Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH...

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Transcript of Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH...

Page 1: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 2: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 3: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 4: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 5: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 6: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

carbocatione

Page 7: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

carbocatione

Page 8: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 9: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 10: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 11: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 12: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 13: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 14: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 15: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 16: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 17: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 18: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 19: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 20: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 21: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 22: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 23: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 24: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 25: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

first step: oxidative addition

second step: reductive elimination

Page 26: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

Reazioni di idroborazione (Chim. Org. I – cap 9)

organoborano

9-Borabicyclo[3.3.1]nonane

Page 27: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

mechanism

Page 28: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 29: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 30: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 31: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 32: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 33: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 34: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 35: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 36: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

addizione di bromo in acqua

Page 37: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 38: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 39: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 40: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 41: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 42: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P
Page 43: Presentazione standard di PowerPoint · 2020. 10. 8. · — pph, Pd(0) Oxidative addition Pd(0) OH . pd(o) Pd(0) pph3 Pd—PPh3 Pd(0) Ph,P pd(ll) Pd(0) Oxidative addition Ph p ph3P

The Amphidinolide T-Series - University of North Carolina …€¦ ·  · 2007-05-02The Amphidinolide T-Series ... Pd/C, EtOAc 2 steps 74% O O Me Me O TBDPSO OMOM O Me PPh3=CH2 THF

The Amphidinolide T-Series - University of North Carolina …€¦ ·  · 2007-05-02The Amphidinolide T-Series ... Pd/C, EtOAc 2 steps 74% O O Me Me O TBDPSO OMOM O Me PPh3=CH2 THF

D. N. 2. - ssb.no · pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. 8,4 2, 20 6 0,820 2,4 2,8 2,4 - ,68 2,2 2,600 6 ... 75 , ,442 28 20 2 ,82 dnhvn.,022 0 0 155 , ,48

D. N. 2. - ssb.no · pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. pd. 8,4 2, 20 6 0,820 2,4 2,8 2,4 - ,68 2,2 2,600 6 ... 75 , ,442 28 20 2 ,82 dnhvn.,022 0 0 155 , ,48

Pédale · 2017. 1. 13. · pd-9000 pd-6800 pd-5800 pd-5700-c pd-r550 pd-r540-la pd-m9000 pd-m9020 pd-m8000 pd-m8020 pd-m990 pd-m995 pd-t700 pd-t420 pd-t400 pd-mt50

Pédale · 2017. 1. 13. · pd-9000 pd-6800 pd-5800 pd-5700-c pd-r550 pd-r540-la pd-m9000 pd-m9020 pd-m8000 pd-m8020 pd-m990 pd-m995 pd-t700 pd-t420 pd-t400 pd-mt50

'0 PD&E STUDY GN SEGMENT 5 0 20 100 SHEET NO. [FGFND FIRE ...

'0 PD&E STUDY GN SEGMENT 5 0 20 100 SHEET NO. [FGFND FIRE ...

APPENDIX I - ANZDATA · hospital pd 6 8 7 3 3 12 14 25 8 0 86 satellite pd 0 0 0 0 0 0 0 0 0 0 0 hospital hd 0 4 35 89 136 205 228 275 123 4 1099 satellite hd 0 0 1 4 16 9 12 14 7

APPENDIX I - ANZDATA · hospital pd 6 8 7 3 3 12 14 25 8 0 86 satellite pd 0 0 0 0 0 0 0 0 0 0 0 hospital hd 0 4 35 89 136 205 228 275 123 4 1099 satellite hd 0 0 1 4 16 9 12 14 7

[PD] Documentos - ETOM - Release 12-0 v12-2

[PD] Documentos - ETOM - Release 12-0 v12-2

SYNTHESIS OF NOVEL BIPYRIDINE AND TERPYRIDINE LIGANDS … · et Biochimie Pharmacologique ... Xyl, 140°C, 24 h Cl2Pd(PPh3)2 5% PPh3 10% N N N N SnBu31 eq. Cl 65 % Cl Cl Xyl, 140°C,

SYNTHESIS OF NOVEL BIPYRIDINE AND TERPYRIDINE LIGANDS … · et Biochimie Pharmacologique ... Xyl, 140°C, 24 h Cl2Pd(PPh3)2 5% PPh3 10% N N N N SnBu31 eq. Cl 65 % Cl Cl Xyl, 140°C,

Jdbc4[1].0 Pd Spec

Jdbc4[1].0 Pd Spec

Pd(OAc) /S=PPh3 Accelerated Activation of · 1 Pd(OAc)2/S=PPh3 Accelerated Activation of gem-Dichloroalkenes for the Construction of 3-Arylchromones Jianming Liu,a,* Weiwei Song,a

Pd(OAc) /S=PPh3 Accelerated Activation of · 1 Pd(OAc)2/S=PPh3 Accelerated Activation of gem-Dichloroalkenes for the Construction of 3-Arylchromones Jianming Liu,a,* Weiwei Song,a

