PROJECT: DATE: TO: RE: ATTN: JOB: WE ARE SENDING...
Transcript of PROJECT: DATE: TO: RE: ATTN: JOB: WE ARE SENDING...
16D5323-0341No.
Restoration Specialists IncPO Box 29 Broomfield CO 80038
TO:
08/02/2016DATE:
070000-Thermal and MoistureProtection
RE:
John BosioATTN:
Shop Drawings
Letter
Prints
Change Order
Plans
Samples
Specifications / Product Data
Other:
Approval
Your Use
As Requested
Review and Comment
Attached
Separate Cover Via:
Approved as Submitted
Approved as Noted
Returned After Loan
Resubmit
Submit
Returned
Returned for Corrections
Due Date: 08/02/2016
WE ARE SENDING: SUBMITTED FOR:
SENT VIA:
ACTION TAKEN:
TRANSMITTAL
James GettmanSigned:
PROJECT: DPS Sandra Todd-Williams ECE
08/02/2016
Date
079200.01
Code
Joint Sealant Product Data
Description
Revise andResubmit
Status
JOB: 16D5323
CC:
Item
Submittal 070000
Package
1
Rev. Copies
Ph/Fax: 303-460-8060 303-469-6517
NOTES:
5995 Greenwood Plaza Blvd.Suite 100Greenwood Village, CO 80111-4710303-571-5377303-629-7467 (fax)
Submittal Cover Sheet
Project Name Far NE ECE
Project Number 16D5323
Date 07-19-2016
Architect Larson Incitti Architects
Contractor GH Phipps Construction Companies
Prepared by/Subcontractor Restoration Specialists, Inc
Supplier
Manufacturer
Submittal Number 079200.01
Specification Section 079200
Drawing Number/Location
Contractor Review
A/E Review
Contractor Notes:
Submitted for Approval
RESTORATION SPECIALISTS INC Submittal LetterPO BOX 29 BROOMFIELD, CO 80038
Submittal Number: 16086-01Date: 07/18/2016
Job No: 16086Page 1 of 2
Please respond by: 07/22/2016
Angelique Kallio, CIT Jim Gettman
Restoration Specialists, Inc GH Phipps,Inc.
To: Job Site:
GH Phipps,Inc. DPS Far NE ECE Center
5995 Greenwood Plaza Blvd Ste 100 Greenwood Village, CO 80111-4710Attn: Jim Gettman
50th & Cathay Street Denver, CO 80249
Regarding:
Joint Sealant Submittal
We hereby submit the following for your approval.
DRAW/SPEC. NO. SECTION NO. ITEM NO. DESCRIPTION
079200 1.4 1 RSI Qualifications
079200 2 RSI Material Schedule
079200 2.1 3 Sealant for Horizontal Site work - Tremco Vulkem 45SSL - Product data & Certification
079200 2.1 4 Sealant for Exterior Vertical Surfaces - Tremco Dymeric 240 FC - Product Data & Certification
079200 2.1 5 Sealant for perimeter porcelain tile - Dow Corning 786 - Product Data - Only available colors: White, Transparent White, Almond, Clear & Gray
079200 2.2 6 Backer Rod - Backer Rod Mfg - Mile High Foam Closed Cell Backer Rod - Product Data & Certification
072900 2.1 7 Color Charts: Tremco Vulkem 45SSL Tremco 240FC
079200 8 Safety Data Sheets: Tremco Vulkem 45SSL Tremco 240FC Dow Corning 786 Mile High Foam Backer Rod
RESTORATION SPECIALISTS INC Submittal LetterPO BOX 29 BROOMFIELD, CO 80038
Submittal Number: 16086-01Date: 07/18/2016
Job No: 16086Page 2 of 2
Please respond by: 07/22/2016
Angelique Kallio, CIT Jim Gettman
Restoration Specialists, Inc GH Phipps,Inc.
Remarks:
Joint Sealant Submittal. Hard copy color charts will be sent separately via US Mail. Please return reviewed submittal to [email protected] and copy [email protected]. Thank you.
Tremco Incorporated 11879 E Bates Circle, Aurora, CO 80014 www.tremcosealants.com
Global Sealants Division Rich Degitis 888-770-8958 Corporate Voicemail
District Manager 303-745-5751 Phone
Commercial Sealants & Waterproofing 720-253-3763 Cellular Phone 303-873-1010 Fax
April 17, 2008
John Bosio
Restoration Specialists Inc
6930 W 116th
Avenue
Broomfield, CO 80038
RE: Approved Applicator Status
Gentleman:
This letter will confirm that Restoration Specialists Inc is an Approved Applicator for all of Tremco’s Sealant,
Membrane, and Coating Systems. We have been involved with RSI on many projects over the years and our
experience with them has been nothing but positive. We look forward to continuing this relationship and recommend
them highly.
If you have any questions or if I can be of assistance in any way please do not hesitate to call.
Sincerely,
Rich Degitis
Rich Degitis
Tremco Incorporated
DOWCORNING
January 1,2011
Restoration Specialist Inc.6930 W. 116th Avenue, Suite 50Broomfield, CO80038
Attention: John Bosio Emai1:[email protected]
Reference: Restoration Specialist Inc. and Dow Corning Corporation
Dear Mr. Bosio:
Dow Coming is pleased to support Restoration Specialist Inc. using Dow ComingConstruction Sealants for their work. Restoration Specialist Inc. has been applyingDow Coming Construction Sealants on projects in the Colorado area. RestorationSpecialist Inc. has been purchasing these sealants from Smalley & Company formany years and installing them, to our knowledge, according to Dow Comingguidelines. Dow Coming and Smalley & Company are available to help chosencontractors work on projects and apply Dow Coming materials in accordance withinDow Coming specifications, should this be needed.
I trust this satisfies your inquiry and if you or your customer have any questions,please contact me at 415-971-6006.
Sincerely,
DOW CORNING CORPORATION
Andy ShivesApplication Sales EngineerSan Francisco, CACeIl [email protected]
Dow Corning CorporationMidland, Michigan 48686-0994
Phone: (989)496-4000www.dowcorning.com
Restoration Specialists, Inc.Joint Sealant Material Schedule
Job Name: DPS Far NE ECE Center RSI Job# 16086Gen. Cont: GH PhippsSupt: John Ledingham Site Tele #: Site Address: 50th & Cathay St, Denver, CO 80249Revised Date: 5/3/2016 Project MGR: Chad Hinshaw
Job Description:
Caulking includes site expansion joints, Masonry Control Joints, Hollow Metal Frames in exterior & CMU walls, perimeter porcelain tile & other misc. exterior caulking
CAULKING Material Color 3/4" Site Work Tremco 45SSL - Adjacent to Building - Curb/Walk
3/8" Perimeter Porcelain Tile Dow 786
3/8" Masonry Control Joints Tremco 240FC
HM Frames - Ext Doors Tremco 240FC - HM in CMU Misc. Caulking
a
One-Part, Semi-Self-Leveling SealantVulkem® 45SSLProduct DescriptionVulkem 45SSL is a one-part, moisture-curing, low-modulus polyurethane sealant. It provides exceptional wear and tear resistance required in high traffic areas.
Features and BenefitsVulkem 45SSL is a traffic rated, pourable, semi-self-leveling sealant with exceptional primerless adhesion and movement capability. Vulkem 45SSL is suitable for continuous immersion in non-chlorinated water and can be applied to damp and green concrete. The technology in Vulkem 45SSL provides the sealant with greater UV resistance and will not out gas.
UsesVulkem 45SSL is formulated for use in expansion joints in sidewalks, swimming pool decks, plazas, floors and any other horizontal surface with slopes up to 6% (e.g. 1 in. rise for every 16 in. run).
ColorsBlack, Buff, Gray, Limestone, White.
Packaging1-qt (890-mL) cartridges, 2-gal (7.6-L) and 5-gal (18.9-L) pails, and 55-gal (208-L) drums
Coverage Rate308 linear feet of joint per gallon for 1/4 in. x 1/4 in. (6mm x 6mm) joints. For specific coverage rates that include joint size, and usage efficiencies, visit our website usage calculator at www.tremcosealants.com.
Applicable Standards Vulkem 45SSL meets or exceeds the requirements of the following specifications:• ASTM C920, Type S, Grade P, Class 35, Use T, M, A, O and I (Class 2)• CAN/CGSB 19.13-M87, MC-1-25-B-N
Joint DesignVulkem 45SSL may be used in any horizontal joint designed in accordance with accepted architectural/engineering practices. Joint width should be 4 times anticipated movement, but not less than 1/4 in. (6mm).
Joint BackingClosed cell or reticulated polyethylene backer rod is recommended as joint backing to control sealant depth and to ensure intimate contact of sealant with joint walls. Backer rod needs to be properly friction fitted for use with self-leveling sealants to prevent leak out of sealant during cure. Where depth of joint will prevent the use of backer rod, an adhesive backed polyethylene tape (bond breaker tape) should be used to prevent three-sided adhesion. All backing should be dry at time of sealant application.
Page 1 of 2
TYPICAL PHYSICAL PROPERTIES(Results of recent testing at 72˚F (22˚C) after 21 days cure time.)
Property Test Method Typical ValueRheological Properties ASTM C639 Semi-self-leveling, levels moderately* Holds up to 6% Slope Weight Loss ASTM C1246 3%Hardness Properties, scale “A” ASTM C661 40-45Skin Time (tooling time) 1.5-2 hoursTack-Free Time ASTM C679 <5 hoursStain & Color Change ASTM C510 No stain, No color changeAdhesion to Concrete ASTM C794 Before water: 31 pli After water: 28 pli Green: >15 pli Damp: >15pli Accelerated Weathering ASTM C793 PassMovement Capability ASTM C719 ** +100% / -50%Tensile Strength ASTM D412 250-300 psiElongation ASTM D412 600-750%Tear Strength ASTM D412 35 pli (156N) *There is no method specific in ASTM C920 that defines the rheology of a semi-self-leveling sealant.** Modified ASTM C719
www.tremcosealants.com
0514/V45SSLSD Page 2 of 2
Sealant DimensionsW = Sealant width, D = Sealant depth,
EXPANSION JOINTS - The minimum width and depth of any sealant application should be 1/4 in. x 1/4 in. (6mm x 6mm).
The depth (D) of sealant may be equal to the width (W) of joints that are less than 1/2 in. wide. For joints ranging from 1/2 in. to 1 in. (13mm to 25mm) wide, the sealant depth should be approximately one-half of the joint width.
The maximum depth (D) of any sealant application should 1/2 in. (13mm). For joints that are wider than 1in. (25mm) contact your local Tremco Sales Representative or Tremco Technical Services.
Surface PreparationsSurfaces must be sound and clean. All release agents, existing waterproofing, dust, loose mortar, laitance, paints, or other finishes must be removed. This can be accomplished with a thorough wire brushing, grinding, sandblasting, or solvent washing, depending on the contamination.
Tremco recommends that surface temperatures be 40˚ F (5˚ C) or above at the time the sealant is applied. If sealant must be applied in temperatures below 40˚ F, please refer to the Tremco Guide for Applying Sealants in Cold Weather that can be found on our website at www.tremcosealants.com.
PrimingWhere deemed necessary, use Vulkem Primer #191 Low-VOC for porous surfaces, and TREMprime Non-Porous Primer for metals. Vulkem 45SSL typically adheres to concrete and stone without primers; however, Tremco always recommends that a mock-up or field adhesion test be performed on the actual materials being used on the job to verify the need for a primer. A description of the field adhesion test can be found in appendix X1 of ASTM C1193, Standard Guide for Use of Joint Sealants.
ApplicationVulkem 45SSL is easy to apply with conventional caulking equipment. Ensure that the backer rod is friction fitted properly
to provide the proper width-to-depth ratio and any primers have been applied. Fill the joint completely from the backer rod up, and allow the sealant to self-level to a smooth, even finish. For a cleaner finish, mask the sides of the joint with tape prior to filling.
Cure TimeAt 75° F (23.9° C), 50% R.H. a skin forms within 5 hours. Curing continues at a rate of approximately 1/16 in. (1.6mm) depth per day. The cure time will increase as the temperature and/or humidity decrease. A good rule of thumb is one additional day of cure for every 10° F decrease in temperature. Cure time can be increased by adding water when using pails of Vulkem 45SSL. Please refer to the Technical Bulletin on Vulkem 45SSL Activator that can be found on our website at www.tremcosealants.com.
