Results Results TCEQ Exceeds TCEQ Exceeds TCEQ

ppbv ppbv ppbv ppbv Sht Term

TCEQ

LgTerm

TCEQ

Short Term

Grab 24hr ESL (ppb) Sh Term ESL(ppb) Lg Term ESL Basis

Dec 13 09 5-Feb 18-Feb 18-Feb

TO-14

Benzene 71432 78.0

4.81 0.00

:l 6.~0

S.S.4Cl

54.0

Yes

1.4

'Wes

Health

Chlorometha ne

74873

50.4

0.56

0.65

0.00 0.00 500.0 No

50.0

No Health

Dichlorodifluoromethane (F12) 75718 120.9 0.48

0.49

30.60 0.48 10000.0 No 1000.0 No Health

Dichlorotetrafluoroethane (F114) 76142 170.9

0.00

0.00

39.00 0.68 10000.0

1000.0 Health

Ethyl benzene 100411 92.0

1.00

0.00 0.00 3.18 460.0

No

46.0

No Odor

Styrene 100425 104.0 0.00 0.00 0.00 10.80 25.0 33.0 Odor

Toluene 108883 92.0 7.93 0.00 27.00 0.00 170.0 No 330.0 No Odor

1,3,S-Tri methylbenzene/4-Ethyltoluene 108678 120.2

2.48

0.00 0.00

1.26

250.0 No 25.0

No

Health

1,2,4 Trimethylbenzene

95636

120.2

0.95 0.00 0.00 0.00 5000.0 No 500.0 No Health

m&p Xylenes 1330207 106.0 5.30 0.00 0.00

11.40

80.0 No 42.0 No Odor

o-Xylene 95476 106.0 2.28 0.00 0.00

1.73

380.0 No 42.0 No Odor

TIC

Cyclohexadiene

628411 80 23.4 2030 No No Odor

Isobutane

75285 58 11.90

6.74 2040 No 204 No

Odor

Camphene 79925 136 2.85 No

No

Carbon Disulfide** 75150 76

1 A,.,QQ

]$;AMD

10

'f~

1 ej;

Health

Dimethyl Disulfide 624920

94

~~ )

5 ea

0.5

~$. Health

Dimethyl Trisulfide

3658808 126

l.:t~

5e.s,

0.5

es

Propynyl Benzene 116 7.20

Methyl Ethyl Disulfide

2E+07

108

]~~( )

5 0.5

~El

Diethyl Trisulfide 3600246 154 6.20 16 No 1.6

fS-S


2/20

)

)

enton Ra )Resources

Air Monitoring Results Denton City/Range Resources

Pollutant CAS MW Results Results Results Results TCEQ Exceeds

TCEQ

Exceeds

TCEQ

ppbv ppbv ppbv ppbv Sht Term TCEQ Lg Term

TCEQ

Short Term

Grab 24hr

ESL(ppb)

Sh Term

ESL(ppb) LgTerm

ESLBasis

Dec 13 09 5-Feb 18-Feb 18-Feb

C3 Hydrocarbon

C4 Hydrocarbon

58

C5 Hydrocarbon 72 35.50

C6 Hydrocarbon

58

42.00


C9 Hydrocarbon 8

10.60


C12 Hydrocarbon 23.40

C13 Hydrocarbon

184

13.70 11.70

I_M_e_t_h_an_e -J[I o....:p_m-JO2.9pm~ 3.5pm

0

1.9pm

0'-- 1].... _

**Indicates the const ituent has disaster potential


3/20

Laboratory Results

December 13, 2009


4/20

_ GD Air Testing Inc.

r>

www.gdair.com

CLIENT: Alisa Rich

Wolf Eagle

PO Box 270541

Flowermound, TX 75022'

Project No.:

Denton Range Resource ~aseline

GOAir Testing Lab.

10:

Report Date:

Date Analyzed:

Analyzed by:

GO Air QC Batch:

Method:

NELAP Certification :

G009-0347 -001

17-Dec-09

16-Dec-09

LAJ

QC-121609T014

EPAT014

T1

04704364 09

TX

REPORT OF ANALYTICAL RESULTS Page 1 of 2

SAMPLE DESCRIPTION

MATRIX

SAMPLE BY

SAMPLED DATE IRECEIVED

-300ft. East of Compressor Site

Air

O.S.

,

12/13/09 .

