51

ภาคผนวก

ภาคผนวก 1ก : องค์ประกอบของสารในส่วนที่ 1 กระบวนการหมักอ้อย Component ID Type Component name Alias

H2O Conventional WATER H2O

ETHANOL Conventional ETHANOL C2H6O-2

GLUCOSE Conventional DEXTROSE C6H12O6

GALACTOS Conventional DEXTROSE C6H12O6

MANNOSE Conventional DEXTROSE C6H12O6

XYLOSE Conventional D-XYLOSE C5H10O5-U

ARABINOS Conventional D-XYLOSE C5H10O5-U

CELLOB Conventional SUCROSE C12H22O11

SUCROSE Conventional SUCROSE C12H22O11

GLUCOLIG Conventional DEXTROSE C6H12O6

GALAOLIG Conventional DEXTROSE C6H12O6

MANOLIG Conventional DEXTROSE C6H12O6

XYLOLIG Conventional D-XYLOSE C5H10O5-U

ARABOLIG Conventional D-XYLOSE C5H10O5-U

EXTRACT Conventional DEXTROSE C6H12O6

LGNSOL Conventional VANILLIN C8H8O3-D1

HMF Conventional HMF C6H6O3-U

FURFURAL Conventional FURFURAL C5H4O2

AACID Conventional ACETIC-ACID C2H4O2-1

LACID Conventional LACTIC-ACID C3H6O3-D1

XYLITOL Conventional XYLITOL C5H12O5-U

GLYCEROL Conventional GLYCEROL C3H8O3

SUCCACID Conventional SUCCINIC-ACID C4H6O4-2

NH3 Conventional AMMONIA H3N

H2SO4 Conventional SULFURIC-ACID H2SO4

NH4SO4 Conventional AMMONIUM-SULFATE (NH4)2SO4

NH4ACET Conventional AMMONIUM-ACETATE C2H7NO2

DAP Conventional DIAMMONIUM-PHOSPHATE (NH4)2HPO4

HNO3 Conventional NITRIC-ACID HNO3

52

Component ID Type Component name Alias

NANO3 Conventional SODIUM-NITRATE NANO3

NAOH Conventional SODIUM-HYDROXIDE NAOH

CNUTR Conventional DEXTROSE C6H12O6

WNUTR Conventional DEXTROSE C6H12O6

DENAT Conventional N-HEPTANE C7H16-1

H2S Conventional HYDROGEN-SULFIDE H2S

SO2 Conventional SULFUR-DIOXIDE O2S

OIL Conventional OLEIC-ACID C18H34O2

O2 Conventional OXYGEN O2

N2 Conventional NITROGEN N2

NO Conventional NITRIC-OXIDE NO

NO2 Conventional NITROGEN-DIOXIDE NO2

CO Conventional CARBON-MONOXIDE CO

CO2 Conventional CARBON-DIOXIDE CO2

CH4 Conventional METHANE CH4

CELLULOS Solid CELLULOSE CELLULOSE

GALACTAN Solid CELLULOSE CELLULOSE

MANNAN Solid CELLULOSE CELLULOSE

XYLAN Solid XYLAN C5H8O4-U

ARABINAN Solid XYLAN C5H8O4-U

LIGNIN Solid VANILLIN C8H8O3-D1

ACETATE Solid ACETIC-ACID C2H4O2-1

PROTEIN Solid PROTEIN CHONS-U3

ASH Solid CALCIUM-OXIDE CAO

ENZYME Solid ENZYME CHONS-U3

DENZ Solid ENZYME CHONS-U3

ZYMO Solid ZYMO CHON-U1

TRICHO Solid TRICHO CHONS-U2

BIOMASS Solid BIOMASS CHONS-U1

TAR Solid D-XYLOSE C5H10O5-U

Component ID Type Component name Alias

LIME Solid CALCIUM-HYDROXIDE CA(OH)2

53

CASO4 Solid CALCIUM-SULFATE CASO4

C Solid CARBON-GRAPHITE C

ภาคผนวก 2ก : สูตรเคมีขององค์ประกอบของสารในส่วนที่ 1 กระบวนการหมักอ้อย ที่ไม่ปรากฏในฐานข้อมูล โปรแกรม Aspen plus