Damp/Green ConcreteVulkem 45SSL can be applied to green concrete 24 hours after the forms have been removed. All concrete sealers or curing agents need to be removed by grinding before applying sealant. The concrete can be damp during application, but do not apply sealant where there is standing water in or close to the joints. It is recommended to catalyze with water when applying sealant on damp surfaces.
Clean upExcess sealant adjacent to the joint interface can be carefully removed with xylene or mineral spirits before the sealant cures. Any utensils used for tooling can also be cleaned with xylene or mineral spirits.
Limitations• Do not apply over contaminated surfaces.• Do not use in immersed conditions that contain chlorinated water.• Use with adequate ventilation.• Always utilize the accompanying MSDS for information on Personal Protective Equipment (PPE) and health hazards.
WarrantyTremco warrants its Products to be free of defects in materials, but makes no warranty as to appearance or color. Since methods of application and on-site conditions are beyond our control and can affect performance, Tremco makes no other warranty, expressed or implied including warranties of MERCHANTABILITY and FITNESS FOR A PARTICULAR PURPOSE, with respect to Tremco Products. Tremco’s sole obligation shall be, at its option, to replace or refund the purchase of the quantity of Tremco Products proven to be defective and Tremco shall not be liable for any loss or damage.
Tested system numbers FF-D-1062 and FW-D-1058
Please refer to our website at www.tremcosealants.com for the most up-to-date Product Data Sheets.
Tremco Commercial Sealants & Waterproofing3735 Green Road, Beachwood, OH 44122 // Phone: 216.292.5000 // 800.321.7906
220 Wicksteed Avenue, Toronto, ON M4H 1G7 // Phone: 416.421.3300 // 800.363.32131451 Jacobson Avenue, Ashland OH 44805 // Phone: 419.289.2050 // 800.321.6357
www.tremcosealants.com
We certify that Vulkem® 45 SSL has been tested against ASTM C 920, Standard Specification for Elastomeric Joint Sealants and does conform to the specification requirements and is classified as follows:
Type: S (Single Component) Grade: P (Pourable) Class: 35 (+/ - 35% joint movement) Use: T (Traffic)
M (Mortar) A (Aluminum) O (Other) I (Immersion Service – Class 2).
We further certify that Vulkem 45 SSL conforms to the requirements of Federal Specification TT-S-00230C, Type I, Class A. Vulkem 45 SSL meets CAN/CGSB 2-19.13, MC-1-25 B-N. Although Vulkem 45 SSL is not NSF registered, or previously authorized by USDA, it does meet the requirements for use in Federally inspected food processing facilities provided it is not used in areas where food is being processed, prepared or packaged. The material must also be applied in a manner which prevents any direct or indirect contamination of food. Additionally, before any food product can be placed in the area of treatment, the sealant must be allowed to cure according to manufacturer’s recommendations and the area should be sufficiently free of odor to prevent food contamination. Vulkem 45 SSL may be used in registered establishments operating under the Canadian Food Inspection Agency. The Canadian Food Inspection Agency has approved Vulkem 45 SSL for use in CFIA regulated facilities for situations involving non food contact. In addition, Vulkem 45 SSL is listed with Underwriters Laboratories in the following systems:
FF-D-1062 FW-D-1058 HW-D-1053 WW-D-1053
Rev. 03/31/15
Dymeric ® 240FCHigh Performance Multi-Component Polyurethane SealantProduct DescriptionDymeric® 240FC is a gun grade, multi-component, chemically curing, polyurethane sealant that includes a tintable base, curative packet, and a choice of 70 standard colors. A Limestone Pretinted version is available.
Basic UsesDymeric 240FC applications range from pre-cast tilt-up concrete, masonry, and exterior insulating and finishing systems (EIFS), to metal curtain walls, and perimeter joints around doors and windows. It can also be used in certain water immersion applications.
Features and BenefitsDymeric 240FC is an all around general-purpose sealant that provides flexible, long life and durable waterproofing for both new construction and restoration projects in a fast curing formulation. Dymeric 240FC is formulated to be a lightweight material designed for extremely easy mixing, even in cold temperatures. Dymeric 240FC is a solvent-free product that is compliant with all existing VOC regulations. Please contact your local Sales Representative or Tremco’s Technical Service Department for information regarding immersed conditions.
ColorsDymeric 240FC is available as a base and curative that can be tinted to your choice of 70 standard colors, or we can match a special color for you. A color pak is not required for the pretint version.
Packaging1.5 ga (5.7 L) and 3 gal (11.4 L) kits with pre-measured pouches of curing agent. Pretint in 1.5 gallons (5.7 L) only.
Coverage Rates308 feet of joint per gal for a 1/4” x 1/4” joint. For specific
coverage rates that include joint size, and usage efficiencies, visit our website usage calculator at www.tremcosealants.com.
Fire-Rated SystemsFF-D-1061, FF-S-1030, FW-D-1057, FW-S-1014, HW-D-1052, HW-S-1011, WW-D-1052, WW-S-1033
Applicable StandardsDymeric 240FC meets or exceeds the requirements of the following specifications:
• ASTM C920-02 Type M, Grade NS, Class 50, Use I (Class 2), T, NT, M, A and O (granite)
• U.S. Federal Specification TT-S-00227E Class A, Type II • CAN/CGSB 19.24-M90 Class B, Type II
Joint DesignDymeric 240FC may be used in any vertical or horizontal joint designed in accordance with accepted architectural/engineering practices. Joint width should be 4 times anticipated movement, but not less than 1/4” (6.4 mm).
Joint BackingClosed cell or reticulated polyethylene backer rod is recommended as joint backing to control sealant depth and to ensure intimate contact of sealant with joint walls when tooling. Where depth of joint will prevent the use of backer rod, an adhesive backed polyethylene tape (bond breaker tape) should be used to prevent three-sided adhesion. All backing should be dry at time of sealant application.
Pot Life (after curative packet added)3.0-3.5 hr at 77 °F (25 °C) 1.5-2.0 hr at 95 °F (35 °C) 1.0-1.5 hr at 120 °F (48.9 °C)
Page 1 of 2
TYPICAL PHYSICAL PROPERTIESProperty Test Method Typical ValueLow Temperature Flexibility ASTM C793 Passes at -65 ˚F (-54 ˚C) Hardness, durometer scale “A” ASTM C661 30 ±3Weight Loss ASTM C1246 PassesSkin Time (tooling time) 3 hrTack Free Time ASTM C679 19 hrStain & Color Change ASTM C510 No stain, No color changeAdhesion-in-Peel ASTM C794 >10 pli (pass)Accelerated Weathering ASTM C793 PassMovement Capability ASTM C719 modified ±50%
www.tremcosealants.com
1014/DYMERIC240FCSD Page 2 of 2
Sealant DimensionsW = Sealant width, D = Sealant depth, C = Contact area.
EXPANSION JOINTS - The minimum width and depth of any sealant application should be 1/4” x 1/4” (6 mm x 6 mm).
The depth (D) of sealant may be equal to the width (W) of joints that are less than 1/2” wide. For joints ranging from 1/2” to 1” (13 mm to 25 mm) wide, the sealant depth should be approximately one-half of the joint width.
The maximum depth (D) of any sealant application should be 1/2” (13 mm). For joints that are wider than 1” (25 mm) contact Tremco’s Technical Service Department, or your local Tremco field representative.
WINDOW PERIMETERS – For fillet beads, or angle beads around windows and doors, the sealant should exhibit a minimum surface contact area (C) of 1/4” onto each substrate.
Surface PreparationsSurfaces must be sound, clean, and dry. All release agents, existing waterproofing, dust, loose mortar, laitance, paints, or other finishes must be removed. This can be accomplished with a thorough wire brushing, grinding, sandblasting, or solvent washing, depending on the contamination.
Tremco recommends that surface temperatures be 40 ˚F (5 ˚C) or above at the time the sealant is applied. If sealant must be applied in temperatures below 40 ˚F, please refer to the Tremco Guide for Applying Sealants in Cold Weather that can be found on our website at www.tremcosealants.com.
PrimingWhere deemed necessary, use Tremco Primer #171 for porous substrates and TREMprime Non-Porous Primer for metals and plastics. Dymeric 240FC typically adheres to common construction substrates without primers; however, Tremco always recommends that mock-up or field adhesion test be performed on the actual materials being used on the job to verify the need for a primer. The field adhesion test can be found in appendix X1 of ASTM C1193, Standard Guide for Use of Joint Sealants.
ApplicationMix in accordance with instructions on the pail using the entire pre-measured curative packet and your selected Universal Color Pak. One color pack should be used with 1.5-gal pails and 2 color packs should be used in the 3-gal pails. Mix all three parts for a minimum of 6 minutes, scrapping the sides of the pail and until there are no color striations. A color pak is not required for the pretint version.
Ensure the backer rod is friction fitted properly and any primers have been applied. Apply sealant with conventional caulking equipment filling the joint from the backer rod up. Immediately tool the sealant with a spatula to ensure intimate contact with the joint walls. Dry tooling is always preferred, although xylene can be used in limited amounts to slick the spatula if needed.For a cleaner finish, mask the sides of the joint with tape prior to filling.
Cure Time:At 72 ˚F (22 ˚C) Dymeric 240FC will reach full cure in about 48 hours. As the temperatures decrease, the cure time will increase. A good rule of thumb is an additional 24 hours for every 10°F decrease in temperature.
Clean upExcess sealant and smears adjacent to the joint interface can be carefully removed with xylene or mineral spirits before the sealant cures. Any utensils used for tooling can also be cleaned with xylene or mineral spirits.
Limitations• Do not apply Dymeric 240FC to damp or contaminated surfaces.• Always utilize the accompanying MSDS for information on Personal Protective Equipment (PPE) and health hazards.• For best results, always use a Universal Color Pak.
WarrantyTremco warrants its sealants to be free of defects in materials, but makes no warranty as to appearance or color. Since methods of application and on-site conditions are beyond our control and can affect performance, Tremco makes no other warranty, expressed or implied including warranties of MERCHANTABILITY and FITNESS FOR A PARTICULAR PURPOSE, with respect to Tremco sealants. Tremco’s sole obligation shall be, at its option, to replace or refund the purchase of the quantity of Tremco sealant proven to be defective and Tremco shall not be liable for any loss or damage.
UL Tested Systems FF-D-1061, FF-S-1030, FW-D-1057, FW-S-1014, WW-D-1052, WW-S-1033, HW-D-1052, HW-S-1011
Please refer to our website at www.tremcosealants.com for the most up-to-date Product Data Sheets.
Tremco Commercial Sealants & Waterproofing3735 Green Road, Beachwood, OH 44122 // Phone: 216.292.5000 // 800.321.7906
220 Wicksteed Avenue, Toronto, ON M4H 1G7 // Phone: 416.421.3300 // 800.363.32131451 Jacobson Avenue, Ashland OH 44805 // Phone: 419.289.2050 // 800.321.6357
www.tremcosealants.com
We certify that Dymeric® 240FC has been tested against ASTM C 920, Standard Specification for Elastomeric Joint Sealants and does conform to the specification requirements. Dymeric 240FC is classified as follows:
Type: M (Multi-Component) Grade:NS (Non-sag) Class: 50 (+/ - 50% modified ASTM C719) Use: T (Traffic)
M (Mortar) A (Aluminum) O (Other) I (Immersion Service, Class II)
Although Dymeric 240FC is not NSF registered, or previously authorized by USDA, it does meet the requirements for use in Federally inspected food processing facilities provided it is not used in areas where food is being processed, prepared or packaged. The material must also be applied in a manner which prevents any direct or indirect contamination of food. Additionally, before any food product can be placed in the area of treatment, the sealant must be allowed to cure according to manufacturer’s recommendations and the area should be sufficiently free of odor to prevent food contamination. Dymeric 240FC may be used in registered establishments operating under the Canadian Food Inspection Agency. The Canadian Food Inspection Agency has approved Dymeric 240FC for use in CFIA regulated facilities for situations involving non food contact. In addition, Dymeric 240FC is listed with Underwriters Laboratories in the following systems:
FF-S-1030 FW-D-1057 FW-S-1014 WW-D-1052 HW-D-1052 HW-S-1011
Rev. 09/26/14
Product Information
SiliconeSealants
FEATURES• Cured sealant is mildew resistant• Remains permanently flexible
without shrinking, cracking,crumbling or drying out
• Resists staining, spotting and colorchanges
• Resists moisture and free steam• Retains original design properties
even after years of exposure
COMPOSITION• One-part, acetoxy-cure silicone
rubber sealant
Dow Corning® 786Silicone Sealant
Silicone rubber sealant for nonporous surfaces, showers, tubs,sinks and plumbing fixtures
APPLICATIONSDow Corning® 786 Silicone Sealant is designed to seal nonporous surfaces aroundshowers, tubs, sinks and plumbing fixtures where conditions of high humidity andtemperature extremes exist. Typical applications include:• Sealing around shower-tub enclosures, tubs, sinks, urinals and whirlpools• Sealing around bathroom fixtures• Waterproofing rimless sinks• Ceramic tile grouting
TYPICAL PROPERTIESSpecification Writers: Please contact your local Dow Corning Sales Application Engineeror Dow Corning Customer Service before writing specifications on this product.