12115109

CONSTITUENT

MW CAS

PQL* RESULT NOTE

ppbv

ppbv

ug/cu M

Benzene 78

71432 0.26 4.81 15.3

Benzylchloride 126.6 100447 0.26 NO NO

Bromomethane (Methyl Bromide)

94.9 74839

0.26

NO

NO

Carbon tetrachloride

153.8 56235

0.26

NO

NO

Chlorobenzene

112.6 108907 0.26 NO

NO

Chloroethane (Ethyl Chloride)

64.5 75003 0.26 NO

NO

Chloroform 119 67663

0.26 NO NO

Chloromethane (Methyl Chloride)

50.4

74873 0.26 0.56

1.15

1,2-Dibromoethane (EDB)

187.9 106934 0.26 NO

ND

1,2-Dichlorobenzene

147 95501 0.26

NO

ND

r

1,3-Dichlorobenzene 147

541731 0.26 NO

ND

1,4-Dichlorobenzene

147 106467 0.26

NO ND

1,1-Dichloroethane 99

75343 0.26 NO

ND

1,1-Dichlorethene

97 75354 0.26

NO ND

Dichlorodifluoromethane (F12) 120.9 75718

0.26 0.38

1.88

Dichlorotetrafluoroethane (F114)

170.9 76142 0.26

NO ND

1,2-Dichloroethane (EDC) 99

107062

0.26

NO

ND

cis-1,2-Dichloroethene 97 156694 0.26 NO ND

trans-1,2-Dichloroethene

97 156605

0.26

NO ND

Dichloromethane (Methylene chloride) 84.9

75092 0.26

NO ND

1,2-Dichloropropane 113.

78875 0.26 NO NO

cis-1,3-Dichloropropene

111 10061015

0.26 NO ND

trans-1,3-Dichloropropene

111 10061026

0.26

NO ND

Ethylbenzene

106

100411 0.26 1.00 4.34

Hexachlorobutadiene

260.8 87683

0.65 NO ND

Styrene

104

100425 0.26 NO ND

1,1,2,2-Tetrachloroethane

167.9 79345 0.26

NO

ND

Tetrachloroethene (PCE)

165.8 127184 0.26 NO

ND

Toluene

92

108883

0.26 7.93

29.8

1,1,1-Trichloroethane (TCA)

133.4

71556

0.26 NO

ND

1,1,2-Trichloroethane

133.4

79005 0.26

NO ND

1,3,5-Trimethylbenzene/4-Ethyltoluene 120.2 108678 0.26 2.48 12.2

1,2,4-Trimethylbenzene 120.2 95636 0.26

0.95

4.67

1,2,4-Trichlorobenzene 181.5

120821

0.65

NO

ND

Trichloroethene (TCE)

131.3 79016

0.26

NO ND

awed

651 N. Plano Road, Suite 429, Richardson, TX 75081, USA Tel: (972) 480-8908 Fax (972) 480-8308


5/20

~ GD

Air Testing Inc.

www.gdair.com

r>

CLIENT: Alisa Rich

Wolf Eagle

PO Box 270541

Flowermound, TX 75022'

Project No.:

Denton Range 'Resource Baseline

GD Air Testing lab. 10:

Report Date:

Date Analyzed:

Analyzed by:

GD Air QC Batch:

Method:


GD09-0347 -001

17-Dec-09

16-Dec-09

LAJ

QC-121609T014

EPAT014

T104704364 09 TX

REPORT OF ANALYTICAL RESULTS

Page 2 of2

SAMPLE DESCRIPTION

MATRIX SAMPLE BY


-300ft. East of Compressor Site

Air D.S.

12113/09 12/15/09

CONSTITUENT

MW

CAS

PQl*

RESULT NOTE

ppbv

ppbv

ug/cu M

Trichlorofluoromethane (F-11)

137.4

75694

0.26

NO NO

Trichloritrifluoroethane (F-113)

187.4

76131 0.26 NO NO

Vinyl Chloride

62.5

75104

0.26 NO NO

m&p-Xylenes

106 1330207 0.26 5.30 23.0

o-Xylene

106 95476

0.26

2.28

9.88

Tentatively Identified Compounds (TICs)

Unidentified sulfide group

1.29 14.7 NA

C4 Hydrocarbon

58 1.29 6.20

14.7

lsobutane

58 1.29 11.9 28.2

r>

C5 Hydrocarbon

72 1.29 35.5 105

Carbon disulfide

76

1.29

12.0

37.3

C6 Hydrocarbon

58 1.29

42.0 99.6

C8 Hydrocarbon 114

1.29

4.64 21.6

C9 Hydrocarbon

128

1.29 10.6 55.5

C10 Hydrocarbon

142

1.29 56.4 328

C13 Hydrocarbon

184

1.29

13.7 103

Surrogate Recovery Report Spiked

ppbv

Found

ppbv

R%

1,4-Difluorobenzene (SS1) 118.1 540363 5.00

Bromofluorobenzene (SS2) 175 460004 5.00

5.59

3.57

112

71

*Comparison with the method blank this sample run with a dilution factor of:

Canister #145 was received at an initial pressure of 0.5psi and pressurized to 4.9psi.

