Lecture 3: Coupling Constants Coupling Constants the chemical shift
PRE-AP CHEMISTRY EQUATIONS AND CONSTANTS€¦ · Web viewChemistry is the study of matter, its...
Transcript of PRE-AP CHEMISTRY EQUATIONS AND CONSTANTS€¦ · Web viewChemistry is the study of matter, its...
Chemistry (H) Syllabus 2019 - 20 Mrs. Erin WeeksEufaula High School [email protected]
Required Material: 3-ring binder (2 inch recommended) College Rule spiral notebook for notes College Rule composition notebook (100 pages)
for vocabulary
3 Page Divider pack Pen only (traditional blue or black ink only) Scientific calculator
Course Description: Chemistry is the study of matter, its composition, structure, properties, the changes it undergoes, and the energy involved. Through notes, lectures, projects, videos, assignments, and labs, students will learn facts, formulas and principles that comprise an introduction to Chemistry and will develop critical thinking and problem solving skills in relationship to scientific thought and study. We will study dimensional analysis, atomic structure, atomic theory, electron configuration, chemical reactions, the mole, stoichiometry and more as time allows.
Grade Scale: Grades will be determined by weighted scale: Tests – 55%, Homework/Quizzes/Labs/Projects – 45%Grading Scale: A= 90-100 B=80-89 C=70-79 D-60-69 F=59 and below *If your average is a 69 or below, I encourage you to visit with me outside of class. Semester Grade = 20% Semester Test + 80% Both 9 Weeks Average
Assignments Types and Grades Vocabulary – you will be responsible for keeping a vocabulary notebook and using it to study your key
terms. You will be given vocabulary quizzes during each chapter study. Vocabulary notebooks will be collected on the day of the chapter test. If notebook is complete for that chapter, 2 extra credit points will be given to that chapter test score. It is your responsibility to prepare and learn the key terms.
Regular Studying – Students should engage in regular studying of their notes for at least 15 – 30 minutes per day as a minimum. This is considered a standing assignment.
Skills & Concept Homework – Homework Assignments are given for practicing science skills and science concepts. Grades are very rarely given for these assignments, but students are expected to do them regardless. If you choose not to do your homework, you will not be prepared for the quiz that will be over the skills and concepts. If you need more help you should make time to visit with me.
Quizzes/In-class assignments – Used to practice and strengthen students’ understanding and comprehension of learned skills and science concepts.
Chapter Tests – Used to demonstrate students overall mastery of the skills and science concepts. Answers Only: Answers only on any math will not be accepted. YOU MUST SHOW ALL WORK to receive
credit.
Make-up work/ Late Work: It is your responsibility as outlined in the student handbook to obtain and complete your make-up work. You have the amount of days absent to complete any assignments you have missed. If you are not sure what you have missed…it is your responsibility to ask me or another student and get your work. If you are not sure when your make-up work needs to be turned in…ASK!
My late work policy is as follows: 1 day 50%, any later 0%. Exceptions are rare but can occur…You must talk to me!
Laboratory: Laboratory work is an important part of science and will require a report/assignment to be completed. The laboratory is a serious and potentially dangerous place. To participate in labs, the student and parent or guardian must have read, signed, dated, and returned a safety contract. Additionally, the student must complete a safety lab, and perform 100% proficiency on a safety exam.
'Horseplay' or other unsafe or disruptive behavior will not be tolerated. Failure by any student to comply with lab rules will result in dismissal from future lab activities.
Make-Up Labs:Most labs in this course require advanced preparation and set-up and because of this lab make-up will consist of a 2-page written report over an assigned topic that will be due two days after assigned.
Missed Tests Test dates are announced at least one week before the test. All make-up tests will be a different test from the original and may include more essay/short answer type
questions. If a student knows he/she will be absent on a test day, I highly recommend that the student visit with me to
arrange a time to take the regular test early or before school on the day following the scheduled test day. If you miss a test it must be made up on the following Tuesday after school. Failure to do so will result in a zero.
(Special circumstances aside.)o If you are unable to make-up your test during that time, you must see me BEFOREHAND to
schedule a different time.