C H O N S

ARABINAN 5 8 4 ARABINOS 5 10 5

ARABOLIG 5 8 4 BIOMASS 1 1.64 0.39 0.23 0.0035

DENZ 1 1.59 0.42 0.24 0.01 ENZYME 1 1.59 0.42 0.24 0.01 PROTEIN 1 1.57 0.31 0.29 0.007

TAR 5 10 5 TRICHO 1 1.645 0.445 0.205 0.005 XYLAN 5 8 4

XYLITOL 5 12 5 XYLOLIG 5 8 4 XYLOSE 5 10 5

ZYMO 1 1.8 0.5 0.2

XYLOSE ADDITIONAL DATA Atom 1 Atom 2 Number Type Number Type Bond type

2 C 1 O Single bond

2 C 3 C Single bond 3 C 4 C Single bond

4 C 5 C Single bond 5 C 6 C Single bond

6 C 1 O Single bond 10 O 3 C Single bond

4 C 9 O Single bond 5 C 8 O Single bond 6 C 7 O Single bond

54

ภาคผนวก 3ก : องค์ประกอบของสารในส่วนที่ 2 กระบวนการดีไฮเดรชัน และพอลิเมอไรเซชัน

Component ID Type Component name Alias ETHAN-01 Conventional ETHANOL C2H6O-2

ETHYL-01 Conventional ETHYLENE C2H4 WATER Conventional WATER H2O

DIETH-01 Conventional DIETHYL-ETHER C4H10O-5 ACETA-01 Conventional ACETALDEHYDE C2H4O-1

1-BUT-01 Conventional 1-BUTENE C4H8-1 HYDRO-01 Conventional HYDROGEN H2

HDPE Polymer HIGH-DENSITY-POLY(ETHYLENE) HDPE C2H4-R Segment ETHYLENE-R C2H4-R TITAN-01 Conventional TITANIUM-TETRACHLORIDE TICL4 TRIET-01 Conventional TRIETHYL-ALUMINUM C6H15AL N-HEX-01 Conventional N-HEXANE C6H14-1

HDPE(S) Solid HIGH-DENSITY-POLY(ETHYLENE) HDPE NITRO-01 Conventional NITROGEN N2

OXYGE-01 Conventional OXYGEN O2

55

ภาคผนวก 4ก : ค่าพารามิเตอร์ของกระบวนการหมักอ้อย CPIALE-1

Components ARABINOS XYLOLIG ARABOLIG XYLITOL TAR

Temperature units C C C C C Property units cal/mol-K cal/mol-K cal/mol-K cal/mol-K cal/mol-K

1 22.53245916 22.53245916 22.53245916 27.77013471 22.53245916 2 80.55651094 80.55651094 80.55651094 82.94592529 80.55651094 3 1080.25 1080.25 1080.25 -541.554 1080.25

4 40.59663705 40.59663705 40.59663705 -37.07246585 40.59663705 5 477.209 477.209 477.209 619.498 477.209

6 0 0 0 0 0 7 8.31447 8.31447 8.31447 8.31447 8.31447 8 -73.15 -73.15 -73.15 -73.15 -73.15 9 726.85 726.85 726.85 726.85 726.85

CPIG-1

Components XYLOSE HMF NANO3 Temperature units C K C

Property units cal/mol-K J/kmol-K cal/mol-K 1 37.26888724 -23327.1 22.22461068

2 0.139989846 706.431 0 3 -0.00015497 -0.611538 0

4 7.37E-08 0.000204391 0 5 0 0

6 0 0 7 6.85 280 -273.15

8 826.85 1100 1726.85 9 8.605426579 36029.2 0 10 0.006320869 20.2733 0 11 1.5 1.5 0 12

56

CPLTML-1 Components XYLITOL

Temperature units C

Property units cal/mol-K 1 71.97023999 2 0.54680287

3 -0.003641628 4 1.06E-05 5 0 6 4 7 92.88 8 116.85

CPSO1-1 Components XYLAN ARABINAN LIGNIN BIOMASS ZYMO

Temperature units K K K K K Property units J/kmol-K J/kmol-K J/kmol-K J/kmol-K J/kmol-K