*RESULTS Listed as 'ND' were not detected at or above the listed PQl (Practical Quantitation Limit).

* The control limit for Surrogate Recovery % of all spiked compound is 70% - 130%. Only one is required to pass.

*Concentrations in ug/cu M reported at 760 mm Hg pressure and 298 deg.K.

*QAlQC

reports followed this report; include: Method blank, Blank spike (BS) and Blank spike duplicate (BSO)

1.29

Respectfully submitted

~D ~\

G~

Laboratory Director

Data File: varian\121609.B\091216-14-0347-1.sms

Report File: GDAIR D:\Client-Report\GD09-0347-001



6/20

~ GD Air Testing Inc.

www.

gdair.com

r>.

CLIENT: GO Air Testing, Inc. GO Air Testing Lab. 10:

Method Blank

Report Date:

12/17/09

Date Analyzed:

12/16/09

Analyzed by:

LAJ

GO Air QC Batch: QC-121609

Project No.: Method: EPAT014


T1 0 4704364-09- TX

REPORT OF METHOD BLANK RESULTS

Page 1 of2

SAMPLE DESCRIPTION MATRIX SAMPLE BY


BLK

Air

CONSTITUENT MW CAS

PQL* RESULT NOTE

ppbv

ppbv ug/cu M

Benzene 78 71432 . 0.20

NO

NO

Benzylchloride 126.6 100447 0.20

NO NO

Bromomethane (Methyl Bromide) 94.9 74839 0.20 NO NO

Carbon tetrachloride 153.8 56235

0.20 NO NO

Chlorobenzene

112.6 108907 0.20

NO NO

Chloroethane (Ethyl Chloride) 64.5

75003 0.20 NO NO

Chloroform

119 67663 0.20

NO NO


50.4 74873

0.20

NO

NO


187.9 106934 0.20

NO

NO

1,2-Dichlorobenzene

147 95501 0.20

NO NO

~

1,3-Dichlorobenzene

147 541731 0.20

NO NO

1,4-Dichlorobenzene

147

106467 0.20 NO

NO

1,1-Dichloroethane

99

75343 0.20

NO NO

1,1-Dichlorethene

97 75354 0.20

NO NO

Dichlorodifluoromethane (F12)

120.9 75718

0.20

NO NO


170.9 76142

0.20

NO NO

1,2-Dichloroethane (EOC)

99 107062 0.20 NO NO

cis-1,2-0ichloroethene

97 156694

0.20

NO

NO

trans-1,2-0ichloroethene

97 156605

0.20

NO NO

Oichloromethane (Methylene chloride)

84.9 75092

0.20

NO NO

1,2-0ichloropropane

113 78875

0.20

NO NO

cis-1,3-0ichloropropene

111 10061015

0.20 NO NO

trans-1,3-0ichloropropene

111 10061026

0.20 NO NO

Ethylbenzene

106 100411 0.20

NO

NO

Hexachlorobutadiene

260.8

87683 0.50

NO NO

Styrene

104

100425 0.20

NO

NO


167.9 79345

0.20

NO NO


165.8 127184

0.20 NO

NO

Toluene

92 108883

0.20

NO NO

1,1,1-Trichloroethane (TCA) 133.4 71556 0.20 NO NO

1,1,2- Trichloroethane

133.4

79005

0.20

NO

NO

1,3,5- Trimethylbenzene/4-Ethyltoluene

120.2

108678 0.20

NO

NO

1,2,4-Trimethylbenzene

120.2 95636

0.20

NO

NO

1,2,4-Trichlorobenzene

181.5

120821 0.50

NO

NO


131.3 79016

0.20

NO

NO

r

65] N. Plano Road, Suite 429, Richardson, TX 7508], USA Tel: (972) 480-8908 Fax (972) 480-8308


7/20

_ GD Air Testing Inc.

r>.