Method Test Unit Result
As SuppliedASTM C 679 Tack-Free Time
at 25°C (77°F), 50% RH minutes 20Tooling Time minutes 5-11
ASTM C 639 Flow, sag or slump NilColor White, transparent white,
almond, clear, grayApplication Temperature Range °C (°F) -37 to 60 (-35 to 140)VOC Content1 g/L 33
As Cured – 7 days at 25°C (77°F) and 50% RHASTM D 2240 Durometer Hardness, Shore A points 25ASTM D 412 Ultimate Tensile Strength, psi (MPa) 325 (2.1)ASTM D 624 Tear Strength ppi (kN/m) 25 (4.4)ASTM C 794 Peel Strength pli (kN/m) 20 (3.5)ASTM C 603 Extrusion Rate g/min 3501Based on South Coast Air Quality Management District of California. Maximum VOC is listed both inclusive andexclusive of water and exempt compounds. For a VOC data sheet for a specific sealant color, please send your requestto [email protected].
DESCRIPTIONDow Corning 786 Silicone Sealant is asingle-component, ready-to-usesilicone rubber sealant. The sealantadheres to many nonporous surfaces,such as porcelain, cultured marble,marble, painted areas and glass,without the use of a primer.
Cured Dow Corning 786 SiliconeSealant is mildew resistant even inprolonged hot and humid environments.
Dow Corning 786 Silicone Sealant isavailable in white and transparent.
Dow Corning 786 Silicone Sealantis compatible with most substrates.However, adhesion and compatibilityshould be evaluated in each instanceprior to use.
Primers: Primers are not usuallyrequired on ceramic, glass and glazedsurfaces. It is possible that certain
products should be primed formaximum adhesion. A recommendedprimer for use with metals, formicaand plastics is Dow Corning® 1200Prime Coat. Refer to the SurfacePreparation Guide, No. 61-182, formore specific recommendations. Incases where doubt exists, a sampleshould be tested before full-scale use.
APPROVALS/SPECIFICATIONSDow Corning 786 Silicone Sealantmeets the qualifications of:• ASTM C 920, Type S, Grade NS,
Class 25, Use NT, when tested toglass and aluminum
• Canadian Specification CGSB19-GP-22M
• FDA Regulation No. 21 CFR177.2600 (subject to end usecompliance with any applicabletotal extractives limitations)
• National Sanitation FoundationStandard 51
HOW TO USEPlease consult the Dow CorningAmericas Technical Manual, Form No.62-1112, for detailed information onstate-of-the-art application methodsand joint design. Please contact yourlocal Dow Corning Sales ApplicationEngineer for specific advice.
Preparatory WorkBonding surfaces on both new andremedial jobs must be sound, clean,dry, and free of dust, frost and soapresidue.
Wipe the surfaces using a clean, oil-free rag saturated with solvent such asxylol, toluol or methyl ethyl ketone.
CAUTION: When using flammablesolvents, keep away from heat andopen flames. Use only with adequateventilation. Avoid prolonged or
repeated skin contact. Always followsolvent container label instructions.
Do not flood surfaces with moresolvent than necessary. Do not cleansurfaces with soap, detergent or anywater-based cleaner. Make sure thatapparently clean surfaces are notcovered with a thin film ofconstruction dust.
PrimingAlthough primers are not usuallyrequired on ceramic, glass and glazedsurfaces, it is possible that certainproducts should be primed formaximum adhesion. A bead of thesilicone sealant on the substratematerial to test adhesion prior togeneral job use is alwaysrecommended.
MaskingIf bead lines of exact shapes arerequired, use masking tape beforeapplying Dow Corning 786 SiliconeSealant. Remove immediately after abead is completed and before a “skin”forms (5-10 minutes).
ApplicationDow Corning 786 Silicone Sealantcan be applied directly from thecaulking cartridge with either an air-operated or hand-operated cartridgegun. Do not break the cartridge sealuntil just before use.
After applying the sealant and a skinhas formed, do not disturb the joint for48 hours. A previously openedcartridge may be reused by removingthe cured plug of sealant from the tip.
ToolingTooling is recommended and, ifpossible, should be completed in onecontinuous stroke.
Tool the joints within 10 minutes ofapplication. Remove masking tapebefore a surface skin begins to form.Once a surface skin begins to form, itwill be torn off when the tape isremoved, leaving a rough surface.
Clean-UpExcess sealant should be cleaned offtools and nonporous surfaces while itis in the uncured state, by using acommercial solvent such asxylol, toluol or methyl ethyl ketone.
MaintenanceCured sealant can be cleaned withsoap and water. If sealant becomesdamaged, replace damaged portion.
HANDLING PRECAUTIONSPRODUCT SAFETY INFORMATIONREQUIRED FOR SAFE USE IS NOTINCLUDED IN THIS DOCUMENT.BEFORE HANDLING, READ PROD-UCT AND MATERIAL SAFETYDATA SHEETS AND CONTAINERLABELS FOR SAFE USE, PHYSICALAND HEALTH HAZARD INFOR-MATION. THE MATERIAL SAFETYDATA SHEET IS AVAILABLE ONTHE DOW CORNING WEBSITE ATWWW.DOWCORNING.COM, ORFROM YOUR DOW CORNINGSALES APPLICATION ENGINEER,OR DISTRIBUTOR, OR BY CALL-ING DOW CORNING CUSTOMERSERVICE.
USABLE LIFE ANDSTORAGEWhen stored in original unopenedcontainers at or below 32°C (90°F),Dow Corning 786 Silicone Sealant hasa shelf life of 30 months from date ofmanufacture. Refer to productpackaging for “Use By” date.
PACKAGINGDow Corning 786 Silicone Sealant issupplied in 10.3-fl oz (305-mL)cartridges.
LIMITATIONSDow Corning 786 Silicone Sealant isnot recommended for use inapplications involving:• Structural silicone glazing• Floor joints where physical abuse
or abrasion is likely to beencountered
• Prolonged water immersion• Porous surfaces, such as masonry• Building materials that might bleed
oils or solvents – materials such asimpregnated wood, partiallyvulcanized rubber gaskets or tapesor adhesives
• Totally confined spaces, becausethe sealant requires atmosphericmoisture for cure
• Surfaces sensitive to corrosion byacetic acid vapors (a byproduct ofsealant cure)
This product is neither tested norrepresented as suitable for medicalor pharmaceutical uses.
SHIPPING LIMITATIONSNone.
HEALTH ANDENVIRONMENTALINFORMATIONTo support customers in their productsafety needs, Dow Corning has anextensive Product Stewardship organ-ization and a team of Product Safetyand Regulatory Compliance (PS&RC)specialists available in each area.
For further information, please seeour website, www.dowcorning.com,or consult your local Dow CorningSales Application Engineer.
AVAILABILITYDow Corning 786 Silicone Sealantis marketed throughout the Americasthrough construction distributors andbuilding supply outlets.
LIMITED WARRANTYINFORMATION – PLEASEREAD CAREFULLYThe information contained herein isoffered in good faith and is believedto be accurate. However, becauseconditions and methods of use of ourproducts are beyond our control, thisinformation should not be used insubstitution for customer’s tests toensure that Dow Corning’s productsare safe, effective, and fully satis-factory for the intended end use.Suggestions of use shall not be takenas inducements to infringe any patent.
Dow Corning’s sole warranty is thatthe product will meet the Dow Corningsales specifications in effect at thetime of shipment.
Your exclusive remedy for breach ofsuch warranty is limited to refund ofpurchase price or replacement of anyproduct shown to be other than aswarranted.
DOW CORNING SPECIFICALLYDISCLAIMS ANY OTHER EXPRESSOR IMPLIED WARRANTY OFFITNESS FOR A PARTICULARPURPOSE OR MERCHANTABILITY.
DOW CORNING DISCLAIMSLIABILITY FOR ANY INCIDENTALOR CONSEQUENTIAL DAMAGES.
A 10-year General Product LimitedWarranty is available. Some testingmay be required. Consult yourDow Corning Sales ApplicationEngineer for details.
Printed in USA Dow Corning is a registered trademark of Dow Corning Corporation.Form No. 61-974J-01 AGP7868 ©2000-2005 Dow Corning Corporation. All rights reserved.
Backer Rod Mfg. Inc. March 2014
TECHNICAL DATA SHEET
MMIILLEE HHIIGGHH FFOOAAMM® CLOSED CELL POLYETHYLENE BACKER ROD
1. PRODUCT NAME
MILE HIGH FOAM®
2. EXCLUSIVELY SOLD BY
Backer Rod Mfg. Inc. 4244 N. Broadway Denver, CO 80216 Phone: 800-595-2950 Fax: 303-308-0393 Web: www.backerrod.com
3. PRODUCT DESCRIPTION
Per ASTM C 1330 type C Mile High Foam® is a resilient, polyethylene backer rod used as a backing material for cold applied elastomeric caulking sealants. Mile High Foam® controls the depth of the sealant installation and ensures cross – sectional hour-glass configuration. No bond breaker is required. Specific Uses Include:
Expansion joints Highway joints Glazing Log home chinking Parking Decks Curtain walls Coping joints Isolation joints Temporary joint seal
4. COMPOSITION AND MATERIAL Mile High Foam® is a round, black, resilient, extruded closed cell polyethylene backer rod with a water resistant outer skin. It is compatible with most known cold applied sealants such as urethane, silicone, acrylic, butyl, polysulfide, latex, and log chinking sealants.
5. INSTALLATION Joint openings must be free of all contaminants, loose materials, dry and free of frost. Select correct rod size for joint width. With a blunt instrument or roller, seat rod to depth recommended by sealant manufacturer.
6. COMPATIBILITY Mile High Foam® is chemically inert and will resist gasoline, oil, and most solvents. Product will not stain or adhere to sealants.
SEALANT
MILE HIGH FOAM
Backer Rod Mfg. Inc. March 2014
11. LIMITATIONS Do not use with hot applied sealants. Do not puncture, over compress or stretch MILE HIGH FOAM during installation.
12. AVAILABILITY AND COST MILE HIGH FOAM is marketed nationally and internationally by select authorized distributors. For name, address and telephone number of your nearest distributor please contact us at: 800-595-2950 or [email protected]
MADE IN THE U.S.A.
13. WARRANTY Unless otherwise agreed to in writing, MILE HIGH FOAM is sold without warranty, express or implied. Buyer must make their own determination as to the suitability of the product and application. Sizes and lengths of product shown are at time of packaging and will vary with climate conditions after manufacture.
14. TECHNICAL SERVICES Please contact Backer Rod Mfg. Inc. for technical guidance, special project engineering designs and drawings.
