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Electronic Spectroscopy

Circular Dichroism

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Birefringence

Optical Rotary Dispersion (ORD)

Δn = nleft – nright

𝑅𝑜𝑡𝑎𝑡𝑖𝑜𝑛 = 𝛼= 𝜋𝜆(𝑛𝑙𝑒𝑓𝑡 − 𝑛𝑟𝑖𝑔ℎ𝑡)

𝑆𝑝𝑒𝑐𝑖𝑓𝑖𝑐 𝑅𝑜𝑡𝑎𝑡𝑖𝑜𝑛 = [𝛼] = 100𝛼𝑙𝑐

l = length in dmc = concentration in g/dl

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Circular Dichroism

Δε = εleft – εright

Θ(rad) = ¼ ln 10 Δε

Θ(deg) = 3298.2 Δε

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