1 -9529.9 -9529.9 39752.8 35910 38409 2 547.25 547.25 498.84 3 0 4 0 5 0 6 0 7 298.15 298.15 298.15 298.15 298.15 8 1000

57

Components TAR TRICHO ENZYME DENZ PROTEIN

Temperature units K K K K K

Property units J/kmol-K J/kmol-K J/kmol-K J/kmol-K J/kmol-K

1 -9529.9 35910 35533 35533 35533

2 547.25 0

3 0

4 0

5 0

6 0

7 298.15 298.15 298.15 298.15 298.15

DHVLTD-1

Components XYLOSE ARABINOS XYLOLIG ARABOLIG TAR Temperature units C C C C C

Property units cal/mol cal/mol cal/mol cal/mol cal/mol 1 10.723038 10.72304 10.72304 10.72304 10.72304 2 0.845038 0.845038 0.845038 0.845038 0.845038 3 -0.0749576 -0.07496 -0.07496 -0.07496 -0.07496 4 -2.89E-01 -0.28909 -0.28909 -0.28909 -0.28909 5 599.85 599.85 599.85 599.85 599.85 6 4 4 4 4 4 7 -18.15 -18.15 -18.15 -18.15 -18.15 8 599.85 599.85 599.85 599.85 599.85

58

DHVLWT-1 Components ASH XYLITOL XYLAN LIGNIN ZYMO

Temperature units C C C C C

Property units cal/mol cal/mol cal/mol cal/mol cal/mol 1 71498.34122 14780.39 0 0 0 2 3396.85 366.419 -273.15 -273.15 -273.15

3 0.443994602 0.38 0.38 0.38 0.38 4 -0.149835978 0 0 0 0 5 3396.85 366.419 -273.15 -273.15 -273.15

Components ARABINAN BIOMASS DENZ HMF CELLULOS

Temperature units

C C C K C

Property units

cal/mol cal/mol cal/mol J/kmol cal/mol

1 0 0 0 80550000 0

2 -273.15 -273.15 -273.15 335.1 -273.15

3 0.38 0.38 0.38

4 0 0 0

5 -273.15 -273.15 -273.15

KLDIP-1

Components XYLITOL ASH XYLAN LIGNIN ZYMO

Temperature units C C C C C

Property units kcal-m/hr-sqm-K kcal-m/hr-sqm-K kcal-m/hr-

sqm-K kcal-m/hr-

sqm-K kcal-m/hr-sqm-K

1 -3.525279781 -0.62182 -728.689 -1177.84 -235.532

2 0.024027637 0.000778 -11.1636 -17.9427 -3.70505 3 -5.94E-05 -2.88E-07 -0.06416 -0.10252 -0.02188 4 6.49E-08 4.56E-11 -0.00016 -0.00026 -5.75E-05 5 -2.66E-11 -2.73E-15 -1.57E-07 -2.48E-07 -5.67E-08 6 552.25 3396.85 -273.15 -273.15 -273.15

7 727.839 5686.65 -244.379 -247.992 -227.353

59

Components ARABINAN BIOMASS DENZ HMF

Temperature units C C C C

Property units kcal-m/hr-sqm-K kcal-m/hr-sqm-K kcal-m/hr-sqm-K kcal-m/hr-sqm-K

1 -728.689 -237.526 -236.392 -0.18864

2 -11.1636 -3.73767 -3.71915 0.003822

3 -0.06416 -0.02208 -0.02197 -1.85E-05

4 -0.00016 -5.80E-05 -5.77E-05 3.79E-08

5 -1.57E-07 -5.72E-08 -5.69E-08 -2.93E-11

6 -273.15 -273.15 -273.15 259.55

7 -244.379 -227.133 -227.252 450.5519

KLTMLP-1 Components XYLOSE ARABINOS XYLOLIG ARABOLIG TAR

Temperature units C C C C C Property units kcal-m/hr-sqm-K kcal-m/hr-sqm-K kcal-m/hr-sqm-K kcal-m/hr-sqm-K kcal-m/hr-sqm-K

1 0.184288835 0.184289 0.184289 0.184289 0.184289 2 -0.000182581 -0.00018 -0.00018 -0.00018 -0.00018