7. PHYSICAL PROPERTIES
Physical Properties
Property Value ASTM Test
Method
Density (nominal) 1.25 - 2 lb/ft³ D 1622 Out-gassing > 1 C 1253 Compression Recovery > 90 D 5249 Tensile Strength PSI 39 – 50 PSI D 1623 Temperature Range -90°F to 210°F D 5249 Water Absorption 0.002 g/cm³ C 1016 – Proc. B
8. PACKAGING INFORMATION
Packaging Information Linear Feet Per Unit / (metric) Weights and Measurements
Diameter Mini Box Standard Box Super Box Mini Carton 18-1/4" x 18-1/4" x 15" 5 lbs ea. 1/4" (6mm) 2500 (762m) 6400 (1951m) 3/8" (10mm) 1400 (427m) 3600 (1097m) Standard Carton 18-1/4" x 18-1/4" x 30-1/2" 10 lbs ea. 1/2" (13mm) 800 (244m) 2500 (762m) 5/8" (16mm) 550 (168m) 1550 (472m) Super Carton 13-3/4" x 13-3/4" x 74-1/4" 14 lbs ea. 3/4" (19mm) 400 (122m) 1100 (335m) 7/8" (22mm) 850 (257m) Mini Carton 1" (25mm) 550 (168m) ● 1 spool per carton
1-1/4" (32mm) 400 (122m) Standard Carton 1-1/2" (38mm) 420 (128m) ● 1/4" through 3/4" 2 spools per carton
2" (51mm) 252 (77m) ● 7/8” through 1-1/4" 1 spool per carton 2-1/2" (63mm) 162 (49m) Super Carton
3" (76mm) 102 (31m) ● 1-1/2" through 4" manufactured in 6' lengths
4" (102mm) 54 (16m)
9. LIMITATIONS Do not use with hot applied sealants. Do not puncture, over compress or stretch MILE HIGH FOAM® during installation.
10. AVAILABILITY AND COST MILE HIGH FOAM® is marketed nationally and internationally by select authorized distributors. For name, address and telephone number of your nearest distributor please contact us at: 800-595-2950 or [email protected]
11. WARRANTY Unless otherwise agreed to in writing, MILE HIGH FOAM® is sold without warranty, express or implied. Buyer must make their own determination as to the suitability of the product and application. Sizes and lengths of product shown are at time of packaging and will vary with climate conditions after manufacture.
12. TECHNICAL SERVICES Please contact Backer Rod Mfg. Inc. for technical guidance, special project engineering designs and drawings.
MADE IN THE U.S.A.
Backer Rod Mfg. Inc. Reply to: � 4244 N. Broadway • Denver, CO 80216 � 2929 Walker Drive • P.O. Box 8005 • Green Bay, WI 54308-9229 Phone 303-308-0363 • Fax 303-308-0393 Phone 920-406-4000 • Fax 920-406-4040
October 3, 2013
GENERAL CERTIFICATE OF COMPLIANCE
DESCRIPTION: BACKER ROD MFG. INC. SEALANT BACKING PRODUCTS
Denver foam
Titan Foam™
Mile High Foam
Mile High Foam XL™
Ultra Block
THESE PRODUCTS ARE TESTED TO AND MEET THE REQUIREMENTS OF THE FOLLOWING STANDARDS:
DENVER FOAM® TITAN FOAM™ MILE HIGH FOAM® MILE HIGH FOAM XL™ ULTRA BLOCK®
▪ ASTM D 1622 ▪ ASTM D 1622 ▪ ASTM D 1622 ▪ ASTM D 1622 ▪ ANSI/UL 2079
▪ ASTM D 1623 ▪ ASTM C 1253 ▪ ASTM C 1016 proc B ▪ ASTM D 1623 ▪ ASTM E 84
▪ ASTM C 1016 ▪ ASTM D 5249 type 3 ▪ ASTM C 1253 ▪ ASTM C 1016 proc B ▪ ASTM E 814
▪ ASTM D 5249 Type 1 ▪ ASTM D 1623 ▪ ASTM D 5249 type 3 ▪ ASTM D 5249 type 1 ▪ ASTM E 1399
▪ ASTM D 3574 ▪ ASTM C 1016 proc B ▪ ASTM D 1623 ▪ ASTM C 1253 ▪ ASTM E 119
▪ ASTM C 1330 Type O ▪ ASTM C 1330 type B ▪ ASTM C 1330 type C ▪ ASTM C 1330 type C ▪ ASTM C 719
▪ NFPA 251
▪ NFPA 255
No asbestos, PCB’s, or lead are used or contained in these products. All products are proudly
manufactured in the USA.
Bill Bergel
Sales, Marketing and Technical Services
White
Limestone
Gray
Aluminum Stone
Ivory
Buff
Anodized Aluminum
RedwoodTan
Black
Clear
Aluminum
Dark Bronze
Standard Colors
Vu
lkem
45SSl
Vu
lkem
445SSl
Bu
tyl S
ea
lan
t
tr
em
flex 8
34
tr
em
Sil 6
00
tr
em
Sil 2
00
Pr
og
laze
• Color deposits shown here are approximate.• Custom colors are available for most sealants. Please contact Tremco Customer Service for more information.
300m
L
Drums
300m
L
300m
L60
0mL
300m
L60
0mL
300m
L
890m
L
300m
L
890m
L
22
2
2
2
2
2
2
5
5
300m
L
890m
L
22
2
2
2
5
5
300m
L
300m
L
300m
L
300m
L
300m
L60
0mL
300m
L
300m
L
300m
L
300m
L
300m
L 5600m
L
300m
L
300m
L
300m
L
300m
L
300m
L
300m
L 5600m
L
300m
L
890m
L
300m
L 300 mL (10 fl. oz.) Cartridge 600m
L
600 mL (20.3 fl. oz.) Sausage
2 2 Gallon (7.57 Liters) Pail 5 5 Gallon (18.9 Liters) Pail
890m
L 850 mL (28.7 fl. oz.) Cartridge ‡
‡All Vulkem Products filled to 890 mL (30 fl. oz.) Comes in neutral, tintable base. Color paks available in additional colors.
890m
L
Legend: Icons above indicate standard product offering.
Specialty Construction Sealants Color Chart
For MSDS and Spec Data Sheets visit our website: www.tremcosealants.com
‡All Vulkem Products filled to 890 mL (30 fl. oz.) Comes in neutral, tintable base. Color paks available in additional colors.
Vulkem 45SSL Vulkem 45SSL is a one-part, semi-self-leveling, moisture curing, low modulus polyurethane sealant especially developed for sealing joints in level and/or slightly sloped surfaces. It is suitable for continuous immersion in non-chlorinated water and can be applied to damp concrete. For green concrete applications, Vulkem 45SSL can be applied as early as 24 hours after the concrete forms have been pulled.
Vulkem 445SSL Vulkem 445SSL is a multi-component, semi-self-leveling, moisture curing, low modulus polyurethane sealant that has the unique capability to adhere to damp or green concrete. Vulkem 445SSL provides exceptional wear and tear resistance in high traffic areas and is formulated for use in expansion joints in sidewalks, swimming pool decks, plazas and any other horizontal surface with slopes up to 6%.
Butyl Sealant Tremco Butyl Sealant is a one-part sealant for use in a variety of applications, such as corrugated sheet lap joints, curtainwall applications, bedding thresholds, secondary seals in glazing and where a seal is required against Tremco neoprene or EPDM gaskets.
Tremflex 834 Tremflex 834 is a pure acrylic sealant used for general purpose interior and exterior caulking and as a back-bedding glazing compound.
Tremsil 600 Tremsil 600 is a one-part, neutral cure, fast skinning, medium modulus silicone sealant. Tremsil 600 is ideal for use as an in-plant glazing sealant for applications that include back bedding, cap, heel and toe beads and sash joinery. It can also be used in a variety of commercial construction applications.
Tremsil 200 Tremsil 200 is a one-part, acetoxy silicone sealant that produces a weather-tight seal to glass, metal, porcelain, ceramic, and most painted surfaces. White contains a fungicide, making it suitable for use in bathrooms. Clear is available with or without a fungicide.
Proglaze Proglaze is a one-part, moisture curing, acetoxy silicone sealant. Proglaze provides a high-performance seal for a wide variety of glazing applications such as cap beads and metal-to-metal joints. Additional uses include a variety of in-plant applications.
Specialty Construction Sealants Color Chart
Tremco Commercial Sealants & Waterproofing3735 Green road, Beachwood, oh 44122 // Phone: 216.292.5000 // 800.321.7906
220 wicksteed avenue, toronto, on M4h 1G7 // Phone: 416.421.3300 // 800.363.32131451 JacoBson avenue, ashland oh 44805 // Phone: 419.289.2050 // 800.321.6357
0413SCSCCwww.tremcosealants.com
This guide only offers a general representation of our color offering. Colors viewed on a computer screen or printed will vary and will never be an exact representation of the actual pigment. When matching is critical, please refer to our color card or sample color strips.
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
1/7 445805A 333
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : VULKEM 45 SSL LIMESTONE QT CTG Product code : 445805A 333 COMPANY : Tremco Incorporated
3735 Green Road Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300 Product use : Sealant
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Limestone. Non-sag gunnable paste. May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel. Acute Potential Health Effects/ Routes of Entry
Inhalation : May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization.
Eyes : Direct contact may cause mild irritation. Ingestion : May cause gastrointestinal irritation, nausea, and vomiting. Skin : May cause sensitization resulting in irritation, itching and redness. Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function. Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver, kidney damage. Xylene overexposure may affect fetal development. Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis may result from breathing free silica. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (Group 2B) based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. Fillers are encapsulated and not expected to be released from product under normal conditions of use. Prolonged or repeated exposure to mineral spirits (petroleum naphtha or stoddard solvent) may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system (CNS) effects, and adverse liver, kidney, and lung effects.
Target Organs: Skin, Eye, Ingestion, Lung
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
2/7 445805A 333
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Polyurethane Polymer NJ TSRN# 51721300-5358P 15.0 - 40.0 ASEP 70775-94-9 15.0 - 40.0 Calcium Carbonate (Limestone) 1317-65-3 15.0 - 40.0 Polyvinyl chloride 9002-86-2 15.0 - 40.0 Stoddard solvent (Mineral Spirits) 8052-41-3 5.0 - 10.0 Titanium dioxide 13463-67-7 3.0 - 7.0 Calcium oxide 1305-78-8 1.0 - 5.0 Xylene 1330-20-7 1.0 - 5.0 Isophorone Diisocyanate 4098-71-9 0.1 - 1.0 Ethylbenzene 100-41-4 0.1 - 1.0 Hydrotreated heavy naphthenic distillate 64742-52-5 0.1 - 1.0 1,2,4-Trimethylbenzene 95-63-6 0.1 - 1.0 Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 0.1 - 1.0 Aluminum oxide 1344-28-1 0.1 - 1.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 93 °C, > 199 °F Method : Setaflash Closed Cup Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion products
: Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for firefighters
: Use accepted fire fighting techniques. Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA).
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
3/7 445805A 333
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep container closed when not in use. Since emptied containers retain product residue and vapor, observe precautions even after container is emptied. Store under dry warehouse conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or supplied air respirator when airborne contaminant level(s) are expected to exceed exposure limits indicated on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate (Limestone)
1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction. OSHA PEL: 15 mg/m3 Total dust. ACGIH TWA: 3 mg/m3 Respirable particles. ACGIH TWA: 10 mg/m3 Inhalable particles. OSHA TWA: 15 mg/m3 Total dust. OSHA TWA: 5 mg/m3 Respirable fraction.
Polyvinyl chloride 9002-86-2 ACGIH TWA: 1 mg/m3 Respirable fraction. OSHA PEL: 5 mg/m3 Respirable fraction. OSHA PEL: 15 mg/m3 Total dust. OSHA TWA: 5 mg/m3 Respirable fraction. OSHA TWA: 15 mg/m3 Total dust.
Stoddard solvent (Mineral Spirits)
8052-41-3 ACGIH TWA: 100 ppm OSHA PEL: 2,900 mg/m3
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
4/7 445805A 333
Chemical Name CAS Number Regulation Limit Form
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3 OSHA PEL: 15 mg/m3 Total dust. OSHA TWA: 15 mg/m3 Total dust. OSHA TWA: 5 mg/m3 Respirable fraction.
Calcium oxide 1305-78-8 ACGIH TWA: 2 mg/m3 OSHA PEL: 5 mg/m3 OSHA TWA: 15 mg/m3 Total dust. OSHA TWA: 5 mg/m3 Respirable fraction.