CLIENT: GO Air Testing, Inc.

GO Air Testing Lab.

10:

Report Date:

Date Analyzed:

Analyzed by:

GO Air QC Batch:

Method:

NELAP Certification

:

Project No.: QC

REPORT OF ANALYTICAL RESUL TS

www.gdair.com

Method Blank

12/17/09

12/16/09

LAJ

QC-121609

EPAT014

T1 47 4364 9 TX

Page 2 of2

SAMPLE DESCRIPTION

MATRIX SAMPLE BY


BLK Air

CONSTITUENT

MW CAS

137.4 75694

187.4 76131

62.5

75104

106

1330207

106 95476


Trichloritrifluoroethane (F-113)

Vinyl Chloride

m&p-Xylenes

o-Xylene

Surrogate Recovery Report

PQL*

ppbv

0.20

0.20

0.20

0.50

0.20

Spiked

ppbv

RESULT

NOTE

ppbv uglcu M

NO NO

NO NO

NO NO

NO NO

NO

NO

Found R%

ppbv

5.34 106.8

4.61

92.2

1.0

1,4-Difluorobenzene (SS1)

Bromofluorobenzene (SS2)

118.1 540363

175 460004


5.00

5.00

*RESUL TS Listed as 'NO' were not detected at or above the listed PQL (Practical Quantitation Limit).


*Concentrations in uglcu M reported at 760 mm Hg pressure and 298 deg.K.

*QNQC

reports followed this report include: Method blank, Blank spike (BS) and Blank spike duplicate (BSD)


GO Air Testing, Inc.

~ 10, ~ document.

V \

v


10/20

Laboratory Results

February 5, 2010


11/20


12/20

~ GD Air Testing Inc.

f)

www.gdair.com

CLIENT: Alisa Rich

Wolf Eagle

PO Box 270541

Flowermound, TX 75022

Project No.: NA

GOAir Testing Lab.

10:

Report Date:

Date Analyzed:

Analyzed by: .

GO Air QC Batch:

Method:


G010-0021-001

16-Feb-10

10-Feb-1 0

LAJ

QC-02101OT014

EPAT014

T104704364 09 TX


Page 1 of 2

SAMPLE DESCRIPTION

MATRIX SAMPLE BY


Denton

Air

NA

02/05/10

02/09/10

CONSTITUENT

MW CAS PQL*

RESULT

NOTE

ppbv

ppbv

ug/cu M

Benzene

78

71432

0.5 NO

NO

Benzylchloride

126.6

100447 0.5 NO

NO

Bromomethane (Methyl Bromide) 94.9 74839 0.5 NO NO

Carbon tetrachloride

153.8 56235 0.5 NO

NO

Chlorobenzene

112.6 108907 0.5 NO NO

Chloroethane (Ethyl Chloride)

64.5 75003 0.5

NO NO

Chloroform

119

67663 0.5 NO

NO


50.4

74873 0.5

0.645 1.33


187.9

106934

0.5

NO

NO

1,2-Dichlorobenzene

147 95501 0.5

NO NO

r

1,3-Dichlorobenzene

147

541731 0.5 NO

NO

1,4-Dichlorobenzene

147 106467 0.5

NO

NO

1,1-Dichloroethane

99 74343

0.5 NO

NO

1,1-Dichlorethene

97

75354 0.5

NO

NO

Dichlorodifluoromethane (F12)

120.9

75718 0.5

0.49

2.42


170.9 76142 0.5

NO

NO

1,2-Dichloroethane (EDC) 99 107062 0.5 NO NO

cis-1,2-Dichloroethene 97 156592 0.5 NO

NO

trans-1 ,2-Dichloroethene

97 156605

0.5 NO

NO

Dichloromethane (Methylene chloride)

84.9 75092

0.5 NO

NO

1,2-Dichloropropane

113

78875 0.5 NO

NO

cis-1 ,3-Dichloropropene

111 10061015 0.5

NO

NO

trans-1,3-Dichloropropene 111 10061026 0.5 NO

NO

Ethylbenzene 106 100414 0.5

NO

NO

Hexachlorobutadiene 260.8 87683 1.1

NO NO

Styrene

104 100425 0.5

NO

NO


167.9 79345 0.5

NO NO


165.8 127184 O.S

NO NO

Toluene

92

108883 0.5 NO

NO

1,1,1-Trichloroethane (TCA)