3 1.18E-07 1.18E-07 1.18E-07 1.18E-07 1.18E-07 4 -2.20E-11 -2.20E-11 -2.20E-11 -2.20E-11 -2.20E-11

5 4 4 4 4 4 6 -73.15 -73.15 -73.15 -73.15 -73.15

7 506.85 506.85 506.85 506.85 506.85

KVTMLP-1 Components XYLOSE ARABINOS XYLOLIG ARABOLIG XYLITOL TAR

Temperature units C C C C C C

Property units kcal-m/hr-sqm-

K kcal-m/hr-

sqm-K kcal-m/hr-

sqm-K kcal-m/hr-

sqm-K kcal-m/hr-

sqm-K kcal-m/hr-

sqm-K 1 0.003741644 0.003742 0.003742 0.003742 0.001614 0.003742

2 2.62E-05 2.62E-05 2.62E-05 2.62E-05 4.20E-05 2.62E-05 3 3.41E-08 3.41E-08 3.41E-08 3.41E-08 -6.67E-09 3.41E-08

4 -2.33E-11 -2.33E-11 -2.33E-11 -2.33E-11 4.78E-12 -2.33E-11 5 4.00E+00 4.00E+00 4.00E+00 4.00E+00 4.00E+00 4.00E+00

6 366.85 366.85 366.85 366.85 366.85 366.85 7 1026.85 1026.85 1026.85 1026.85 1026.85 1026.85

60

MULAND-1 Components ASH NH4SO4 CELLULOS MANNAN GALACTAN XYLOSE

Temperature units K C C C C C

Property units cP cP cP cP cP cP 1 74.48 81.16 81.26 81.26 81.26 -15.55 2 -27259.04 -12127.32 -12127.32 -12127.32 -12127.32 7560.00

3 -8.43 -10.25 -10.25 -10.25 -10.25 0.00 4 3670.00 1126.85 1126.85 1126.85 1126.85 441.85 5 5959.80 1706.85 1706.85 1706.85 1706.85 547.10

Components ARABINOS XYLOLIG ARABOLIG HMF C

Temperature units C C C C C Property units cP cP cP cP cP

1 570.42 570.35 570.35 208.78 149.45

2 -52492.56 -52492.56 -52492.56 -14965.80 -67474.61 3 -75.70 -75.70 -75.70 -30.02 -16.01

4 441.85 441.85 441.85 532.70 4493.85 5 608.37 608.37 608.37 723.70 6468.75

MULDIP-1

Components XYLITOL PROTEIN SUCROSE

Temperature units C C C

Property units cP cP cP

1 -2267.4 -2267.4 -2267.4

2 138900 138910 138910

3 320 320.55 320.55

4 0 0 0

5 0 0 0

6 323 323 323

7 418 418 418

61

MUVTML-1 Components XYLOSE ARABINOS XYLOLIG ARABOLIG XYLITOL TAR

Temperature units C C C C C C

Property units cP cP cP cP cP cP 1 0.006549 0.006549 0.006549 0.006549 0.006747 0.006549 2 2.75E-05 2.75E-05 2.75E-05 2.75E-05 2.84E-05 2.75E-05