Xylene 1330-20-7 ACGIH TWA: 100 ppm ACGIH STEL: 150 ppm OSHA PEL: 435 mg/m3
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Non-sag gunnable paste
Color : Limestone
Odor : Petroleum Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Insoluble
Specific Gravity : 1.32
% Volatile Weight : 7 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong acids.Strong bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Xylene, CAS-No.: 1330-20-7 Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg (
Rat ) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse ) Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
5/7 445805A 333
Isophorone Diisocyanate, CAS-No.: 4098-71-9 Acute oral toxicity (LD-50 oral) 2,500 mg/kg ( Mouse ) 1,000 mg/kg ( Rat ) Acute inhalation toxicity (LC-50) 0.033 mg/l for 4 h ( Rat ) 0.123 mg/l for 4 h ( Rat ) Acute dermal toxicity (LD-50 dermal) 1,060 mg/kg ( Rat )
Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 5,460 mg/kg ( Rat ) 3,500 mg/kg ( Rat ) Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Dispose of in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
CFR / DOT: Not Regulated
TDG: Not Regulated
IMDG: Not Regulated
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory. This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : Xylene 1330-20-7 Ethylbenzene 100-41-4
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
Fire Hazard
OSHA Hazardous Components :
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
6/7 445805A 333
Calcium Carbonate (Limestone) 1317-65-3 Polyvinyl chloride 9002-86-2 Stoddard solvent (Mineral Spirits) 8052-41-3 Titanium dioxide 13463-67-7 Calcium oxide 1305-78-8 Xylene 1330-20-7 Isophorone Diisocyanate 4098-71-9 Ethylbenzene 100-41-4 Hydrotreated heavy naphthenic distillate 64742-52-5 1,2,4-Trimethylbenzene 95-63-6 Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 Aluminum oxide 1344-28-1
OSHA Status: Considered hazardous based on the following criteria:
: Irritant Carcinogen
OSHA Flammability : IIIA
Regulatory VOC (less water and exempt solvent)
: 103 g/l
VOC Method 310 : 7 %
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen: Hydrotreated heavy naphthenic distillate 64742-52-5 Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3 Stoddard solvent (Mineral Spirits) 8052-41-3 Calcium oxide 1305-78-8 Xylene 1330-20-7 Isophorone Diisocyanate 4098-71-9 Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 Benzene 71-43-2 Vinyl chloride 75-01-4 Phenol 108-95-2
Penn RTK Components : Polyurethane Polymer NJ TSRN# 51721300-5358P ASEP 70775-94-9 Calcium Carbonate (Limestone) 1317-65-3 Polyvinyl chloride 9002-86-2 Stoddard solvent (Mineral Spirits) 8052-41-3 Titanium dioxide 13463-67-7 Calcium oxide 1305-78-8 Xylene 1330-20-7
NJ RTK Components : Polyurethane Polymer NJ TSRN# 51721300-5358P ASEP 70775-94-9 Calcium Carbonate (Limestone) 1317-65-3 Polyvinyl chloride 9002-86-2 Stoddard solvent (Mineral Spirits) 8052-41-3 Titanium dioxide 13463-67-7 Calcium oxide 1305-78-8 Xylene 1330-20-7
Material Safety Data Sheet
VULKEM 45 SSL LIMESTONE QT CTG Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
7/7 445805A 333
Hydrotreated heavy naphthenic distillate 64742-52-5 Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Components under California Proposition 65: WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other
reproductive harm
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammability 2
Reactivity 0
PPE
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol Legend ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act
RCRA - Resource Conservation and Recovery Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
OSHA - Occupational Safety and Health Administration
Material Safety Data Sheet
Dymeric 240 FC Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
1/16 862240 802
This is a kit that contains the following components:
DYMERIC 240 FC DYMERIC 240 FC CURATIVE
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
3/16 800000051684 862240 802
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : DYMERIC 240 FC Product code : 862240 802 COMPANY : Tremco Incorporated
3735 Green Road Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300 Product use : Sealant
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Off-White. Non-sag gunnable paste. May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel. Acute Potential Health Effects/ Routes of Entry
Inhalation : May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization.
Eyes : Direct contact may cause mild irritation. Ingestion : May cause gastrointestinal irritation, nausea, and vomiting. Skin : May cause sensitization resulting in irritation, itching and redness. Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function. Prolonged or repeated exposure to butyl benzyl phthalate may cause reduced body weights and adverse effects on the liver, kidney, spleen, pancreas, and reproductive organs. The International Agency for Research on Cancer (IARC) has classified ceramic fiber, fibrous glasswool, and mineral wool (rockwool and slagwool) as possible human carcinogens (Group 2B) based on sufficient evidence of carcinogenicity in animals but insufficient data in humans. In the National Toxicology Program's (NTP) 7th Annual Report on Carcinogens (1994), respirable glasswool was classified as reasonably anticipated to be carcinogenic. OSHA considers fibrous glass dust a nuisance dust. Fibrous glass can cause dermatitis, local irritation. Fillers are encapsulated and not expected to be released from product under normal conditions of use.
Target Organs: Skin, Eye, Ingestion, Lung
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
4/16 800000051684 862240 802
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Calcium carbonate 471-34-1 40.0 - 70.0 Polyol NJ TSRN# 517213--6317P 40.0 - 70.0 Fibrous Glass 65997-17-3 10.0 - 30.0 Calcium oxide 1305-78-8 1.0 - 5.0 Butyl benzyl phthalate 85-68-7 1.0 - 5.0 Hydrotreated heavy naphthenic distillate 64742-52-5 0.1 - 1.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available. Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion products
: Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for firefighters
: Use accepted fire fighting techniques. Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA).
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate container for disposal.
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
5/16 800000051684 862240 802
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep container closed when not in use. Since emptied containers retain product residue and vapor, observe precautions even after container is emptied. Store under dry warehouse conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or supplied air respirator when airborne contaminant level(s) are expected to exceed exposure limits indicated on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Fibrous Glass 65997-17-3 ACGIH TWA: 5 mg/m3 Inhalable fraction.
Calcium oxide 1305-78-8 ACGIH TWA: 2 mg/m3 OSHA PEL: 5 mg/m3 OSHA TWA: 15 mg/m3 Total dust. OSHA TWA: 5 mg/m3 Respirable fraction.
Hydrotreated heavy naphthenic distillate
64742-52-5 OSHA PEL: 2,000 mg/m3 OSHA PEL: 5 mg/m3 Mist. ACGIH TWA: 5 mg/m3 Inhalable fraction.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Non-sag gunnable paste
Color : Off-White
Odor : Mild Ester
pH : Not available.
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
6/16 800000051684 862240 802
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : NA
Specific Gravity : 0.966
% Volatile Weight : 0 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong acids.Strong bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Calcium carbonate, CAS-No.: 471-34-1 Acute oral toxicity (LD-50 oral) 6,450 mg/kg ( Rat )
Butyl benzyl phthalate, CAS-No.: 85-68-7
Acute oral toxicity (LD-50 oral) 13,500 mg/kg ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Dispose of in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
CFR / DOT: Not Regulated
TDG: Not Regulated
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
7/16 800000051684 862240 802
IMDG: Not Regulated
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory. This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
OSHA Hazardous Components :
Calcium carbonate 471-34-1 Fibrous Glass 65997-17-3 Calcium oxide 1305-78-8 Fibrous Glass 65997-17-3 Calcium oxide 1305-78-8 Butyl benzyl phthalate 85-68-7 Hydrotreated heavy naphthenic distillate 64742-52-5
OSHA Status: Considered hazardous based on the following criteria:
: Irritant Carcinogen
OSHA Flammability : Not Regulated
When appropriately mixed with the other part, product has a VOC less water and exempt solvent of: 5 g/l Regulatory VOC (less water and exempt solvent)
: 1 g/l
VOC Method 310 : 0 %
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen: Hydrotreated heavy naphthenic distillate 64742-52-5
U.S. State Regulations:
MASS RTK Components : Calcium carbonate 471-34-1 Fibrous Glass 65997-17-3 Calcium oxide 1305-78-8 Butyl benzyl phthalate 85-68-7 Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
8/16 800000051684 862240 802
Benzene 71-43-2
Penn RTK Components : Calcium carbonate 471-34-1 Polyol NJ TSRN# 517213--6317P Fibrous Glass 65997-17-3 Calcium oxide 1305-78-8 Butyl benzyl phthalate 85-68-7
NJ RTK Components : Calcium carbonate 471-34-1 Polyol NJ TSRN# 517213--6317P Fibrous Glass 65997-17-3 Calcium oxide 1305-78-8 Butyl benzyl phthalate 85-68-7 Hydrotreated heavy naphthenic
distillate 64742-52-5
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm:
65997-17-3 Fibrous Glass 85-68-7 Butyl benzyl phthalate 14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammability 1
Reactivity 0
PPE
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol Legend ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act
RCRA - Resource Conservation and Recovery Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
Material Safety Data Sheet
DYMERIC 240 FC
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
9/16 800000051684 862240 802
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
OSHA - Occupational Safety and Health Administration
Material Safety Data Sheet
DYMERIC 240 FC CURATIVE
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
11/16 800000051685 862240 802
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : DYMERIC 240 FC CURATIVE Product code : 862240 802 COMPANY : Tremco Incorporated
3735 Green Road Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300 Product use : Sealant
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Amber. Liquid solution. May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel. Acute Potential Health Effects/ Routes of Entry
Inhalation : May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization.
Eyes : Direct contact may cause mild irritation. Ingestion : May cause gastrointestinal irritation, nausea, and vomiting. Skin : May cause sensitization resulting in irritation, itching and redness. Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function. Organosilane may cause liver injury with fibrosis after repeated and prolonged overexposure. A long-term NTP study showed that oral exposure to toluene diisocyanate (TDI) caused cancer in rats and mice. A lifetime inhalation study sponsored by the International Isocyanate Institute did not show carcinogenic activity in rats. May cause allergic skin and respiratory sensitization. Fillers are encapsulated and not expected to be released from product under normal conditions of use.
Target Organs: Skin, Eye, Ingestion, Lung
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Material Safety Data Sheet
DYMERIC 240 FC CURATIVE
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
12/16 800000051685 862240 802
Polyurethane polymer NJ TSRN# 51721300-5028P > 60.0 2,4-Toluene diisocyanate 584-84-9 1.0 - 5.0 Toluene-2,6-Diisocyanate 91-08-7 0.1 - 0.5
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : > 200 °F, > 93 °C Method : Setaflash Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion products
: Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for firefighters
: Use accepted fire fighting techniques. Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA).
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep container closed when not in use. Since emptied containers retain product residue and vapor, observe precautions even after container is emptied. Store under dry warehouse conditions away from heat and all ignition sources.
