Polymery Cvut V1
description
Transcript of Polymery Cvut V1
Polymer processing
Institute of Chemical Technology in Prague
Department of Chemical Engineering
Group of Polymer Reactor Engineering
Michal Vonka
Outline
• Polymerization
• Polymer structure and properties
• Polyethylene terephthalate
• Polymer processing and blow molding
• Injection molding
• Recycling and further usage
• Health risks
• Conclusions and summary
Creation of polymer –polymerization
Monomer + monomer Dimer
Dimer + something
n-times repeated
Dead polymer chain (product?)
Active chain
Loosing of chain activity
reaction
reaction
Reaction mechanism :
n is important
n is virtually EVERYTHINGChain properties:• Length• Branching
Material properties: • Crystallinity • The Chain Length Distribution (CLD)• Gloss• Glass transition temperature• Melting point• Impact resistance• Young modulus
Polymer chains and semi-crystallic structure
semi-cystallic polymer
spherulite
10 µm
lamellae and
amorphous phase
curving and
branching of
lamella
10 nm
Entanglement
Chain Length Distribution
Number of species
Typical chain length distribution
Affected properties :
• Crystallinity • Glass transition temperature• Melting point• Gloss• Impact resistance• Young modulus• Etc…
PET example:particle size: 0.5 - 10 micron (gloss)Young modulus: 2800 – 3100 MPa
100 pm size of carbon atom
PET• Synonym to POLYESTER
• Many forms and industrially produced types (CLD, additives)
• Additives – color, gloss, conductivity, tensile strength,
impact resistance
• Usage: synthetic fibres (60%), beverage, food and other
liquid containers (30%), combination with glass fiber
• Year production 5 000 kt/year
• Price 0.5–1.25 !/kg
• Glass transition temperature ~ 75 °C
• Melting point 250 – 270 °C
Polycondensation of PET:
DimethylphtalateEthanediol
Methanol
Polyethylene terephthalate
Injection molding – PET prefabricate & the lid
Injector (230 – 250 °C)
Mold (5 – 20 MPa)
• Mass production vs. cooling rates of the mold
• More layers
Molten polymer
Mold? Molding?
Blow molding – the bottle
High pressure injectorFurnace
PET prefabricate
in the moving bed
• Mass production (100 000 pc / day)
• Attaching the lid
Recycling
• Sorting the types of polymers
• EXTREME costs vs. ECOLOGY
Two ways:
– Chemical way (decomposing to process intermediates and adding into the fresh production – lowering quality)
– Mechanical way (cleaning and new usage)
Mostly for more-layer PET
Degradation and health risks
• Phthalates– Teratogenes?
• Light degradation
• Thermal oxidationStoichiometric
Non-stoichiometric
Small particles of carbon (2-7 microns)
C
Ketones and aldehydes (irritants, carcinogens)
Summary and conclusions
• Polymer : chains & semi-crystalic structure
• The molding conditions are essential to the final product
• Additives
• Difficult recycling
• Degradation
• Health risks
• Usage
???