133.4

71556 O.S NO

NO

1,1,2-Trichloroethane

133.4

79005

0.5 NO

NO

1,3,S-Trimethylbenzene/4-Ethyltoluene 120.2 108678 O.S NO

NO

1,2,4-Trimethylbenzene

120.2 95636

0.5 NO

NO

1,2,4-Trichlorobenzene

181.S 120821

1.1 NO

NO


131.3

79016 O.S

NO NO

('\

PAGE 2 OF 9



13/20

_ GD Air Testing Inc. www.gdair.com

CLIENT: Alisa Rich

Wolf Eagle

PO Box 270541

Flowermound, TX 75022

Project No.: NA

GO Air Testing lab.

10:

Report Date:

Date Analyzed:

Analyzed by:

GO Air QC Batch:

Method:


GD10-0021-001

16-Feb-10

10-Feb-10

LAJ

QC-021010T014

EPAT014

T104704364 09 TX


Page 2 of 2

SAMPLE DESCRIPTION

MATRIX SAMPLE BY


Denton

Air NA

02/05/10

02/09/10

CONSTITUENT

MW CAS PQl* RESULT

NOTE

ppbv

ppbv

ug/cu M


;37.4

75694 0.5

ND

NO

Trichloritrifluoroethane (F-113) 187.4 76131 0.5 ND NO

Vinyl Chloride

62.5

75014

0.5

ND

NO

m&p-Xylenes

106

1330207

0.5

ND

NO

o-Xylene

106 95476 0.5

ND

NO

Tentatively Identif ied Compounds (TICs)

C3 Hydrocarbon

44 2.3

16.4 29.5

Isobutane

58

2.3

6.74

16.0

C5 Hydrocarbon 72

2.3

7.27

21.4

r

C6 Hydrocarbon

58

2.3

3.32

7.88

Camphene

136

2.3 2.85

15.9

C10 Hydrocarbon

170 1.6

10.7

74.4

1,4-Difluorobenzene (SS1) 118.1 540363 5.00

Bromofluorobenzene (SS2) 175 460004 5.00

Spiked

ppbv

Found

ppbv

R%

urrogate Recovery Report

5.52

5.29

110

106


Canister #2877 was received at an init ial pressure of -6.3psi and pressurized to 4.4psi.

*RESUl TS Listed as 'ND' were not detected at or above the listed POL (Practical Quantitation Limit).


*Concentrations in ug/cu M reported at 760 mm Hg pressure and 298 deg.K.

*OA/QC reports followed this report include: Method blank, Blank spike (BS) and Blank spike duplicate (BSD)

2.27


GO Air Testing, Inc.

lv\{;y

bo

lX 0~

GeOrge Dai, Ph.D.

Laboratory Director

Data File:varian/1 00210-11-0021-1.sms

Report File: GDAIR D:\Client-Report\GD10-0021-001

PAGE 30F 9


----------------------------------------------------------------------


14/20

_ GD

Air Testing Inc

www gdair com

CLIENT:

Alisa Rich

Wolf Eagle

PO Box 270541

Flower Mound TX 75027

GD Air Testing Lab. ID:

Report Date:

Date Analyzed:

Analyzed by:

GD QC Batch:

Method:

G01 0-0021-1 F

2/18/2010

2/1712010

JCA

QC-021710F

ASTM 1945

Site: NA

REPORT OF ANAL YTICAL RESUL TS

Page 1 of 1

SAMPLe: DESCRIPTION

MATRIX

SAMPLED BY


Denton

Air NA

02 05 10 02 09 10

CONSTITUENT

MW PQL* RESULT

NOTE

ppmv ppmv

Methane

16.0 2.3 9

Ethane

30.0 2.3

NO

Propane

44.0

2.3

NO

Butane

58.0 2.3

NO

Pentane

72.0 2.3 NO

r> .

Hexane

86.0 2.3 NO

Canister #2877 was received at an initial pressure of -6.3psi and was pressurized to 4.4psi.

*Comparision with the method blank this sample run with a dilution factor of: 3

*RESUL TS Listed as 'ND' were not detected at or above the listed PQL (Practical Quantitation Limit).


*QAlQC reports followed this report include: Method blank, Blank spike (BS) and Blank spike duplicate (BSD)


GD Air Testing, Inc.

f\ --:

t ,

--

Razyor Ranch Gas Unit in Denton, Texas

Documents

Transcript of Razyor Ranch Gas Unit in Denton, Texas