3 -2.21E-09 -2.21E-09 -2.21E-09 -2.21E-09 -2.36E-09 -2.21E-09

4 -5.57E-13 -5.57E-13 -5.57E-13 -5.57E-13 -5.48E-13 -5.57E-13

5 4 4 4 4 4 4

6 366.85 366.85 366.85 366.85 366.85 366.85

7 1026.85 1026.85 1026.85 1026.85 1026.85 1026.85

NATOM-1

Components XYLAN CELLULOS HMF GALACTAN MANNAN Temperature units

Property units

1 5 6 6 6 6

2 8 10 6 10 10

3 4 5 3 5 5

4 0

PCES-1

Parameters Units Data set HMF H2SO4 XYLOSE PROTEIN XYLAN

ZC 1 0.295048

VB cc/mol 1 75.44034 65.7589 157.8482

OMEGA 1 -0.55497

DHVLB cal/mol 1 13890.8 0 0

RGYR meter 1 2.54E-10

RKTZRA 1 0.079298

VLSTD cc/mol 1 56.60832 94.2763 0 0

DGFORM cal/mol 1 -153067

TC C 1 -226.788 -244.089

62

Parameters Units Data set ZYMO ARABINAN BIOMASS DENZ CELLULOS

DHVLB cal/mol 1 0 0 0 0

RKTZRA 1 0.206044

VLSTD cc/mol 1 0 0 0 0 146.977

TC C 1 -226.89 -244.089 -226.668 -226.788

Parameters Units Data set MANNAN GALACTAN GLUCOLIG MANOLIG GALAOLIG

RKTZRA 1 0.206044 0.206044 0.07154 0.07154 0.07154

VLSTD cc/mol 1 146.977 146.977 152.61 152.61 152.61

Parameters Units Data set ASH NH4SO4 CNUTR WNUTR GLUCOSE

RKTZRA 1 0.291766 0.29186 0.07154 0.07154 0.07154

VLSTD cc/mol 1 866.9276 298.9063 152.61 152.61 152.61

Parameters Units Data set GALACTOS MANNOSE XYLITOL EXTRACT LGNSOL

RKTZRA 1 0.07154 0.07154 0.177825 0.07154 0.220096

VLSTD cc/mol 1 152.61 152.61 40.77811 152.61 126.905

Parameters Units Data set ARABINOS XYLOLIG ARABOLIG NANO3 LIME

RKTZRA 1 0.079298 0.079298 0.079298 0.2917 0.29186

VLSTD cc/mol 1 94.2763 94.2763 94.2763 40.2364 298.9063

DGFORM cal/mol 1 -153067

Parameters Units Data set TAR C NAOH CASO4

RKTZRA 1 0.189042

VLSTD cc/mol 1 94.2763 5.18409 20.8595 298.9063

63

PLXANT-1 Components NH4ACET ASH HMF

Temperature units K C C

Property units atm atm atm

1 -1.00E+20 37.52683 114.8703

2 -48457.5 -15309.6

3 0 0

4 0 0

5 -2.9648 -13.7334

6 4.70E-24 3.81E-18

7 6 6

8 3396.85 259.55

9 5746.85 457.862

PSTDEP-1

Components XYLOSE ARABINOS XYLOLIG ARABOLIG TAR

Temperature units C C C C C

Property units atm atm atm atm atm

1 6.00E+01 59.96547 59.96547 59.96547 59.96547

2 -36835.9 -36835.9 -36835.9 -36835.9 -36835.9

3 0 0 0 0 0

4 0 0 0 0 0

5 0 0 0 0 0

6 0 0.00E+00 0.00E+00 0 0

7 0 0 0 0 0

8 0 0 0 0 0

9 201.08 201.08 201.08 201.08 201.08

10 214.87 214.87 214.87 214.87 214.87

64

PURE-1 Parameters Units Data set XYLOSE ARABINOS GLUCOLIG XYLOLIG MANOLIG GALAOLIG

MUP (J*cum)**.5 1 5.85E-25 5.85E-25 5.85E-25 5.85E-25 5.85E-25 5.85E-25

RGYR meter 1 6.15E-11 6.15E-11 6.15E-11 6.15E-11 6.15E-11 6.15E-11

Parameters Units Data set ARABOLIG XYLITOL PROTEIN CNUTR WNUTR HMF

MUP (J*cum)**.5 1 5.85E-25 5.85E-25 5.85E-25 5.85E-25 5.85E-25 5.85E-25

RGYR meter 1 6.15E-11 6.15E-11 6.15E-11 6.15E-11 6.15E-11 6.15E-11

SIGDIP-1 Components ASH XYLITOL XYLOSE ARABINOS XYLOLIG ARABOLIG HMF

Temperature units

C C C C C C C

Property units dyne/cm dyne/cm dyne/cm dyne/cm dyne/cm dyne/cm dyne/cm 1 139.21358 194.8873 291.3517 291.3517 291.3517 291.3517 138.4683 2 1.2222222 1.222222 1.222222 1.222222 1.222222 1.222222 1.222222

3 -2.17E-10 -1.87E-09 -4.76E-09 -4.76E-09 -4.76E-09 -4.76E-09 -1.40E-09 4 2.40E-10 2.10E-09 5.33E-09 5.33E-09 5.33E-09 5.33E-09 1.57E-09 5 -9.67E-11 -8.27E-10 -2.04E-09 -2.04E-09 -2.04E-09 -2.04E-09 -6.21E-10 6 3396.85 366.419 441.85 441.85 441.85 441.85 259.55 7 5626.45 578.47 599.4616 599.4616 599.4616 599.4616 443.2418

