Quadrupole Isolation
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Transcript of Quadrupole Isolation
Quadrupole Isolation
Broadband
(+) ESI 9.4 T FT-ICR MSDeepwater Horizon
Oil Spill Contaminant
m/z 1000800600400
Figure S1
m/z440435430425420415410
Quadrupole Isolation
500 Acquisitions
Deepwater HorizonOil Spill Contaminant
423.42423.41 425.424425.422425.42
C28H55O2
m/z 423.41966*m/z 423.419657
S/N 605150 ppb
C28H55O118O1
S/N<1
+ 2.00424
= m/z 425.42390
Figure S2 (+) ESI 9.4 T FT-ICR MS
QuadIsolation
SWIFTIsolation
m/z425.330425.326
C29H43O118O1
m/z 425.33003*m/z 425.330003
117 ppbS/N 19.8
C29H43O118O1
m/z 425.33010*m/z 425.330003
219 ppbS/N = 6.4
m/z425.424425.422425.420
C28H55O118O1
m/z 425.42390*m/z 425.423904
21 ppbS/N 7.6
C28H55O118O1
S/N < 1
*Calculated
(+) ESI 9.4 T FT-ICR MSDeepwater Horizon
Oil Spill Contaminant
Figure S3
C25H45O5
S/N 25.5
C24H46N1O2S113C1
S/N 28.2
C27H43O2 13C2
S/N 53.1
C25H45O5
S/N 65.7
C24H46N1O2S113C1
S/N 97.0
C27H43O2 13C2
S/N 135.9
C27H53 N1O22D1
S/N<0
C27H53 N1O22D1
S/N 4.4
466465464 m/z 466465464
SWIFT B
SWIFT A
1 Acquisition
C33H54N1
S/N ≈ 2632
C33H54N1
S/N ≈ 1726
1 Acquisition
Figure S4
C32H54N113C1
(+) ESI 9.4 T FT-ICR MSHeavy Crude Oil
C32H54N113C1
465.427465.426465.425465.424465.423465.422465.421465.420
SignalMagnitude ≈ 1.6
SignalMagnitude ≈ 1.3 SWIFT B
C33H5415N1
465.42200*465.42211S/N = 8.7249 ppb
C33H5415N1
465.42211*465.42211S/N = 3.140 ppb
465.436465.434465.432
C33H53N12D1
465.43130*465.43125S/N = 14.0105 ppb
465.436465.434465.432
C33H53N12D1
465.43129*465.43125S/N = 7.376 ppb
1 Acquisition
*Calculated
Figure S5
(+) ESI 9.4 T FT-ICR MSHeavy Crude Oil
SWIFT A
1 Acquisition
C32H53N2
S/N 47.4
C32H53N2
S/N 43.1
C30H58 S115N1
S/N 12.1
C30H58 S115N1
S/N 13.3