'0 PD&E STUDY GN SEGMENT 4 0 20 100 SHEET NO. 4-LANE …

'0 PD&E STUDY GN SEGMENT 4 0 20 100 SHEET NO. 4-LANE …

Педала · 2017. 1. 13. · pd-9000 pd-6800 pd-5800 pd-5700-c pd-r550 pd-r540-la pd-m9000 pd-m9020 pd-m8000 pd-m8020 pd-m990 pd-m995 pd-t700 pd-t420 pd-t400 pd-mt50

Педала · 2017. 1. 13. · pd-9000 pd-6800 pd-5800 pd-5700-c pd-r550 pd-r540-la pd-m9000 pd-m9020 pd-m8000 pd-m8020 pd-m990 pd-m995 pd-t700 pd-t420 pd-t400 pd-mt50

Supporting Information - rsc.org · triphenylphosphine (TPP), diisopropyl azodicarboxylate (DIAD), CuI, PdCl2(PPh3)2, trimethylethynylsilane, dicyclohexylcarbodiimide (DCC), dimethylaminopyridine

Supporting Information - rsc.org · triphenylphosphine (TPP), diisopropyl azodicarboxylate (DIAD), CuI, PdCl2(PPh3)2, trimethylethynylsilane, dicyclohexylcarbodiimide (DCC), dimethylaminopyridine

TEXAS DEPARTMENT OF PUBLIC SAFETY 2018 DWI · PDF filekilleen 0 0 0 0 0 0 county attorney's office 1 belton 0 0 0 0 0 0 harker heights pd 32 0 0 4 4 0 0 killeen pd 380 9 0 82 76 6

TEXAS DEPARTMENT OF PUBLIC SAFETY 2018 DWI · PDF filekilleen 0 0 0 0 0 0 county attorney's office 1 belton 0 0 0 0 0 0 harker heights pd 32 0 0 4 4 0 0 killeen pd 380 9 0 82 76 6

Myers The Stille Reaction Chem 115 - Harvard University · Myers Chem 115 Andrew Haidle, Jeff Kohrt The Stille Reaction Pd(PPh3)4 Pd(OAc)2 O Stille Reaction conditions: • Catalyst:

Myers The Stille Reaction Chem 115 - Harvard University · Myers Chem 115 Andrew Haidle, Jeff Kohrt The Stille Reaction Pd(PPh3)4 Pd(OAc)2 O Stille Reaction conditions: • Catalyst:

Miguel-Mission 230 kV #2 Project C R C omment Set PPH3 ... · Miguel-Mission 230 kV #2 Project COMMENTS AND RESPONSES TO COMMENTS C omment Set PPH3 Public Participation H earing –

Miguel-Mission 230 kV #2 Project C R C omment Set PPH3 ... · Miguel-Mission 230 kV #2 Project COMMENTS AND RESPONSES TO COMMENTS C omment Set PPH3 Public Participation H earing –

2010 Ncce Pd 2 0 Final

2010 Ncce Pd 2 0 Final

Лекция 25 - chem.msu.su€¦ · ЭтиреакциинепроисходятбезPd -катализатора! CH3 Br H Ph H Br H HH H Pd Pd(PPh3)4 P H3C CH3CN, Et3N H Ph H

Лекция 25 - chem.msu.su€¦ · ЭтиреакциинепроисходятбезPd -катализатора! CH3 Br H Ph H Br H HH H Pd Pd(PPh3)4 P H3C CH3CN, Et3N H Ph H

Development of a new class of PSMA radioligands comprising ...tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)4, 0.01 mmol) in the presence of 30 equiv morpholine (12 mmol) in DCM

Development of a new class of PSMA radioligands comprising ...tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)4, 0.01 mmol) in the presence of 30 equiv morpholine (12 mmol) in DCM

DOI:10.1002/adsc.201501150 Palladium-Catalyzed Tandem ......6Pd(PPh3)4 Na2CO3 THF 80 9 7Pd(PPh3)4 Cs2CO3 THF 80 6 8Pd(PPh3)4 KOHTHF 80 32 9Pd(PPh3)4 t-BuOK THF 80 trace 10 Pd(PPh3)4

DOI:10.1002/adsc.201501150 Palladium-Catalyzed Tandem ......6Pd(PPh3)4 Na2CO3 THF 80 9 7Pd(PPh3)4 Cs2CO3 THF 80 6 8Pd(PPh3)4 KOHTHF 80 32 9Pd(PPh3)4 t-BuOK THF 80 trace 10 Pd(PPh3)4

L 1 1 0 0 1 5 0 Validation of PD-L1 Expression on D HCC78 ... · PD-L1 expression levels on carcinoma cell lines were identified by flow cytometry. For analytical validation, ...

L 1 1 0 0 1 5 0 Validation of PD-L1 Expression on D HCC78 ... · PD-L1 expression levels on carcinoma cell lines were identified by flow cytometry. For analytical validation, ...