USRDEF1

Parameters Units Data set PROTEIN TAR ARABINAN XYLAN BIOMASS

MW 1 22.8396 150.1314 132.117 132.117 23.238

DHFORM cal/mol 1

TB K 1 0 634.957 0 0 0

TC K 1 873

PC Pa 1 6577700

OMEGA 1 1.09358

VC cum/kmol 1 0.336929

DHSFRM cal/mol 1 -17618 -182100 -182100 -182100 -23200

65

Parameters Units Data set NH4ACET NH4SO4 NANO3 ACETATE

DHFORM cal/mol 1 -147163 -282041 -111068

DHSFRM cal/mol 1 -108992

VLSTD cc/mol 1 66

Parameters Units Data set ZYMO TRICHO ENZYME DENZ HMF

MW 1 24.6264 23.8204 24.0156 24.0156 126.11

DHFORM cal/mol 1 -79774.5

TB K 1 0 0 532.7

TC K 1 731.012

PC Pa 1 5235810

OMEGA 1 0.993647

VC cum/kmol 1 0.3425

RKTZRA 1 0.198178

DHSFRM cal/mol 1 -31169.4 -23200 -17900.1 -17900.1

Parameters Units Data set XYLOLIG XYLOSE ARABINOS ARABOLIG XYLITOL

MW 1 132.1161 150.1314 150.1314 132.1161 152.1473

DHFORM cal/mol 1 -149413 -216753 -216753 -149413 -222246

TB K 1 634.957 634.957 634.957 634.957 639.569

TC K 1 873 873 873 873 869

PC Pa 1 6577700 6577700 6577700 6577700 6762900

OMEGA 1 1.09358 1.09358 1.09358 1.09358 1.21556

VC cum/kmol 1 0.336929 0.336929 0.336929 0.336929 0.498722

DHSFRM cal/mol 1 -267149

SG 1 1.59409 1.59409

ZC 1 0.305325 0.305325 0.466805

66

USRDEF2 Parameters Units Data set GLUCOLIG MANOLIG GALAOLIG CELLULOS MANNAN GALACTAN

MW 1 162.1424 162.1424 162.1424

DHFORM cal/mol 1 -192875 -192875 -192875 DHSFRM cal/mol 1 -233200 -233200 -233200

VSPOLY-1

Components XYLAN ARABINAN BIOMASS ZYMO TAR Temperature units K K K K K

Property units cum/kmol cum/kmol cum/kmol cum/kmol cum/kmol 1 0.0864 0.0864 0.01549 0.0164 0.0864 2 0 3 0 4 0 5 0 6 298.15 298.15 298.15 298.15 298.15

7 1000

Components TRICHO ENZYME DENZ PROTEIN Temperature units K K K K

Property units cum/kmol cum/kmol cum/kmol cum/kmol 1 0.01549 0.0152 0.0152 0.0152 2 0 3 0 4 0

5 0 6 298.15 298.15 298.15 298.15

7

67

WAGN25-1 Components XYLOSE ARABINOS XYLOLIG ARABOLIG XYLITOL TAR

Temperature units C C C C C C

Property units atm atm atm atm atm atm 1 -12.2555 -12.2555 -12.2555 -12.2555 -13.0519 -12.2555 2 5.40676 5.40676 5.40676 5.40676 6.22307 5.40676

3 -11.6289 -11.6289 -11.6289 -11.6289 -13.4917 -11.6289 4 -5.34356 -5.34356 -5.34356 -5.34356 -5.33814 -5.34356 5 4.173112 4.173112 4.173112 4.173112 4.200882 4.173112 6 599.85 599.85 599.85 599.85 595.85 599.85 7 -73.15 -73.15 -73.15 -73.15 92.88 -73.15 8 599.85 599.85 599.85 599.85 595.85 599.85