Material Safety Data Sheet
DYMERIC 240 FC CURATIVE
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
13/16 800000051685 862240 802
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or supplied air respirator when airborne contaminant level(s) are expected to exceed exposure limits indicated on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm ACGIH STEL: 0.02 ppm
Toluene-2,6-Diisocyanate 91-08-7 ACGIH TWA: 0.005 ppm ACGIH STEL: 0.02 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid solution
Color : Amber
Odor : Mild
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Negligible
Specific Gravity : 1.06
% Volatile Weight : 1 %
Material Safety Data Sheet
DYMERIC 240 FC CURATIVE
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
14/16 800000051685 862240 802
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong acids.Strong bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
2,4-Toluene diisocyanate, CAS-No.: 584-84-9 Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat ) Acute inhalation toxicity (LC-50) 14 mg/l for 4 h ( Rat ) 10 mg/l for 4 h ( Mouse ) 13 mg/l for 4
h ( Guinea pig ) 11 mg/l for 4 h ( Rabbit )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Dispose of in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
CFR / DOT: Not Regulated
TDG: Not Regulated
IMDG: Not Regulated
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
Material Safety Data Sheet
DYMERIC 240 FC CURATIVE
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
15/16 800000051685 862240 802
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : 2,4-Toluene diisocyanate 584-84-9 Toluene-2,6-Diisocyanate 91-08-7
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
OSHA Hazardous Components :
2,4-Toluene diisocyanate 584-84-9 Toluene-2,6-Diisocyanate 91-08-7
OSHA Status: Considered hazardous based on the following criteria:
: Irritant Sensitizer
OSHA Flammability : Not Regulated
Regulatory VOC (less water and exempt solvent)
: 17 g/l
VOC Method 310 : 1 %
U.S. State Regulations:
MASS RTK Components : 2,4-Toluene diisocyanate 584-84-9 Toluene-2,6-Diisocyanate 91-08-7
Penn RTK Components : Polyurethane polymer NJ TSRN# 51721300-5028P 2,4-Toluene diisocyanate 584-84-9
NJ RTK Components : Polyurethane polymer NJ TSRN# 51721300-5028P 2,4-Toluene diisocyanate 584-84-9
WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or other reproductive harm:
584-84-9 2,4-Toluene diisocyanate 91-08-7 Toluene-2,6-Diisocyanate
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammability 1
Reactivity 0
PPE
Material Safety Data Sheet
DYMERIC 240 FC CURATIVE
Version 2.0 Print Date 07/09/2012 REVISION DATE: 07/08/2012
16/16 800000051685 862240 802
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol Legend ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act
RCRA - Resource Conservation and Recovery Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
OSHA - Occupational Safety and Health Administration
SAFETY DATA SHEET DOW CORNING(R) 786 SILICONE SEALANT - M US ALMOND
Version 1. 0
Revision Date: 02/10/2015
MSDS Number: 1281671-00001
Date of last issue: - Date of first issue: 02/10/2015
1 / 12
SECTION 1. IDENTIFICATION
Product name
: DOW CORNING(R) 786 SILICONE SEALANT - M US ALMOND
Product code
: 000000000002067765
Manufacturer or supplier's details Company name of supplier
: Dow Corning Corporation
Address
: South Saginaw Road Midland Michigan 48686
Telephone
: (989) 496-6000
Emergency telephone
: 24 Hour Emergency Telephone : (989) 496-5900 CHEMTREC : (800) 424-9300
Recommended use of the chemical and restrictions on use Recommended use
: Adhesive, binding agents
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Not a hazardous substance or mixture.
GHS Label element Not a hazardous substance or mixture. Precautionary Statements
: Prevention: P271 Use only outdoors or in a well-ventilated area.
Other hazards None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Silicone elastomer
Hazardous ingredients
Chemical Name CAS-No. Concentration (%) Silicon dioxide 7631-86-9 >= 5 - < 10 Titanium dioxide 13463-67-7 >= 0.1 - < 1
SECTION 4. FIRST AID MEASURES
SAFETY DATA SHEET DOW CORNING(R) 786 SILICONE SEALANT - M US ALMOND
Version 1. 0
Revision Date: 02/10/2015
MSDS Number: 1281671-00001
Date of last issue: - Date of first issue: 02/10/2015
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If inhaled
: If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact
: Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact
: Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
If swallowed
: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms and effects, both acute and delayed
: None known.
Protection of first-aiders
: No special precautions are necessary for first aid responders.
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing media
: None known.
Specific hazards during fire fighting
: Exposure to combustion products may be a hazard to health.
Hazardous combustion prod-ucts
: Carbon oxides Silicon oxides Formaldehyde
Specific extinguishing meth-ods
: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if nec-essary. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SAFETY DATA SHEET DOW CORNING(R) 786 SILICONE SEALANT - M US ALMOND
Version 1. 0
Revision Date: 02/10/2015
MSDS Number: 1281671-00001
Date of last issue: - Date of first issue: 02/10/2015
3 / 12
Personal precautions, protec-tive equipment and emer-gency procedures
: Follow safe handling advice and personal protective equip-ment recommendations.
Environmental precautions
: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
: Soak up with inert absorbent material. For large spills, provide diking or other appropriate contain-ment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor-bent. Local or national regulations may apply to releases and dis-posal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
: Use only with adequate ventilation.
Advice on safe handling
: Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage
: Keep in properly labeled containers. Store in accordance with the particular national regulations.
Materials to avoid
: Do not store with the following product types: Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients CAS-No. Value type (Form of exposure)
Control parame-ters / Permissible concentration
Basis
Silicon dioxide 7631-86-9 TWA (Dust) 20 Million particles per cubic foot
OSHA Z-3
SAFETY DATA SHEET DOW CORNING(R) 786 SILICONE SEALANT - M US ALMOND
Version 1. 0
Revision Date: 02/10/2015
MSDS Number: 1281671-00001
Date of last issue: - Date of first issue: 02/10/2015
4 / 12
(Silica) TWA (Dust) 80 mg/m3
/ %SiO2 (Silica)
OSHA Z-3
TWA 6 mg/m3 (Silica)
NIOSH REL
Titanium dioxide 13463-67-7 TWA (total dust)
15 mg/m3 OSHA Z-1
TWA 10 mg/m3 (Titanium dioxide)
ACGIH
Engineering measures : Processing may form hazardous compounds (see section 10). Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.
Personal protective equipment Respiratory protection
: No personal respiratory protective equipment normally required.
Hand protection Remarks
: Wash hands before breaks and at the end of workday.
Eye protection
: Wear the following personal protective equipment: Safety glasses
Skin and body protection
: Skin should be washed after contact.
Hygiene measures
: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may re-quire added precautions.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: paste
Color
: Almond
Odor
: Acetic acid
Odor Threshold
: No data available
pH
: Not applicable
Melting point/freezing point
: No data available
Initial boiling point and boiling : Not applicable
SAFETY DATA SHEET DOW CORNING(R) 786 SILICONE SEALANT - M US ALMOND
Version 1. 0
Revision Date: 02/10/2015
MSDS Number: 1281671-00001
Date of last issue: - Date of first issue: 02/10/2015
5 / 12
range
Flash point
: Not applicable
Evaporation rate
: Not applicable
Flammability (solid, gas)
: Not classified as a flammability hazard
Upper explosion limit
: No data available
Lower explosion limit
: No data available
Vapor pressure
: Not applicable
Relative vapor density
: No data available
Relative density
: 1.04
Solubility(ies) Water solubility
: No data available
Partition coefficient: n-octanol/water
: No data available
Autoignition temperature
: No data available
Decomposition temperature
: No data available
Viscosity Viscosity, dynamic
: Not applicable
Explosive properties
: Not explosive
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
Molecular weight
: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Not classified as a reactivity hazard.
Chemical stability
: Stable under normal conditions.
Possibility of hazardous reac-tions
: Use at elevated temperatures may form highly hazardous compounds. Can react with strong oxidizing agents. Acetic acid is formed upon contact with water or humid air. Hazardous decomposition products will be formed at elevated temperatures.
Conditions to avoid : None known.
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Incompatible materials
: Oxidizing agents
Hazardous decomposition products Thermal decomposition
: Formaldehyde
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Skin contact Ingestion Eye contact
Acute toxicity Not classified based on available information.
Ingredients: Silicon dioxide: Acute oral toxicity
: LD50 (Rat): > 3,300 mg/kg Assessment: The substance or mixture has no acute oral tox-icity Remarks: Information taken from reference works and the literature.
Acute inhalation toxicity
: LC50 (Rat): > 2.08 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity Remarks: Information taken from reference works and the literature.
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Information taken from reference works and the literature.
Titanium dioxide: Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): > 6.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity
Skin corrosion/irritation Not classified based on available information.
Product: Result: No skin irritation
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Remarks: Based on data from similar materials
Ingredients: Silicon dioxide: Result: No skin irritation Remarks: Information taken from reference works and the literature. Titanium dioxide: Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation Not classified based on available information.
Product: Result: No eye irritation Remarks: Based on data from similar materials
Ingredients: Silicon dioxide: Result: No eye irritation Remarks: Information taken from reference works and the literature. Titanium dioxide: Species: Rabbit Result: No eye irritation
Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information.
Ingredients: Silicon dioxide: Assessment: Does not cause skin sensitization. Test Type: Skin: test type not specified Species: Guinea pig Remarks: No known sensitising effect. Information taken from reference works and the literature. Titanium dioxide: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative
Germ cell mutagenicity Not classified based on available information.
Ingredients: Silicon dioxide:
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Genotoxicity in vitro
: Result: negative Remarks: Information taken from reference works and the literature.
Genotoxicity in vivo
: Application Route: Ingestion Result: negative Remarks: Information taken from reference works and the literature.
Germ cell mutagenicity - Assessment
: Animal testing did not show any mutagenic effects.
Titanium dioxide: Genotoxicity in vitro
: Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo
: Test Type: In vivo micronucleus test Species: Mouse Result: negative
Carcinogenicity Not classified based on available information.
Ingredients: Titanium dioxide: Species: Rat Application Route: inhalation (dust/mist/fume) Exposure time: 24 Months Method: OECD Test Guideline 453 Result: positive Remarks: The mechanism or mode of action may not be relevant in humans. The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. Carcinogenicity - Assess-ment
: Limited evidence of carcinogenicity in inhalation studies with animals.
IARC
Group 2B: Possibly carcinogenic to humans
Titanium dioxide
13463-67-7
OSHA
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.
NTP
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity Not classified based on available information.
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STOT-single exposure Not classified based on available information.
STOT-repeated exposure Not classified based on available information.
Repeated dose toxicity
Ingredients: Titanium dioxide: Species: Rat NOAEL: 24,000 mg/kg Application Route: Ingestion Exposure time: 28 d Species: Rat NOAEL: 10 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 2 y Remarks: The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard.
Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients: Titanium dioxide: Toxicity to fish
: LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h
Toxicity to algae
: EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l Exposure time: 72 h
Toxicity to bacteria
: EC50: > 1,000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209
Persistence and degradability No data available
Bioaccumulative potential No data available
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Mobility in soil No data available
Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Resource Conservation and Recovery Act (RCRA)
: This product has been evaluated for RCRA characteristics and does not meet the criteria of hazardous waste if discarded in its purchased form.
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste han-dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG Not regulated as a dangerous good
IATA-DGR Not regulated as a dangerous good
IMDG-Code Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
49 CFR Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
Ingredients CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
Acetic acid 64-19-7 5000 * Acetic anhydride 108-24-7 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
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SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards
: No SARA Hazards
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US State Regulations
Pennsylvania Right To Know Dimethyl siloxane, hydroxy-terminated 70131-67-8 70 - 90 % Silicon dioxide 7631-86-9 5 - 10 % Acetic acid 64-19-7 0 - 0.1 % Acetic anhydride 108-24-7 0 - 0.1 %
New Jersey Right To Know Dimethyl siloxane, hydroxy-terminated 70131-67-8 70 - 90 % Silicon dioxide 7631-86-9 5 - 10 % Dimethyl siloxane, trimethylsiloxy-terminated 63148-62-9 1 - 5 %
California Prop 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories: DSL
: All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).
TSCA
: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA)
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SECTION 16. OTHER INFORMATION
Further information NFPA: HMIS III:
Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average OSHA Z-3 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet
: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/
Revision Date
: 02/10/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-formation and belief at the date of its publication. The information is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro-vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un-less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in-cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8
Flammability
Hea
lth Instability
0
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
0
Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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SECTION 1. IDENTIFICATION
Product name
: DOW CORNING(R) 786 SILICONE SEALANT - M TRA NSLUCENT WHITE
Product code
: 000000000001886282
Manufacturer or supplier's details Company name of supplier
: Dow Corning Corporation
Address
: South Saginaw Road Midland Michigan 48686
Telephone
: (989) 496-6000
Emergency telephone
: 24 Hour Emergency Telephone : (989) 496-5900 CHEMTREC : (800) 424-9300
Recommended use of the chemical and restrictions on use Recommended use
: Adhesive, binding agents
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Not a hazardous substance or mixture.
GHS Label element Not a hazardous substance or mixture. Precautionary Statements
: Prevention: P271 Use only outdoors or in a well-ventilated area.
Other hazards None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Silicone elastomer
Hazardous ingredients
Chemical Name CAS-No. Concentration (%) Silicon dioxide 7631-86-9 >= 5 - < 10
SECTION 4. FIRST AID MEASURES
If inhaled : If inhaled, remove to fresh air.
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Get medical attention if symptoms occur.
In case of skin contact
: Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact
: Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
If swallowed
: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms and effects, both acute and delayed
: None known.