Technology Policy A Chromebook will be available for students to use in class at appropriate times , therefore, cell phones, smart watches (any brand), and any other portable/wearable technology use will not be permitted in class. These items must be turned off and stored during class. A container is provided at each desk for technology storage and it is the student’s responsibility to collect their items at the end of class. Violations of this policy will coincide with the EHS Cell Phone Policy. This includes during any coded school lockdown or drills, and other safety drills.
Expectations:1. Always show respect—to your classmates, to visitors, and to me. It makes everything run a lot smoother
and we will be able to enjoy the class so much more.2. Always be willing and ready to learn and participate—class is so much more fun when you actually want
to learn something new and are prepared to have a conversation about the topics.3. Always be on time. That means in your seat and ready to work by the time the tardy bell rings.4. Restroom usage - go before you come to class. 5. No food, candy, or drinks permitted in class. Gum will only be permitted as long as I don’t see it or hear
it.
Binders: It is important to keep up with your vocabulary, old tests, and notes for the semester. Your semester test will come from ALL the information that is taught during the semester. There will also be a few items that carry-over to next semester that will be recommended to keep. It is recommended that you use your page dividers to organize your binder into the following categories:
o Handoutso Testso Extras
Page Headings:1. For worksheets fill in the blanks. If work is being done on loose leaf paper, in the top right corner head your
paper this way: First and Last name Class name and hour Date
2. If work is being done on loose leaf paper, the chapter and assignment name should be on the top line at the left. Example: Ch. 1 Vocabulary Quiz 1
CHEMISTRY EQUATIONS AND CONSTANTS
ATOMIC STRUCTURE
hE λνc λ
hcE
BEHAVIOR OF GASES
Ptotal = P1 + P2 + P3 + …
P1 • V1 = P2 • V2
V1 • T2 = V2 • T1 or
PV = nRT
22
22
11
11
TnVP
TnVP
SOLUTIONS
solutionof liter(n) soluteof moles (M) Molarity
Molaity (m)
V1M1 = V2M2
Kw = [H+][OH–] = 1 x 10‒14 (at 25°C)
pH = – log [H+]
pOH = – log [OH–]
[H+] = 10 – pH
[OH–] = 10 – pOH
pH + pOH = 14
THERMOCHEMISTRY
q = mCΔT (q = ΔH at constant pressure)
ΔH = moles x ΔHfus ΔH = moles x ΔHvap
OTHER FORMULAS
VmD
100)(
valueaccepted
valuealexperimentvalueacceptederror%
(100)yieldltheoretica
yieldlxperimentaeyield%
EQUILIBRIUM
For reaction aA + bB ↔ cC + dD:
b a
d c
BADC
eqK Rate = k[A]x[B]y
CONSTANTS AND CONVERSIONS
Avogadro’s Number = 6.022 x 1023 particles per mole
h = Planck’s Constant = 6.63 x 10‒34 J·s
c = Speed of Light = 3.0 x 108 m/s
STP = 0 °C and 1 atm
0°C = 273 K
Volume of Ideal Gas at STP = 22.4 L/mol
1 atm = 760 mm Hg = 760 torr = 101.33 kPa = 14.7 psi
KmolkPaL
KmoltorrL
KmolatmL 8.314 or 62.4 or 0.0821 R
1 cm3 = 1 mL 1 dm3 = 1 L
1 calorie (cal) = 4.184 joules (J)
1000 calories (cal) = 1 Calorie (Cal) = 1 kilocalorie (kcal)
Specific Heat of Water = 4.184 J/g°C
The Periodic Table of ElementsYou are responsible for memorizing the element names and symbols.
We will work on these 20 elements at a time and take quizzes beginning Sept 6.
Electronegativity Values
Naming CompoundsIs the first element a ___?
Does the compound include Hydrogen
and an element from the periodic table?
Yes No, It has Hydrogen and a Polyatomic Ion.
Name the compound using the Prefix
“hydro-“ and change the ending to “-ic
acid”Ex: HCl
Hydrochloric Acid
Hydrogen(This compound is an acid)
Use your polyatomic ion sheet to find the
name of the polyatomic ion in the
compound.Does it end in –ite or
–ate?