68

ภาคผนวก 1ข : ฟังก์ชัน Design spec DS-1 Variable Definition

MIX Stream-Var Stream=101 Substream=MIXED Variable=MASS-FLOW Units=tons/year

CI Stream-Var Stream=101 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

ภาคผนวก 2ข : ฟังก์ชัน Design spec DS-2

Variable Definition Q Heat-Duty Stream=QE201 Units=MW

69

ภาคผนวก 3ข : ฟังก์ชัน Design spec DS-3 Variable Definition TEMP Stream-Var Stream=209 Substream=MIXED Variable=TEMP Units=C

ภาคผนวก 4ข : ฟังก์ชัน Calculator C-1 Variable Information flow Definition MIX Export variable Stream-Var Stream=101 Substream=MIXED Variable=MASS-FLOW Units=tons/year CI Import variable Stream-Var Stream=101 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

Calculation method : Fortran Execute : First Code F MIX=CI/1.440045067 ภาคผนวก 5ข : ฟังก์ชัน Calculator C-2 Variable Information flow Definition WATER Export variable Stream-Var Stream=102 Substream=MIXED Variable=MASS-FLOW Units=tons/year

MIX Import variable Stream-Var Stream=101 Substream=MIXED Variable=MASS-FLOW Units=tons/year CI Import variable Stream-Var Stream=101 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

Calculation method : Fortran Execute : Use import/export variables Code F WATER=(MIX+CI)*3.341826797

70

ภาคผนวก 6ข : ฟังก์ชัน Calculator C-3

Variable Information flow Definition

ACID Export variable Mass-Flow Stream=204 Substream=MIXED Component=H2SO4 Units=tons/year F211M Import variable Stream-Var Stream=206 Substream=MIXED Variable=MASS-FLOW Units=tons/year

F211C Import variable Stream-Var Stream=206 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

Calculation method : Fortran Execute : Use import/export variables Code F ACID=0.11*(F211M)

ภาคผนวก 7ข : ฟังก์ชัน Calculator C-4

Variable Information flow Definition H2SO4 Import variable Mole-Flow Stream=218 Substream=MIXED Component=H2SO4 Units=kmol/sec

AACID Import variable Mole-Flow Stream=218 Substream=MIXED Component=AACID Units=kmol/sec NH3 Export variable Mole-Flow Stream=219 Substream=MIXED Component=NH3 Units=kmol/sec

Calculation method : Fortran Execute : Use import/export variables Code F NH3=1.005*(2*H2SO4+AACID) ภาคผนวก 8ข : ฟังก์ชัน Calculator C-5

Variable Information flow Definition H2SO4 Export variable Mole-Flow Stream=222 Substream=MIXED Component=H2SO4 Units=kmol/sec

NH3 Import variable Mole-Flow Stream=221 Substream=MIXED Component=NH3 Units=kmol/sec

Calculation method : Fortran Execute : Use import/export variables Code F H2SO4=0.5*NH3

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ภาคผนวก 9ข : ฟังก์ชัน Calculator C-6 Variable Information flow Definition

MIX Export variable Stream-Var Stream=301 Substream=MIXED Variable=MASS-FLOW Units=tons/year

CI Export variable Stream-Var Stream=301 Substream=CISOLID Variable=MASS-FLOW Units=tons/year F223M Import variable Stream-Var Stream=223 Substream=MIXED Variable=MASS-FLOW Units=tons/year F223C Import variable Stream-Var Stream=223 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

Calculation method : Fortran Execute : Use import/export variables Code F X=1.4*(F223M+F223C) F MIX=0.947414677*X F CI=X-MIX ภาคผนวก 10ข : ฟังก์ชัน Calculator C-7 Variable Information flow Definition

MIX310 Import variable Stream-Var Stream=310 Substream=MIXED Variable=MASS-FLOW Units=tons/year CI310 Import variable Stream-Var Stream=310 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

MIX311 Export variable Stream-Var Stream=311 Substream=MIXED Variable=MASS-FLOW Units=tons/year CI311 Export variable Stream-Var Stream=311 Substream=CISOLID Variable=MASS-FLOW Units=tons/year

Calculation method : Fortran Execute : Use import/export variables Code F X=MIX310+CI310 F DAP=MIX311+CI311 F CSL=MIX312+CI312 F DAP=X/1695.448311 F CSL=X/210.6650987 F MIX311=DAP F CI310=0 F MIX312=0.75*CSL F CI312=0.25*CSL