Protection of first-aiders
: No special precautions are necessary for first aid responders.
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing media
: None known.
Specific hazards during fire fighting
: Exposure to combustion products may be a hazard to health.
Hazardous combustion prod-ucts
: Carbon oxides Silicon oxides Formaldehyde
Specific extinguishing meth-ods
: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if nec-essary. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- : Follow safe handling advice and personal protective equip-
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tive equipment and emer-gency procedures
ment recommendations.
Environmental precautions
: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
: Soak up with inert absorbent material. For large spills, provide diking or other appropriate contain-ment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor-bent. Local or national regulations may apply to releases and dis-posal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
: Use only with adequate ventilation.
Advice on safe handling
: Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage
: Keep in properly labeled containers. Store in accordance with the particular national regulations.
Materials to avoid
: Do not store with the following product types: Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients CAS-No. Value type (Form of exposure)
Control parame-ters / Permissible concentration
Basis
Silicon dioxide 7631-86-9 TWA (Dust) 20 Million particles per cubic foot (Silica)
OSHA Z-3
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TWA (Dust) 80 mg/m3 / %SiO2 (Silica)
OSHA Z-3
TWA 6 mg/m3 (Silica)
NIOSH REL
Engineering measures : Processing may form hazardous compounds (see section 10). Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.
Personal protective equipment Respiratory protection
: No personal respiratory protective equipment normally required.
Hand protection Remarks
: Wash hands before breaks and at the end of workday.
Eye protection
: Wear the following personal protective equipment: Safety glasses
Skin and body protection
: Skin should be washed after contact.
Hygiene measures
: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may re-quire added precautions.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: paste
Color
: white, translucent
Odor
: Acetic acid
Odor Threshold
: No data available
pH
: Not applicable
Melting point/freezing point
: No data available
Initial boiling point and boiling range
: Not applicable
Flash point
: Not applicable
Evaporation rate : Not applicable
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Flammability (solid, gas)
: Not classified as a flammability hazard
Upper explosion limit
: No data available
Lower explosion limit
: No data available
Vapor pressure
: Not applicable
Relative vapor density
: No data available
Relative density
: 1.04
Solubility(ies) Water solubility
: No data available
Partition coefficient: n-octanol/water
: No data available
Autoignition temperature
: No data available
Decomposition temperature
: No data available
Viscosity Viscosity, dynamic
: Not applicable
Explosive properties
: Not explosive
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
Molecular weight
: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Not classified as a reactivity hazard.
Chemical stability
: Stable under normal conditions.
Possibility of hazardous reac-tions
: Use at elevated temperatures may form highly hazardous compounds. Can react with strong oxidizing agents. Acetic acid is formed upon contact with water or humid air. Hazardous decomposition products will be formed at elevated temperatures.
Conditions to avoid
: None known.
Incompatible materials
: Oxidizing agents
Hazardous decomposition products Thermal decomposition : Formaldehyde
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SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Skin contact Ingestion Eye contact
Acute toxicity Not classified based on available information.
Ingredients: Silicon dioxide: Acute oral toxicity
: LD50 (Rat): > 3,300 mg/kg Assessment: The substance or mixture has no acute oral tox-icity Remarks: Information taken from reference works and the literature.
Acute inhalation toxicity
: LC50 (Rat): > 2.08 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity Remarks: Information taken from reference works and the literature.
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Information taken from reference works and the literature.
Skin corrosion/irritation Not classified based on available information.
Product: Result: No skin irritation Remarks: Based on data from similar materials
Ingredients: Silicon dioxide: Result: No skin irritation Remarks: Information taken from reference works and the literature.
Serious eye damage/eye irritation Not classified based on available information.
Product: Result: No eye irritation Remarks: Based on data from similar materials
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Ingredients: Silicon dioxide: Result: No eye irritation Remarks: Information taken from reference works and the literature.
Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information.
Ingredients: Silicon dioxide: Assessment: Does not cause skin sensitization. Test Type: Skin: test type not specified Species: Guinea pig Remarks: No known sensitising effect. Information taken from reference works and the literature.
Germ cell mutagenicity Not classified based on available information.
Ingredients: Silicon dioxide: Genotoxicity in vitro
: Result: negative Remarks: Information taken from reference works and the literature.
Genotoxicity in vivo
: Application Route: Ingestion Result: negative Remarks: Information taken from reference works and the literature.
Germ cell mutagenicity - Assessment
: Animal testing did not show any mutagenic effects.
Carcinogenicity Not classified based on available information. IARC
No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.
NTP
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
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Reproductive toxicity Not classified based on available information.
STOT-single exposure Not classified based on available information.
STOT-repeated exposure Not classified based on available information.
Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Resource Conservation and Recovery Act (RCRA)
: This product has been evaluated for RCRA characteristics and does not meet the criteria of hazardous waste if discarded in its purchased form.
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste han-dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG Not regulated as a dangerous good
IATA-DGR Not regulated as a dangerous good
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IMDG-Code Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
49 CFR Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
Ingredients CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
Acetic acid 64-19-7 5000 * Acetic anhydride 108-24-7 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards
: No SARA Hazards
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US State Regulations
Pennsylvania Right To Know Dimethyl siloxane, hydroxy-terminated 70131-67-8 70 - 90 % Silicon dioxide 7631-86-9 5 - 10 % Acetic acid 64-19-7 0 - 0.1 % Acetic anhydride 108-24-7 0 - 0.1 %
New Jersey Right To Know Dimethyl siloxane, hydroxy-terminated 70131-67-8 70 - 90 % Silicon dioxide 7631-86-9 5 - 10 % Dimethyl siloxane, trimethylsiloxy-terminated 63148-62-9 1 - 5 %
California Prop 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other reproductive defects.
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The ingredients of this product are reported in the following inventories: IECSC
: All ingredients listed or exempt.
PICCS
: All ingredients listed or exempt.
AICS
: All ingredients listed or exempt.
DSL
: All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).
REACH
: All ingredients (pre-)registered or exempt.
TSCA
: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information NFPA: HMIS III:
Full text of other abbreviations NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek OSHA Z-3 / TWA : 8-hour time weighted average Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
Flammability
Hea
lth Instability
0
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
0
Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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compile the Material Safety Data Sheet
eChem Portal search results and European Chemicals Agency, http://echa.europa.eu/
Revision Date
: 02/10/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-formation and belief at the date of its publication. The information is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro-vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommenda-tions in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8
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SECTION 1. IDENTIFICATION
Product name
: DOW CORNING(R) 786 SILICONE SEALANT - M GREY
Product code
: 000000000003019501
Manufacturer or supplier's details Company name of supplier
: Dow Corning Corporation
Address
: South Saginaw Road Midland Michigan 48686
Telephone
: (989) 496-6000
Emergency telephone
: 24 Hour Emergency Telephone : (989) 496-5900 CHEMTREC : (800) 424-9300
Recommended use of the chemical and restrictions on use Recommended use
: Adhesive, binding agents
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification Not a hazardous substance or mixture.
GHS Label element Not a hazardous substance or mixture. Precautionary Statements
: Prevention: P271 Use only outdoors or in a well-ventilated area.
Other hazards None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Silicone elastomer
Hazardous ingredients
Chemical Name CAS-No. Concentration (%) Silicon dioxide 7631-86-9 >= 5 - < 10 Titanium dioxide 13463-67-7 >= 0.1 - < 1
SECTION 4. FIRST AID MEASURES
If inhaled : If inhaled, remove to fresh air.
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Get medical attention if symptoms occur.
In case of skin contact
: Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact
: Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.
If swallowed
: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms and effects, both acute and delayed
: None known.
Protection of first-aiders
: No special precautions are necessary for first aid responders.
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing media
: None known.
Specific hazards during fire fighting
: Exposure to combustion products may be a hazard to health.
Hazardous combustion prod-ucts
: Carbon oxides Silicon oxides Formaldehyde
Specific extinguishing meth-ods
: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if nec-essary. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- : Follow safe handling advice and personal protective equip-
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tive equipment and emer-gency procedures
ment recommendations.
Environmental precautions
: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
: Soak up with inert absorbent material. For large spills, provide diking or other appropriate contain-ment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor-bent. Local or national regulations may apply to releases and dis-posal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
: Use only with adequate ventilation.
Advice on safe handling
: Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage
: Keep in properly labeled containers. Store in accordance with the particular national regulations.
Materials to avoid
: Do not store with the following product types: Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients CAS-No. Value type (Form of exposure)
Control parame-ters / Permissible concentration
Basis
Silicon dioxide 7631-86-9 TWA (Dust) 20 Million particles per cubic foot (Silica)
OSHA Z-3
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TWA (Dust) 80 mg/m3 / %SiO2 (Silica)
OSHA Z-3
TWA 6 mg/m3 (Silica)
NIOSH REL
Titanium dioxide 13463-67-7 TWA (total dust)
15 mg/m3 OSHA Z-1
TWA 10 mg/m3 (Titanium dioxide)
ACGIH
Engineering measures : Processing may form hazardous compounds (see section 10). Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.
Personal protective equipment Respiratory protection
: No personal respiratory protective equipment normally required.
Hand protection Remarks
: Wash hands before breaks and at the end of workday.
Eye protection
: Wear the following personal protective equipment: Safety glasses
Skin and body protection
: Skin should be washed after contact.
Hygiene measures
: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may re-quire added precautions.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: paste
Color
: gray
Odor
: Acetic acid
Odor Threshold
: No data available
pH
: Not applicable
Melting point/freezing point
: No data available
Initial boiling point and boiling range
: Not applicable
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Flash point
: Not applicable
Evaporation rate
: Not applicable
Flammability (solid, gas)
: Not classified as a flammability hazard
Upper explosion limit
: No data available
Lower explosion limit
: No data available
Vapor pressure
: Not applicable
Relative vapor density
: No data available
Relative density
: 1.04
Solubility(ies) Water solubility
: No data available
Partition coefficient: n-octanol/water
: No data available
Autoignition temperature
: No data available
Decomposition temperature
: No data available
Viscosity Viscosity, dynamic
: Not applicable
Explosive properties
: Not explosive
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
Molecular weight
: No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Not classified as a reactivity hazard.
Chemical stability
: Stable under normal conditions.
Possibility of hazardous reac-tions
: Use at elevated temperatures may form highly hazardous compounds. Can react with strong oxidizing agents. Acetic acid is formed upon contact with water or humid air. Hazardous decomposition products will be formed at elevated temperatures.
Conditions to avoid
: None known.
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Incompatible materials
: Oxidizing agents
Hazardous decomposition products Thermal decomposition
: Formaldehyde
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Skin contact Ingestion Eye contact
Acute toxicity Not classified based on available information.
Ingredients: Silicon dioxide: Acute oral toxicity
: LD50 (Rat): > 3,300 mg/kg Assessment: The substance or mixture has no acute oral tox-icity Remarks: Information taken from reference works and the literature.
Acute inhalation toxicity
: LC50 (Rat): > 2.08 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity Remarks: Information taken from reference works and the literature.
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Information taken from reference works and the literature.
Titanium dioxide: Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): > 6.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity
Skin corrosion/irritation Not classified based on available information.
Product: Result: No skin irritation Remarks: Based on data from similar materials
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Ingredients: Silicon dioxide: Result: No skin irritation Remarks: Information taken from reference works and the literature. Titanium dioxide: Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation Not classified based on available information.
Product: Result: No eye irritation Remarks: Based on data from similar materials
Ingredients: Silicon dioxide: Result: No eye irritation Remarks: Information taken from reference works and the literature. Titanium dioxide: Species: Rabbit Result: No eye irritation
Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information.
Ingredients: Silicon dioxide: Assessment: Does not cause skin sensitization. Test Type: Skin: test type not specified Species: Guinea pig Remarks: No known sensitising effect. Information taken from reference works and the literature. Titanium dioxide: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative
Germ cell mutagenicity Not classified based on available information.
Ingredients: Silicon dioxide: Genotoxicity in vitro : Result: negative
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Remarks: Information taken from reference works and the literature.
Genotoxicity in vivo
: Application Route: Ingestion Result: negative Remarks: Information taken from reference works and the literature.
Germ cell mutagenicity - Assessment
: Animal testing did not show any mutagenic effects.