Non-Metal(except Hydrogen)
(This compound is molecular )
Look at the subscripts in the compound. Use prefixes to indicate
the amount of each atom.
Ex: N2O5
Dinitrogen PentoxideCO
Carbon Monoxide
Prefixes:1: mono 6: hexa2: di 7: hepta3: tri 8: octa4: tetra 9: nona5: penta 10: deca
Metal
Do you have a Polyatomic Ion? Hint: There will be 3 or more elements
in the compound. Or check your polyatomic ion sheet.
Yes
Name the metal, just like it is and then name the polyatomic ion. If the metal is a transition metal, include a roman numeral to indicate the change.
Ex: NaOHSodium Hydroxide
No
Name the metal, and then name the non-metal. If the metal is a transition metal, include a roman numeral to indicate the change.
Ex: NaClSodium Chloride
MnO2
Manganese (II) Oxide
Non-metals are to the right of the zig-zag line on the Periodic Table plus Hydrogen.
Metals are to the left of the zig-zag line on the Periodic Table.
-ite ending
Change the ending to –ous acid.
Ex: H2SO3
Sulfurous Acid
-ate ending
Change the ending to –ic acid.
Ex: H2SO4
Sulfuric Acid
WRITING COMPOUND FORMULASIONICS ACIDS COVALENTS
1. Write down your two ions with their charge.
2. If you see a roman numeral, it is telling you the positive charge of the metal.
3. Add subscripts in order to cancel out the charge of the ions to zero for the overall compound.
4. If you need a balancing subscript on a polyatomic ion, add parentheses around the polyatomic ion, and place the balancing subscript outside of the parentheses.
1. You will be able to pick out these compounds easily because they include the term ACID!
2. Determine which ion is in the acid based on the name.Hydro-__-ic acid = __-ide ion (nonmetal)__-ic acid = __-ate ion__-ous acid = __-ite ion
3. Balance the charge on the ion using H+1 ions at the front of the compound.
4. Add (aq) to the end of the compound, as all acids are aqueous solutions!
1. You will be able to pick out these compounds easily because they include PREFIXES!
2. Determine if the covalent is organic (one word name with –ane ending) or if it is inorganic (two word name).
3. If organic, determine the carbon # subscript from the prefix, and determine the hydrogen # subscript from presence of “cyclo”
4. If inorganic, determine subscripts from prefixes
HINT: –ATE and –ITE endings = Polyatomic Ions, but –IDE endings = Non-Metals (except OH-1 and CN-1)
POLYATOMIC IONS TO MEMORIZE!YOU MUST MEMORIZE NAME, FORMULA, AND CHARGE!
CATIONSNH4
+ ammonium H3O+ Hydromium
ANIONS -1 -2 -3
HSO4– Bisulfate SO4
2–Sulfate AsO43– Arsenate
HSO3– Bisulfite SO3
2–Sulfite AsO33– Arsenite
HS– Bisulfide S2O32– Thiosulfate
HCO3– Bicarbonate CO3
2– Carbonate
H2PO4– Dihydrogen Phosphate HPO4
2– Monohydrogen Phosphate PO43– Phosphate
PO33– Phosphite
BrO4– Perbromate CrO4
2– ChromateBrO3
– Bromate Cr2O72– Dichromate
BrO2– Bromite C2O4
2– OxalateBrO– Hypobromite O2
2– Peroxide
ClO4– Perchlorate
ClO3– Chlorate
ClO2– Chlorite
ClO– Hypochlorite
CN– Cyanide CNO– CyanateSCN– Thiocyanate Prefixes and suffixes (what they mean)
IO4
– Periodate -ate ‘most common variety’ (T43) IO3
– Iodate -ite one less oxygen atom than “ate” variety (same charge)
IO2– Iodite per- one more oxygen than “ate” variety (same charge)
IO– Hypoiodite hypo- one less oxygen than “ite” variety (same charge)
NO3
– Nitrate -ide only one kind of atom in the anion NO2
– Nitrite thio- one oxygen atom replaced by sulfur (S)
OH– Hydroxide
MnO4– Permanganate bi- one H+ added to divalent anion
C2H3O2– (CH3COO-) Acetate (Ethanoate) di- two H+ added to divalent anion
POLYATOMIC IONS you don’t need to memorize
HC2O4– Hydrogen Oxalate C7H6O2
2– Benzoate Fe(CN)63– Ferricyanide
O2– Superoxide SeO4
2– Selenate Fe(CN)64– Ferrocyanide
HC8H4O4– Hydrogen Phthalate SiO3
2– Silicate
C8H4O42– Phthalate SiF6
2– Hexafluorosilicate SiO44– Orthosilicate
C4H4O62– Tartrate P2O7
4– Pyrophosphate
NOTE: The charge can be shown either before or after the number… both are correct. Also, if a charge is either +1 or –1, you may show just the sign (+ or –). The 1 is not required to be shown.