Titanium dioxide: Genotoxicity in vitro
: Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo
: Test Type: In vivo micronucleus test Species: Mouse Result: negative
Carcinogenicity Not classified based on available information.
Ingredients: Titanium dioxide: Species: Rat Application Route: inhalation (dust/mist/fume) Exposure time: 24 Months Method: OECD Test Guideline 453 Result: positive Remarks: The mechanism or mode of action may not be relevant in humans. The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. Carcinogenicity - Assess-ment
: Limited evidence of carcinogenicity in inhalation studies with animals.
IARC
Group 2B: Possibly carcinogenic to humans
Titanium dioxide
13463-67-7
OSHA
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.
NTP
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity Not classified based on available information.
STOT-single exposure Not classified based on available information.
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STOT-repeated exposure Not classified based on available information.
Repeated dose toxicity
Ingredients: Titanium dioxide: Species: Rat NOAEL: 24,000 mg/kg Application Route: Ingestion Exposure time: 28 d Species: Rat NOAEL: 10 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 2 y Remarks: The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard.
Aspiration toxicity Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients: Titanium dioxide: Toxicity to fish
: LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h
Toxicity to algae
: EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l Exposure time: 72 h
Toxicity to bacteria
: EC50: > 1,000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
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Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Resource Conservation and Recovery Act (RCRA)
: This product has been evaluated for RCRA characteristics and does not meet the criteria of hazardous waste if discarded in its purchased form.
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste han-dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG Not regulated as a dangerous good
IATA-DGR Not regulated as a dangerous good
IMDG-Code Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
Domestic regulation
49 CFR Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
Ingredients CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
Acetic acid 64-19-7 5000 * Acetic anhydride 108-24-7 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
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SARA 311/312 Hazards
: No SARA Hazards
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US State Regulations
Pennsylvania Right To Know Dimethyl siloxane, hydroxy-terminated 70131-67-8 70 - 90 % Silicon dioxide 7631-86-9 5 - 10 % Acetic acid 64-19-7 0 - 0.1 % Acetic anhydride 108-24-7 0 - 0.1 %
New Jersey Right To Know Dimethyl siloxane, hydroxy-terminated 70131-67-8 70 - 90 % Silicon dioxide 7631-86-9 5 - 10 % Dimethyl siloxane, trimethylsiloxy-terminated 63148-62-9 1 - 5 %
California Prop 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories: DSL
: All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).
TSCA
: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA)
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SECTION 16. OTHER INFORMATION
Further information NFPA: HMIS III:
Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average OSHA Z-3 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet
: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/
Revision Date
: 02/12/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-formation and belief at the date of its publication. The information is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information pro-vided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommenda-tions in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8
Flammability
Hea
lth Instability
0
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
0
Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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1. PRODUCT AND COMPANY IDENTIFICATION Dow Corning Corporation South Saginaw Road Midland, Michigan 48686
24 Hour Emergency Telephone:
Customer Service: Product Disposal Information:
CHEMTREC:
(989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300
MSDS No.: 02023695
Revision Date: 2013/07/08
Generic Description: Silicone elastomer Physical Form: Paste
Color: Colorless Odor: Acetic acid odor
NFPA Profile:
Health 1 Flammability 1 Instability/Reactivity 0
Note: NFPA = National Fire Protection Association 2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects Eye:
Direct contact may cause mild irritation.
Skin:
May cause mild irritation.
Inhalation:
Irritates respiratory passages very slightly.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects Skin:
No known applicable information.
Inhalation:
No known applicable information.
Oral:
No known applicable information.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
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The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS Number Wt % Component Name
17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane
4253-34-3 1.0 - 5.0 Methyltriacetoxysilane
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES Eye:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the eyelid(s) open. Obtain medical attention.
Skin: No health effects expected. If irritation does occur flush with lukewarm, gently flowing water for 5 minutes. If irritation persists, obtain medical advice.
Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air. If irritation persists, obtain medical advice.
Oral: If irritation or discomfort occur, obtain medical advice.
Notes to Physician: Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES Flash Point:
Not applicable.
Autoignition Temperature:
Not determined.
Flammability Limits in Air:
Not determined.
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures:
Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool.
Unusual Fire Hazards:
None.
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6. ACCIDENTAL RELEASE MEASURES Containment/Clean up:
Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements.
Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required.
7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. This material in its finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical dusts) or 484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name
Exposure Limits
17689-77-9 Ethyltriacetoxysilane
See acetic acid comments.
4253-34-3 Methyltriacetoxysilane
See acetic acid comments.
Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls Local Ventilation: None should be needed. General Ventilation: Recommended.
Personal Protective Equipment for Routine Handling
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Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.
Suitable Gloves:
Handle in accordance with good industrial hygiene and safety practices.
Inhalation:
No respiratory protection should be needed.
Suitable Respirator:
None should be needed.
Personal Protective Equipment for Spills Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.
Inhalation/Suitable Respirator:
No respiratory protection should be needed.
Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable care.
Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Paste
Color: Colorless Odor: Acetic acid odor
Specific Gravity @ 25°C: 1.04 Viscosity: Not determined.
Freezing/Melting Point: Not determined. Boiling Point: Not determined.
Vapor Pressure @ 25°C: Not determined. Vapor Density: Not determined.
Solubility in Water: Not determined. pH: Not determined.
Volatile Content: Not determined. Flash Point: Not applicable.
Autoignition Temperature: Not determined. Flammability Limits in Air: Not determined.
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Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.
10. STABILITY AND REACTIVITY Chemical Stability:
Stable.
Hazardous Polymerization:
Hazardous polymerization will not occur.
Conditions to Avoid:
None.
Materials to Avoid:
Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8.
Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.
11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
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This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances (40 CFR 355): None. Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: No Chronic: No
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Fire: No Pressure: No Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities. Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold. Supplemental State Compliance Information California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm.
None known. New Jersey
CAS Number
Wt %
Component Name
70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated
7631-86-9 7.0 - 13.0 Silicon dioxide
63148-62-9 1.0 - 5.0 Polydimethylsiloxane
17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane
4253-34-3 1.0 - 5.0 Methyltriacetoxysilane
Pennsylvania CAS Number
Wt %
Component Name
70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated
7631-86-9 7.0 - 13.0 Silicon dioxide
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Revision Date: 2013/07/08 DOW CORNING(R) 786 SILICONE SEALANT - M CLEAR
16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate.
(R) indicates Registered Trademark
: November 15, 2015
Product Name : Mile High Foam® closed cell polyethylene foam backer rod
Other Names :
: Bay Foam Products Inc.
2240 West Peoria Ave.
Phoenix, AZ 85029
Tel: 602-943-4151
Appearance :
Density : 1.25 - 2 lbs per cu. ft.
Solubility in Water : Insoluble
Stability and Reactivity :
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Auto-Ignition Point: :
PRODUCT INFORMATION SHEET
MILE HIGH FOAM® Closed Cell Polyethylene Backer Rod
IMPORTANT INFORMATION: Flexible polyethylene is an "article", not a chemical, as defined in 29 CFR
1910.1200©. It does not require a Safety Data Sheet under OSHA's Hazard Communication Standard. As a
service to our customers, however, Backer Rod Mfg. Inc. has produced this Product Information Sheet.
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
SECTION 2 - PHYSICAL AND CHEMICAL CHARACTERISTICS
343°F (ASTM D 1929)
Since flexible polyethylene foam is a solid, physical characteristics such as boiling point, vapor pressure, vapor
density evaporation rate, etc., do not apply.
Date of Preparation
Manufacturer Name
SECTION 3 - FIRE HAZARD INFORMATION
Closed cell low density polyethylene foam (LDPE)
www.bayfoamproducts.com
Cellular flexible material, dark gray or black in color. May also be in various
colors.
Stable. No hazardous polymerization will occur in normal use.
Prolonged exposure to temperatures in excess of 196°F may cause some loss
of volatile components (e.g., flame retardants) through evaporation.
Unprotected polyethylene foam will discolor and degrade under prolonged
exposure to UV light.
Solvent resistance will vary with solvent type.
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Fire Hazard :
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Extinguishing Media :
Fire-fighting Protection :
Exposure Limits : None Established
Acute Toxicity : Skin Absorption Not likely. Non irritating
: Swallowing None determined
: Inhalation Inhalation of foam dust may cause irritation to nose,
throat, and lungs
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: Eye Contact Foam dust may cause eye irritation or injury
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SECTION 4 - HEALTH HAZARDS
SECTION 5 - HANDLING AND STORAGE
Keep foam away from sparks, naked lights, open flames, exposed electrical elements, or other ignition
sources. Smoking should be forbidden in areas where material is stored or processed.
Maintain adequate sprinkler protection where large volumes of foam are kept (e.g., warehouses,
fabrication areas and storage rooms). Check for compliance with insurance regulations, local building codes
or other legal requirements.
Fire-fighting personnel must be equipped with self contained breathing
apparatus (SCBA) and fire-fighting clothing.
Skin Contact Non irritating
Once ignited, polyethylene foam is difficult to extinguish. Foam fires that
appear to be extinguished may smolder and re-ignite. Always have fire
officials determine wheather a fire has been extinguished.
WARNING: Polyethylene Foam will burn if exposed to an open flame or
other sufficient heat source. Do not expose polyethylene foam to open
flames or any other direct or indirect high temperature ignition source such
as burning operations, welding, space heaters or naked lights.
MILE HIGH FOAM® Closed Cell Polyethylene Foam Backer Rod
SECTION 3 - FIRE HAZARD INFORMATION cont.
Water spray, dry chemical, foam or carbon dioxide
Piles of foam dust can be readily ignited and present a potential fire hazard.
High concentrations of foam dust in the air can be a potential explosion hazard
if exposed to flame, sparks, or other ignition sources.
Once ignited, polyethylene foam will burn rapidly, releasing great heat and
consuming oxygen at a high rate. In an enclosed space the resulting
deficiency of oxygen will present a danger of suffocation to the occupants.
Hazardous gasses released by the burning foam can be incapacitating or fatal
to human beings if inhaled in sufficient quantities.
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Protective Equipment :
Ventilation :
Skin :
Eyes :
Ingestion : None necessary unless throat is obstructed
Inhalation :
SECTION 7 - EMERGENCY AND FIRST AID PROCEDURES
MILE HIGH FOAM® Closed Cell Polyethylene Foam Backer Rod
SECTION 5 - HANDLING AND STORAGE cont.
Be aware that terms sometimes used to describe polyethylene foam, like "fire retardant" and "flame
resistant", do not mean fire safety under all conditions. Flammability ratings from small-scale laboratory
tests are not to be taken as an indication of the material's behavior under actual fire conditions.
SECTION 6 - PERSONAL PROTECTION AND EXPOSURE CONTROLS
Mechanical ventilation should be considered in operations that generate
abnormal quantities of foam dust, or where thermal decomposition of the
foam occurs (e.g., hot-wire cutting, heat sealing, hot stamping and flame
laminating.)
Unless exposure to foam dust is anticipated, dust masks, goggles, and gloves
are not required. Long sleeves are recommended if arms are repeatedly
rubbed against foam.
Never use foam as an exposed interior wall or ceiling finish
Maintain sufficient aisle space to permit access for fire-fighting equipment and personnel to all foam
storage areas.
Do not allow cuttings or foam scrap to accumulate.
The information presented here is offered for your consideration, investigation and verification. The
information is presented in good faith and was obtained from sources Bay Foam Products Inc. believes to
be reliable. Bay Foam Products Inc., however, makes no representation as to the completeness and
accuracy. Bay Foam Products Inc. makes no warranty, expressed or implied, with respect to the information
contained herein.
Bay Foam Products Inc. cannot anticipate all conditions under which this information and the product may be
used. The conditions of handling, storage, use, and disposal of the product are beyond Bay Foam Products
Inc.'s control. Thus, we expressly disclaim responsibility or liablility for any loss, damage or expense arising
out of reliance on the information contained herein. You are advised to make your own determination as to
safety, suitability and appropriate manner of handling, storage, use and disposal.
Wash off any foam dust.
Flush thoroughly with water.
Consult physician if coughing, discomfort, or obstruction of air passage occurs.
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