Solubility of Common Ionic Compounds in Water
SOLUBLE COMPOUNDS (aq) EXCEPTIONS (s)All Group 1 salts None
All ammonium (NH4+1) salts None
All NO3−1, ClO3
−1, ClO4−1, and C2H3O2
−1
saltsNone
All Cl−1, Br−1, I−1 salts Ag+1, Hg2+2 (mercury (I)), Pb+2
All F−1 salts Mg+2 Ca+2, Sr+2, Ba+2, Pb+2
All salts of SO4−2 Ca+2, Sr+2, Ba+2, Pb+2, Ag+1,
Hg2+2
INSOLUBLE COMPOUNDS (s) EXCEPTIONS (aq)All salts of OH−1 Group I, NH4
+1, Ba+2, Sr+2, Ca+2
All other monatomic and polyatomic anions
Group I and NH4+1
Graphing Guidelines – Sketched Graph vs. Constructed Graph
SKETCHED GRAPH CONSTRUCTED GRAPHMake graph using a PENCIL Make graph using a PENCIL on a sheet of GRAPH PAPERInclude a title for the graph that includes a description of the purpose of the graph/experiment
Include a title for the graph that includes a description of the purpose of the graph/experiment
Use as much of given space as possible for your single quadrant
Use as much of the graph paper as possible (at least ¾ of the space) for your single quadrant
X axis = independent variableY axis = dependent variable
X axis = independent variableY axis = dependent variable
X & Y axis drawn free-handed as straight as possible X & Y axis drawn using a RULERX & Y axis labeled, including units X & Y axis labeled, including units No scale needed on X & Y axis Show the scale with marked interval divisions along the X & Y axis, starting
at the origin (0,0) – do not break the axis with a “squiggle”No individual points plotted Plot each individual point - if plotting more than one set of data on the same
graph, use a different color or symbol to distinguish each set of dataDraw a general line or curve to represent the trend of the data
Draw either a trend line (using a ruler) or trend curve that lies as close to the data as possible – do not connect the dotsYou may be asked to extrapolate a graph – this means that you will extend your trend line (using a ruler) with a dashed line beyond your data points until it crosses an axisIf a data point is notable – either because it’s important to the results, or it’s extremely outside the general trend – be sure to notate it
Relationship between Volume and Temperatureusing Charles’ Law
Relationship between Volume and Temperature using Charles’ Law
STUDENT / PARENT ACKNOWLEDGMENT
Student: I have read the above syllabus, listened to the expectations of me as explained in class, and understand them. I will do my best to make a positive contribution to this class and not deprive others from the opportunity of learning or deprive the teacher the opportunity of teaching.
I understand that I can receive help for any homework or assignment I do not understand but I must come see Mrs. Weeks to get that help!
I also understand that labs and activities are part of the course work and it is essential that I behave appropriately at all times.
Student Name (print) ___________________________________________
Student signature ______________________________________________ Date: _____________
Parent/Guardian: I have read Mrs. Weeks’ syllabus and understand what is expected of my student in this class. I understand what is expected of my student during class, labs, and activities. I am also aware of the procedures for my child with make-up labs, assignments and tests and understand the cell phone policy.
Signature: _____________________________________________________ Date: _____________